Assessment, formation mechanism, and different source contributions of dissolved salt pollution in the shallow groundwater of Hutuo River alluvial-pluvial fan in the North China Plain

Abstract

With rapid urbanization and industrialization processes, the problem of groundwater pollution under the influence of various human activities has become increasingly severe in most developed areas of China. However, the problem of dissolved salt pollution caused by increasing concentrations of conventional ions is often overlooked and easier to be seen as a high background of natural formation rather than pollution. The Hutuo River alluvial fan in North China was selected as the study area; dissolved salt pollution is evaluated based on the factor analysis method (FA); groundwater exploitation, pollutant input, and the attenuation of the vadose zone were discussed to explain the salt pollution; the formation mechanism and different source contributions were also explored. The results show that the total hardness (TH) and nitrate are the main contributing indicators of salt pollution in the Hutuo River alluvial fan. The long-term overexploitation of groundwater promoted the leaching and nitrification reactions, resulting in a large area of moderate to strong salt pollution in the top unit of the alluvial fan, which accounted for 51.6% of the salt pollution according to the multivariate regression model. In addition, the input pollution generated by various types of pollution sources along with rainfall infiltration is also an important driving factor. The surface pollution load and hydrogeological conditions affected the cation exchange and leaching, resulting in a point distribution of strong salt pollution, with a contribution rate of 37.6%. The analysis of the factors that affect salt pollution and the specific contributions in different regions cannot only help decision-makers understand the causes of water quality deterioration but also propose solutions in a targeted manner.

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References

  1. Abualnaeem MF, Yusoff I, Ng TF, Alias Y, Raksmey M (2018) Assessment of groundwater salinity and quality in Gaza coastal aquifer, Gaza Strip, Palestine: an integrated statistical, geostatistical and hydrogeochemical approaches study. Sci Total Environ 615:972–989

    CAS  Article  Google Scholar 

  2. Adams S, Titus R, Pietersen K, Tredoux G, Harris C (2001) Hydrochemical characteristics of aquifers near Sutherland in the Western Karoo, South Africa. J Hydrol 241:91–103

    CAS  Article  Google Scholar 

  3. Anning DW, Flynn ME (2014) Dissolved-solids sources, loads, yields, and concentrations in streams of the conterminous United States: U. S. Geol Surv Sci Investig Rep 2014-5012:101

    Google Scholar 

  4. Chaudhuri S, Ale S (2014) Long term (1960-2010) trends in groundwater contamination and salinization in the Ogallala Aquifer in Texas. J Hydrol 513(513):376–390

    CAS  Article  Google Scholar 

  5. Güler C, Kurt MA, Alpaslan M, Akbulut C (2012) Assessment of the impact of anthropogenic activities on the groundwater hydrology and chemistry in tarsus coastal plain (Mersin, SE Turkey) using fuzzy clustering, multivariate statistics and gis techniques. J Hydrol 414–415(3):435–451

    Article  CAS  Google Scholar 

  6. Helena B, Pardo R, Vega M, Barrado E, Fernandez JM, Fernandez L (2000) Temporal evolution of groundwater composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Water Res 34:807–816

    CAS  Article  Google Scholar 

  7. Huang GX, Sun JC, Zhang Y, Chen ZY, Liu F (2013) Impact of anthropogenic and natural processes on the evolution of groundwater chemistry in a rapidly urbanized coastal area, South China. Sci Total Environ 463-464:209–221

    CAS  Article  Google Scholar 

  8. Kong D, Harmon TC (1996) Using the multiple cell balance method to solve the problem of two-dimensional groundwater flow and contaminant transport with nonequilibrium sorption. J Contam Hydrol 23(4):285–301

    CAS  Article  Google Scholar 

  9. Kumari R, Datta PS, Rao MS (2018) Anthropogenic perturbations induced groundwater vulnerability to pollution in the industrial Faridabad District, Haryana, India [J]. Environ Earth Sci 77(5):187

    Article  CAS  Google Scholar 

  10. Landon MK, Green CT, Belitz K, Singleton MJ, Esser BK (2011) Relations of hydrogeologic factors, groundwater reduction–oxidation conditions, and temporal and spatial distributions of nitrate, central-eastside San Joaquin Valley, California, USA. Hydrogeol J 19:1203–1224

    CAS  Article  Google Scholar 

  11. Lee L, Helsel D (2005) Baseline models of trace elements in major aquifers of the United States. Appl Geochem 20(8):1560–1570

    CAS  Article  Google Scholar 

  12. Li FL, YANG XY, YANG TS (1965) Hydrogeological survey report of water supply in Shijiazhuang. Hydrogeological observation station of Hebei Geological Bureau, Hebei (in Chinese)

    Google Scholar 

  13. Li HJ, Lv SH, Lu WX (2006) Effect of organic material in the aquifer on groundwater quality. Geol Sci Technol Inform 25(4):82–85 (in Chinese)

    Google Scholar 

  14. Li J, Yang Y, Huan H, Li MX, Xi BD, Lv NQ, Wu L, Xie YW, Li X, Yang JJ (2016a) Method for screening prevention and control measures and technologies based on groundwater pollution intensity assessment. Sci Total Environ 551-552:143–154

    CAS  Article  Google Scholar 

  15. Li Y, Zhang Z, Fei Y, Chen H, Qian Y, Yu D (2016b) Investigation of quality and pollution characteristics of groundwater in the Hutuo River alluvial plain, North China plain. Environ Earth Sci 75:1–10

    Article  Google Scholar 

  16. Lin CY, Abdullah MH, Praveena SM, Yahaya AHB, Musta B (2012) Delineation of temporal variability and governing factors influencing the spatial variability of shallow groundwater chemistry in a tropical sedimentary island. J Hydrol 432-433(none):26–42

    CAS  Article  Google Scholar 

  17. Liu Y, Qiao XC, Jiang QF, Chang S, Zhu YY, Wang SJ (2016) Spatial distribution and influencing factors of nitrate content in groundwater of alluvial-pluvial fan of Hutuo River. J Agro-Environ Sci 35(5):947–954 (in Chinese)

    CAS  Google Scholar 

  18. Lockhart K, King A, Harter T (2013) Identifying sources of groundwater nitrate contamination in a large alluvial groundwater basin with highly diversified intensive agricultural production. J Contam Hydrol 151:140–154

    CAS  Article  Google Scholar 

  19. Lu Y, Tang C, Chen J, Yao H (2016) Assessment of major ions and heavy metals in groundwater: a case study from Guangzhou and Zhuhai of the Pearl River Delta, China. Front Earth Sci 10(2):340–351

    CAS  Article  Google Scholar 

  20. Mukherjee A, Scanlon BR, Fryar AE, Saha D, Ghosh A, Chowdhuri S (2012) Solute chemistry and arsenic fate in aquifers between the Himalayan foothills and Indian craton (including central Gangetic plain): influence of geology and geomorphology. Geochim Cosmochim Acta 90(4):283–302

    CAS  Article  Google Scholar 

  21. Pekey H, Karaka D, Bakoglu M (2004) Source apportionment of trace metals in surface waters of a polluted stream using multivariate statistical analyses. Mar Pollut Bull 49:809–818

    CAS  Article  Google Scholar 

  22. Peng C, He JT, Wang ML, Zhang ZG, Wang L (2017) Identifying and assessing human activity impacts on groundwater quality through hydrogeochemical anomalies and NO3-, NH4+, and COD contamination: a case study of the Liujiang River Basin Hebei Province, P.R. China. Environ Sci Pollut Res Int 25(4):3539–3556 (2):1-18

    Article  CAS  Google Scholar 

  23. Qin R, Wu Y, Xu Z, Xie D, Zhang C (2013) Assessing the impact of natural and anthropogenic activities on groundwater quality in coastal alluvial aquifers of the lower Liaohe River Plain, NE China. Appl Geochem 31(2):142–158

    CAS  Article  Google Scholar 

  24. Reimann C, Filzmoser P, Garrett RG (2005) Background and threshold: critical comparison of methods of determination. Sci Total Environ 346:1–3), 1-16

    CAS  Article  Google Scholar 

  25. Shen Z, Zhu W, Zhong Z (1985) Basis of hydrogeochemistry. Geological Publishing House, Beijing, pp 149–155 (in Chinese)

    Google Scholar 

  26. Wang HQ (1999) Optimal upstream weighting in the multiple-cell-balance method for simulating mass transport in ground water. Comput Geosci 25(6):683–694

    Article  Google Scholar 

  27. Wang S, Sun JC, Li ZH (2004) Groundwater quality evaluation in northwest China. Hydrogeol Eng Geol in Chinese

  28. Wang J, He JT, Chen H (2012) Assessment of groundwater contamination risk using hazard quantification, a modified DRASTIC model and groundwater value, Beijing Plain, China. Sci Total Environ 432:216–226

    CAS  Article  Google Scholar 

  29. Wang ML, He JT, Cui YF, He BN, Peng C (2016) Study on groundwater contamination risk assessment method based on reduced coefficient. Acta Sci Circumst 36(12):4510–4519 (in Chinese)

    CAS  Google Scholar 

  30. Wei C, Guo H, Di Z, Yang W, Han S, An Y (2016) Occurrence and hydrogeochemical characteristics of high-fluoride groundwater in Xiji county, southern part of Ningxia province, china. Environ Geochem Health 38(1):275–290

    CAS  Article  Google Scholar 

  31. Yu K, Hao A, Li D, Liu Z (2001) Distribution of groundwater salinity pollution and the polluting mechanism in Shijiazhuang. Earth Science Frontiers 8(1):151–154 (in Chinese)

    CAS  Google Scholar 

  32. Zhang C, Wu L, Luo Y, Zhang H, Christie P (2008) Identifying sources of soil inorganic pollutants on a regional scale using a multivariate statistical approach: role of pollutant migration and soil physicochemical properties. Environ Pollut 151:470–476

    CAS  Article  Google Scholar 

  33. Zhang Y, Sun JC, Huang GX, Jing JH, Chen X, Liu JT (2011) A preliminary study of natural background levels of groundwater in the Zhujiang River Delta. Geol China 38(1):190–196 (in Chinese)

    Google Scholar 

  34. Zhang DZ, Li HM, Zhan XY, Xia YZ, 2014. Characteristics of groundwater salt pollution in a typical leather-contaminated site. Hydrogeol Eng Geol. (in Chinese)

  35. Zhang Q, Sun J, Liu J, Huang G, Lu C, Zhang Y (2015) Driving mechanism and sources of groundwater nitrate contamination in the rapidly urbanized region of south china. J Contam Hydrol 182:221–230

    CAS  Article  Google Scholar 

  36. Zhang Q, Wang H, Wang Y, Yang M, Zhu L (2017) Groundwater quality assessment and pollution source apportionment in an intensely exploited region of northern china. Environ Sci Pollut Res Int 24(20):16639–16650

    CAS  Article  Google Scholar 

  37. Zhang XW, He JT, Liu D, Ni Z, Zhang C (2018) An analysis of the stress effects and methods of the shallow groundwater quality in the Hutuo River alluvial fan. Hydrogeol Eng Geol 45(5):48–56 (in Chinese)

    Google Scholar 

  38. Zhao JQ, Li S, Yang P, Gao M, Shi Y, Liang H, Wang Y, Wang Z, Zhu T, 2011. Geological Environment Monitoring Report of Shijiazhuang City, Hebei Province: 2006-2010. Hebei Prov Geol Environ Monit Station. (in Chinese)

  39. Zou SZ, Zhang JB, Li J, Lin J, Tian JY, Chen HH (2002) Analysis of shallow groundwater salt pollution feature and mechanism in the southwest suburb of Beijing city. Hydrogeol Eng Geol 29(1):5–9 (in Chinese)

    CAS  Google Scholar 

Download references

Funding

This study was financially supported by the Project of China Geological Survey (DD20160309).

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Correspondence to Jiangtao He.

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Zhang, X., He, J., He, B. et al. Assessment, formation mechanism, and different source contributions of dissolved salt pollution in the shallow groundwater of Hutuo River alluvial-pluvial fan in the North China Plain. Environ Sci Pollut Res 26, 35742–35756 (2019). https://doi.org/10.1007/s11356-019-06502-2

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Keywords

  • Dissolved salt pollution
  • Groundwater overexploitation
  • Human activities
  • Attenuation in aeration zone
  • Hutuo River alluvial-pluvial fan