Abstract
Carbon nano-onions (CNOs) are fascinating zero-dimensional carbon materials owning distinct multi-shell architecture. Their physicochemical properties are highly related to the parent material selected and the synthesis protocol involved. In the present work, we report for the first time novel CNO structures encompassing discrete carbon allotropes, namely, H18 carbon, Rh6 carbon, and n-diamond. These structures were cost-effectively synthesized in gram scale by facile flame pyrolysis of paraffinum liquidum, a highly refined mineral oil. The as-synthesized and chemically refashioned CNOs are quasi-spherical self-assembled mesopores, manifesting remarkable stability and hydrophilicity. The CNO structures exhibit excellent dye adsorption characteristics with high removal capacity of 1397.35 mg/g and rapid adsorption kinetics with a minimal adsorbent dosage of 10 mg/L, for a low concentration of 20 mg/L methylene blue dye. The novel CNOs assure potential implementation in the remediation of low concentration and high volume of dye-contaminated wastewater.
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Acknowledgments
The authors are thankful to the Center for Research, CHRIST (Deemed to be University), Bengaluru, for providing necessary facilities for the successful completion of this work. AVR is thankful to the DST-INSPIRE Fellowship Grant (DST/INSPIRE/03/2015/004970). We also acknowledge the IISc, Bengaluru; IUCNN; M G University, Kottayam; and SAIF, CUSAT, Cochin, for the help and facilities provided for the characterization of the samples.
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This work is a part of a patent application filed with the Indian Patent Office.
Details: A. V. Ramya and Manoj. B, CHRIST (Deemed to be University).
Indian Patent Ref. No. E-12/2691/2019/CHE and App. Number 201941052829, published on 27 December 2019.
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Venkatesan, R.A., Balachandran, M. Novel carbon nano-onions from paraffinum liquidum for rapid and efficient removal of industrial dye from wastewater. Environ Sci Pollut Res 27, 43845–43864 (2020). https://doi.org/10.1007/s11356-020-09981-w
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DOI: https://doi.org/10.1007/s11356-020-09981-w