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Water-soluble ion components of PM10 during the winter-spring season in a typical polluted city in Northeast China

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Abstract

From January 1 to April 22, 2014, an online analyzer for monitoring aerosols and gases (MARGA) was used to measure and analyze water-soluble ions in inhalable particulate matter with a diameter less than 10 μm (PM10) during winter-spring in Shenyang city, China. The results yielded three main findings. (1) During the entire observation period and in seven pollution episodes, SO42−, NO3−, and NH4+ (SNA) accounted for 84.4–93.1% of the total water-soluble ions (TWSIs). TWSIs accounted for 32% of PM10 mass during the entire observation period, and the contribution of TWSIs in PM10 ranged from 33.4–43.1% in the seven pollution episodes. The contribution of TWSIs components increased during the pollution episodes, but certain differences were observed in different pollution episodes. In terms of ionic equilibrium, the total concentration of negative ions was slightly greater than that of positive ions and the difference was 3.1% of the total ion load on average, indicating that local aerosols are mainly neutral. The water-soluble ions show clear diurnal variation with the high concentration around 09:00 for SO42−, NH4+, and Cl− which is consistent with the high heating grade index. (2) Pollution episodes often occur in Northeast China, especially during the winter period. Due to the low temperature in the winter, the local coal burning for heating is one of the main sources of pollution besides vehicle exhaust and industrial pollution, which is supported by the higher NO3−/SO42− ratio in April than that in January to March. Sometimes, under the prevailing wind directions of W and SSW, the long-distance transport of pollutants from the Beijing-Tianjin-Hebei region and Shandong province superimposed on local pollution leads to the most severe pollution, such as Ep3 and Ep5. (3) SO42− concentration is closely related to ambient water vapor pressure (e*), with increase as e* increased depending on the temperature. NO3− concentration showed a linear relationship of excess NH4+, which suggests homogeneous gas-phase reaction of ammonia and nitric acid is possibly an important pathways of nitrate formation in the haze pollution process in Shenyang City. In addition, our results also suggest the nighttime liquid-phase reaction may cause large increases of nitrate in the haze pollution process.

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References

  • An JL, Li Y, Tang YJ, Chen Y, Qu Y (2014) Advances in HONO sources, HONO simulations, and the impacts of the HONO sources on regional or global air quality. China Environ Sci 34(2):273–281 (in Chinese)

    CAS  Google Scholar 

  • Baek BH, Aneja VP (2004) Measurement and analysis of the relationship between ammonia, acid gases, and fine particles in eastern North Carolina. J Air Waste Manage Assoc 54:623–633

    Article  CAS  Google Scholar 

  • Brown SS, Stark H, Ryerson TB, Williams EJ, Nicks DK, Trainer M et al (2003) Nitrogen oxides in the nocturnal boundary layer, simultaneous in situ measurements of NO3, N2O5, NO2, NO, and O3. J Geophys Res Atmos 108(D9):4299

    Article  Google Scholar 

  • Cao GL, An XQ, Zhou CH, Ren YQ, Tu J (2010) Emission inventory of air pollutants in China. China Environ Sci 30:900–906

    CAS  Google Scholar 

  • Chang WL, Bhave PV, Brown SS, Riemer N, Stutz J, Dabdub D (2011) Heterogeneous atmospheric chemistry, ambient measurements, and model calculations of N2O5: a review. Aerosol Sci Technol 45(6):665–695

    Article  Google Scholar 

  • Chen WW, Tong DN, Zhang SC, Dan M, Zhang XL, Zhao HM (2015) Temporal variability of atmospheric particulate matter and chemical composition during a growing season at an agricultural site in northeastern China. J Environ Sci 38(38):133–141

    Article  Google Scholar 

  • Cheng YG, Zheng C, Wei Q, Mu B, Zheng Z, Wang M et al (2016) Reactive nitrogen chemistry in aerosol water as a source of sulfate during haze events in China. Sci Adv 2(12):e1601530

  • Cui Y, Zhao CY, Zhou XY, Ao X, Wang T, Li Q et al (2016) Climatic characteristics of haze days in northeast of China over the past 50 years. China J Environ Sci 36(6):1630–1637

    Google Scholar 

  • Finlayson-Pitts BJ, Pitts JN (1997) Tropospheric air pollution: ozone, airborne toxics, polycyclic aromatic hydrocarbons, and particles. Science 276:1045–1051

    Article  CAS  Google Scholar 

  • Finlayson-Pitts BJ, Wingen LM, Sumner AL, Syomin D, Ramazan KA (2003) The heterogeneous hydrolysis of NO2 in laboratory systems and in outdoor and indoor atmospheres: integrated mechanism. Phys Chem Chem Phys 5:223–242

    Article  CAS  Google Scholar 

  • Guo XM, Hao JM, Duan L, Yi HH, Li XH (2006) Characteristics of water soluble ions emitted from large coal-fired power plant boilers. J Tsinghua Univ (Science Tech) 46(12):1991–1994

    CAS  Google Scholar 

  • Guo H, Weber RJ, Nenes A (2017) High levels of ammonia do not raise fine particle pH sufficiently to yield nitrogen oxide-dominated sulfate production. Sci Rep 7:12109

    Article  Google Scholar 

  • Han LH, Chen YY, Jia L, Cheng SY, Xu YF, Ning HB et al (2014) Heterogeneous reactions of NO2 on MgO particle surfaces. Sci China Chem 44(12):2004–2012

    CAS  Google Scholar 

  • He H, Wang YS, Ma QX et al (2014) Corrigendum: mineral dust and NOx promote the conversion of SO2 to sulfate in heavy pollution days. Sci Reports 4:6092

    Article  CAS  Google Scholar 

  • Hong Y, Ma YJ, Wang XQ, Zhang YH, Lu ZY, Wang YF et al (2013) External influences in the haze episode in the central city group of Liaoning: a case study (in Chinese). Acta Sci Circumst 33(8):2115–2122

    CAS  Google Scholar 

  • Hong Y, Li CL, Li XL, Ma YJ, Wang XQ, Zhang YH et al (2018) Analysis of compositional variation and source characteristics of water-soluble ions in PM2.5 during several winter-haze pollution episodes in Shenyang, China. Atmosphere 9:280. https://doi.org/10.3390/atmos9070280

    Article  Google Scholar 

  • Hu WW, Hu M, Yuan B, Jimenez JK, Tang Q, Peng JF et al (2013) Insights on organic aerosol aging and the influence of coal combustion at a regional receptor site of central eastern China. Atmos Chem Phys 13(19):10095–10112

    Article  Google Scholar 

  • Hu YQ, Ma ZH, Feng YJ, Wang C, Chen YY, He M (2015) Emission characteristics of water-soluble ions in fumes of coal fired boilers in Beijing. Environ Sci 36(6):966–1974

    Google Scholar 

  • Huang X, Liu Z, Zhang J, Wen T, Ji D, Wang Y (2016) Seasonal variation and secondary formation of size-segregated aerosol water-soluble inorganic ions during pollution episodes in Beijing. Atmos Res 168:70–79

    Article  CAS  Google Scholar 

  • Intergovernmental Panel on Climate Change (IPCC) (1995) Climate change. Cambridge University Press, New York

    Google Scholar 

  • Jacobson MC, Hansson HC, Noone KJ, Charlson RJ (2000) Organic atmospheric aerosols: review and state of the science. Rev Geophys 38:267–294. https://doi.org/10.1029/1998RG000045

    Article  CAS  Google Scholar 

  • Jiang Y, He GY, Luo B, Chen JW, Wang B, Du YS et al (2009) Pollution characteristics of inorganic water-soluble ions in atmospheric particulate matter in Chengdu plain. Environ Sci 37(8):2863–2870

    Google Scholar 

  • Jimenez JL, Canagaratna MR, Donahue NM, Prevot AS, Zhang Q, Kroll JH et al (2009) Evolution of organic aerosols in the atmosphere. Science 11 326(5959):1525–1529. https://doi.org/10.1126/science.1180353

    Article  CAS  Google Scholar 

  • Jongejan PAC, Bai Y, Veltkamp AC, Wyers GP, Slanina J (1997) An automated field instrument for the determination of acidic gases in air. Int J Environ Anal Chem 66(4):241–251. https://doi.org/10.1080/03067319708028367

    Article  CAS  Google Scholar 

  • Khlystov A, Wyers GP, Slanina J (1995) The steam-jet aerosol collector. Atmos Environ 29(17):2229–2234. https://doi.org/10.1016/1352-2310(95)00180-7

    Article  CAS  Google Scholar 

  • Li CL, Bosch C, Kang SC, Andersson A, Chen PF, Zhang QG, Cong Z, Chen B, Qin D, Gustafsson Ö (2016) Sources of black carbon to the Himalayan–Tibetan Plateau glaciers. Nat Commun 7:12574. https://doi.org/10.1038/ncomms12574

    Article  CAS  Google Scholar 

  • Mariani LR, Mello W (2007) PM2.5–10, PM2.5 and associated water-soluble inorganic species at a coastal urban site in the metropolitan region of Rio de Janeiro. AtmosEnviron 41:2887–2892. https://doi.org/10.1016/j.atmosenv.2006.12.009

    Article  CAS  Google Scholar 

  • Masiol M, Benetello F, Harrison RM, Formenton G, De Gaspari F, Pavoni B (2015) Spatial, seasonal trends and transboundary transport of PM2.5 inorganic ions in the Veneto region (northeastern Italy). AtmosEnviron 117:19–31. https://doi.org/10.1016/j.atmosenv.2015.06.044

    Article  CAS  Google Scholar 

  • McLaren R, Salmon RA, Liggio J, Hayden KL, Anlauf KG, Leaitch WR (2004) Nighttime chemistry at a rural site in the lower Fraser Valley. Atmos Environ 38(34):5837–5848

    Article  CAS  Google Scholar 

  • Meng YJ, Wang SY, Zhao XF (2000) An analysis of air pollution and weather conditions during heavy fog days in Beijing area (in Chinese). Weather 26(3):40–43

    Google Scholar 

  • Miao HY, Wen TX, Wang L, Xu H (2016) Characteristics of water-soluble inorganic ions in atmospheric aerosols in Shenyang. J Environ Sci 37(6):2017–2024

    Google Scholar 

  • Observation and Forecast Level of Haze (2010) Standard of meteorological industry of the People’s Republic of China QX/T 113–2010. China Meteorological Administration, Beijing, China

    Google Scholar 

  • Pathak RK, Chan CK (2005) Inter-particle and gas-particle interactions in sampling artifacts of PM2.5in filter-based samplers. Atmos Environ 39:1597–1607

    CAS  Google Scholar 

  • Pathak RK, Yao XH, Chan CK (2004) Sampling artifacts of acidity and ionic species in PM2.5. Environ Sci Technol 38:254–259

    Article  CAS  Google Scholar 

  • Pathak RK, Wu WS, Wang T (2009) Summertime PM2.5 ionic species in four major cities of China: nitrate formation in an ammonia-deficient atmosphere. Atmos Chem Phys 9(5):1711–1722

    Article  CAS  Google Scholar 

  • Platt U, Perner D, Harris G et al (1980) Observations of nitrous acid in an urban atmosphere by differential optical absorption. Nature 285:312–314

    Article  CAS  Google Scholar 

  • Sun YL, Zhuang GS, Tang AH, Wang Y, An ZS (2006) Chemical characteristics of PM2.5 and PM10 in haze-fog episodes in Beijing. EnvironSci Technol 40:3148–3155

    Article  CAS  Google Scholar 

  • Sun YL, Wang ZF, Fu PQ, Jiang Q, Yang T, Li J, Ge X (2013) The impact of relative humidity on aerosol composition and evolution processes during wintertime in Beijing, China. Atmos Environ 77:927–934. https://doi.org/10.1016/j.atmosenv.2013.06.019

  • Sun YL, Jiang Q, Wang ZF, Fu PQ, Jie Li YT et al (2014) Investigation of the sources and evolution processes of severe haze pollution in Beijing in January 2013. J Geophys Res 119:4380–4398. https://doi.org/10.1002/2014JD021641

    Article  Google Scholar 

  • Sun YL, Wang ZF, Du W, Zhang Q, Wang QQ, Fu PQ et al (2015) Long-term real-time measurements of aerosol particle composition in Beijing, China, seasonal variations, meteorological effects, and source analysis. Atmos Chem Phys 15(17):10149–10165

    Article  CAS  Google Scholar 

  • Tan JH, Duan JC, Chen DH, Wang XH, Guo SJ, Bi XH, Sheng GY, He KB, Fu JM (2009) Chemical characteristics of haze during summer and winter in Guangzhou. Atmos Res 94(2):238–245

    Article  CAS  Google Scholar 

  • Trebs I, Meixner FX, Slanma J, Otjes R, Jongejan P, Andreae MO (2004) Real-time measurements of ammonia, acid trace gases and water-soluble inorganic aerosol species at a rural site in the Amazon Basin. Atmos Chem Phys 4(1):967–987. https://doi.org/10.5194/acpd-4-1203-2004

    Article  CAS  Google Scholar 

  • Wang XQ, Yang T, Wang ZF (2011) Impact of dust-haze episode from one air pollution control region to the other: one case study (in Chinese). Clim Environ Res 16(6):690–696

    Google Scholar 

  • Xu H, Chen JQ, He DT, Cheng P, Wang W, Zhu L et al (2017) Climatic characteristics of haze weather during heating periods from 1980 to 2015 at Shenyang region (in Chinese). J Meteor Environ 33(2):87–94. https://doi.org/10.3969/j.issn.1673-503X.2017.01.011

    Article  Google Scholar 

  • Yang T, Yan PZ, Wang ZF, Li JJ, Zhang WD, Yao XF et al (2017) Evaluation and formation mechanism of a severe air pollution in Northeast China in November 2015 (in Chinese). ActaScien Circum 37(1):44–51. https://doi.org/10.13671/j.hjkxxb.2016.0160

    Article  CAS  Google Scholar 

  • Zhang ZF, Zhu T, Zhao DF, Hong-jin L (2009) Heterogeneous reactions of NO2 on mineral particle surfaces. Prog Chem Z1:282–287

    Google Scholar 

  • Zhang RH, Li Q, Zhang RN (2014) Meteorological conditions for the persistent severe fog and haze event over eastern China in January 2013. China Earth Sci 57:26–35

  • Zhang YJ, Tang LL, Wang Z, Yu HX, Sun YL, Liu D, Qin W, Canonaco F, Prévôt ASH, Zhang HL, Zhou HC (2015) Insights into characteristics, sources, and evolution of submicron aerosols during harvest seasons in the Yangtze River delta region, China. Atmos Chem Phys 15(3):1331–1349

    Article  Google Scholar 

  • Zhao XJ, Zhao PS, Xu J, Meng W, Pu WW, Dong F et al (2013) Analysis of a winter regional haze event and its formation mechanism in the North China Plain. Atmos Chem Phys 13:5685–5696

    Article  Google Scholar 

  • Zhou BH, Wang GH, Zhang CZ, Shi WG (2013) Pollutions characteristics of water-souble ions of fine particle during spring festival over Xi’an southern. Environ Chem 32(3):498–504

    CAS  Google Scholar 

  • Zhu T, Shang J, Zhao DF (2010) The roles of heterogeneous chemical processes in the formation of an air pollution complex and gray haze. Sci Sin Chim 40(12):1731–1740 (in Chinese)

    Article  Google Scholar 

Download references

Funding

This research was funded by the National Key R&D Program of China (2017YFC021230101); the Institute of the Atmospheric Environment, China Meteorological Administration, Shenyang (2017SYIAEMS6); the Institute of Atmospheric Physics, Chinese Academy of Sciences (LAPC-KF-2017-02); the Fundamental Research Funds of the Scientific Research Special Fund for Public Service (GYHY201406031); the Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Special Forecast Core Business Development Projects (CMAHX20160307); a Scientific and Technological Research Project of Liaoning Meteorological Bureau (201502); and the National Natural Science Foundation of China (41375146).

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Authors and Affiliations

  1. Institute of Atmospheric Environment, China Meteorological Administration, Shenyang, 110166, China

    Ye Hong, Yanjun Ma, Yunhai Zhang, Xiaolan Li, Deping Zhou,  Yangfeng Wang & Ningwei Liu

  2. State Key Laboratory of Severe Weather/Key Laboratory of Atmospheric Chemistry of China Meteorological Administration, Chinese Academy of Meteorological Sciences, Beijing, 100081, China

    Junying Sun

  3. Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing, 100085, China

    Chaoliu Li

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  1. Ye Hong
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  2. Yanjun Ma
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Correspondence to Junying Sun.

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Hong, Y., Ma, Y., Sun, J. et al. Water-soluble ion components of PM10 during the winter-spring season in a typical polluted city in Northeast China. Environ Sci Pollut Res 26, 7055–7070 (2019). https://doi.org/10.1007/s11356-019-04199-x

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