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Study on the influencing factors of removal of NOX from cement kiln flue gas by sewage sludge as a denitration agent

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Abstract

Experimental study on the influencing factors of using sewage sludge as a denitration agent for cement industry was carried out on a self-made laboratory-scale fluid-bed reactor. Results indicate that sludge combustion at 900 °C shows an ideal NOX (the sum of NO and NO2) removal activity under simulated working conditions of cement precalciner. The optimal removal efficiency of NOX can reach 70.36 ± 3.59% in the presence of cement raw meal (CRM) at a sludge particle size range of 0.18–0.25 mm and the sludge dosage of 0.75 g/min. Besides, the NOX removal efficiency increases to 76.94 ± 5.02% in the absence of CRM, indicating that cement raw meal inhibits the NOX removal. This phenomenon may be attributed to the fact that CRM has promotion effect on NH3 produced and obvious inhibitory effect on CO produced; while NH3 and CO play a leading role in NOX reduction, the combined effect leads to the decrease of NOX removal. Moreover, the relationship between the composition of CRM on the inhibition of NOX removal is MgO < CaCO3 < CRM < Al2O3 <Fe2O3. Meanwhile, the effect of additive variety on the sludge denitration activity indicates that urea significantly promotes the NOX removal, which is attributed to the decomposition of urea to form NH3. The stability experiment shows that sludge denitration efficiency remains stable above 70% in the presence of CRM and can reach over 80% when adding appropriate urea. This method can realize the removal of NOX in the cement kiln flue gas and the resource utilization of sludge. It is a promising method for sludge disposal.

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Funding

This work was supported by the National Natural Science Foundation of China (NSFC-51778264), the Youth Top-notch Talent Special Support Program of Guangdong Province (2016TQ03Z576), the Project of Science and Technology Program of Guangdong Province (2017B020237002 and 2018B020208002), and Outstanding Young Scientific and Technological Talent Support Program of South China Institute of Environmental Sciences.

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Authors and Affiliations

  1. South China Institute of Environmental Sciences, the Ministry of Ecology and Environment, Guangzhou, 510655, Guangdong, China

    Xiang Xiao, Jun Luo, Zhenghui Xu, Haiwen Wu, Jianhang Huang & Ping Fang

  2. Guangdong Province Engineering Laboratory for Air Pollution Control, Guangzhou, 510655, Guangdong, China

    Xiang Xiao, Jun Luo, Zhenghui Xu, Haiwen Wu, Jianhang Huang & Ping Fang

  3. Yellow River Engineering Consulting Co., Ltd, Zhengzhou, 450003, Henan, China

    Haizhen Huang

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  1. Xiang Xiao
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  2. Jun Luo
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  3. Haizhen Huang
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  4. Zhenghui Xu
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  5. Haiwen Wu
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  6. Jianhang Huang
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  7. Ping Fang
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Correspondence to Ping Fang.

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Xiao, X., Luo, J., Huang, H. et al. Study on the influencing factors of removal of NOX from cement kiln flue gas by sewage sludge as a denitration agent. Environ Sci Pollut Res 27, 41342–41349 (2020). https://doi.org/10.1007/s11356-020-10126-2

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