Abstract
The presence and enrichment of heavy metals in dust depositions have been recognized as an emerging environmental health issues in the urban and industrial areas. In this study, the deposition of some metals was found in Qom, a city located in a semi-desert area in Iran that is surrounded by industrial areas. Dust deposition samples were collected using five sampling stations during a year. Dust samples were digested applying acidic condition and then, the metal content was analyzed using inductively coupled plasma technology (ICP-OES). Comparative results showed the following order, from the maximum to the minimum concentration (mg/kg dust) of elements: Ca > Al > Fe > Mg > Ti > Si > K > B > Sr > Mn > P > Ba > Cr > Zn > Ni > Sn > Pb > V > Na > Cu > Co > U > Li > Ce > Ag. The differences among the average concentrations of metals in the five stations were not significant (p value > 0.05). The average concentration of some metals increased significantly during cold seasons. In this study, the cluster analysis (CA) and princicipal component analysis (PCA) were applied, and relationships among some elements in different clusters were found. In addition, the geo-accumulation and enrichment analysis revealed that the following metals had been enriched more than the average values: boron, silver, tin, uranium, lead, zinc, cobalt, chromium, lithium, nickel, strontium, and coper. The presence of thermal power plant, pesticide manufacturing plants, publishing centers, traffic jam, and some industrial areas around the city has resulted in the enrichment of some metals (particularly in cold seasons with atmospheric stable conditions) in dust deposition.
Similar content being viewed by others
References
ASTM (2004) Standard test method for collection and measurement of dustfall (settleable particulate matter)
Azarakhshi M, Mahdavi M, Arzani H, Ahmadi H (2012) Assessment of the Palmer drought severity index in arid and semi arid rangeland: (case study: Qom province, Iran). Desert 16:77–86
Bellis DJ, Satake K, Inagaki M, Zeng J, Oizumi T (2005) Seasonal and long-term change in lead deposition in central Japan: evidence for atmospheric transport from continental Asia. Sci Total Environ 341:149–158
Boonyatumanond R, Murakami M, Wattayakorn G, Togo A, Takada H (2007) Sources of polycyclic aromatic hydrocarbons (PAHs) in street dust in a tropical Asian mega-city, Bangkok, Thailand. Sci Total Environ 384:420–432
Brunekreef B, Holgate ST (2002) Air pollution and health. Lancet 360:1233–1242
Butean C, Berinde ZM, Mihali C, Michnea AM, Gavra A, Simionescu M (2014) Atmospheric deposition of copper and zinc in Maramures County (Romania). Acta Chemica Iasi 22:165–176
Chen H, Lu X, Chang Y, Xue W (2014) Heavy metal contamination in dust from kindergartens and elementary schools in Xi’an, China. Environ Earth Sci 71:2701–2709
Cheng M-F, Ho S-C, Chiu H-F, Wu T-N, Chen P-S, Yang C-Y (2008) Consequences of exposure to Asian dust storm events on daily pneumonia hospital admissions in Taipei, Taiwan. J Toxic Environ Health A 71:1295–1299
Choi H, Zhang Y, Kim K (2008) Sudden high concentration of TSP affected by atmospheric boundary layer in Seoul metropolitan area during duststorm period. Environ Int 34:635–647
Chung Y-s, Kim H-s, Dulam J, Harris J (2003) On heavy dustfall observed with explosive sandstorms in Chongwon-Chongju, Korea in 2002. Atmos Environ 37:3425–3433
Çöl M, Çöl C (2003) Environmental boron contamination in waters of Hisarcik area in the Kutahya Province of Turkey. Food Chem Toxicol 41:1417–1420
De Longueville F, Hountondji Y-C, Henry S, Ozer P (2010) What do we know about effects of desert dust on air quality and human health in West Africa compared to other regions? Sci Total Environ 409:1–8
Dockery D, Pope A (1996) Epidemiology of acute health effects: summary of time-series studies. Harvard University Press, Cambridge, pp 123–147
Feng S, Liu H, Zhang N, Lin H, Du X, Liu Y (2012) Contamination assessment of copper, lead, zinc and chromium in dust fall of Jinan, NE China. Environ Earth Sci 66:1881–1886
Fouladi Fard R, Naddafi K, Yunesian M, Nabizadeh Nodehi R, Dehghani MH, Hassanvand MS (2016) The assessment of health impacts and external costs of natural gas-fired power plant of Qom. Environ Sci Pollut Res:1–15
Ghrefat HA, Abu-Rukah Y, Rosen MA (2011) Application of geoaccumulation index and enrichment factor for assessing metal contamination in the sediments of Kafrain Dam, Jordan. Environ Monit Assess 178:95–109
Gunawardana C, Goonetilleke A, Egodawatta P, Dawes L, Kokot S (2012) Source characterisation of road dust based on chemical and mineralogical composition. Chemosphere 87:163–170
Haldar P, Pavord ID, Shaw DE, Berry MA, Thomas M, Brightling CE, Wardlaw AJ, Green RH (2008) Cluster analysis and clinical asthma phenotypes. Am J Respir Crit Care Med 178:218–224
Hamaiedh H, El-Hasan T (2011) Inorganic chemistry, granulometry and mineralogical characteristics of the dust fall over phosphate mine adjacent area, central Jordan. Environ Earth Sci 62:1771–1777
Han Y, Cao J, Posmentier ES, Fung K, Tian H, An Z (2008) Particulate-associated potentially harmful elements in urban road dusts in Xi’an, China. Appl Geochem 23:835–845
Harrad S, Ibarra C, Robson M, Melymuk L, Zhang X, Diamond M, Douwes J (2009) Polychlorinated biphenyls in domestic dust from Canada, New Zealand, United Kingdom and United States: implications for human exposure. Chemosphere 76:232–238
Hsu SC, Liu SC, Huang YT, Lung SCC, Tsai F, Tu JY, Kao SJ (2008) A criterion for identifying Asian dust events based on Al concentration data collected from northern Taiwan between 2002 and early 2007. J Geophys Res Atmos 1984–2012:113
IRIMO-Qom (2013) Iranian Meteorological Office Data Processing Center. Islamic Republic of Iran Meteorological Office, Qom
Isalou AA, Litman T, Shahmoradi B (2014) Testing the housing and transportation affordability index in a developing world context: a sustainability comparison of central and suburban districts in Qom, Iran. Transp Policy 33:33–39
Joshi UM, Vijayaraghavan K, Balasubramanian R (2009) Elemental composition of urban street dusts and their dissolution characteristics in various aqueous media. Chemosphere 77:526–533
Kara M, Dumanoglu Y, Altiok H, Elbir T, Odabasi M, Bayram A (2014) Seasonal and spatial variations of atmospheric trace elemental deposition in the Aliaga industrial region, Turkey. Atmos Res 149:204–216
Khadivi-Khub A, Kameli M, Moshfeghi N, Ebrahimi A (2015) Phenotypic characterization and relatedness among some Iranian pomegranate (Punica granatum L.) accessions. Trees 29:893–901
Khazaei M, Mahvi AH, Fard RF, Izanloo H, Yavari Z, Tashayoei HR (2013) Dental caries prevalence among schoolchildren in urban and rural areas of Qom province, central part of Iran. Middle-East J Sci Res 18:584–591
Khuzestani RB, Souri B (2013) Evaluation of heavy metal contamination hazards in nuisance dust particles, in Kurdistan Province, western Iran. J Environ Sci 25:1346–1354
Kurt-Karakus PB (2012) Determination of heavy metals in indoor dust from Istanbul, Turkey: estimation of the health risk. Environ Int 50:47–55
Kvietkus K, Šakalys J, Valiulis D (2011) Trends of atmospheric heavy metal deposition in Lithuania. Lith J Phys 51:359–369
Lee P-K, Youm S-J, Jo HY (2013) Heavy metal concentrations and contamination levels from Asian dust and identification of sources: a case-study. Chemosphere 91:1018–1025
Lu X, Li LY, Wang L, Lei K, Huang J, Zhai Y (2009) Contamination assessment of mercury and arsenic in roadway dust from Baoji, China. Atmos Environ 43:2489–2496
Lue Y, Liu L, Hu X, Wang L, Guo L, Gao S, Zhang X, Tang Y, Qu Z, Cao H (2010) Characteristics and provenance of dustfall during an unusual floating dust event. Atmos Environ 44:3477–3484
Lynam MM, Dvonch JT, Hall NL, Morishita M, Barres JA (2014) Trace elements and major ions in atmospheric wet and dry deposition across central Illinois, USA. Air Qual Atmos Health 8:135–147
Marrugo-Negrete JL, Urango-Cardenas ID, Núñez SMB, Díez S (2014) Atmospheric deposition of heavy metals in the mining area of the San Jorge river basin, Colombia. Air Qual Atmos Health 7:577–588
Melaku S, Morris V, Raghavan D, Hosten C (2008) Seasonal variation of heavy metals in ambient air and precipitation at a single site in Washington, DC. Environ Pollut 155:88–98
Mijić Z, Stojić A, Perišić M, Rajšić S, Tasić M, Radenković M, Joksić J (2010) Seasonal variability and source apportionment of metals in the atmospheric deposition in Belgrade. Atmos Environ 44:3630–3637
Moja S, Mnisi J (2013) Seasonal variations in airborne heavy metals in Vanderbijl park, South Africa. J Environ Chem Ecotoxicol 5:227–233
Momani KA, Jiries AG, Jaradat QM (2000) Atmospheric deposition of Pb, Zn, Cu, and Cd in Amman, Jordan. Turk J Chem 24:231–238
Müller G (1969) Index of geoaccumulation in sediments of the Rhine River. GeoJournal 2:108–118
Mun’im Mohd Han N, Latif MT, Othman M, Dominick D, Mohamad N, Juahir H, Tahir NM (2014) Composition of selected heavy metals in road dust from Kuala Lumpur city centre. Environ Earth Sci 72:849–859
Nriagu JO (1988) A silent epidemic of environmental metal poisoning? Environ Pollut 50:139–161
Pandey SK, Tripathi B, Mishra VK (2008) Dust deposition in a sub-tropical opencast coalmine area, India. J Environ Manag 86:132–138
Parks JL, Edwards M (2005) Boron in the environment. Crit Rev Environ Sci Technol 35:81–114
Purcell TW, Peters JJ (1998) Sources of silver in the environment. Environ Toxicol Chem 17:539–546
Qiao Q, Huang B, Zhang C, Piper JD, Pan Y, Sun Y (2013) Assessment of heavy metal contamination of dustfall in northern China from integrated chemical and magnetic investigation. Atmos Environ 74:182–193
Rashki A, Eriksson PG, Rautenbach CW, Kaskaoutis DG, Grote W, Dykstra J (2013) Assessment of chemical and mineralogical characteristics of airborne dust in the Sistan region, Iran. Chemosphere 90:227–236
Rout T, Masto RE, Padhy P, Ram L, George J, Joshi G (2015) Heavy metals in dusts from commercial and residential areas of Jharia coal mining town. Environ Earth Sci 73:347–359
Shakour Ali AA, El Taieb NM, Ibrahim AMAYH, El SGA (2011) Heavy metals enrichement in deposited particulate matter at Abu Zaabal industrial area–Egypt. J Am Sci 7:347–352
Sharma RK, Agrawal M (2005) Biological effects of heavy metals: an overview. J Environ Biol 26:301–313
Shin E-C, Craft BD, Pegg RB, Phillips RD, Eitenmiller RR (2010) Chemometric approach to fatty acid profiles in Runner-type peanut cultivars by principal component analysis (PCA). Food Chem 119:1262–1270
Sipos P, Kovács VK, Márton E, Németh T, May Z, Szalai Z (2012) Lead and zinc in the suspended particulate matter and settled dust in Budapest, Hungary. Eur Chem Bull 1:449–454
Soriano A, Pallarés S, Pardo F, Vicente A, Sanfeliu T, Bech J (2012) Deposition of heavy metals from particulate settleable matter in soils of an industrialised area. J Geochem Explor 113:36–44
Taylor SR (1964) Abundance of chemical elements in the continental crust: a new table. Geochim Cosmochim Acta 28(8):1273–1285
Thakur M, Deb MK, Imai S, Suzuki Y, Ueki K, Hasegawa A (2004) Load of heavy metals in the airborne dust particulates of an urban city of central India. Environ Monit Assess 95:257–268
Wang L, Lu X, Ren C, Li X, Chen C (2014) Contamination assessment and health risk of heavy metals in dust from Changqing industrial park of Baoji, NW China. Environ Earth Sci 71:2095–2104
Wei B, Yang L (2010) A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China. Microchem J 94:99–107
Wong C, Li X, Zhang G, Qi S, Peng X (2003) Atmospheric deposition of heavy metals in the Pearl River Delta, China. Atmos Environ 37:767–776
Woods WG (1994) An introduction to boron: history, sources, uses, and chemistry. Environ Health Perspect 102:5–11
Yazbeck C, Kloppmann W, Cottier R, Sahuquillo J, Debotte G, Huel G (2005) Health impact evaluation of boron in drinking water: a geographical risk assessment in Northern France. Environ Geochem Health 27:419–427
Yongming H, Peixuan D, Junji C, Posmentier ES (2006) Multivariate analysis of heavy metal contamination in urban dusts of Xi’an, Central China. Sci Total Environ 355:176–186
Zheng N, Liu J, Wang Q, Liang Z (2010) Heavy metals exposure of children from stairway and sidewalk dust in the smelting district, northeast of China. Atmos Environ 44:3239–3245
Acknowledgments
We would like to thank the Medical Geology Department of Geological Survey of Iran for their collaboration. The authors also wish to express their deepest gratitude to Mr. M. Zohrab Baigy for his collaboration in editing an earlier draft of this article.
Funding
This study received financial and technical supports from the Institute for Environmental Research (IER) of Tehran University of Medical Sciences (grant number 92-01-46-20879) and Research Center for Environmental Pollutants, Qom University of Medical Sciences (grant number 91334).
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Responsible editor:Gerhard Lammel
Rights and permissions
About this article
Cite this article
Fouladi Fard, R., Naddafi, K., Hassanvand, M.S. et al. Trends of metals enrichment in deposited particulate matter at semi-arid area of Iran. Environ Sci Pollut Res 25, 18737–18751 (2018). https://doi.org/10.1007/s11356-018-2033-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-018-2033-z