Abstract
The demand for green engineering environmentally friendly nanomaterials had made carbon nanotube a suitable material to keep metal–organic frameworks (MOFs) in the application of wastewater treatment and air pollution monitoring systems. This review summarizes many of the recent research accomplishments in the synthesis of MOFs and MOFs-carbon hybrid nanocomposites for various applications such as wastewater treatment and removal of hazardous gases (CO, SO2, H2S and NH3) with emphasis on MOF/CNTs composites. This review focuses on the efficient removal of pollutants from the environment using adsorption techniques. Another important application of MOFs composite discussed in this review is sensor materials for environmental pollution.
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Abdi J, Vossoughi M, Mahmoodi NM, Alemzadeh I (2017) Synthesis of metal-organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal. Chem Eng J 326:1145–1158
Ahmed DS, Haider AJ, Mohammad M (2013) Comparesion of functionalization of multi-walled carbon nanotubes treated by oil olive and nitric acid and their characterization. Energy Procedia 36:1111–1118
Ahsan MA, Jabbari V, Islam MT, Turley RS, Dominguez N, Kim H, Castro E, Hernandez-Viezcas JA, Curry ML, Lopez J, Gardea-Torresdey JL, Noveron JC (2019) Sustainable synthesis and remarkable adsorption capacity of MOF/graphene oxide and MOF/CNT based hybrid nanocomposites for the removal of Bisphenol A from water. Sci Total Environ 673:306–317
Ahsan MA, Jabbari V, Imam MA, Castro E, Kim H, Curry ML et al (2020) Nanoscale nickel metal organic framework decorated over graphene oxide and carbon nanotubes for water remediation. Sci Total Environ 698:134214
Anjum M, Miandad R, Waqas M, Gehany F, Barakat M (2016) Remediation of wastewater using various nano-materials. Arab J Chem
Azad FN, Ghaedi M, Dashtian K, Hajati S, Pezeshkpour V (2016) Ultrasonically assisted hydrothermal synthesis of activated carbon–HKUST-1-MOF hybrid for efficient simultaneous ultrasound-assisted removal of ternary organic dyes and antibacterial investigation: Taguchi optimization. Ultrason Sonochem 31:383–393
Bakshi SR, Lahiri D, Agarwal A (2010) Carbon nanotube reinforced metal matrix composites-a review. Int Mater Rev 55(1):41–64
Bandosz TJ (2006) Activated carbon surfaces in environmental remediation. Elsevier
Ben-Mansour R, Qasem NA, Habib MA (2018) Adsorption characterization and CO 2 breakthrough of MWCNT/Mg-MOF-74 and MWCNT/MIL-100 (Fe) composites. Int J Energy Environ Eng 9(2):169–185
Bloch ED, Hudson MR, Mason JA, Chavan S, Crocellà V, Howe JD et al (2014) Reversible CO binding enables tunable CO/H2 and CO/N2 separations in metal–organic frameworks with exposed divalent metal cations. J Am Chem Soc 136(30):10752–10761
Britt D, Tranchemontagne D, Yaghi OM (2008) Metal-organic frameworks with high capacity and selectivity for harmful gases. Proc Natl Acad Sci 105(33):11623–11627
Bruce N, Perez-Padilla R, Albalak R (2000) Indoor air pollution in developing countries: a major environmental and public health challenge. Bull World Health Organ 78:1078–1092
Burtch NC, Jasuja H, Walton KS (2014) Water stability and adsorption in metal–organic frameworks. Chem Rev 114(20):10575–10612
Cai Z, Sun Y, Liu W, Pan F, Sun P, Fu J (2017) An overview of nanomaterials applied for removing dyes from wastewater. Environ Sci Pollut Res 24(19):15882–15904
Campagnol N, Van Assche T, Boudewijns T, Denayer J, Binnemans K, De Vos D et al (2013) High pressure, high temperature electrochemical synthesis of metal–organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies. J Mater Chem A 1(19):5827–5830
Chappanda KN, Shekhah O, Yassine O, Patole SP, Eddaoudi M, Salama KN (2018) The quest for highly sensitive QCM humidity sensors: the coating of CNT/MOF composite sensing films as case study. Sensors Actuators B Chem 257:609–619
Chen X, Lukaszczuk P, Tripisciano C, Rümmeli MH, Srenscek-Nazzal J, Pelech I et al (2010) Enhancement of the structure stability of MOF-5 confined to multiwalled carbon nanotubes. Phys Status Solidi B 247(11–12):2664–2668
Cheong VF, Moh PY (2018) Recent advancement in metal–organic framework: synthesis, activation, functionalisation, and bulk production. Mater Sci Technol 34(9):1025–1045
Chowdhury T, Zhang L, Zhang J, Aggarwal S (2018) Removal of arsenic (III) from aqueous solution using metal organic framework-graphene oxide nanocomposite. Nanomaterials. 8(12):1062
Cook TR, Zheng Y-R, Stang PJ (2012) Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal–organic materials. Chem Rev 113(1):734–777
Cortés-Súarez J, Celis-Arias V, Beltrán HI, Tejeda-Cruz A, Ibarra IA, Romero-Ibarra JE, Sánchez-González E, Loera-Serna S (2019) Synthesis and characterization of an SWCNT@ HKUST-1 composite: enhancing the CO2 adsorption properties of HKUST-1. ACS Omega 4(3):5275–5282
da Silva CG, Faria JL (2003) Photochemical and photocatalytic degradation of an azo dye in aqueous solution by UV irradiation. J Photochem Photobiol A Chem 155(1–3):133–143
Dąbrowski A (2001) Adsorption—from theory to practice. Adv Colloid Interf Sci 93(1–3):135–224
Dai Y, Li M, Liu F, Xue M, Wang Y, Zhao C (2019) Graphene oxide wrapped copper-benzene-1, 3, 5-tricarboxylate metal organic framework as efficient absorbent for gaseous toluene under ambient conditions. Environ Sci Pollut Res 26(3):2477–2491
Das AK, Vemuri RS, Kutnyakov I, McGrail BP, Motkuri RK (2016) An efficient synthesis strategy for metal-organic frameworks: dry-gel synthesis of MOF-74 framework with high yield and improved performance. Sci Rep 6:28050
Deng S, Upadhyayula VK, Smith GB, Mitchell MC (2008) Adsorption equilibrium and kinetics of microorganisms on single-wall carbon nanotubes. IEEE Sensors J 8(6):954–962
Dias EM, Petit C (2015) Towards the use of metal–organic frameworks for water reuse: a review of the recent advances in the field of organic pollutants removal and degradation and the next steps in the field. J Mater Chem A 3(45):22484–22506
Ebrahim AM, Jagiello J, Bandosz TJ (2015) Enhanced reactive adsorption of H 2 S on cu–BTC/S-and N-doped GO composites. J Mater Chem A 3(15):8194–8204
Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O'keeffe M et al (2002) Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science. 295(5554):469–472
Ersan G, Kaya Y, Apul OG, Karanfil T (2016) Adsorption of organic contaminants by graphene nanosheets, carbon nanotubes and granular activated carbons under natural organic matter preloading conditions. Sci Total Environ 565:811–817
Faustini M, Kim J, Jeong G-Y, Kim JY, Moon HR, Ahn W-S et al (2013) Microfluidic approach toward continuous and ultrafast synthesis of metal–organic framework crystals and hetero structures in confined microdroplets. J Am Chem Soc 135(39):14619–14626
Feng S, Li X, Zhao S, Hu Y, Zhong Z, Xing W et al (2018) Multifunctional metal organic framework and carbon nanotube-modified filter for combined ultrafine dust capture and SO 2 dynamic adsorption. Environ Sci Nano 5(12):3023–3031
Férey G (2008) Hybrid porous solids: past, present, future. Chem Soc Rev 37(1):191–214
Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM (2013) The chemistry and applications of metal-organic frameworks. Science. 341(6149):1230444
Garcia-Perez E, Serra-Crespo P, Hamad S, Kapteijn F, Gascon J (2014) Molecular simulation of gas adsorption and diffusion in a breathing MOF using a rigid force field. Phys Chem Chem Phys 16(30):16060–16066
Gautam RK, Chattopadhyaya MC (2016) Advanced nanomaterials for wastewater remediation. CRC press
Gu Y, Wang Y, Li H, Qin W, Zhang H, Wang G et al (2020) Fabrication of hierarchically porous NH2-MIL-53/wood-carbon hybrid membrane for highly effective and selective sequestration of Pb2+. Chem Eng J 124141
Guan W-J, Zheng X-Y, Chung KF, Zhong N-S (2016) Impact of air pollution on the burden of chronic respiratory diseases in China: time for urgent action. Lancet 388(10054):1939–1951
Gupta VK, Agarwal S, Saleh TA (2011) Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. J Hazard Mater 185(1):17–23
Hadi P, Yeung KY, Barford J, An KJ, McKay G (2015) Significance of microporosity on the interaction of phenol with porous graphitic carbon. Chem Eng J 269:20–26
Han T, Xiao Y, Tong M, Huang H, Liu D, Wang L et al (2015) Synthesis of CNT@ MIL-68 (Al) composites with improved adsorption capacity for phenol in aqueous solution. Chem Eng J 275:134–141
Hasan Z, Jhung SH (2015) Removal of hazardous organics from water using metal-organic frameworks (MOFs): plausible mechanisms for selective adsorptions. J Hazard Mater 283:329–339
Howarth AJ, Peters AW, Vermeulen NA, Wang TC, Hupp JT, Farha OK (2016) Best practices for the synthesis, activation, and characterization of metal–organic frameworks. Chem Mater 29(1):26–39
Hwang YK, Hong DY, Chang JS, Jhung SH, Seo YK, Kim J et al (2008) Amine grafting on coordinatively unsaturated metal centers of MOFs: consequences for catalysis and metal encapsulation. Angew Chem 120(22):4212–4216
Jabbari V, Veleta J, Zarei-Chaleshtori M, Gardea-Torresdey J, Villagrán D (2016) Green synthesis of magnetic MOF@ GO and MOF@ CNT hybrid nanocomposites with high adsorption capacity towards organic pollutants. Chem Eng J 304:774–783
Ji W-J, Zhai Q-G, Li S-N, Jiang Y-C, Hu M-C (2011) The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant. Chem Commun 47(13):3834–3836
Jiang H, Feng Y, Chen M, Wang Y (2013) Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity. Int J Hydrog Energy 38(25):10950–10955
Jung D-W, Yang D-A, Kim J, Kim J, Ahn W-S (2010) Facile synthesis of MOF-177 by a sonochemical method using 1-methyl-2-pyrrolidinone as a solvent. Dalton Trans 39(11):2883–2887
Kang IJ, Khan NA, Haque E, Jhung SH (2011) Chemical and thermal stability of isotypic metal–organic frameworks: effect of metal ions. Chem Eur J 17(23):6437–6442
Kemp KC, Seema H, Saleh M, Le NH, Mahesh K, Chandra V et al (2013) Environmental applications using graphene composites: water remediation and gas adsorption. Nanoscale. 5(8):3149–3171
Khan NA, Hasan Z, Jhung SH (2013) Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review. J Hazard Mater 244:444–456
Khan A, Wang J, Li J, Wang X, Chen Z, Alsaedi A, Hayat T, Chen Y, Wang X (2017) The role of graphene oxide and graphene oxide-based nanomaterials in the removal of pharmaceuticals from aqueous media: a review. Environ Sci Pollut Res 24(9):7938–7958
Khlifi R, Olmedo P, Gil F, Feki-Tounsi M, Chakroun A, Rebai A et al (2013) Blood nickel and chromium levels in association with smoking and occupational exposure among head and neck cancer patients in Tunisia. Environ Sci Pollut Res 20(11):8282–8294
Klinowski J, Paz FAA, Silva P, Rocha J (2011) Microwave-assisted synthesis of metal–organic frameworks. Dalton Trans 40(2):321–330
Ko FW, Hui DS (2012) Air pollution and chronic obstructive pulmonary disease. Respirology. 17(3):395–401
Kosuru L, Bouchaala A, Jaber N, Younis MI (2016) Humidity detection using metal organic framework coated on QCM. Journal of Sensors;2016
Kumar V, Kumar S, Kim K-H, Tsang DC, Lee S-S (2018) Metal organic frameworks as potent treatment media for odorants and volatiles. Environ Res
Kusin FM, Akhir NIM, Mohamat-Yusuff F, Awang M (2017) Greenhouse gas emissions during plantation stage of palm oil-based biofuel production addressing different land conversion scenarios in Malaysia. Environ Sci Pollut Res 24(6):5293–5304
Li J-R, Kuppler RJ, Zhou H-C (2009) Selective gas adsorption and separation in metal–organic frameworks. Chem Soc Rev 38(5):1477–1504
Li S, Chen Y, Pei X, Zhang S, Feng X, Zhou J et al (2016) Water purification: adsorption over metal-organic frameworks. Chin J Chem 34(2):175–185
Li H, Wang K, Sun Y, Lollar CT, Li J, Zhou H-C (2017) Recent advances in gas storage and separation using metal–organic frameworks. Mater Today
Liang W, D'Alessandro DM (2013) Microwave-assisted solvothermal synthesis of zirconium oxide based metal–organic frameworks. Chem Commun 49(35):3706–3708
Lin K-YA, Yang H, Hsu F-K (2018) Zr-metal organic framework and derivatives for adsorptive and photocatalytic removal of acid dyes. Water Environ Res 90(2):144–154
Liu X, Wang M, Zhang S, Pan B (2013) Application potential of carbon nanotubes in water treatment: a review. J Environ Sci 25(7):1263–1280
Liu X-W, Sun T-J, Hu J-L, Wang S-D (2016) Composites of metal–organic frameworks and carbon-based materials: preparations, functionalities and applications. J Mater Chem A 4(10):3584–3616
Lu M, Li L, Shen S, Chen D, Han W (2019) Highly efficient removal of Pb 2+ by a sandwich structure of metal–organic framework/GO composite with enhanced stability. New J Chem 43(2):1032–1037
Luo S, Wang J (2018) MOF/graphene oxide composite as an efficient adsorbent for the removal of organic dyes from aqueous solution. Environ Sci Pollut Res 25(6):5521–5528
Mahmoodi NM, Oveisi M, Taghizadeh A, Taghizadeh M (2019) Novel magnetic amine functionalized carbon nanotube/metal-organic framework nanocomposites: from green ultrasound-assisted synthesis to detailed selective pollutant removal modelling from binary systems. J Hazard Mater 368:746–759
Mao J, Ge M, Huang J, Lai Y, Lin C, Zhang K et al (2017) Constructing multifunctional MOF@ rGO hydro-/aerogels by the self-assembly process for customized water remediation. J Mater Chem A 5(23):11873–11881
Marteel AE, Davies JA, Olson WW, Abraham MA (2003) Green chemistry and engineering: drivers, metrics, and reduction to practice. Annu Rev Environ Resour 28(1):401–428
McHugh LN, Terracina A, Wheatley PS, Buscarino G, Smith MW, Morris RE (2019) Metal–organic framework-activated carbon composite materials for the removal of Ammonia from contaminated airstreams. Angew Chem Int Ed 58(34):11747–11751
Oveisi M, Asli MA, Mahmoodi NM (2019) Carbon nanotube based metal-organic framework nanocomposites: synthesis and their photocatalytic activity for decolorization of colored wastewater. Inorg Chim Acta 487:169–176
Perreault F, De Faria AF, Elimelech M (2015) Environmental applications of graphene-based nanomaterials. Chem Soc Rev 44(16):5861–5896
Petit C, Bandosz TJ (2009) MOF–graphite oxide composites: combining the uniqueness of graphene layers and metal–organic frameworks. Adv Mater 21(46):4753–4757
Petit C, Bandosz TJ (2010) Enhanced adsorption of ammonia on metal-organic framework/graphite oxide composites: analysis of surface interactions. Adv Funct Mater 20(1):111–118
Pi Y, Li X, Xia Q, Wu J, Li Z, Li Y et al (2017) Formation of willow leaf-like structures composed of NH 2-MIL68 (in) on a multifunctional multiwalled carbon nanotube backbone for enhanced photocatalytic reduction of Cr (VI). Nano Res 10(10):3543–3556
Pokhrel J, Bhoria N, Wu C, Reddy KSK, Margetis H, Anastasiou S et al (2018) Cu-and Zr-based metal organic frameworks and their composites with graphene oxide for capture of acid gases at ambient temperature. J Solid State Chem 266:233–243
Prasanth K, Rallapalli P, Raj MC, Bajaj H, Jasra RV (2011) Enhanced hydrogen sorption in single walled carbon nanotube incorporated MIL-101 composite metal–organic framework. Int J Hydrog Energy 36(13):7594–7601
Qadir NU, Said SA, Mansour RB, Mezghani K, Ul-Hamid A (2016) Synthesis, characterization, and water adsorption properties of a novel multi-walled carbon nanotube/MIL-100 (Fe) composite. Dalton Trans 45(39):15621–15633
Rada ZH, Abid HR, Sun H, Shang J, Li J, He Y et al (2018) Effects of-NO2 and-NH2 functional groups in mixed-linker Zr-based MOFs on gas adsorption of CO2 and CH4. Progress in Natural Science: Materials International 28(2):160–167
Reed DA, Xiao DJ, Gonzalez MI, Darago LE, Herm ZR, Grandjean F, Long JR (2016) Reversible CO scavenging via adsorbate-dependent spin state transitions in an iron (II)–triazolate metal–organic framework. J Am Chem Soc 138(17):5594–5602
Rehfuess E, Organization WH (2006) Fuel for life: household energy and health
Rehman A, Farrukh S, Hussain A, Fan X, Pervaiz E (2019) Adsorption of CO 2 on amine-functionalized green metal-organic framework: an interaction between amine and CO 2 molecules. Environ Sci Pollut Res:1–12
Ricco R, Styles MJ, Falcaro P (2019) MOF-based devices for detection and removal of environmental pollutants. Metal-Organic Frameworks (MOFs) for Environmental Applications: Elsevier, p 383–426
Rieth AJ, Tulchinsky Y, Dincă M (2016) High and reversible ammonia uptake in mesoporous azolate metal–organic frameworks with open Mn, co, and Ni sites. J Am Chem Soc 138(30):9401–9404
Sabouni R, Kazemian H, Rohani S (2014) Carbon dioxide capturing technologies: a review focusing on metal organic framework materials (MOFs). Environ Sci Pollut Res 21(8):5427–5449
Salehi S, Anbia M (2017) High CO2 adsorption capacity and CO2/CH4 selectivity by nanocomposites of MOF-199. Energy Fuel 31(5):5376–5384
Sapsanis C, Omran H, Chernikova V, Shekhah O, Belmabkhout Y, Buttner U, Eddaoudi M, Salama KN (2015) Insights on capacitive interdigitated electrodes coated with MOF thin films: humidity and VOCs sensing as a case study. Sensors. 15(8):18153–18166
Sasikala SP, Lim J, Kim IH, Jung HJ, Yun T, Han TH et al (2018) Graphene oxide liquid crystals: a frontier 2D soft material for graphene-based functional materials. Chem Soc Rev 47(16):6013–6045
Schikowski T, Sugiri D, Ranft U, Gehring U, Heinrich J, Wichmann H-E et al (2005) Long-term air pollution exposure and living close to busy roads are associated with COPD in women. Respir Res 6(1):152
Shah MS, Tsapatsis M, Siepmann JI (2017) Hydrogen sulfide capture: from absorption in polar liquids to oxide, zeolite, and metal–organic framework adsorbents and membranes. Chem Rev 117(14):9755–9803
Shekhah O, Arslan HK, Chen K, Schmittel M, Maul R, Wenzel W, Wöll C (2011) Post-synthetic modification of epitaxially grown, highly oriented functionalized MOF thin films. Chem Commun 47(40):11210–11212
Shonnard DR, Kicherer A, Saling P (2003) Industrial applications using BASF eco-efficiency analysis: perspectives on green engineering principles. Environ Sci Technol 37(23):5340–5348
Stock N, Biswas S (2011) Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chem Rev 112(2):933–969
Sule R, Mishra AK (2019) Synthesis of mesoporous MWCNT/HKUST-1 composite for wastewater treatment. Appl Sci 9(20):4407
Surya SG, Bhanoth S, Majhi SM, More YD, Teja VM, Chappanda KN (2019) A silver nanoparticle-anchored UiO-66 (Zr) metal–organic framework (MOF)-based capacitive H 2 S gas sensor. CrystEngComm. 21(47):7303–7312
Thornton AW, Nairn KM, Hill JM, Hill AJ, Hill MR (2009) Metal−organic frameworks impregnated with magnesium-decorated fullerenes for methane and hydrogen storage. J Am Chem Soc 131(30):10662–10669
Tiwari JN, Mahesh K, Le NH, Kemp KC, Timilsina R, Tiwari RN et al (2013) Reduced graphene oxide-based hydrogels for the efficient capture of dye pollutants from aqueous solutions. Carbon. 56:173–182
Tofighy MA, Mohammadi T (2011) Adsorption of divalent heavy metal ions from water using carbon nanotube sheets. J Hazard Mater 185(1):140–147
Tomic E (1965) Thermal stability of coordination polymers. J Appl Polym Sci 9(11):3745–3752
Ullah S, Shariff AM, Bustam MA, Elkhalifah AEI, Gonfa G, Kareem FAA (2016) The role of multiwall carbon nanotubes in Cu-BTC metal-organic frameworks for CO2 adsorption. J Chin Chem Soc 63(12):1022–1032
Upadhyayula VK, Deng S, Mitchell MC, Smith GB (2009) Application of carbon nanotube technology for removal of contaminants in drinking water: a review. Sci Total Environ 408(1):1–13
Valekar AH, Batule BS, Kim MI, Cho K-H, Hong D-Y, Lee U-H et al (2018) Novel amine-functionalized iron trimesates with enhanced peroxidase-like activity and their applications for the fluorescent assay of choline and acetylcholine. Biosens Bioelectron 100:161–168
Vimercati L, Gatti MF, Gagliardi T, Cuccaro F, De Maria L, Caputi A et al (2017) Environmental exposure to arsenic and chromium in an industrial area. Environ Sci Pollut Res 24(12):11528–11535
Wang D, Wu G, Zhao Y, Cui L, Shin C-H, Ryu M-H, Cai J (2018) Study on the copper (II)-doped MIL-101 (Cr) and its performance in VOCs adsorption. Environ Sci Pollut Res 25(28):28109–28119
Wang Y, Pan C, Chu W, Vipin AK, Sun L (2019) Environmental remediation applications of carbon nanotubes and graphene oxide: adsorption and catalysis. Nanomaterials. 9(3):439
Wu Z, Yuan X, Zhong H, Wang H, Jiang L, Zeng G et al (2017) Highly efficient adsorption of Congo red in single and binary water with cationic dyes by reduced graphene oxide decorated NH2-MIL-68 (Al). J Mol Liq 247:215–229
Xiao Y, Han T, Xiao G, Ying Y, Huang H, Yang Q et al (2014) Highly selective adsorption and separation of aniline/phenol from aqueous solutions by microporous MIL-53 (Al): a combined experimental and computational study. Langmuir. 30(41):12229–12235
Xiong W, Zeng Z, Li X, Zeng G, Xiao R, Yang Z, Zhou Y, Zhang C, Cheng M, Hu L, Zhou C, Qin L, Xu R, Zhang Y (2018) Multi-walled carbon nanotube/amino-functionalized MIL-53 (Fe) composites: remarkable adsorptive removal of antibiotics from aqueous solutions. Chemosphere. 210:1061–1069
Xu P, Zeng GM, Huang DL, Feng CL, Hu S, Zhao MH, Lai C, Wei Z, Huang C, Xie GX, Liu ZF (2012) Use of iron oxide nanomaterials in wastewater treatment: a review. Sci Total Environ 424:1–10
Xu R, Wang Y, Duan X, Lu K, Micheroni D, Hu A, Lin W (2016) Nanoscale metal–organic frameworks for ratiometric oxygen sensing in live cells. J Am Chem Soc 138(7):2158–2161
Yamagiwa H, Sato S, Fukawa T, Ikehara T, Maeda R, Mihara T et al (2014) Detection of volatile organic compounds by weight-detectable sensors coated with metal-organic frameworks. Sci Rep 4:6247
Yan J, Yu Y, Xiao J, Li Y, Li Z (2016) Improved ethanol adsorption capacity and coefficient of performance for adsorption chillers of Cu-BTC@ GO composite prepared by rapid room temperature synthesis. Ind Eng Chem Res 55(45):11767–11774
Yang SJ, Choi JY, Chae HK, Cho JH, Nahm KS, Park CR (2009) Preparation and enhanced hydrostability and hydrogen storage capacity of CNT@ MOF-5 hybrid composite. Chem Mater 21(9):1893–1897
Yang C, Wu S, Cheng J, Chen Y (2016) Indium-based metal-organic framework/graphite oxide composite as an efficient adsorbent in the adsorption of rhodamine B from aqueous solution. J Alloys Compd 687:804–812
Yang J-M, Ying R-J, Han C-X, Hu Q-T, Xu H-M, Li J-H, Wang Q, Zhang W (2018) Adsorptive removal of organic dyes from aqueous solution by a Zr-based metal–organic framework: effects of Ce (III) doping. Dalton Trans 47(11):3913–3920
Yassine O, Shekhah O, Assen AH, Belmabkhout Y, Salama KN, Eddaoudi M (2016) H2S sensors: fumarate-based fcu-MOF thin film grown on a capacitive interdigitated electrode. Angew Chem Int Ed 55(51):15879–15883
Yu L-l, Luo Z-f, Y-y Z, Wu S-c, Yang C, Cheng J-h (2019) Contrastive removal of oxytetracycline and chlortetracycline from aqueous solution on Al-MOF/GO granules. Environ Sci Pollut Res 26(4):3685–3696
Yuan W, Garay AL, Pichon A, Clowes R, Wood CD, Cooper AI et al (2010) Study of the mechanochemical formation and resulting properties of an archetypal MOF: Cu3 (BTC) 2 (BTC= 1, 3, 5-benzenetricarboxylate). CrystEngComm. 12(12):4063–4065
Zhang Z, Wang H, Chen X, Zhu C, Wei W, Sun Y (2015) Chromium-based metal–organic framework/mesoporous carbon composite: synthesis, characterization and CO2 adsorption. Adsorption. 21(1–2):77–86
Zhang X, Xu Y, Ye B (2018) An efficient electrochemical glucose sensor based on porous nickel-based metal organic framework/carbon nanotubes composite (Ni-MOF/CNTs). J Alloys Compd 767:651–656
Zhao S, Chen D, Wei F, Chen N, Liang Z, Luo Y (2017) Removal of Congo red dye from aqueous solution with nickel-based metal-organic framework/graphene oxide composites prepared by ultrasonic wave-assisted ball milling. Ultrason Sonochem 39:845–852
Zhitkovich A (2011) Chromium in drinking water: sources, metabolism, and cancer risks. Chem Res Toxicol 24(10):1617–1629
Zhu B-J, Yu X-Y, Jia Y, Peng F-M, Sun B, Zhang M-Y et al (2012) Iron and 1, 3, 5-benzenetricarboxylic metal–organic coordination polymers prepared by solvothermal method and their application in efficient As (V) removal from aqueous solutions. J Phys Chem C 116(15):8601–8607
Zhu L, Meng L, Shi J, Li J, Zhang X, Feng M (2019) Metal-organic frameworks/carbon-based materials for environmental remediation: a state-of-the-art mini-review. J Environ Manag 232:964–977
Zu D-D, Lu L, Liu X-Q, Zhang D-Y, Sun L-B (2014) Improving hydrothermal stability and catalytic activity of metal–organic frameworks by graphite oxide incorporation. J Phys Chem C 118(34):19910–19917
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Sule, R., Mishra, A.K. MOFs-carbon hybrid nanocomposites in environmental protection applications. Environ Sci Pollut Res 27, 16004–16018 (2020). https://doi.org/10.1007/s11356-020-08299-x
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DOI: https://doi.org/10.1007/s11356-020-08299-x