Abstract
This work presents a ceramic monolith with a honeycomb structure obtained from a natural zeolite (clinoptilolite), bentonite, and alumina. The monolith obtained by extrusion had a cell density of 57 CPSI (cells per square inch), an open frontal area of 52% w/w, and a wall thickness of 0.9 mm. The raw materials and the natural zeolite ceramic monolith (NZCM) were characterized by X-ray diffraction, N2 adsorption-desorption at 77 K, CO2 adsorption at 273 K, mercury intrusion-extrusion, axial compression tests, resistance to leaching at acidic and basic pH, and point of zero charge. The NZCM presented an SBET = 31 m2∙g-1, a modal micropore size of 0.44 nm, a porosity of 39%, the compressive stress = 14 MPa, and a pHPZC = 7.5. The NZCM was used as an inexpensive and easy-to-handle adsorbent to remove methylene blue (MB) dye in batch studies of kinetics and adsorption isotherms. From modeling of adsorption kinetic data, the predominant phenomenon in this system was physisorption. The modeling of adsorption isotherm data shows that the material has homogeneous active sites. The adsorption occurs by monolayer formation, finding a maximum capacity removal rate of 27 mg MB per gram of NZCM. Compared to other structured materials, a high capacity for removing MB with the ceramic monolith was obtained along with good mechanical properties and resistance in acidic and alkaline environments.
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References
Ahrouch M, Gatica JM, Draoui K, Vidal H (2019) Adding value to natural clays as low-cost adsorbents of methylene blue in polluted water through honeycomb monoliths manufacture. SN Appl Sci 1:1595. https://doi.org/10.1007/s42452-019-1636-4
Akgül M, Karabakan A (2011) Promoted dye adsorption performance over desilicated natural zeolite. Microporous Mesoporous Mater 145(1):157–164. https://doi.org/10.1016/j.micromeso.2011.05.012
Anjaneyulu Y, Sreedhara-Chary N, Suman-Raj S (2005) Decolourization of industrial effluents – available methods and emerging technologies – a review. Rev Environ Sci Technol 4:245–273. https://doi.org/10.1007/s11157-005-1246-z
Ávila P, Montes M, Miró E (2005) Monolithic reactors for environmental applications: a review on preparation Technologies. Chem Eng J 109(1–3):11–36. https://doi.org/10.1016/j.cej.2005.02.025
Baig SA, Sheng T, Hu Y, Lv X, Xu X (2013) Adsorptive removal of arsenic in saturated sand filter containing amended adsorbents. Ecol Eng 60:345–353. https://doi.org/10.1016/j.ecoleng.2013.09.001
Baig SA, Sheng T, Sun C, Xue X, Tan L, Xu X (2014) Arsenic removal from aqueous solutions using Fe3O4-HBC composite: effect of calcination on adsorbents performance. PLoS ONE 9(6):e100704. https://doi.org/10.1371/journal.pone.0100704
Baig SA, Wang Q, Wang Z, Zhu J, Lou Z, Sheng T, Xu X (2014) hexavalent chromium removal from solutions: surface efficacy and characterizations of three iron containing minerals. CLEAN - Soil, Air, Water 42(10):1409–1414. https://doi.org/10.1002/clen.201300805
Bayat M, Sohrabi M, Royaee SJ (2012) Degradation of phenol by heterogeneous Fenton reaction using Fe/clinoptilolite. J Ind Eng Chem 18(3):957–962. https://doi.org/10.1016/j.jiec.2011.09.004
Bello MM, Raman AAA, Asghar A (2020) Activated carbon as carrier in fluidized bed reactor for Fenton oxidation of recalcitrant dye: oxidation-adsorption synergy and surface interaction. Journal of Water Process Engineering 33:101001. https://doi.org/10.1016/j.jwpe.2019.101001
Bulavová P, Parmentier J, Slovák V (2018) Facile synthesis of soft-templated carbon monoliths with hierarchical porosity for fast adsorption from liquid media. Microporous Mesoporous Mater 272:155–165. https://doi.org/10.1016/j.micromeso.2018.06.024
De Souza V, Villarroel-Rocha J, De Araujo M, Sapag K, Pergher S (2018) Basic treatment in natural clinoptilolite for improvement of physicochemical properties. Minerals 8:595. https://doi.org/10.3390/min8120595
Dehmani Y, El Khalki O, Mezougane H, Abouarnadasse S (2021) Comparative study on adsorption of cationic dyes and phenol by natural clays. Chemical Data Collections 33(1–2):100674. https://doi.org/10.1016/j.cdc.2021.100674
Dias AD, Sampaio A, Bezerra RM (2007) Environmental applications of fungal and plant systems: decolourisation of textile wastewater and related dyestuffs. Environmental Bioremediation Technologies: 445-463. https://doi.org/10.1007/978-3-540-34793-4_19
Dos-Santos A, Cervantes F, Van-Lier J (2007) Review paper on current technologies for decolourisation of textile wastewaters: perspectives for anaerobic biotechnology. Bioresour Technol 98:2369–2385. https://doi.org/10.1016/j.biortech.2006.11.013
Dubinin MM (1960) The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chem Rev 60(2):235–241. https://doi.org/10.1021/cr60204a006
Duran-Rivera B, Moreno-Suarez JR, García-Ramírez SI (2018) Decolorization of a textile effluent and methylene blue by three white rot fungi (WRF) at pilot and laboratory scale. Latin American Journal of Biotechnology and Life Sciences 3(4):709–714. https://doi.org/10.21931/RB/2018.03.04.4
Dziedzicka A, Sulikowski B, Ruggiero-Mikołajczyk M (2016) Catalytic and physicochemical properties of modified natural clinoptilolite. Catal Today 259(1):50–58. https://doi.org/10.1016/j.cattod.2015.04.039
El Mouzdahir Y, Elmchaouri A, Mahboub R, Gil A, Korili SA (2010) Equilibrium modeling for the adsorption of methylene blue from aqueous solutions on activated clay minerals. Desalination 250(1):335–338. https://doi.org/10.1016/j.desal.2009.09.052
Elovich SY, Larinov OG (1962) Theory of adsorption from solutions of non-electrolytes on solid adsorbents. Russ Chem Bull 11:198–203. https://doi.org/10.1007/BF00908017
Fan L, Zhou B, Zhang S, Hu S, Mi X, Sun R, Wu Y (2021) Adsorptive removal of low-concentration Cr(VI) in aqueous solution by Mg–Al layered double oxides. Bull Environ Contam Toxicol 106(1):134–145. https://doi.org/10.1007/s00128-020-03053-y
Freundlich HMF (1906) Over the adsorption in solution. J Phys Chem 57:385–470
García-Carvajal C, Villarroel-Rocha J, Curvale D, Barroso MM, Sapag K (2019) Arsenic (V) removal from aqueous solutions using natural clay ceramic monoliths. Chem Eng Commun 206(11):1440–1451. https://doi.org/10.1080/00986445.2018.1564910
García-Carvajal C (2019b) Síntesis y caracterización de materiales cerámicos conformados mediante la técnica de extrusión y peletización. Master’s Thesis. National University of San Luis, San Luis, Argentina
Gatica JM, Gómez DM, Harti S, Vidal H (2013) Clay honeycomb monoliths for water purification: Modulating methylene blue adsorption through controlled activation via natural coal templating. Appl Surf Sci 277:242–248. https://doi.org/10.1016/j.apsusc.2013.04.034
Gemici BT, Ozel HU, Ozel HB (2021) Removal of methylene blue onto forest wastes: adsorption isotherms, kinetics and thermodynamic analysis. Environ Technol Innov 22:101501. https://doi.org/10.1016/j.eti.2021.101501
Gonçalves IMC, Gomes A, Brás R, Ferra MIA, Amorim MTP, Porter RS (2000) Biological treatment of effluent containing textile dyes. Color Technol 116(12):393–397. https://doi.org/10.1111/j.1478-4408.2000.tb00016.x
Haji A, Naebe M (2020) Cleaner dyeing of textiles using plasma treatment and natural dyes: a review. J Clean Prod 265:121866. https://doi.org/10.1016/j.jclepro.2020.121866
Hamanaka T (2003) Extruded cordierite honeycomb ceramics for environmental applications. Handbook of Advanced Ceramics 2:367–384. https://doi.org/10.1016/B978-012654640-8/50040-7
Han R, Wang Y, Zou W, Wang Y, Shi J (2007) Comparison of linear and non-linear analysis in estimating the Thomas model parameters for methylene blue adsorption onto natural zeolite in fixed-bed column. J Hazard Mater 145:331–335. https://doi.org/10.1016/j.jhazmat.2006.12.027
Ho YS, McKay G (1998) A comparison of chemisorptions kinetic models applied to pollutant removal on various sorbents. Process Saf Environ Prot 76(4):332–340. https://doi.org/10.1205/095758298529696
Hor KY, Cheng JM, Chong MN, Jin B, Saint C, Poh PE, Aryal R (2016) Evaluation of physicochemical methods in enhancing the adsorption performance of natural zeolite as low-cost adsorbent of methylene blue dye from wastewater. J Clean Prod 118:197–209. https://doi.org/10.1016/j.jclepro.2016.01.056
Horváth G, Kawazoe K (1983) Method for the calculation of effective pore size distribution in molecular sieve carbon. J Chem Eng Jpn 16(6):470–475. https://doi.org/10.1252/jcej.16.470
Hosseini S, Moghaddas H, Soltani SM, Kheawhom S (2020) Technological applications of honeycomb monoliths in environmental processes: a review. Process Saf Environ Prot 133:286–300. https://doi.org/10.1016/j.psep.2019.11.020
Ioannou Z, Karasavvidis C, Dimirkou A, Antoniadis V (2013) Adsorption of methylene blue and methyl red dyes from aqueous solutions onto modified zeolites. Water Sci Technol 67(5):1129–1136. https://doi.org/10.2166/wst.2013.672
Jiangsu Yixing Nonmetallic Chemical Machinery Factory Co., Ltd. (2021). Ceramic honeycomb monolithic catalyst support. Available in http://ceramicsubstrate.wholesale.infospaceinc.com/pz583d5a5-ceramic-honeycomb-monolithic-catalyst-support.html
Katheresan V, Kansedo J, Lau SY (2018) Efficiency of various recent wastewater dye removal methods: a review. J Environ Chem Eng 6:4676–4697. https://doi.org/10.1016/j.jece.2018.06.060
Kul TO, Ören AH (2018). Hydration of geosynthetic clay liners (GCLs) on compacted zeolite. Geosynthetics International 1–11. https://doi.org/10.1680/jgein.18.00038
Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1368
Largitte L, Pasquier R (2016) A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon. Chem Eng Res Des 109:495–504. https://doi.org/10.1016/j.cherd.2016.02.006
Lu J, Ayele BA, Liu X, Chen Q (2020). Electrocatalytic activities of engineered carbonaceous cathodes for generation of hydrogen peroxide and oxidation of recalcitrant reactive dye. Journal of Electroanalytical Chemistry, 114579. https://doi.org/10.1016/j.jelechem.2020.11457
Minamoto C, Fujiwara N, Shigekawa Y, Tada K, Yano J, Yokoyama T, Minamoto Y, Nakayama S (2021) Effect of acidic conditions on decomposition of methylene blue in aqueous solution by air microbubbles. Chemosphere 263:128141. https://doi.org/10.1016/j.chemosphere.2020.128141
Motsa MM, Mamba BB, Thwala JM, Msagati TAM (2011) Preparation, characterization, and application of polypropylene–clinoptilolite composites for the selective adsorption of lead from aqueous media. J Colloid Interface Sci 359(1):210–219. https://doi.org/10.1016/j.jcis.2011.02.067
Mustafa S, Dilara B, Nargis K, Naeem A, Shahida P (2002) Surface properties of the mixed oxides of iron and silica. Colloids Surf, A 205(3):273–282. https://doi.org/10.1016/s0927-7757(02)00025-0
Novais RM, Ascensão G, Tobaldi DM, Seabra MP, Labrincha JA (2018) Biomass fly ash geopolymer monoliths for effective methylene blue removal from wastewaters. J Clean Prod 171:783–794. https://doi.org/10.1016/j.jclepro.2017.10.078
O’Connor D, Hou D, Ok YS, Song Y, Sarmah AK, Li X, Tack FMG (2018) Sustainable in situ remediation of recalcitrant organic pollutants in groundwater with controlled release materials: a review. J Control Release 283:200–213. https://doi.org/10.1016/j.jconrel.2018.06.007
Pinzón ML, Vera LE (2009). Modeling of Cr (III) bioadsorption kinetics using orange peel. Dyna, 76 (160): 95-106. ISSN: 0012-7353. (in Spanish) https://www.redalyc.org/articulo.oa?id=49612068033
Qiao Z, Sun R, Wu Y, Hu S, Liu X, Chan J (2020). Microbial Heterotrophic Nitrification-Aerobic Denitrification Dominates Simultaneous Removal of Aniline and Ammonium in Aquatic Ecosystems. Water, Air, & Soil Pollution, 231(3). https://doi.org/10.1007/s11270-020-04476-3
Qiu M, Qian C, Xu J, Wu J, Wang G (2009) Studies on the adsorption of dyes into clinoptilolite. Desalination 243(1–3):286–292. https://doi.org/10.1016/j.desal.2008.04.029
Radoor S, Karayil J, Jayakumar A, Parameswaranpillai J, Siengchin S (2021) Removal of Methylene Blue Dye from Aqueous Solution using PDADMAC Modified ZSM-5 Zeolite as a Novel Adsorbent. J Polym Environ 29(10):3185–3198. https://doi.org/10.1007/s10924-021-02111-8
Rafatullah M, Sulaiman O, Hashim R, Ahmad A (2010) Adsorption of methylene blue on low-cost adsorbents: a review. J Hazard Mater 177(1–3):70–80. https://doi.org/10.1016/j.jhazmat.2009.12.047
Rida K, Bouraoui S, Hadnine S (2013) Adsorption of methylene blue from aqueous solution by kaolin and zeolite. Appl Clay Sci 83–84:99–105. https://doi.org/10.1016/j.clay.2013.08.015
Rożek P, Król M, Mozgawa W (2020) Lightweight geopolymer-expanded glass composites for removal of methylene blue from aqueous solutions. Ceram Int 46(12):19785–19791. https://doi.org/10.1016/j.ceramint.2020.05.011
Rushdi Y, El-Eswed B, Al-Muhtaseb AH (2011) Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions: kinetics, mechanism, and thermodynamics studies. Chem Eng J 171(3):1143–1149. https://doi.org/10.1016/j.cej.2011.05.012
Saad MEK, Mnasri N, Mhamdi M, Chafik T, Elaloui E, Moussaoui Y (2015) Removal of methylene blue onto mineral matrices. Desalin Water Treat 56(10):2773–2780. https://doi.org/10.1080/19443994.2015.1012338
Salazar-Rabago JJ, Leyva-Ramos R, Rivera-Utrilla J, Ocampo-Perez R, Cerino-Cordova FJ (2017) Biosorption mechanism of methylene blue from aqueous solution onto white pine (Pinus durangensis) sawdust: effect of operating conditions. Sustainable Environment Research 27(1):32–40. https://doi.org/10.1016/j.serj.2016.11.009
Santoso E, Ediati R, Kusumawati Y, Bahruji H, Sulistiono DO, Prasetyoko D (2020) Review on recent advances of carbon based adsorbent for methylene blue removal from waste water. Mater. Today Chem. 16:100233. https://doi.org/10.1016/j.mtchem.2019.100233
Sarma GK, Sengupta S, Bhattacharyya KG (2011) Methylene blue adsorption on natural and modified clays. Sep Sci Technol 46(10):1602–1614. https://doi.org/10.1080/01496395.2011.565012
Shaban M, Abukhadra MR, Shahien MG, Ibrahim SS (2018) Novel bentonite/zeolite-NaP composite efficiently removes methylene blue and Congo red dyes. Environ Chem Lett 16(1):275–280. https://doi.org/10.1007/s10311-017-0658-7
Shackelford JF, Doremus RH (2008) Ceramic and glass materials: structure, properties and, processing. Springer Science & Business Media, USA
Technistro®. (2021). Ceramic Honeycomb. Available in https://www.techinstro.com/ceramic-honeycomb/
Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KSW (2015) Physisorption of gases with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry 87:9–10. https://doi.org/10.1515/pac-2014-1117
Ultracore Inc. (2021). UQF-314-3/8-3.0 astroquartz/cyanate ester. Available in http://ultracorinc.com/products/quartz
Wang S, Zhu ZH, Coomes A, Haghseresht F, Lu GQ (2005) The physical and surface chemical characteristics of activated carbons and the adsorption of methylene blue from wastewater. J Colloid Interface Sci 284(2):440–446. https://doi.org/10.1016/j.jcis.2004.10.050
Weber WJ Jr, Morris JC (1963) Kinetics of adsorption on carbon from solution. J Sanit Eng Div Am Soc Civ Eng 89:31–60
Whang TJ, Huang HY, Hsieh MT, Chen JJ (2009) Laser-induced silver nanoparticles on titanium oxide for photocatalytic degradation of methylene blue. Int J Mol Sci 10(11):4707–4718. https://doi.org/10.3390/ijms10114707
WHO (2019). Press communication: 1-in-3-people-globally-do-not-have-access-to-safe-drinking-water, UNICEF & WHO: https://www.who.int/es/news-room/detail/18-06-2019-1-in-3-people-globally-do-not-have-access-to-safe-drinking-water-%E2%80%93-unicef-who.
Yagub MT, Sen TK, Afroze S, Ang HM (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Colloid Interface Sci 209:172–184. https://doi.org/10.1016/j.cis.2014.04.002
Yaseen DA, Scholz M (2019) Textile dye wastewater characteristics and constituents of synthetic effluents: a critical review. Int J Environ Sci Technol 16:1193–1226. https://doi.org/10.1007/s13762-018-2130-z
Yukselen-Aksoy Y (2010) Characterization of two natural zeolites for geotechnical and geoenvironmental applications. Appl Clay Sci 50(1):130–136. https://doi.org/10.1016/j.clay.2010.07.015
Zhang Z, Xu L, Liu Y, Feng R, Zou T, Zhang Y, Kang Y, Zhou P (2021) Efficient removal of methylene blue using the mesoporous activated carbon obtained from mangosteen peel wastes: kinetic, equilibrium, and thermodynamic studies. Microporous Mesoporous Mater 315:110904. https://doi.org/10.1016/j.micromeso.2021.110904
Zhou Y, Lu J, Zhou Y, Liu Y (2019) Recent advances for dyes removal using novel adsorbents: a review. Environ Pollut 252:352–365. https://doi.org/10.1016/j.envpol.2019.05.072
Acknowledgments
A special thanks to Dra. Maria Martha Barroso Quiroga (INTEQUI, CONICET-UNSL) for the XRD analysis, membranes, and biomaterials laboratory (UNSL) for providing the equipment for mechanical tests of the NZCM and to Dr. José Arroyo Gómez for his assistance in proofreading the manuscript.
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This work was financially supported by UNSL and CONICET (Argentina).
CONICET,CONICET-Doctoral scholarship,Universidad Nacional de San Luis
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CG-C: conceptualization, investigation, formal analysis, data curation, visualization, writing—original draft. JV-R: conceptualization, methodology, investigation, formal analysis, writing—review and editing. VCdS: conceptualization, investigation, methodology, data analysis. KS: conceptualization, methodology, resources, supervision, project administration, funding acquisition, writing—review and editing. All authors read and approved the final manuscript.
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García-Carvajal, C., Villarroel-Rocha, J., de Souza, V.C. et al. Development of ceramic honeycomb monolith from natural zeolite tested as adsorbent to remove methylene blue in aqueous media. Environ Sci Pollut Res 29, 79890–79902 (2022). https://doi.org/10.1007/s11356-022-18569-5
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DOI: https://doi.org/10.1007/s11356-022-18569-5