Abstract
Representative sampling of suspended particulate matter is fundamental for assessing river sediment quality, including the distribution and physicochemical characterisation of particles at different hydrological events. This study compares time-integrated samplers and discrete sampling methods, focusing on (a) the representativeness of the different methods and (b) the comparability between the various sampling techniques. The study investigates whether different sampling devices used under the same conditions can reproduce the annual mean. Two time-integrated sampling techniques (Binnensammler floating collector (BS); self-constructed Phillips sampler (PS)) and two discrete sampling systems (continuous-flow centrifuge (CFC); hydrocyclone (HC)) were compared. The monitoring program (August 2013 to August 2014) was conducted using a 4-week sampling frequency at two different monitoring stations in the Rhine river basin. The analysis of physicochemical parameters included total organic carbon (TOC), particulate phosphorus (PP), grain size distribution (GSD), metals, and organic pollutants (PCBs, HCB, PAH). A nested analysis of variance (ANOVA) was used to evaluate the dependence of suspended matter quality parameters on the sampling method, the sampling device, and the sampling station. According to ANOVA, physical and chemical parameters as well as persistent organic pollutants are homogenous for the time-integrated samplers PS and BS. Comparing PS and the reference technique CFC, only the mean annual concentration of TOC is significantly higher for CFC (5.91%; PS, 4.53%) due to degradation processes. With the exception of TOC, Ni, and GSD, data of BS was comparable with that of CFC. Comparing CFC and HC, there are significant differences for GSD, Zn, and Ni. An analysis of the time series of GSD < 63 μm and sum of PAHs confirms the findings of the nested ANOVA, showing that HC time series display significant differences compared with the other samplers.
Similar content being viewed by others
Abbreviations
- BS:
-
Binnensammler
- PS:
-
Phillips sampler
- HC:
-
Hydrocyclone
- CFC:
-
Continuous-flow centrifuge
- SPM:
-
Suspended particulate matter
- GSD:
-
Grain size distribution
References
Backhaus K, Erichson B, Plinke W, Weiber R (2011) Multivariate Analysemethoden, 13th edn. Springer, Heidelberg
Bain J, Morgan D (1982) Laboratory separation of clays by hydrocycloning. Clay Miner 18:33–47
Bortz J, Schuster C (2010) Statistik für Human- und Sozialwissenschaftler. Springer, Heidelberg
Breitung V (1997) Probenahme mit einer Durchlaufzentrifuge zur Gewinnung von Schwebstoffen für die Schadstoffanalyse aus fließenden Gewässern. Deutsche Gewässerkundl Mitt 41:113–117
Davis BE (2005) A guide to the proper selection and use of federally approved sediment and water-quality samplers. U.S. Geological Survey Open-File Report 2005-1087, U.S. Geological Survey, Reston, VA
de Mendiburu F (2014) agricolae: Statistical Procedures for Agricultural Research. R package version 1.2-1. http://CRAN.R-project.org/package=agricolae
DIN 38407-3 (1998) German standard methods for the determination of water, waste water and sludge—jointly determinable substances (group F). Part 3: Determination of polychlorinated biphenyls (F 3)
DIN 38407-39 (2011) German standard methods for the examination of water, waste water and sludge—jointly determinable substances (group F). Part 39: Determination of selected polycyclic aromatic hydrocarbons (PAH)—method using gas chromatography with mass spectrometric detection (GC-MS) (F 39)
DIN 38414-20 (1996) German standard methods for the examination of water, waste water and sludge—sludge and sediments (group S). Part 20: Determination of 6 polychlorinated biphenyls (PCB) (S 20)
Doriean NJC, Teasdale PR, Welsh DT, Brooks AP, Bennett WW (2019) Evaluation of a simple, inexpensive, in situ sampler for measuring time-weighted average concentrations of suspended sediment in rivers and streams. Hydrol Process 33:678–686
Droppo IG (2001) Rethinking what constitutes suspended sediment. Hydrol Process 15:1551–1564
EC (2009) Guidance on surface water chemical monitoring under the water framework directive. Technical report. 2009-025, Luxembourg
EN 13137:2001 (2001) Characterization of waste—determination of total organic carbon (TOC) in waste, sludges and sediments.
EN 38406-6:1998-07 (1998) German standard methods for the examination of water, waste water and sludge—cations (group E). Part 6: Determination of lead by atomic absorption spectrometry (AAS).
EU (2010) On chemical monitoring of sediment and biota under the water framework directive. Technical report. 2010-041, Luxembourg
Gao L, Gao B, Xu D, Penga W, Lu J (2019) Multiple assessments of trace metals in sediments and their response to the water level fluctuation in the Three Gorges Reservoir, China. Sci Total Enivon 648:197–205
Gautam P, Carsella JS, Kinney CA (2014) Presence and transport of the antimicrobials triclocarban and triclosan in a wastewater-dominated stream and freshwater environment. Water Res 48:247–256
Grams PE, Buscombe D, Topping DJ, Kaplinski M, Hazel Jr JE (2018) How many measurements are required to construct an accurate sand budget in a large river? Insights from analyses of signal and noise. Earth Surf Proc Land 44(1):1–401
Gray JR, Gartner JW (2009) Technological advances in suspended-sediment surrogate monitoring. Water Resour Res 45:W00D29
Heininger P, Schild R, de Beer K, Planas C, Roose P, Sortkjaer O (2002) International pilot study for the determination of riverine inputs of polycyclic aromatic hydrocarbons (PAHs) to the maritime area on the basis of a harmonised methodology: Final report. OSPAR-Pilotstudie. Federal Environmental Agency. Texte, vol. 57/02. http://www.umweltbundesamt.de/sites/default/files/medien/publikation/long/2183.pdf
Horowitz A (1979) A primer on trace metal-sediment chemistry, 2nd edn. United States Geological Survey Water-Supply Paper 2277. https://pubs.usgs.gov/of/1991/0076/report.pdf
Horowitz A (2004) Monitoring suspended sediment and associated trace element and nutrient fluxes in large river basins in the USA Sediment Transfer through the Fluvial System. IAHS Publ 288:419–428
International Commission for the Protection of the Rhine (ICPR) (2019) Rhine monitoring programme—chemical component 2015-2020. https://www.iksr.org/fileadmin/user_upload/DKDM/Dokumente/Fachberichte/FR/rp_Fr_0222.pdf
ISO 13320 (2009) Particle size analysis—laser diffraction methods.
ISO 15586 (2003) Water quality—determination of trace elements using atomic absorption spectrometry with graphite furnace.
ISO 15587-2 (2002) Water quality—digestion for the determination of selected elements in water -- Part 2: Nitric acid digestion.
ISO 5667-17 (2008) Water quality—sampling. Part 17: Guidance on sampling of bulk suspended solids, International Organization for Standardization.
ISO 6468 (1996) Water quality—determination of certain organochlorine insecticides, polychlorinated biphenyls and chlorobenzenes—gas chromatographic method after liquid-liquid extraction.
ISO 6878 (2004) Water quality—determination of phosphorus—ammonium molybdate spectrometric method.
Keller M (1994) HCB load on suspended solids and in sediments of the river Rhine. Water Sci Technol 29(3):129–131
Kellner E, Hubbart JA (2018) Spatiotemporal variability of suspended sediment particle size in a mixed-land-use watershed. Sci Total Environ 15(615):1164–1175
Keßler S, Pohlert T, Breitung V, Bierl R (2015) Vergleich neuartiger Geräte zur Schwebstoffgewinnung für das chemische Gewässermonitoring—SchwebSam. Koblenz. Bundesanstalt für Gewässerkunde. In: Mitt Nr. 32. ISBN: 978-940247-12-4
Kiff P (1977) Evaluation of a hydrocyclone for on-site sediment separation. J Sediment Res 47:1365–1374
Krein A, Schorer M (2000) Road runoff pollution by polycyclic aromatic hydrocarbons and its contribution to river sediments. Water Res 34(16):4110–4115
Kurtenbach A, Gallé T, Bierl R, Symader W (2015) Temporal dynamics of cohesive sediment and associated pollutant transport in mid-mountain gravel bed rivers. 18th “International Workshop on Physical Processes in Natural Waters (PPNW2015)”, Universität Landau. https://www.uni-koblenz-landau.de/en/campus-landau/faculty7/environmental-sciences/uphys-en/ppnw-2015/docs/PPNW2015.pdf
Martinez E, Gros M, Lacorte S, Barceló D (2004) Simplified procedures for the analysis of polycyclic aromatic hydrocarbons in water, sediments and mussels. J Chromatogr A 1047:181–188
Martínez-Carreras N, Krein A, Gallart F, Iffly JF, Pfister L, Hoffmann L, Owens PN (2010a) Assessment of different colour parameters for discriminating potential suspended sediment sources and provenance: a multi-scale study in Luxembourg. Geomorphology 118:118–129
Martínez-Carreras N, Krein A, Udelhoven T, Gallart F, Iffly JF, Hoffmann L, Pfister L, Walling D (2010b) A rapid spectral-reflectance-based fingerprinting approach for documenting suspended sediment sources during storm runoff events. J Soils Sediments 10:400–413
Marttila H, Kløve B (2014) Spatial and temporal variation in particle size and particulate organic matter content in suspended particulate matter from peatland-dominated catchments in Finland. Hydrol Process 29:1069–1079
McDonald DM, Lamoureux SF, Warburton J (2010) Assessment of time-integrated fluvial suspended sediment sampler in a high arctic setting. Geografiska Annaler. Series A. Phys Geogr 92:225–235
Miller JR, Orbock Miller SM (2007) Contaminated rivers: a geomorphological-geochemical approach to site assessment and remediation. Springer, Netherlands
Owens PN (2008) Sediment behaviour, functions and management in river basins. In: Owens PN (ed) Sustainable Management of Sediment Resources. Elsevier
Owens PN, Batalla RJ, Collins AJ, Gomez B, Hicks DM, Horowitz AJ, Kondolf GM, Marden M, Page MJ, Peacock DH, Petticrew EL, Salomons W, Trustrum NA (2005) Fine-grained sediment in river systems: environmental significance and management issues. River Res Appl 21:693–717
Perks MT (2014) Suspended Sediment Sampling. In: Clarke LE (ed) Geomorphological Techniques (Online Edition). London, British Society for Geomorphology ISSN 2047-0371
Perks MT, Warburton J, Bracken L (2014) Critical assessment and validation of a time-integrating fluvial suspended sediment sampler. Hydrol Process 28:4795–4807
Phillips JM, Russell MA, Walling DE (2000) Time-integrated sampling of fluvial suspended sediment: a simple methodology for small catchments. Hydrol Process 14:2589–2602
Pohlert T, Hillebrand G, Breitung V (2011a) Effects of sampling techniques on physical parameters and concentrations of selected persistent organic pollutants in suspended matter. J Environ Monit 13:1579–1588
Pohlert T, Hillebrand G, Breitung V (2011b) Trends of persistent organic pollutants in the suspended matter of the River Rhine. Hydrol Process 25:3803–3817
R Core Team (2014) R: A language and environment for statistical computing. R Foundation for Statistical Computing, Vienna, Austria. URL: http://www.R-project.org/
Rees TF, Leenheer JA, Ranville JF (1991) Use of a single-bowl continuous-flow centrifuge for dewatering suspended sediments: Effect on sediment physical and chemical characteristics. Hydrol Process 5:201–214
Sanni SS, Ukaegbu EC (2012) On three-way unbalanced nested analysis of variance. J Math Stat 8:1–14
Schubert B, Heininger P, Keller M, Ricking M, Claus E (2012) Monitoring of contaminants in suspended particulate matter as an alternative to sediments. Trends Anal Chem 36:58–70
SedNet, European Sediment Research Network (2004) Contaminated sediments in European river basins. https://sednet.org/wp-content/uploads/2016/03/Sednet_booklet_final_2.pdf. Accessed on 18 Nov 2019
Smith TA, Owens PN (2014) Flume- and field-based evaluation of a time-integrated suspended sediment sampler for the analysis of sediment properties. Earth Surf Process Landf 39:1197–1207
Struwe K (2014): Effizienzprüfung von Phillips-Sammlern mittels definierter Schwebstoffe. Unpublished results. Bachelor Thesis, Trier University, Department of Hydrology.
Tanse B, Rafiuddi S (2016) Heavy metal content in relation to particle size and organic content of surficial sediments in Miami River and transport potential. Int J Sediment Res 31:324–329. https://doi.org/10.1016/j.ijsrc.2016.05.004
Tekniscience (2015) CEPA High-speed centrifuges. www.tekniscience.com/documents/CEPA.pdf. Accessed 08 Nov 2015
US-EPA (1994) Remediation guidance document. In: Assessment and remediation of contaminated sediments program—Guidance Document 905-B94-003. US EPA
Wasser- und Schifffahrtsverwaltung des Bundes (WSV) (2014) Auszug aus dem Deutschen Gewässerkundlichen Jahrbuch Mosel/Cochem und Rhein/Iffezheim. Data has been provided by the Federal Institute of Hydrology (BfG)
WaterCo (2012) Multicyclone centrifugal pre-filtration—installation and operation manual. www.waterco.com. Accessed 28 Nov 2014
WaterCo (2014) WaterCo—filters. www.waterco.com. Accessed 28 Nov 2014
Westrich B, Förstner U (eds) (2007) Sediment dynamics and pollutant mobility in rivers: an interdisciplinary approach. Springer, Heidelberg
Funding
The project “Vergleich neuartiger Geräte zur Schwebstoffgewinnung für das chemische Gewässermonitoring—SchwebSam” (Comparison of innovative devices for suspended matter sampling for chemical monitoring of rivers) was funded by the Bundesministerium für Verkehr und digitale Infrastruktur (BMVI). We thank the Landesanstalt für Umwelt, Messungen und Naturschutz Baden-Württemberg (LUBW) and the Wasser- und Schifffahrtsamt (WSA) Freiburg for supporting this project.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Christian Gagnon
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Article highlights
- Time-integrated and discrete sampling techniques for suspended sediments have been analyzed for comparability.
- A nested ANOVA shows homogeneity for suspended sediments sampled by different time-integrated techniques.
- Samples of time-integrated Phillips sampler equal discrete samples of continuous-flow centrifuge with the exception of TOC.
- Discrete sampling by hydrocyclone is easy to use but not comparable for all parameters.
Rights and permissions
About this article
Cite this article
Keßler, S., Pohlert, T., Breitung, V. et al. Comparative evaluation of four suspended particulate matter (SPM) sampling devices and their use for monitoring SPM quality. Environ Sci Pollut Res 27, 5993–6008 (2020). https://doi.org/10.1007/s11356-019-07314-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-019-07314-0