Abstract
This paper aims to investigate the role of water in the reduction of diesel exhaust emissions. To do so, a multi-zone thermodynamic model coupled to a novel semi-detailed ionic chemical kinetics mechanism is used. This mechanism includes 467 reactions and 105 species containing 51 ionic reactions and 15 ions. The mechanism contains 6 basic ionic reactions, 23 NOx-related ionic reactions, and 22 soot-related ionic reactions. Four different amounts of water are added to the in-cylinder mixture and the effects of water in the formation of soot and NOx are investigated. The results showed that water does not have a regular effect on diesel exhaust soot, but causes a significant reduction in exhaust NOx. Water has decreased the temperature of the combustion chamber and consequently has reduced the ionic current inside the combustion chamber. Reduction of the in-cylinder ion current decreases the mass of NOx-related ions and results in reduced exhaust NOx. Adding 5% water reduces the in-cylinder ion current by 47%. Five percent water also reduces engine exhaust NOx to 33%. Among NOx-related ions, water has the greatest effect on N+ ions and reduces its amount to less than 20%. Water affects the progress rate of ionic reactions, and 5% of water reduces the progress rate of the fastest reaction to 14% of its initial value.
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The datasets used and analyzed during the current study are available from the corresponding author on reasonable request.
Abbreviations
- CAD :
-
crank angle degree
- c v :
-
specific heat constant at constant volume (J/kg K)
- C D :
-
discharge coefficient
- D :
-
cylinder diameter (m)
- d n :
-
nozzle hole diameter (m)
- H :
-
enthalpy (J/kg)
- m :
-
mass (kg)
- MW :
-
molecular weight
- n :
-
number of zones
- n n :
-
number of nozzle holes
- n s :
-
number of species
- P :
-
pressure (Pa)
- Q :
-
heat (J)
- R u :
-
universal ideal gas constant (J/mol K)
- T :
-
temperature (K)
- t :
-
time (s)
- U :
-
internal energy (J)
- u :
-
specific internal energy (J/kg)
- V :
-
volume (m3)
- W :
-
work (J)d
- z :
-
distance between zone center and injector (m)
- Y :
-
mass fraction
- ρ:
-
density (kg/m3)
- \( \dot{\omega} \) :
-
molar rate of production (mole/m3s)
- f:
-
fuel
- i:
-
ith zone
- j:
-
jth species
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Mohammadi, M., Neshat, E. Numerical investigation on the effect of water in the reduction of diesel engine exhaust emissions using a novel ionic chemical kinetics mechanism. Environ Sci Pollut Res 28, 33461–33479 (2021). https://doi.org/10.1007/s11356-021-12904-y
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DOI: https://doi.org/10.1007/s11356-021-12904-y