Skip to main content
Log in

Evaluating salinity variation and origin in coastal aquifer systems with integrated geophysical and hydrochemical approaches

  • Research Article
  • Published:
Environmental Science and Pollution Research Aims and scope Submit manuscript

Abstract

Public concerns have been dramatically increased over potential saltwater intrusion resulting in freshwater resources shortage in coastal aquifers in the past decades. Investigating the distribution and origin of saline water is a key factor to understand coastal groundwater evolution and further assist its management. Here we evaluate the horizontal and vertical spatial variability of the coastal groundwater salinity and its potential key influencing factors based on integrated hydrochemical and geoelectrical approaches in the Pearl River Estuary (PRE), South China. The electrical resistivity tomography and geochemical data show a decrease of salinity from the coast to the inland with a water type varying from Cl–Na to HCO3–Ca at the regional scale. Points with higher/lower salinity values than those in the surrounding environment occasionally exist in the study region. In the cross section, the zone 2–90 m below the surface has low resistivity values, which correspond to high-salinity values in the subsurface. The moderate resistivity values at 0–2 m depth illustrate an infiltration of freshwater. The complex salinity distribution pattern is mainly controlled by the heterogeneity of formation and distribution of primary flow paths, while the coastal groundwater salinity evolution is shaped by the joint influence of paleo-seawater intrusion, the ion mixing processes, and the water–rock interaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

Data availability

All data generated or analyzed during this study are included in this published article.

References

  • Adepelumi AA, Ako BD, Ajayi TR, Afolabi O, Omotoso EJ (2009) Delineation of saltwater intrusion into the freshwater aquifer of Lekki Peninsula, Lagos. Nigeria Environmental Geology 56(5):927–933

    Article  CAS  Google Scholar 

  • Alabjah B, Amraoui F, Chibout M, Slimani M (2018) Assessment of saltwater contamination extent in the coastal aquifers of Chaouia (Morocco) using the electric recognition. J Hydrol 566:363–376

    Article  Google Scholar 

  • Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. Balkema, Rotterdam, Netherlands

    Google Scholar 

  • Argamasilla M, Barberá JA, Andreo B (2017) Factors controlling groundwater salinization and hydrogeochemical processes in coastal aquifers from southern Spain. Sci Total Environ 580:50–68

    Article  CAS  Google Scholar 

  • Banks D, Frengstad B (2006) Evolution of groundwater chemical composition by plagioclase hydrolysis in Norwegian anorthosites. Geochim Cosmochim Acta 70(6):1337–1355

    Article  CAS  Google Scholar 

  • Barlow PM, Reichard EG (2010) Saltwater intrusion in coastal regions of North America. Hydrogeol J 18(1):247–260

    Article  CAS  Google Scholar 

  • Berthold, S., Bentley, L. R., & Hayashi, M. (2004). Integrated hydrogeological and geophysical study of depression‐focused groundwater recharge in the Canadian prairies. Water Resources Research, 40(6).

  • Boluda-Botella N, Gomis-Yagües V, Ruiz-Beviá F (2008) Influence of transport parameters and chemical properties of the sediment in experiments to measure reactive transport in seawater intrusion. J Hydrol 357(1–2):29–41

    Article  Google Scholar 

  • Carter ES, White SM, Wilson AM (2008) Variation in groundwater salinity in a tidal salt marsh basin, North Inlet Estuary, South Carolina. Estuar Coast Shelf Sci 76(3):543–552

    Article  Google Scholar 

  • Cheung KC, Poon BHT, Lan CY, Wong MH (2003) Assessment of metal and nutrient concentrations in river water and sediment collected from the cities in the Pearl River Delta. South China Chemosphere 52(9):1431–1440

    Article  CAS  Google Scholar 

  • Cong P, Wang R, Li G (2006) Ground resistivity technique measurement for ice jam early warning at freeze-up period of the Yellow River. Adv Water Sci 17(6):877–880

    Google Scholar 

  • Dale RK, Miller DC (2007) Spatial and temporal patterns of salinity and temperature at an intertidal groundwater seep. Estuar Coast Shelf Sci 72(1–2):283–298

    Article  Google Scholar 

  • De Franco, R., Biella, G., Tosi, L., Teatini, P., Lozej, A., Chiozzotto, B., ... & Bassan, V. (2009). Monitoring the saltwater intrusion by time lapse electrical resistivity tomography: the Chioggia test site (Venice Lagoon, Italy). Journal of Applied Geophysics, 69(3-4), 117-130.

  • Delsman, J. R., Van Baaren, E. S., Siemon, B., Dabekaussen, W., Karaoulis, M. C., Pauw, P. S., ... & Dubelaar, C. W. (2018). Large-scale, probabilistic salinity mapping using airborne electromagnetics for groundwater management in Zeeland, the Netherlands. Environmental Research Letters, 13(8), 084011.

  • El Yaouti F, El Mandour A, Khattach D, Benavente J, Kaufmann O (2009) Salinization processes in the unconfined aquifer of Bou-Areg (NE Morocco): a geostatistical, geochemical, and tomographic study. Appl Geochem 24(1):16–31

    Article  CAS  Google Scholar 

  • Fadili A, Mehdi K, Riss J, Najib S, Makan A, Boutayab K (2015) Evaluation of groundwater mineralization processes and seawater intrusion extension in the coastal aquifer of Oualidia, Morocco: hydrochemical and geophysical approach. Arab J Geosci 8(10):8567–8582

    Article  CAS  Google Scholar 

  • Fadili A, Najib S, Mehdi K, Riss J, Malaurent P, Makan A (2017) Geoelectrical and hydrochemical study for the assessment of seawater intrusion evolution in coastal aquifers of Oualidia, Morocco. J Appl Geophys 146:178–187

    Article  Google Scholar 

  • Faye S, Maloszewski P, Stichler W, Trimborn P, Faye SC, Gaye CB (2005) Groundwater salinization in the Saloum (Senegal) delta aquifer: minor elements and isotopic indicators. Sci Total Environ 343(1–3):243–259

    Article  CAS  Google Scholar 

  • Fetter CW (2001) Applied hydrogeology. Prentice-Hall, Upper Saddle River, N.J.

    Google Scholar 

  • Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170(3962):1088–1090

    Article  CAS  Google Scholar 

  • Giménez-Forcada E (2010) Dynamic of sea water interface using Hydrochemical Facies Evolution Diagram. Groundwater 48(2):212–216

    Article  CAS  Google Scholar 

  • Giménez-Forcada E (2014) Space/time development of seawater intrusion: a study case in Vinaroz coastal plain (Eastern Spain) using HFE-Diagram, and spatial distribution of hydrochemical facies. J Hydrol 517:617–627

    Article  CAS  Google Scholar 

  • Goebel M, Pidlisecky A, Knight R (2017) Resistivity imaging reveals complex pattern of saltwater intrusion along Monterey coast. J Hydrol 551:746–755

    Article  Google Scholar 

  • Han D, Kohfahl C, Song X, Xiao G, Yang J (2011) Geochemical and isotopic evidence for palaeo-seawater intrusion into the south coast aquifer of Laizhou Bay. China Applied Geochemistry 26(5):863–883

    Article  CAS  Google Scholar 

  • He Y, Lin K, Chen X, Ye C, Cheng L (2015) Classification-based spatiotemporal variations of pan evaporation across the Guangdong Province. South China Water Resources Management 29(3):901–912

    Article  Google Scholar 

  • He Y, Chen S, Huang R, Chen X, Cong P (2019) Impact of upstream runoff and tidal level on the chlorinity of an estuary in a river network: a case study of Modaomen Estuary in the Pearl River Delta. China Journal of Hydroinformatics 21(2):359–370

    Article  Google Scholar 

  • Hermans T, Vandenbohede A, Lebbe L, Martin R, Kemna A, Beaujean J, Nguyen F (2012) Imaging artificial salt water infiltration using electrical resistivity tomography constrained by geostatistical data. J Hydrol 438:168–180

    Article  CAS  Google Scholar 

  • Huang G, Sun J, Zhang Y, Chen Z, Liu F (2013) Impact of anthropogenic and natural processes on the evolution of groundwater chemistry in a rapidly urbanized coastal area, South China. Sci Total Environ 463:209–221

    Article  CAS  Google Scholar 

  • Huang G, Liu C, Sun J, Zhang M, Jing J, Li L (2018) A regional scale investigation on factors controlling the groundwater chemistry of various aquifers in a rapidly urbanized area: a case study of the Pearl River Delta. Sci Total Environ 625:510–518

    Article  CAS  Google Scholar 

  • Jiao JJ, Wang Y, Cherry JA, Wang XS, Zhi BF, HY, Du, Wen, D.G. (2010) Abnormally high ammonium of natural origin in a coastal aquifer-aquitard system in the Pearl River Delta. China Environ Sci Technol 44(19):7470–7475

    Article  CAS  Google Scholar 

  • Kazakis N, Pavlou A, Vargemezis G, Voudouris KS, Soulios G, Pliakas F, Tsokas G (2016) Seawater intrusion mapping using electrical resistivity tomography and hydrochemical data. An application in the coastal area of eastern Thermaikos Gulf. Greece Science of the Total Environment 543:373–387

    Article  CAS  Google Scholar 

  • Kim JH, Kim KH, Thao NT, Batsaikhan B, Yun ST (2017) Hydrochemical assessment of freshening saline groundwater using multiple end-members mixing modeling: a study of Red River delta aquifer. Vietnam Journal of Hydrology 549:703–714

    Article  CAS  Google Scholar 

  • King J, Oude Essink G, Karaolis M, Siemon B, Bierkens MF (2018) Quantifying geophysical inversion uncertainty using airborne frequency domain electromagnetic data—applied at the province of Zeeland, the Netherlands. Water Resour Res 54(10):8420–8441

    Article  Google Scholar 

  • Klassen J, Allen DM (2017) Assessing the risk of saltwater intrusion in coastal aquifers. J Hydrol 551:730–745

    Article  Google Scholar 

  • Koohbor B, Fahs M, Ataie-Ashtiani B, Belfort B, Simmons CT, Younes A (2019) Uncertainty analysis for seawater intrusion in fractured coastal aquifers: effects of fracture location, aperture, density and hydrodynamic parameters. J Hydrol 571:159–177

    Article  Google Scholar 

  • Kouzana, L., & Benassi, R. (2010). Geophysical and hydrochemical study of the seawater intrusion in Mediterranean semi arid zones. Case of the Korba coastal aquifer (Cap-Bon, Tunisia). Journal of African Earth Sciences, 58(2), 242–254.

  • Larsen F, Tran LV, Van Hoang H, Tran LT, Christiansen AV, Pham NQ (2017) Groundwater salinity influenced by Holocene seawater trapped in incised valleys in the Red River delta plain. Nat Geosci 10(5):376

    Article  CAS  Google Scholar 

  • Liu D, Chen X, Lou Z (2010) A model for the optimal allocation of water resources in a saltwater intrusion area: a case study in Pearl River Delta in China. Water Resour Manage 24(1):63

    Article  Google Scholar 

  • Liu D, Guo S, Shao Q, Jiang Y, Chen X (2014) Optimal allocation of water quantity and waste load in the northwest Pearl River Delta, China. Stoch Env Res Risk Assess 28(6):1525–1542

    Article  Google Scholar 

  • Liu S, Tang Z, Gao M, Hou G (2017) Evolutionary process of saline-water intrusion in Holocene and Late Pleistocene groundwater in southern Laizhou Bay. Sci Total Environ 607:586–599

    Article  CAS  Google Scholar 

  • Liu B, Peng S, Liao Y, Long W (2018) The causes and impacts of water resources crises in the Pearl River Delta. J Clean Prod 177:413–425

    Article  Google Scholar 

  • Liu B, Peng S, Liao Y, Wang H (2019) The characteristics and causes of increasingly severe saltwater intrusion in Pearl River Estuary. Estuar Coast Shelf Sci 220:54–63

    Article  Google Scholar 

  • Loke MH, Acworth I, Dahlin T (2003) A comparison of smooth and blocky inversion methods in 2D electrical imaging surveys. Explor Geophys 34(3):182–187

    Article  Google Scholar 

  • Martínez-Moreno FJ, Monteiro-Santos FA, Bernardo I, Farzamian M, Nascimento C, Fernandes J, Casal B, Ribeiro JA (2017) Identifying seawater intrusion in coastal areas by means of 1D and quasi-2D joint inversion of TDEM and VES data. J Hydrol 552:609–619

    Article  Google Scholar 

  • McInnis, D., Silliman, S., Boukari, M., Yalo, N., Orou-Pete, S., Fertenbaugh, C., ... & Fayomi, H. (2013). Combined application of electrical resistivity and shallow groundwater sampling to assess salinity in a shallow coastal aquifer in Benin, West Africa. Journal of hydrology, 505, 335-345.

  • Najib S, Fadili A, Mehdi K, Riss J, Makan A (2017) Contribution of hydrochemical and geoelectrical approaches to investigate salinization process and seawater intrusion in the coastal aquifers of Chaouia, Morocco. J Contam Hydrol 198:24–36

    Article  CAS  Google Scholar 

  • Nowroozi AA, Stephen BH, Henderson P (1999) Saltwater intrusion into the freshwater aquifer in the eastern shore of Virginia: a reconnaissance electrical resistivity survey. J Appl Geophys 42:1–22

    Article  Google Scholar 

  • Parizi E, Hosseini SM, Ataie-Ashtiani B, Simmons CT (2019) Vulnerability mapping of coastal aquifers to seawater intrusion: review, development and application. J Hydrol 570:555–573

    Article  Google Scholar 

  • Patra H P, Nath SK (1999) Schlumberger geoelectric sounding in ground water (principles, interpretation and applications). A A Balkema Publisher, Rotterdam

  • Qin R, Wu Y, Xu Z, Xie D, Zhang C (2013) Assessing the impact of natural and anthropogenic activities on groundwater quality in coastal alluvial aquifers of the lower Liaohe River Plain, NE China. Appl Geochem 31:142–158

  • Reddy AGS (2013) Evaluation of hydrogeochemical characteristics of phreatic alluvial aquifers in southeastern coastal belt of Prakasam district. South India Environmental Earth Sciences 68(2):471–485

    Article  CAS  Google Scholar 

  • Salem ZE, Al Temamy AM, Salah MK, Kassab M (2016) Origin and characteristics of brackish groundwater in Abu Madi coastal area, northern Nile Delta. Egypt Estuarine, Coastal and Shelf Sicence 178(5):21–35

    Article  CAS  Google Scholar 

  • Small, C., & Nicholls, R. J. (2003). A global analysis of human settlement in coastal zones. Journal of coastal research, 584–599.

  • Sun Z, Chen J, Xie Q, Long A (2011) Status quo of seawater intrusion in western coastal area of Pearl River Estuary: survey and diagnosis. Environmental Science & Technology (china) 34(8):81–84

    Google Scholar 

  • Tully, K., Gedan, K., Epanchin-Niell, R., Strong, A., Bernhardt, E. S., BenDor, T., ... & Weston, N. B. (2019). The invisible flood: the chemistry, ecology, and social implications of coastal saltwater intrusion. Bio Science, 69(5), 368-378.

  • Van Dam JC, Meulenkamp JJ (1967) Some results of the geo-electrical resistivity method in ground water investigations in the Netherlands. Geophys Prospect 15(1):92–115

    Article  Google Scholar 

  • Wang Y, Jiao JJ (2012) Origin of groundwater salinity and hydrogeochemical processes in the confined Quaternary aquifer of the Pearl River Delta, China. J Hydrol 438:112–124

    Article  CAS  Google Scholar 

  • Wang Y, Jiao JJ, Cherry JA (2012) Occurrence and geochemical behavior of arsenic in a coastal aquifer–aquitard system of the Pearl River Delta, China. Sci Total Environ 427:286–297

    Article  CAS  Google Scholar 

  • Wang Y, Jiao JJ, Cherry JA, Lee CM (2013) Contribution of the aquitard to the regional groundwater hydrochemistry of the underlying confined aquifer in the Pearl River Delta, China. Sci Total Environ 461:663–671

    Article  CAS  Google Scholar 

  • Wang, P., Shen, L., Chen, X., Wang, Z., Liang, X., Hu, B. X., ... & Zhai, X. (2019). Response of soil water hydrochemistry and δ13CDIC to changes in spatio-temporal variations under different land covers in SW China karst catchment. Hydrology Research, 50(3), 925-944.

  • Werner AD, Bakker M, Post VEA, Vandenbohede A, Lu C, Ataie-Ashtiani B, Simmons CT, Barry DA (2013) Seawater intrusion processes, investigation and management: recent advances and future challenges. Adv Water Resour 51:3–26

    Article  Google Scholar 

  • Yi L, Ma B, Liu L, Tang G, Wang T (2016) Simulation of groundwater-seawater interaction in the coastal surficial aquifer in Bohai Bay, Tianjin, China. Estuar Coast Shelf Sci 177(5):20–30

    Article  Google Scholar 

  • Zarroca M, Bach J, Linares R, Pellicer XM (2011) Electrical methods (VES and ERT) for identifying, mapping and monitoring different saline domains in a coastal plain region (Alt Empordà, Northern Spain). J Hydrol 409(1–2):407–422

    Article  CAS  Google Scholar 

  • Zhang XY, Miao J, Hu BX, Liu H, Zhang H, Ma Z (2017) Hydrogeochemical characterization and groundwater quality assessment in intruded coastal brine aquifers. Environ. Sci. Pollut. Res. 24(26):21073–21090

    Article  CAS  Google Scholar 

  • Zhang XY, Hu BX, Wang P, Chen J, Yang L, Xiao K, Zhang X (2018) Hydrogeochemical evolution and heavy metal contamination in groundwater of a reclaimed land on Zhoushan Island. Water 10(3):316

    Article  CAS  Google Scholar 

  • Zhang J, Zhang XY, Niu J, Hu BX, Soltanian MR, Han Q, Yang L (2019) Prediction of groundwater level in seashore reclaimed land using wavelet and artificial neural network-based hybrid model. J. Hydrol. 577:123948

    Article  Google Scholar 

  • Zhang X, Dong F, Dai H, Hu BX, Qin G, Li D, Lv X, Dai Z, Soltanian MR (2020) Influence of lunar semidiurnal tides on groundwater dynamics in estuarine aquifers. Hydrogeol J 28:1419–1429

  • Zong Y, Yim WWS, Yu F, Huang G (2009) Late Quaternary environmental changes in the Pearl River mouth region. China Quat Int 206:35–45

    Article  Google Scholar 

Download references

Funding

This research was supported by the Water Resource Science and Technology Innovation Program of Guangdong Province (2017–26), National Natural Science Foundation of China (51709127, 41702244, 41972249), and Natural Science Foundation of Guangdong Province, China (Grant No. 2017A030310172).

Author information

Authors and Affiliations

Authors

Contributions

PW wrote the manuscript with support from XZ. XZ conceived of the presented idea and developed the proof outline. PW analyzed the experiment data and presented the figures and tables. DL carried out the field investigation and worked out the data analysis. YH designed and performed the experiments. All authors discussed the results and contributed to the final manuscript.

Corresponding author

Correspondence to Xiaoying Zhang.

Ethics declarations

Ethics approval and consent to participate

Not applicable.

Consent for publication

Not applicable.

Conflict of interest

The authors declare no competing interests.

Additional information

Responsible Editor: Xianliang Yi

Publisher's note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Appendix

Appendix

Table 3 Physicochemical characteristics of groundwater samples in monitoring wells

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, P., Zhang, X., Hao, Y. et al. Evaluating salinity variation and origin in coastal aquifer systems with integrated geophysical and hydrochemical approaches. Environ Sci Pollut Res 29, 34038–34054 (2022). https://doi.org/10.1007/s11356-021-18277-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11356-021-18277-6

Keywords

Navigation