Abstract
In the transportation of petroleum, large amount of oil polluted water will be produced, and the oil polluted water pumping into ocean will destroy ocean environment. To address oil-bearing ballast water, we fabricated a novel type of Fe–C microelectrolysis filler by using magnet powder, coconut shell biochar powder, bentonite, ammonium oxalate, and nickel powder. The COD and oil content removal efficiencies of 100 g/L oily wastewater were approximately 79.82% and 91.68%, respectively, after 100 min treatment at the following conditions: Fe–C mass ratio, 5:1; bentonite content, 20%; calcination temperature, 900 °C; calcination time, 2 h; ammonium oxalate content, 1.5%; and amount of nickel addition, 6.78%. The characteristics of the Fe–C microelectrolysis filler were analyzed. The surface structure of the filler was loose and porous, and its pores were developed. The Brunauer–Emmett–Teller (BET) surface area reached 49.4667 m2 g−1. A microelectrolysis filler is mainly mesoporous and contains large pores. Its average pore size is 2.6942 nm. Meanwhile, the results of our XRD analysis showed that some fillers were metal oxides, and most of them were simple metal substances.
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Chang SH, Wang KS, Chao SJ, Peng TH, Huang LC (2009) Degradation of azo and anthraquinone dyes by a low-cost Fe0/air process. J Hazard Mater 166:1127–1133. https://doi.org/10.1016/j.jhazmat.2008.12.021
Chu JY, Cai XX, Fan D, Guan HL (2010) Treatment of low concentration oily ballast water from Yangtze River by ozone oxidation. J Jiangsu Univ (Nat Sci Ed) 31:221–224. https://doi.org/10.3969/j.issn.1671-7775.2010.02.020
Guan TZ, Xu XJ, Meng JW, Ma L, Chen XH, Shi GF (2013) Micro-electrolysis enhanced by microwave to treat nitrobenzene wastewater. Chin J Environ Eng 7:2239–2244
Han HQ, Zhu Y (2011) Study on modification and application of bentonite. Inorg Chem Ind 43:5–8
Han YH, Li H, Liu ML, Sang YM, Liang CZ, Chen JQ (2016) Purification treatment of dyes wastewater with a novel micro-electrolysis reactor. Sep Purif Technol 170:241–247. https://doi.org/10.1016/j.seppur.2016.06.058
Jiricek M, Sracek O, Janda V (2007) Removal of chlorinated solvents from carbonate-buffered water by zero-valent iron. Cent Eur J Chem 5:87–106. https://doi.org/10.2478/s11532-006-0071-8
Kruk M, Jaroniec M (2001) Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chem Mater 13(10):3169–3183. https://doi.org/10.1021/cm0101069
Pang WQ, Fan XZ, Xu HX, Li YH (2009) Intensity of spherical agglomerated boron particles. Chin J Energy Mater 17:510–513
Pendyal B, Johns MM, Marshall WE, Ahmedna M, Rao RM (1999) Removal of sugar colorants by granular activated carbons made from binders and agricultural by-products. Bioresour Technol 69:45–51. https://doi.org/10.1016/S0960-8524(98)00172-2
Qi PS, Chen ZL, Li H, Liu YZ (2008) Pretreatment of refractory dyeing wastewater with the micro-electrolysis-Fenton process. J China Univ Min Technol 37:685–689
Ren J, Ma HR, Wang BH, Jiao WJ (2010) Treatment of mother liquor of dyeing wastewater with Fe/C electrolysis-Fenton oxidation-coagulation sedimentation-biochemical process. Chin J Environ Eng 4:1457–1462
Wang DX, Ma WC, Han HJ, Li K, Xu H, Fang F, Hou BL, Jia SY (2016a) Enhanced anaerobic degradation of Fischer-Tropsch wastewater by integrated UASB system with Fe-C micro-electrolysis assisted. Chemosphere 164:14–24. https://doi.org/10.1016/j.chemosphere.2016.08.074
Wang LQ, Yang Q, Wang DB, Li XM, Zeng GM, Li ZJ, Deng YC, Liu J, Yi KX (2016b) Advanced landfill leachate treatment using iron-carbon microelectrolysis-Fenton process: process optimization and column experiments. J Hazard Mater 318:460–467. https://doi.org/10.1016/j.jhazmat.2016.07.033
Wu SQ, Qi YF, Fan CZ, Dai BB, Huang JC, Zhang X, Chen T, Zhou WL, He SB, Gao L (2017) Fe-Ni catalytic micro-electrolysis coupled with biological aerated filter for 2,4,6-trinitrotoluene production wastewater treatment. J Clean Prod 156:679–687. https://doi.org/10.1016/j.jclepro.2017.04.099
Xiong DQ, Wang MH, Bai XY (2005) Study on in-depth treatment of dirty ballast water from oil tankers by ozone oxidation. Tech Equip Environ Pollut Control 6(59–61):83. https://doi.org/10.3969/j.issn.1673-9108.2005.02.015
Xu J, Dong SM, Chai LH, Yang XM (2016a) Preparation research of micro-electrolysis material. Appl Chem Ind 45:1482–1487
Xu XY, Cheng Y, Zhang TT, Ji FY, Xu X (2016b) Treatment of pharmaceutical wastewater using interior micro-electrolysis/Fenton oxidation-coagulation and biological degradation. Chemosphere 152:23–30. https://doi.org/10.1016/j.chemosphere.2016.02.100
Yan DZ, He YF, Wang Y, Wang RM (2009) Modification of bentonite and its application in wastewater treatment. Technol Water Treat 35:25–30
Yang HS (1986) Petroleum transportation and marine protection. China Communications Press, Beijing
Yang ZM, Ma YP, Liu Y, Li QS, Zhou ZY, Ren ZQ (2017) Degradation of organic pollutants in near-neutral pH solution by Fe-C micro-electrolysis system. Chem Eng J 315:403–414. https://doi.org/10.1016/j.cej.2017.01.042
Zhang JS, Chen SJ, Wang XK (2015a) Sustainable treatment of antibiotic wastewater using combined process of microelectrolysis and struvite crystallization. Water Air Soil Pollut 226:1–11. https://doi.org/10.1007/s11270-015-2581-5
Zhang C, Zhou MH, Yu XM, Ma L, Yu FK (2015b) Modified iron-carbon as heterogeneous electro-Fenton catalyst for organic pollutant degradation in near neutral pH condition: characterization, degradation activity and stability. Electrochim Acta 160:254–262. https://doi.org/10.1016/j.electacta.2015.01.092
Zhou X, Wang C, Ji M, Liu J, Han L (2012) Preparation of iron-carbon micro-electrolysis materials for the treatment of industrial wastewater and its application. Ind Water Treat 32:23–26 34
Zou HC, Zhang SX, Luan ZB, Mu Y, Zou DL (2008) Preparation of regular filling for wastewater micro-electrolysis treatment. Environ Prot Chem Ind 28:546–548
Zou DL, Li M, Zou HC, Fan DY, Sun MZ (2010) Treatment of benzene in simulated polluted groundwater by new iron-carbon micro-electrolysis packing. J Jilin Univ (Earth Sci Ed) 40:1441–1445. https://doi.org/10.1360/972010-1322
Zou CL, Jiang W, Liang JY, Su ZM, Yi ML, Zhang S (2017) Study on the preparation and application performance of iron-zinc-carbon micro-electrolysis packing. Ind Saf Environ Prot 43:76–79
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This research was founded by the National Natural Science Foundation of China (41506126, U1809214), Zhejiang public welfare Technology Application Research Project (2016C33054), and Science and Technology Plan Project of Zhou Shan City (2018C21012).
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Kang, M., Chen, Q., Li, J. et al. Preparation and study of a new type of Fe–C microelectrolysis filler in oil-bearing ballast water treatment. Environ Sci Pollut Res 26, 10673–10684 (2019). https://doi.org/10.1007/s11356-019-04480-z
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DOI: https://doi.org/10.1007/s11356-019-04480-z