Abstract
The present study offers the first evaluation of organic and elemental carbon (OC and EC) of submicron (PM1) fraction in Changchun (Northeast China) during a year-long sampling period (October 24, 2016 to October 23, 2017). More than 288 PM1 (particulate matter with an aerodynamic diameter of less than 1 μm) samples were collected. The PM1 concentrations ranged from 3.78 to 451.08 μg·m−3, with an average of 57.73 μg·m−3, which was 1.65 times higher than the Chinese National Standard II. Following the concept of the well-known IMPROVE algorithm, OC and EC values were obtained. The OC values ranged from 1.18 to 82.54 μg∙m−3, and the EC values were from 0.30 to 14.19 μg∙m−3. Total carbon (TC = EC + OC) constituted 9.11–40.35% of the total PM1 mass, and OC dominated over EC. The average OC/EC ratio was 4.78, which implied a low percentage for vehicles and a high contribution of coal and biomass consumption to PM1. Among OC, the annual primary organic carbon (POC) value was 7.69 μg∙m−3, accounting for 63% of the OC, while secondary organic carbon (SOC) contributed 37% with 4.12 μg∙m−3. Among EC, CHAR (EC1) dominated over SOOT (EC2 + EC3), and the CHAR/SOOR ratio ranged from 2.91 to 28.55. The results of the OC and EC values as well as the OC/EC and CHAR/SOOT ratios suggest that possible sources of PM1 include vehicles, coal burning, cooking, and biomass burning.
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Al-Naiema IM, Yoon S, Wang YQ, Zhang YX, Sheesley RJ, Stone EA (2018) Source apportionment of fine particulate matter organic carbon in Shenzhen, China by chemical mass balance and radiocarbon methods. Environ Pollut 240:34–43
Antony Chen L-W, Hans M, Patrick Arnott W, Chow JC, Watson JG, Susott RA, Babbitt RE, Wold CE, Lincoln EN, Hao WM (2007) Emissions from laboratory combustion of wildland fuels: emission factors and source profiles. Environ.Sci.Technol. 41:4317–4325
Cachier H, Bremond MP, Buat-Menard P (1989) Carbonaceous aerosols from different tropical biomass burning sources. NATURE 340:371–373
Cao JJ, Wu E, Chow JC (2005) Characterization and source apportionment of atmospheric organic and elemental carbon during fall and winter of 2003 in Xi’an. China Atmos Chem Phys 5:10
Cassee FR, Heroux ME, Gerlofs-Nijland ME, Kelly FJ (2013) Particulate matter beyond mass: recent health evidence on the role of fractions, chemical constituents and sources of emission. Inhal Toxicol 25:802–812
Chen D, Cui H, Zhao Y, Yin L, Lu Y, Wang Q (2017) A two-year study of carbonaceous aerosols in ambient PM2.5 at a regional background site for western Yangtze River Delta, China. Atmos Res 183:351–361
Choudhary V, Rajput P, Singh DK, Singh AK, Gupta T (2018) Light absorption characteristics of brown carbon during foggy and non-foggy episodes over the indo-Gangetic plain. Atmos Pollut Res 9:494–501
Chow JC, Watson JG, Kuhns H, Etyemezian V, Lowenthal DH, Crow D, Kohl SD, Engelbrecht JP, Green MC (2004) Source profiles for industrial, mobile, and area sources in the big bend regional aerosol visibility and observational study. Chemosphere 54:185–208
Cong Z, Kang S, Kawamura K, Liu B, Wan X, Wang Z, Gao S, Fu P (2015) Carbonaceous aerosols on the south edge of the Tibetan plateau: concentrations, seasonality and sources. Atmos Chem Phys 15:1573–1584
Ding XX, Kong LD, Du CT, Zhanzakova A, Fu HB, Tang XF, Wang L, Yang X, Chen JM, Cheng TT (2017) Characteristics of size-resolved atmospheric inorganic and carbonaceous aerosols in urban Shanghai. Atmos Environ 167:625–641
Ferreira, T.M., Forti, M.C., de Freitas, C.U., Nascimento, F.P., Junger, W.L., Gouveia, N., 2016. Effects of particulate matter and its chemical constituents on elderly hospital admissions due to circulatory and respiratory diseases. International journal of environmental research and public health 13
Guerrero F, Alvarez-Ospina H, Retama A, Lopez-Medina A, Castro T, Salcedo D (2017) Seasonal changes in the PM1 chemical composition north of Mexico City. Atmosfera 30:243–258
Gunsch MJ, May NW, Wen M, Bottenus CLH, Gardner DJ, VanReken TM, Bertman SB, Hopke PK, Ault AP, Pratt KA (2018) Ubiquitous influence of wildfire emissions and secondary organic aerosol on summertime atmospheric aerosol in the forested Great Lakes region. Atmos Chem Phys 18:3701–3715
Han YM, Cao JJ (2010) Different characteristics of char and soot in the atmosphere and their ratio as an indicator for source identification in Xi’an. China. Atmos. Chem. Phys 12
He K, Yang F, Ma Y, Zhang Q, Yao X, Chan CK, Cadle S, Chan T, Mulawa P (2001) The characteristics of PM2.5 in Beijing, China. Atmos Environ 35:4959–4970
Hou B, Zhuang G, Zhang R, Liu T, Guo Z, Chen Y (2011) The implication of carbonaceous aerosol to the formation of haze: revealed from the characteristics and sources of OC/EC over a mega-city in China. J Hazard Mater 190:529–536
Hu W, Hu M, Hu WW, Zheng J, Chen C, Wu YS, Guo S (2017) Seasonal variations in high time-resolved chemical compositions, sources, and evolution of atmospheric submicron aerosols in the megacity Beijing. Atmos Chem Phys 17:9979–10000
Ji D, Zhang J, He J, Wang X, Pang B, Liu Z, Wang L, Wang Y (2016) Characteristics of atmospheric organic and elemental carbon aerosols in urban Beijing, China. Atmos Environ 125:293–306
Karanasiou A, Minguillón MC, Viana M, Alastuey A, Putaud JP, Maenhaut W, Panteliadis P, Močnik G, Favez O, Kuhlbusch TAJ (2015) Thermal-optical analysis for the measurement of elemental carbon (EC) and organic carbon (OC) in ambient air a literature review. Atmospheric Measurement Techniques Discussions 8:9649–9712
Khan MB, Masiol M, Formenton G, Di Gilio A, de Gennaro G, Agostinelli C, Pavoni B (2016) Carbonaceous PM(2.5) and secondary organic aerosol across the Veneto region (NE Italy). Sci Total Environ 542:172–181
Kim H, Zhang Q, Bae GN, Kim JY, Lee SB (2017) Sources and atmospheric processing of winter aerosols in Seoul, Korea: insights from real-time measurements using a high-resolution aerosol mass spectrometer. Atmos Chem Phys 17:2009–2033
Kim H, Zhang Q, Heo J (2018) Influence of intense secondary aerosol formation and long-range transport on aerosol chemistry and properties in the Seoul metropolitan area during spring time: results from KORUS-AQ. Atmos Chem Phys 18:7149–7168
Křůmal K, Mikuška P, Večeřa Z (2013) Polycyclic aromatic hydrocarbons and hopanes in PM1 aerosols in urban areas. Atmos Environ 67:27–37
Kumar P, Kumar S, Yadav S (2018) Seasonal variations in size distribution, water-soluble ions, and carbon content of size-segregated aerosols over New Delhi. Environ Sci Pollut R 25:6061–6078
Lee BP, Louie PKK, Luk C, Chan CK (2017a) Evaluation of traffic exhaust contributions to ambient carbonaceous submicron particulate matter in an urban roadside environment in Hong Kong. Atmos Chem Phys 17:15121–15135
Lee K, Park J, Kang M, Kim D, Batmunkh T, Bae MS, Park K (2017b) Chemical characteristics of aerosols in coastal and urban ambient atmospheres. Aerosol Air Qual Res 17:908–919
Lewandowska AU, Beldowska M, Witkowska A, Falkowska L, Wisniewska K (2018) Mercury bonds with carbon (OC and EC) in small aerosols (PM1) in the urbanized coastal zone of the Gulf of Gdansk (southern Baltic). Ecotox Environ Safe 157:350–357
Li W, Bai Z (2009) Characteristics of organic and elemental carbon in atmospheric fine particles in Tianjin, China. Particuology 7:432–437
Li CL, Hu YJ, Zhang F, Chen JM, Ma Z, Ye XN, Yang X, Wang L, Tang XF, Zhang RH, Mu M, Wang GH, Kan HD, Wang XM, Mellouki A (2017a) Multi-pollutant emissions from the burning of major agricultural residues in China and the related health-economic effects. Atmos Chem Phys 17:4957–4988
Li HY, Zhang Q, Zhang Q, Chen CR, Wang LT, Wei Z, Zhou S, Parworth C, Zheng B, Canonaco F, Prevot ASH, Chen P, Zhang HL, Wallington TJ, He KB (2017b) Wintertime aerosol chemistry and haze evolution in an extremely polluted city of the North China plain: significant contribution from coal and biomass combustion. Atmos Chem Phys 17:4751–4768
Liu B, Bi X, Feng Y, Dai Q, Xiao Z, Li L, Wu J, Yuan J, Zhang Y (2016) Fine carbonaceous aerosol characteristics at a megacity during the Chinese spring festival as given by OC/EC online measurements. Atmos Res 181:20–28
Liu JW, Ding P, Zong Z, Li J, Tian CG, Chen WH, Chang M, Salazar G, Shen CD, Cheng ZN, Chen YJ, Wang XM, Szidat S, Zhang G (2018) Evidence of rural and suburban sources of urban haze formation in China: a case study from the Pearl River Delta region. J Geophys Res-Atmos 123:4712–4726
Mahapatra PS, Jain S, Shrestha S, Senapati S, Puppala SP (2018) Ambient endotoxin in PM10 and association with inflammatory activity, air pollutants, and meteorology, in Chitwan, Nepal. Sci Total Environ 618:1331–1342
Majewski G, Rogula-Kozlowska W, Rozbicka K, Rogula-Kopiec P, Mathews B, Brandyk A (2018) Concentration, chemical composition and origin of PM1: results from the first long-term measurement campaign in Warsaw (Poland). Aerosol Air Qual Res 18:636–654
Qiu ZW, Song JH, Xu XQ, Luo YP, Zhao RN, Zhou WC, Xiang BH, Hao YZ (2017) Commuter exposure to particulate matter for different transportation modes in Xi’an, China. Atmos Pollut Res 8:940–948
Rajput P, Singh DK, Singh AK, Gupta T (2018) Chemical composition and source-apportionment of sub-micron particles during wintertime over northern India: new insights on influence of fog-processing. Environ Pollut 233:81–91
Ramirez O, de la Campa AMS, Amato F, Catacoli RA, Rojas NY, de la Rosa J (2018) Chemical composition and source apportionment of PM10 at an urban background site in a high-altitude Latin American megacity (Bogota, Colombia). Environ Pollut 233:142–155
Shen Z, Cao J, Arimoto R, Han Y, Zhu C, Tian J, Liu S (2010) Chemical characteristics of fine particles (PM1) from Xi’an, China. Aerosol Sci Technol 44:461–472
Van Ryswyk K, Anastasopolos AT, Evans G, Sun L, Sabaliauskas K, Kula R, Wallace L, Weichenthalt S (2017) Metro commuter exposures to particulate air pollution and PM2.5-associated elements in three Canadian cities: the urban transportation exposure study. Environ Sci Technol 51:5713–5720
Vecchi R, Bernardoni V, Valentini S, Piazzalunga A, Fermo P, Valli G (2018) Assessment of light extinction at a European polluted urban area during wintertime: impact of PM1 composition and sources. Environ Pollut 233:679–689
Wang HL, An JL, Zhu B, Shen LJ, Duan Q, Shi YZ (2017) Characteristics of carbonaceous aerosol in a typical industrial city-Nanjing in Yangtze River Delta, China: size distributions, seasonal variations, and sources. Atmosphere-Basel 8
Wang W, Yu J, Cui Y, He J, Xue P, Cao W, Ying H, Gao W, Yan Y, Hu B, Xin J, Wang L, Liu Z, Sun Y, Ji D, Wang Y (2018) Characteristics of fine particulate matter and its sources in an industrialized coastal city, Ningbo, Yangtze River Delta, China. Atmos Res 203:105–117
Watson JG, Chow JC, Houck JE (2001) PM2.5 chemical source profiles for vehicle exhaust, vegetative burning, geological material, and coal burning in northwestern Colorado during 1995. CHEMOSPHERE 43:1141–1151
Wu ZJ, Zheng J, Wang Y, Shang DJ, Du ZF, Zhang YH, Hu M (2017) Chemical and physical properties of biomass burning aerosols and their CCN activity: a case study in Beijing, China. Sci Total Environ 579:1260–1268
Xia YJ, Tao J, Zhang LM, Zhang RJ, Li SL, Wu YF, Cao JJ, Wang XJ, Ma QX, Xiong Z (2017) Impact of size distributions of major chemical components in fine particles on light extinction in urban Guangzhou. Sci Total Environ 587:240–247
Xu JZ, Zhang Q, Shi JS, Ge XL, Xie CH, Wang JF, Kang SC, Zhang RX, Wang YH (2018) Chemical characteristics of submicron particles at the central Tibetan plateau: insights from aerosol mass spectrometry. Atmos Chem Phys 18:427–443
Yang F, Huang L, Duan F, Zhang W, He K, Ma Y et al (2011a) Carbonaceous species in PM2.5 at a pair of rural/urban sites in Beijing, 2005-2008. Atmos Chem Phys 11:7893–7903
Yang F, Tan J, Zhao Q, Du Z, He K, Ma Y et al (2011b) Characteristics of PM2.5 species in representative megacities and across China. Atmos Chem Phys 11:5207–5219
Yang T, Sun YL, Zhang W, Wang ZF, Liu XG, Fu PQ, Wang XQ (2017) Evolutionary processes and sources of high-nitrate haze episodes over Beijing, spring. J Environ Sci-China 54:142–151
Yao X, Chan CK, Fang M, Cadle S, Chan T, Mulawa P, He K, Ye B (2002) The water-soluble ionic composition of PM2.5 in Shanghai and Beijing, China. Atmos Environ 36:4223–4234
Yu S, Dennis RL, Bhave PV, Eder BK (2004) Primary and secondary organic aerosols over the United States: estimates on the basis of observed organic carbon (OC) and elemental carbon (EC), and air quality modeled primary OC/EC ratios. Atmos Environ 38:5257–5268
Zhang YL, Huang RJ, El Haddad I, Ho KF, Cao JJ, Han Y, Zotter P, Bozzetti C, Daellenbach KR, Canonaco F, Slowik JG, Salazar G, Schwikowski M, Schnelle-Kreis J, Abbaszade G, Zimmermann R, Baltensperger U, Prévôt ASH, Szidat S (2015) Fossil vs. non-fossil sources of fine carbonaceous aerosols in four Chinese cities during the extreme winter haze episode of 2013. Atmos Chem Phys 15:1299–1312
Zhang YL, Ren H, Sun YL, Cao F, Chang YH, Liu SD, Lee XH, Agrios K, Kawamura K, Liu D, Ren LJ, Du W, Wang ZF, Prevot ASH, Szida S, Fu PQ (2017) High contribution of nonfossil sources to submicrometer organic aerosols in Beijing, China. Environ Sci Technol 51:7842–7852
Zhang JJ, Tong L, Huang ZW, Zhang HL, He MM, Dai XR, Zheng J, Xiao H (2018) Seasonal variation and size distributions of water-soluble inorganic ions and carbonaceous aerosols at a coastal site in Ningbo, China. Sci Total Environ 639:793–803
Zheng M, Salmon LG, Schauer JJ, Zeng L, Kiang CS, Zhang Y, Cass GR (2005) Seasonal trends in PM2.5 source contributions in Beijing, China. Atmos Environ 39:3967–3976
Zielinska B, Sagebiel J, McDonald JD, Whitney K, Lawson DR (2012) Emission rates and comparative chemical composition from selected in-use diesel and gasoline fueled vehicles. J Air Waste Manage Assoc 54:1138–1150
Funding
This study was financially supported by the Natural Science Foundation of China (NSFC) (Grant No. 51508224), the National Key Research and Development Program of China (2017YFC0702705), the Jilin Scientific and Technological Development Program (Grant No. 20140520148JH), and the China Scholar Council.
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Li, N., Wei, X., Han, W. et al. Characteristics and temporal variations of organic and elemental carbon aerosols in PM1 in Changchun, Northeast China. Environ Sci Pollut Res 27, 8653–8661 (2020). https://doi.org/10.1007/s11356-019-07494-9
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DOI: https://doi.org/10.1007/s11356-019-07494-9