Abstract
Among the prevalent methods already in existence for the plastic waste management, catalytic pyrolysis has been proved to be an efficient one. The research work involved the synthesis of the catalyst from eucalyptus seeds, a commercially available agricultural waste product aided in pyrolysis. The raw eucalyptus seeds were cleaned, powdered, and surface-modified using sulphuric acid. Analysis of the surface-reformed eucalyptus seeds showed that they possess the characteristics equivalent to the activated carbon and micropores similar to that of zeolite which is used as a catalyst for pyrolysis. Hence, the prepared catalyst was used in the pyrolysis process and its performance was compared with that of the commercial activated carbon and zeolite. Zeolite Y generally lowers the temperature of the pyrolysis reaction to 180–190 °C, while the produced catalyst made the pyrolysis reaction possible between 120 and 130 °C. The output of the pyrolysis reaction was a hydrocarbon oil, which was analysed using gas chromatography-flame ionization detector (GC-FID). The oil was found to have a composition between C6 and C20, which includes petroleum, kerosene, and diesel. Hence, the oil obtained was proven to be more useful, as a fuel for locomotive and reheating purposes.
Similar content being viewed by others
Data Availability
All data generated or analysed during this study are included in this published article.
References
Abdelkhalik A, Elsayed H, Hassan MA, Nour M, Shehata AB, Helmy M (2018) Using thermal analysis techniques for identifying the flash point temperatures of some lubricant and base oils. Egypt J Pet 27:131–136. https://doi.org/10.1016/j.ejpe.2017.02.006
Al-Salem SM, Antelava A, Constantinou A, Manos G, Dutta A (2017) A review on thermal and catalytic pyrolysis of plastic solid waste (PSW). J Environ Manag 197:177–198. https://doi.org/10.1016/j.jenvman.2017.03.084
Areeprasert C, Asingsamanunt J, Srisawat S, Kaharn J, Inseemeesak B, Phasee P, Khaobang C, Siwakosit W, Chiemchaisri C (2017) Municipal plastic waste composition study at transfer station of Bangkok and possibility of its energy recovery by pyrolysis. Energy Procedia 107:222–226. https://doi.org/10.1016/j.egypro.2016.12
Breyer S, Mekhitarian L, Rimez B, Haut B (2017) Production of an alternative fuel by the co-pyrolysis of landfill recovered plastic wastes and used lubrication oils. Waste Manag 60:363–374. https://doi.org/10.1016/j.wasman.2016.12.011
Bungay VC (2017) Kinetic study on the pyrolysis and gasification of plastic waste. Chem Eng Trans 56:193–198. https://doi.org/10.3303/CET1756033
Charitopoulou MA, Kalogiannis KG, Lappas AA, Achilias DS (2020) Novel trends in the thermo-chemical recycling of plastics from WEEE containing brominated flame retardants. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-020-09932-5
Czajczynska D, Nannou T, Anguilano L, Krzyzynska R, Ghazal H, Spencer N, Jouhara H (2017) Potentials of pyrolysis processes in the waste management sector. Energy Procedia 123:387–394. https://doi.org/10.1016/j.egypro.2017.07.275
Ding K, He A, Zhong D, Fan L, Liu S, Wang Y, Chen P, Lei H, Ruan R (2018) Improving hydrocarbon yield via catalytic fast co-pyrolysis of biomass and plastic over ceria and HZSM-5: an analytical pyrolyzer analysis. Bioresour Technol 268:1–8. https://doi.org/10.1016/j.biortech.2018.07.108
Fekhar B, Miskolczi N, Bhaskar T, Kumar J, Dhyani V (2018) Co-pyrolysis of biomass and plastic wastes: investigation of apparent kinetic parameters and stability of pyrolysis oils. IOP Conf Series: Earth Environ Sci 154:12022. https://doi.org/10.1088/1755-1315/154/1/012022
Fivga A, Dimitriou I (2018) Pyrolysis of plastic waste for production of heavy fuel substitute: a techno-economic assessment. Energy 149:865–874. https://doi.org/10.1016/j.energy.2018.02.094
Gandidi IM, Susila MD, Mustofa A, Pambudi NA (2018) Thermal–catalytic cracking of real MSW into bio-crude oil. J Energy Inst 91:304–310. https://doi.org/10.1016/j.joei.2016.11.005
Grima-Olmedo C, Ramirex-Gomez A, Lomez-Lmon D, Clemente-Jul C (2016) Activated carbon from flash pyrolysis of eucalyptus residue. Heliyon 2:e00155. https://doi.org/10.1016/j.heliyon.2016.e00155
Huo E, Lei H, Liu C, Zhang Y, Xin L, Zhao Y, Qian M, Zhang Q, Lin X, Wang C, Mateo W, Villota EM, Ruan R (2020) Jet fuel and hydrogen produced from waste plastics catalytic pyrolysis with activated carbon and MgO. Sci Total Environ 727:138411. https://doi.org/10.1016/j.scitotenv.2020.138411
Kalargaris I, Tian G, Gu S (2017) Influence of advanced injection timing and fuel additive on combustion, performance, and emission characteristics of a DI diesel engine running on plastic pyrolysis oil. J Combust 3126342:1–9. https://doi.org/10.1155/2017/3126342
Kiruba UP, Kumar PS, Prabhakaran C, Aditya V (2014) Characteristics of thermodynamic, isotherm, kinetic, mechanism and design equations for the analysis of adsorption in Cd(II) ions-surface modified Eucalyptus seeds system. J Taiwan Inst Chem Eng 45:297–2968. https://doi.org/10.1016/j.jtice.2014.08.016
Kumar PS, Bharathikumar M, Prabhakaran C, Vijayan S, Ramakrishnan K (2017) Conversion of waste plastics into low-emissive hydrocarbon fuels through catalytic de-polymerization in a new laboratory scale batch reactor. Int J Energy Environ Eng 8:167–173. https://doi.org/10.1007/s40095-015-0167-z
Kunwar B, Cheng HN, Chandrashekaran SR, Sharma BK (2016) Plastics to fuel: a review. Renew Sust Energ Rev 54:421–428. https://doi.org/10.1016/j.rser.2015.10.015
Lin X, Zhang Z, Zhang Z, Sun J, Wang Q, Pittman CU (2018) Catalytic fast pyrolysis of a wood-plastic composite with metal oxides as catalysts. Waste Manag 79:38–47. https://doi.org/10.1016/j.wasman.2018.07.021
Mangesh VL, Padmanabhan S, Ganesan S, Prabhudev Rahul D, Dinesh Kumar Reddy T (2017) Prospects of pyrolysis oil from plastic waste as fuel for diesel engines: a review. IOP Conf Ser: Mater Sci Eng 197:012027. https://doi.org/10.1088/1757-899X/197/1/012027
Miandad R, Barakat MA, Aburiazaiza AS, Rehan M, Nizami AS (2017) Effect of plastic waste types on pyrolysis liquid oil. Int Biodeterior Biodegradation 119:239–252. https://doi.org/10.1016/j.ibiod.2016.09.017
Nespeca MG, Munhoz JFVL, Flumignan DL, de Oliveira JE (2017) Rapid and sensitive method for detecting adulterants in gasoline using ultrafast gas chromatography and partial least square discriminant analysis. Fuel 215:204–211. https://doi.org/10.1016/j.fuel.2017.11.032
Nizami AS, Rehan M, Waqas M, Naqvi M, Ouda OKM, Shahzad K, Miandad R, Khan MZ, Syamsiro M, Ismoil IMI, Pant D (2017) Waste biorefineries: enabling circular economies in developing countries. Bioresour Technol 241:1101–1117. https://doi.org/10.1016/j.biortech.2017.05.097
Ojha DK, Shukla S, Sachin RS, Vinu R (2016) Understanding the interactions between cellulose and polypropylene during fast co-pyrolysis via experiments and DFT calculations. Chem Eng Trans 50:67–72. https://doi.org/10.3303/CET1650012
Patnaik S, Kumar S, Panda AK (2020) Thermal degradation of eco-friendly alternative plastics: kinetics and thermodynamics analysis. Environ Sci Pollut Res 27:14991–15000. https://doi.org/10.1007/s11356-020-07919-w
Ranadhir G, Shashank P, Sreenivasa Rao A (2016) Extraction of fuel from waste plastics and performance analysis in a CI Engine. Int J Sci Eng Res 7:67–72
Rehan M, Miandad R, Barakat MA, Ismail IMI, Almeelbi T, Gardy J, Hassanpour A, Khan MZ, Demirbas A, Nizami AS (2016) Effect of zeolite catalysts on pyrolysis liquid oil. Int Biodeterior Biodegrad 119:162–175. https://doi.org/10.1016/j.ibiod.2016.11.015
Rex P, Miranda LR (2020) Catalytic activity of acid-treated biomass for the degradation of expanded polystyrene waste. Environ Sci Pollut Res 27:438–455. https://doi.org/10.1007/s11356-019-07034-5
Ryu HW, Tsang YF, Lee HW, Jae J, Jung S-C, Lam SS, Park ED, Park Y-K (2019) Catalytic co-pyrolysis of cellulose and linear low-density polyethylene over MgO impregnated catalysts with different acid-base properties. Chem Eng J 373:375–381. https://doi.org/10.1016/j.cej.2019.05.049
Santaweesuk C, Janyalertadun A (2017) The production of fuel oil by conventional slow pyrolysis using plastic waste from a municipal landfill. Int J Environ Sci Dev 8:168–173. https://doi.org/10.18178/ijesd.2017.8.3.941
Sarathy SM, Farooq A, Kalghatgi GT (2017) Recent progress in gasoline surrogate fuels. Prog Energy Combust Sci 65:67–108. https://doi.org/10.1016/j.pecs.2017.09.004
Sharuddin SDA, Abnisa F, Wan MAWD, Aroua MK (2016) A review on pyrolysis of plastic wastes. Energy Convers Manag 115:308–326. https://doi.org/10.1016/j.enconman.2016.02.037
Sharuddin SDA, Abnisa F, Daud WMAW, Aroua MK (2018) Pyrolysis of plastic waste for liquid fuel production as prospective energy resource. IOP Conf Series: Mater Sci Eng 334:012001. https://doi.org/10.1088/1757-899X/334/1/012001
Varfolomeev MA, Abaidullina DI, Gainutdinova AZ, Solomonov BN (2010) FTIR study of H-bonds cooperativity in complexes of 1,2-dihydroxybenzene with proton acceptors in aprotic solvents: Influence of the intramolecular hydrogen bond. Spectrochim Acta A Mol Biomol Spectrosc 77:965–972. https://doi.org/10.1016/j.saa.2010.08.032
Xue Y, Bai X (2018) Synergistic enhancement of product quality through fast co pyrolysis of acid pretreated biomass and waste plastic. Energy Convers Manag 164:629–638. https://doi.org/10.1016/j.enconman.2018.03.036
Yang Z, Lei H, Zhang Y, Qian K, Villota E, Qian M, Yadavalli G, Hua S (2018) Production of renewable alkyl-phenols from catalytic pyrolysis of Douglas fir sawdust over biomass-derived activated carbons. Appl Energy 220:426–436. https://doi.org/10.1016/j.apenergy.2018.03.107
Zhang X, Lei H, Yadavalli G, Lei Z, Yi W, Liu Y (2015) Gasoline-range hydrocarbons produced from microwave-induced pyrolysis of low-density polyethylene over ZSM- 5. Fuel 144:33–42. https://doi.org/10.1016/j.fuel.2014.12.013
Zhang Y, Duan D, Lei H, Villota E, Ruan R (2019) Jet fuel production from waste plastics via catalytic pyrolysis with activated carbons. Appl Energy 251:113337. https://doi.org/10.1016/j.apenergy.2019.113337
Acknowledgements
Authors would like thank Sri Sivasubramaniya Nadar College of Engineering, Chennai, India, for providing the research facilities to carry out this work in time.
Author information
Authors and Affiliations
Contributions
NJ and KK investigated the conversion of waste plastics into liquid fuels and the manuscript was written by them. PSK and SJ analysed and interpreted the experimental results and supervised the work. All authors read and approved the final manuscript.
Corresponding authors
Ethics declarations
Competing interests
The authors declare that they have no competing interests
Ethics approval and consent to participate
It is not applicable to this manuscript.
Consent for publication
It is not applicable to this manuscript.
Additional information
Responsible Editor: Ta Yeong Wu
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Jahnavi, N., Kanmani, K., Kumar, P.S. et al. Conversion of waste plastics into low emissive hydrocarbon fuel using catalyst produced from biowaste. Environ Sci Pollut Res 28, 63638–63645 (2021). https://doi.org/10.1007/s11356-020-11398-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-020-11398-4