Abstract
Textile wastewater contains methylene blue (MB), a major coloring agent in textile industry. Activated carbon (AC) is the most widely used adsorbent in removing dyes from industrial wastewater. However, high production cost of AC is the major obstacle for its wide application in dye wastewater treatment. In this study, a sustainable approach in synthesizing graphenic adsorbent from palm oil mill effluent (POME), a potential carbonaceous source, has been explored. This new development in adsorption technique is considered as green synthesis as it does not require any binder during the synthesis process, and at the same time, it helps to solve the bottleneck of palm oil industry as POME is the main cause contributed to Malaysia’s water pollution problem. The synthesized GSC was characterized through XRD, FESEM, and EDX. The adsorption performance of the synthesized GSC was evaluated by adsorption of MB. The effect of initial concentration of synthetic MB solution (1–20 mg/L) and weight of GSC (5–20 g) were investigated. A remarkable change in color of synthetic MB solution from blue to crystal clear was observed at the end of adsorption study. High efficiency of the synthesized GSC for dye-contaminated wastewater treatment is concluded.
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References
Batsanov SS (2001) Van der Waals radii of elements. Inorg Mater 37:871–885. https://doi.org/10.1023/A:10116257
Dávila-Jiménez MM, Elizalde-González MP, Peláez-Cid AA (2005) Adsorption interaction between natural adsorbents and textile dyes in aqueous solution. Colloids Surf A Physicochem Eng Asp 254:107–114. https://doi.org/10.1016/j.colsurfa.2004.11.022
Dubey R, Bajpai J, Bajpai AK (2015) Green synthesis of graphene sand composite (GSC) as novel adsorbent for efficient removal of Cr (VI) ions from aqueous solution. J Water Process Eng 5:83–94. https://doi.org/10.1016/j.jwpe.2015.01.004
Foo KY, Hameed BH (2010) An overview of dye removal via activated carbon adsorption process. Desalin Water Treat 19:255–274. https://doi.org/10.5004/dwt.2010.1214
Gadekar MR, Ahammed MM (2016) Coagulation/flocculation process for dye removal using water treatment residuals: modelling through artificial neural networks. Desalin Water Treat 57:26392–26400. https://doi.org/10.1080/19443994.2016.1165150
Gao J, Kong D, Wang Y, Wu J, Sun S, Xu P (2013) Production of mesoporous activated carbon from tea fruit peel residues and its evaluation of methylene blue removal from aqueous solutions. Bioresources 8:2145–2160. https://doi.org/10.15376/biores.8.2.2145-2160
Ghasemi N, Mirali S, Ghasemi M, Mashhadi S, Tarraf MH (2012) Adsorption isotherms and kinetics studies for the removal of Pb(II) from aqueous solutions using low-cost adsorbent. Paper presented at the 2012 International Conference on Environment Science and Engieering, Singapoore
Gobi K, Mashitah MD, Vadivelu VM (2011) Adsorptive removal of methylene blue using novel adsorbent from palm oil mill effluent waste activated sludge: equilibrium, thermodynamics and kinetic studies. Chem Eng J 171:1246–1252. https://doi.org/10.1016/j.cej.2011.05.036
Gupta VK, Mittal A, Krishnan L, Mittal J (2006) Adsorption treatment and recovery of the hazardous dye, brilliant blue FCF, over bottom ash and de-oiled soya. J Colloid Interface Sci 293:16–26. https://doi.org/10.1016/j.jcis.2005.06.021
Gupta SS, Sreeprasad TS, Maliyekkal SM, Das SK, Pradeep T (2012) Graphene from sugar and its application in water purification. ACS Appl Mater Interfaces 4:4156–4163. https://doi.org/10.1021/am300889u
Hakam A, Rahman IA, Jamil MSM, Othaman R, Amin MCIM, Lazim AM (2015) Removal of methylene blue dye in aqueous solution by sorption on a bacterial-g-poly-(acrylic acid) polymer network hydrogel. Sains Malaysiana 44:827–834. https://doi.org/10.17576/jsm-2015-4406-08
Hassaan MA, El Nemr A, Madkour FF (2017) Testing the advanced oxidation processes on the degradation of direct blue 86 dye in wastewater. Egypt J Aquat Res 43:11–19. https://doi.org/10.1016/j.ejar.2016.09.006
Karagöz S, Tay T, Ucar S, Erdem M (2008) Activated carbons from waste biomass by sulfuric acid activation and their use on methylene blue adsorption. Bioresour Technol 99:6214–6222. https://doi.org/10.1016/j.biortech.2007.12.019
Krishna RH, Swamy AVVS (2012) Investigation on the effect of particle size and adsorption kinetics to removal of hexavalent chromium from the aqueous solutions using low cost sorbent. Eur Chem Bull 1:258–262. https://doi.org/10.17628/ecb.2012.1.258-262
Lau Y-Y, Wong Y-S, Teng T-T, Morad N, Rafatullah M, Ong S-A (2015) Degradation of cationic and anionic dyes in coagulation-flocculation process using bi-functionalized silica hybrid with aluminum-ferric as auxiliary agent. RSC Adv 5:34206–34215. https://doi.org/10.1039/c5ra01346a
Lazar P, Karlický F, Jurečka P, Kocman M, Otyepková E, Šafářová K, Otyepka M (2013) Adsorption of small organic molecules on graphene. J Am Chem Soc 135:6372–6377. https://doi.org/10.1021/ja403162r
Mohammed RR, Ketabchi MR, McKay G (2014) Combined magnetic field and adsorption process for treatment of biologically treated palm oil mill effluent (POME). Chem Eng J 243:31–42. https://doi.org/10.1016/j.cej.2013.12.084
Simoncic P, Armbruster T (2005) Cationic methylene blue incorporated into zeolite mordenite-Na: a single crystal X-ray study. Microporous Mesoporous Mater 81:87–95. https://doi.org/10.1016/j.micromeso.2005.01.019
Soares GM, Costa-Ferreira M, Pessoa de Amorim MT (2001) Decolorization of an anthraquinone-type dye using a laccase formulation. Bioresour Technol 79:171–177. https://doi.org/10.1016/S0960-8524(01)00043-8
Soon AN, Hameed BH (2011) Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process. Desalination 269:1–16. https://doi.org/10.1016/j.desal.2010.11.002
Wang Z, Xue M, Huang K, Liu Z (2011) Textile dyeing wastewater treatment. In: Advances in treating textile effluent. InTech, pp 92–116
Wawrzkiewicz M (2012) Anion exchange resins as effective sorbents for acidic dye removal from aqueous solutions and wastewaters. Solvent Extr Ion Exch 30:507–523. https://doi.org/10.1080/07366299.2011.639253
Zhu M-X, Lee L, Wang H-H, Wang Z (2007) Removal of an anionic dye by adsorption/precipitation processes using alkaline white mud. J Hazard Mater 149:735–741. https://doi.org/10.1016/j.jhazmat.2007.04.037
Funding
The authors wish to gratefully acknowledge the funding for this work by Dana Penyelidikan Strategik (KRA-2017-016) and Geran Universiti Penyelidikan (GUP-2017-098).
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Responsible editor: Guilherme L. Dotto
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Teow, Y.H., Nordin, N.I. & Mohammad, A.W. Green synthesis of palm oil mill effluent-based graphenic adsorbent for the treatment of dye-contaminated wastewater. Environ Sci Pollut Res 26, 33747–33757 (2019). https://doi.org/10.1007/s11356-018-2189-6
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DOI: https://doi.org/10.1007/s11356-018-2189-6