Manganese dioxide nanoparticles/activated carbon composite as efficient UV and visible-light photocatalyst

Abstract

Manganese dioxide nanoparticles/activated carbon (MnO2/AC) composites and manganese dioxide nanoparticles (MnO2 NPs) are prepared through chemical reduction method. Morphological study shows that MnO2 NPs had cylindrical and spherical shape. The morphological study also revealed that MnO2 NPs were well dispersed on AC while neat Mn NPs present both in dispersed and in agglomerated form. The FT-IR study confirms the synthesis of MnO2 NPs. Zetasizer study presented that the Mn NPs had uniform size and below 100 nm in size and had zeta potential of − 20 mV, which represent its stability in the suspension form. The synthesized Mn/AC composite and Mn NPs were utilized as photocatalysts for the photodegradation of Congo red (CR) dye. The degradation study shows that MnO2/AC composite degraded CR dye more efficiently than MnO2 NPs under UV and normal light irradiation. The efficient degradation of dye by Mn/AC composite is due to the synergistic effect between dye adsorption on AC and rapid photodegradation by supported MnO2 NPs. The results revealed that Mn/AC composite degraded about 98.53% of CR dye within 5 min while MnO2 NPs degraded 66.57% of dye within the same irradiation time. The recycled catalyst also significantly degraded dye which verifies its sustainability. The effect of catalyst dosage and initial dye concentration was conducted. The degradation rate of dye was found drastically faster in tap water (in presence of catalyst), which might be due to the presence of various mineral ions in the tap water.

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References

  1. Akpan UG, Hameed BH (2009) Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: a review. J Hazard Mater 170:520–529

    Article  CAS  Google Scholar 

  2. Dang TD, Le TTH, Hoang TBT, Mai TT (2015) Synthesis of nanostructured manganese oxides based materials and application for supercapacitor. Adv Nat Sci Nanosci Nanotechnol 6:025011

    Article  CAS  Google Scholar 

  3. Erdemoglu S, Aksu SK, Sayılkan F, Izgi B, Asilturk M, Sayilkan H, Frimmel F, Gucer S (2008) Photocatalytic degradation of Congo red by hydrothermally synthesized nanocrystalline TiO2 and identification of degradation products by LC–MS. J Hazard Mater 155:469–476

    Article  CAS  Google Scholar 

  4. Feng L, Xuan Z, Zhao H, Bai Y, Guo J, Su C, Chen X (2014) MnO2 prepared by hydrothermal method and electrochemical performance as anode for lithium-ion battery. Nanoscale Res Lett 9:290–297

    Article  CAS  Google Scholar 

  5. Ganeshan S, Ramasundari P, Elangovan A, Arivazhagan G, Vijayalakshmi R (2017) Synthesis and characterization of MnO2 nanoparticles: study of structural and optical properties. Int J Sci Res Phys Appl Sci 5:5–8

    Google Scholar 

  6. Gong K, Hu Q, Yao L, Li M, Sun D, Shao Q, Qiu B, Guo Z (2018) Ultrasonic pretreated sludge derived stable magnetic active carbon for Cr(VI) removal from wastewater. ACS Sustain Chem Eng 6:7283–7291

    Article  CAS  Google Scholar 

  7. Hamukwaya SL, Zengying Z, Ning W, Hu L, Ahmad U, Jiaoxia Z, Tingting W, Zhanhu G (2019) Enhanced photocatalytic activity of B, N-Codoped TiO2 by a new molten nitrate process. J Nanosci Nanotechnol 19:839–949

    Article  CAS  Google Scholar 

  8. Huang J, Cao Y, Shao Q, Peng X, Guo Z (2017) Magnetic Nanocarbon adsorbents with enhanced hexavalent chromium removal: morphology dependence of Fibrillar vs particulate structures. Ind Eng Chem Res 56:10689–10701

    Article  CAS  Google Scholar 

  9. Huang J, Li Y, Cao Y, Peng F, Cao Y, Shao Q, Liu H, Guo Z (2018) Hexavalent chromium removal over magnetic carbon nanoadsorbents: synergistic effect of fluorine and nitrogen co-doping. J Mater Chem A 6:13062–13074

    Article  CAS  Google Scholar 

  10. Ioannidou O, Zabaniotou A (2007) Agricultural residues as precursors for activated carbon production-a review. Renew Sust Energ Rev 11:1966–2005

    Article  CAS  Google Scholar 

  11. Jaganyi D, Altaf M, Wekesa I (2013) Synthesis and characterization of whisker-shaped MnO2 nanostructure at room temperature. Appl Nanosci 3:329–333

    Article  CAS  Google Scholar 

  12. Koo Y, Littlejohn G, Collins B, Shanov YYVN, Schulz M, Pai D, Sankar J (2014) Synthesis and characterization of ag-TiO2-CNT nanoparticle composites with high photocatalytic activity under artificial light. Composites Part B 57:105–111

    Article  CAS  Google Scholar 

  13. Li Z, Wang B, Qin X, Wang Y, Liu C, Shao Q, Wang N, Zhang J, Shen C, Guo Z (2018) Superhydrophobic/Superoleophilic polycarbonate/carbon nanotubes porous monolith for selective oil adsorption from water. ACS Sustain Chem Eng 6:13747–13755. https://doi.org/10.1021/acssuschemeng.8b01637

    Article  CAS  Google Scholar 

  14. Lin C, Hu L, Cheng C, Sun K, Guo X, Shao Q, Li J, Wang N, Guo Z (2018) Nano-TiNb2O7/carbon nanotubes composite anode for enhanced lithium-ion storage. Electrochim Acta 260:65–72

    Article  CAS  Google Scholar 

  15. Liu S, Cai Y, Cai X, Li H, Zhang F, Mu Q, Liu Y, Wang Y (2013) Catalytic photodegradation of Congo red in aqueous solution by ln(OH)3 (ln = Nd, Sm, Eu, Gd, Tb, and Dy) nanorods. Appl Catal A Gen 453:45–53

    Article  CAS  Google Scholar 

  16. Mamba G, Mbianda XY, Mishra AK (2015) Photocatalytic degradation of the diazo dye naphthol blue black in water using MWCNT/Gd,N,S-TiO2 nanocomposites under simulated solar light. J Environ Sci 33:219–228

    Article  CAS  Google Scholar 

  17. Melghit K, Al-Rabaniah SS (2006) Photodegradation of Congo red under sunlight catalysed by nanorod rutile TiO2. J Photochem Photobiol A Chem 184:331–334

    Article  CAS  Google Scholar 

  18. Mohamed A, El-Sayed R, Osman TA, Toprak MS, Muhammed M, Uheida A (2016) Composite nanofibers for highly efficient photocatalytic degradation of organic dyes from contaminated water. Environ Res 145:18–25

    Article  CAS  Google Scholar 

  19. Padikkaparambil S, Narayanan B, Yaakob Z, Viswanathan S, Tasirin S (2013) Au/TiO2 reusable Photocatalysts for dye degradation. Int J Photoenergy 752605(2013):1–10

    Article  CAS  Google Scholar 

  20. Pan D, Ge S, Zhang X, Mai X, Li S, Guo Z (2018a) Synthesis and photoelectrocatalytic activity of In2O3 hollow microspheres via a bio-template route using yeast templates. Dalton Trans 47:708–715

    Article  CAS  Google Scholar 

  21. Pan D, Ge S, Zhao J, Shao Q, Guo L, Zhang X, Lin J, Xu G, Guo Z (2018b) Synthesis, characterization and photocatalytic activity of mixed-metal oxides derived from NiCoFe ternary layered double hydroxides. Dalton Trans 47:9765–9778

    Article  CAS  Google Scholar 

  22. Pouretedal HR, Kiyani M (2014) Photodegradation of 2-nitrophenol catalyzed by CoO, CoS and CoO/CoS nanoparticles. J Iran Chem Soc 11:271–277

    Article  CAS  Google Scholar 

  23. Reza KM, Kurny ASW, Gulshan F (2017) Parameters affecting the photocatalytic degradation of dyes using TiO2: a review. Appl Water Sci 7:1569–1578

    Article  CAS  Google Scholar 

  24. Rout L, Rengasamy P, Ekka B, Kumar A, Dash P (2015) Supported bimetallic AgSn nanoparticle as an efficient Photocatalyst for degradation of methylene blue dye. NANO 10:1550059

    Article  CAS  Google Scholar 

  25. Sadiq M, Khan M, Numan M, Aman R, Hussain S, Ahmad MS, Sadiq S, Zia MA, Rashid HU, Ali R (2017) Tuning of activated carbon for solvent-free oxidation of cyclohexane. J Chem 2017:1–8. https://doi.org/10.1155/2017/5732761

    CAS  Article  Google Scholar 

  26. Saeed K, Khan I, Park SY (2015) TiO2/amidoxime-modified polyacrylonitrile nanofibers and its application for the photodegradation of methyl blue in aqueous medium. Desalin Water Treat 54:3146–3151

    Article  CAS  Google Scholar 

  27. Saeed K, Khan I, Ahmad Z, Khan B (2018) Preparation, analyses and application of cobalt–manganese oxides/nylon 6,6 nanocomposites. Polym Bull 75:4657–4669. https://doi.org/10.1007/s00289-018-2292-3

    Article  CAS  Google Scholar 

  28. Sangami G, Dharmaraj N (2012) UV–visible spectroscopic estimation of photodegradation of rhodamine-B dye using tin(IV) oxide nanoparticles. Spectrochim Acta A Mol Biomol Spectrosc 97:847–852

    Article  CAS  Google Scholar 

  29. Shivaraju HP, Midhun G, Kumar KMA, Pallavi S, Pallavi N, Behzad S (2017) Degradation of selected industrial dyes using mg-doped TiO2 polyscales under natural sun light as an alternative driving energy. Appl Water Sci 7:3937–3948

    Article  CAS  Google Scholar 

  30. Soltani RDC, Haghighat Z (2016) Visible light photocatalysis of a textile dye over ZnO nanostructures covered on natural diatomite. Turk J Chem 40:454–466

    Article  CAS  Google Scholar 

  31. Song B, Wang T, Sun H, Shao Q, Zhao J, Song K, Hao L, Wang L, Guo Z (2017) Two-step hydrothermally synthesized carbon nanodots/WO3 photocatalysts with enhanced photocatalytic performance. Dalton Trans 46:15769–15777

    Article  CAS  Google Scholar 

  32. Su T, Shao Q, Qin Z, Guo Z, Wu Z (2018) Role of interfaces in two-dimensional Photocatalyst for water splitting. ACS Catal 8:2253–2276

    Article  CAS  Google Scholar 

  33. Velusamy P, Lakshmi G (2017) Enhanced photocatalytic performance of (ZnO/CeO2)-b-CD system for the effective decolorization of rhodamine B under UV light irradiation. Appl Water Sci 7:4025–4036

    Article  CAS  Google Scholar 

  34. Wang H, Xie C, Zhang W, Cai S, Yang Z, Gui Y (2007) Comparison of dye degradation efficiency using ZnO powders with various size scales. J Hazard Mater 141:645–652

    Article  CAS  Google Scholar 

  35. Wang C, Murugadoss V, Kong J, He Z, Mai X, Shao Q, Chen Y, Guo L, Liu C, Angaiah S, Guo Z (2018) Overview of carbon nanostructures and nanocomposites for electromagnetic wave shielding. Carbon 140:696–733

    Article  CAS  Google Scholar 

  36. Wu ZC, Zhang Y, Tao TX, Zhang L, Fong H (2010) Silver nanoparticles on amidoxime fibers for photo-catalytic degradation of organic dyes in waste water. Appl Surf Sci 257:1092–1097

    Article  CAS  Google Scholar 

  37. Wu T, Shao Q, Ge S, Bao L, Liu Q (2016) The facile preparation of novel magnetic zirconia composites with the aid of carboxymethyl chitosan and their efficient removal of dye. RSC Adv 6:58020–58027

    Article  CAS  Google Scholar 

  38. Yang Z, Hao X, Chen S, Ma Z, Wang W, Wang C, Yue L, Sun H, Shao Q, Murugadoss V, Guo Z (2019) Long-term antibacterial stable reduced graphene oxide nanocomposites loaded with cuprous oxide nanoparticles. J Colloid Interface Sci 533:13–23

    Article  CAS  Google Scholar 

  39. Zada N, Khan I, Saeed K (2017) Synthesis of multiwalled carbon nanotubes supported manganese and cobalt zinc oxides nanoparticles for the photodegradation of malachite green. Sep Sci Technol 52:1477–1485

    Article  CAS  Google Scholar 

  40. Zhang D, Zeng F (2010) Structural, photochemical and photocatalytic properties of zirconium oxide doped TiO2 nanocrystallites. Appl Surf Sci 257:867–871

    Article  CAS  Google Scholar 

  41. Zhang L, Qin M, Yu W, Zhang Q, Xie H, Sun Z, Shao Q, Guo X, Hao L, Zheng Y, Guo Z (2017a) Heterostructured TiO2/WO3 nanocomposites for photocatalytic degradation of toluene under visible light. J Electrochem Soc 164:H1086–H1090

    Article  CAS  Google Scholar 

  42. Zhang L, Yu W, Han C, Guo J, Zhang Q, Xie H, Shao Q, Sun Z, Guo Z (2017b) Large scaled synthesis of Heterostructured electrospun TiO2/SnO2 nanofibers with an enhanced photocatalytic activity. J Electrochem Soc 164:H651–H656

    Article  CAS  Google Scholar 

  43. Zhang Y, Qian L, Zhao W, Li X, Huang X, Mai X, Wang Z, Shao Q, Yan X, Guo Z (2018) Highly efficient Fe-N-C nanoparticles modified porous graphene composites for oxygen reduction reaction. J Electrochem Soc 165:H510–H516

    Article  CAS  Google Scholar 

  44. Zhao J, Ge S, Liu L, Shao Q, Mai X, Zhao CX, Hao L, Wu T, Yu Z, Guo Z (2018a) Microwave Solvothermal fabrication of zirconia hollow microspheres with different morphologies using pollen templates and their dye adsorption removal. Ind Eng Chem Res 57:231–241

    Article  CAS  Google Scholar 

  45. Zhao J, Ge S, Pan D, Shao Q, Lin J, Wang Z, Hu Z, Wu T, Guo Z (2018b) Solvothermal synthesis, characterization and photocatalytic property of zirconium dioxide doped titanium dioxide spinous hollow microspheres with sunflower pollen as bio-templates. J Colloid Interface Sci 529:111–121

    Article  CAS  Google Scholar 

  46. Zhao B, Shao Q, Hao L, Zhang L, Liu Z, Zhang B, Ge S, Guo Z (2018c) Yeast-template synthesized Fe-doped cerium oxide hollow microspheres for visible photodegradation of acid orange 7. J Colloid Interface Sci 511:39–47

    Article  CAS  Google Scholar 

  47. Zhua H, Jiang R, Xiao L, Chang Y, Guan Y, Li X, Zeng G (2009) Photocatalytic decolorization and degradation of Congo red on innovative crosslinked chitosan/nano-CdS composite catalyst under visible light irradiation. J Hazard Mater 169:933–940

    Article  CAS  Google Scholar 

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Correspondence to Khalid Saeed.

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Responsible editor: Suresh Pillai

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Khan, I., Sadiq, M., Khan, I. et al. Manganese dioxide nanoparticles/activated carbon composite as efficient UV and visible-light photocatalyst. Environ Sci Pollut Res 26, 5140–5154 (2019). https://doi.org/10.1007/s11356-018-4055-y

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Keywords

  • Manganese dioxide, nanoparticles
  • Activated carbon
  • Photodegradation
  • Congo red
  • Photocatalyst