A critical review on recent developments in MOF adsorbents for the elimination of toxic heavy metals from aqueous solutions

Rani, Lata; Kaushal, Jyotsna; Srivastav, Arun Lal; Mahajan, Pooja

doi:10.1007/s11356-020-10738-8

Review Article
Published: 25 September 2020

A critical review on recent developments in MOF adsorbents for the elimination of toxic heavy metals from aqueous solutions

Lata Rani^1,2,
Jyotsna Kaushal ORCID: orcid.org/0000-0002-0241-5627¹,
Arun Lal Srivastav³ &
Pooja Mahajan¹

Environmental Science and Pollution Research volume 27, pages 44771–44796 (2020)Cite this article

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Abstract

Effective and substantial remediation of contaminants especially heavy metals from water is still a big challenge in terms of both environmental and biological perspectives because of their adverse effects on the human health. Many techniques including adsorption, ion exchange, co-precipitation, chemical reduction, ultrafiltration, etc. are reported for eliminating heavy metal ions from the water. However, adsorption has preferred because of its simple and easy handlings. Several types of adsorbents are observed and documented well for the purpose. Recently, highly porous metal-organic frameworks (MOFs) were developed by incorporating metals and organic ligands together and claimed as potent adsorbents for the remediation of highly toxic heavy metals from the aqueous solutions due to their unique features like greater surface area, high chemical stability, green and reuse material, etc. In this review, the authors discussed systematically some recent developments about secure MOFs to eliminate the toxic metals such as arsenic (both arsenite and arsenate), chromium(VI), cadmium (Cd), mercury (Hg) and lead (Pb). MOFs are observed as the most efficient adsorbents with greater selectivity as well as high adsorption capacity for metallic contamination.

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Centre for Water Sciences, Chitkara University Institute of Engineering and Technology, Chitkara University, Rajpura, Punjab, India
Lata Rani, Jyotsna Kaushal & Pooja Mahajan
Chitkara University School of Basic Sciences, Chitkara University, Baddi, Himachal Pradesh, India
Lata Rani
Chitkara University School of Engineering and Technology, Chitkara University, Baddi, Himachal Pradesh, India
Arun Lal Srivastav

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Lata Rani
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Jyotsna Kaushal
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LR, literature review and drafting of the manuscript; JK, critical review, expert opinion and supervision; PM, graphical design and expert opinion; and ALS, conceptualization and supervision of manuscript. All authors contributed to the research article and approved the final version.

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Rani, L., Kaushal, J., Srivastav, A.L. et al. A critical review on recent developments in MOF adsorbents for the elimination of toxic heavy metals from aqueous solutions. Environ Sci Pollut Res 27, 44771–44796 (2020). https://doi.org/10.1007/s11356-020-10738-8

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Received: 22 May 2020
Accepted: 06 September 2020
Published: 25 September 2020
Issue Date: December 2020
DOI: https://doi.org/10.1007/s11356-020-10738-8

Keywords

MOFs
Ligands
Adsorption
Water contaminants
Heavy metals