Abstract
The chemical composition of atmospheric particulate (PM10) in the Friuli Venezia Giulia (FVG) region (NE Italy) has been characterized for the first time with the help of exploratory data analysis (EDA) techniques (uni-, bi-, and multivariated, i.e., principal components analysis), molecular and elemental diagnostic ratios, and seasonal trends. Despite that the available analytical data was limited to the parameters routinely analyzed on PM10 by ARPA FVG (11 elements and 16 PAH congeners), the large number of samples and of measured chemical parameters, together with the applied techniques of data analysis, allowed us to extract useful latent information from the dataset, resulting in a greater knowledge of both regional and local features. Specifically, we succeeded in matching data patterns to the known pollution sources of some sampling stations, both industrial (two secondary fusion steelworks and one coke oven) and urban (traffic and domestic heating), and in defining the mainly urban or mainly industrial feature of some questionable sampling stations. This is of paramount importance to check for possible industrial inputs in urban stations, allowing policymakers to implement the most appropriate response.
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28 November 2018
Unfortunately, we encountered an error with units of measure in reporting data in the last two columns of Table 3 (on page 28814 in the printed version), so that those data should be changed as reported in the following corrected version of the Table
Notes
ARPA FVG AMCQA Lab is accredited by the Italian National Accreditation Body (Accredia) for the determination of BaP and the four compulsory metals in PM.
References
2004/107/CE (2004) Directive 2004/107/EC of the European Parliament and of the Council of 15 December 2004 relating to arsenic, cadmium, mercury, nickel and polycyclic aromatic hydrocarbons in ambient air
2008/50/CE (2008) Directive 2008/50/EC of the European Parliament and of the Council of 21 May 2008 on ambient air quality and cleaner air for Europe
Acquavita A, Predonzani S, Mattassi G, Rossin P, Tamberlich F, Falomo J, Valic I (2010) Heavy metal contents and distribution in coastal sediments of the Gulf of Trieste (Northern Adriatic Sea, Italy). Water Air Soil Pollut 211:95–111
Agrawal H, Malloy Q, Welch WA, Miller JW, Cocker DR (2008) In-use gaseous and particulate emissions from a modern oceangoing container vessel. Atmos Environ 42:504–5510
Albinet A, Leoz-Garziandia E, Budzinski H, Villenave E, Jaffrezo JL (2008) Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two French alpine valleys—part 1: concentrations, sources and gas/particle partitioning. Atmos Environ 42:43–54
ARPA FVG (2013) Relazionesulla Qualità dell’aria della Zona industriale di Cividale-Moimacco.http://www.arpa.fvg.it/export/sites/default/tema/aria/utilita/Documenti_e_presentazioni/tecnico_scientifiche_docs/Relazione_qualita_aria_zicm_2012.pdf(in Italian). Accessed on 15 September 2017
ARPA FVG (2015) Relazione sulla Qualità dell’aria a Trieste per il sito RFI.http://www.arpa.fvg.it/export/sites/default/tema/aria/utilita/Documenti_e_presentazioni/tecnico_scientifiche_docs/Relazione_qualita_aria_ts_2014.pdf(in Italian). Accessed on 15 September 2017
Amato F, Pandolfi M, Escrig A, Querol X, Alastuey A, Pey J, Perez N, Hopke PK (2009) Quantifying road dust resuspension in urban environment by multilinear engine: a comparison with PMF2. Atmos Environ 43:2770–2780
Astel AM, Giorgini L, Mistaro A, Pellegrini I, Cozzutto S, Barbieri P (2013) Urban BTEX spatiotemporal exposure assessment by chemometric expertise. Water Air Soil Pollut 224(1503):1503. https://doi.org/10.1007/s11270-013-1503-7
Becagli S, Sferlazzo DM, Pace G, di Sarra A, Bommarito C, Calzolai G, Ghedini C, Lucarelli F, Meloni D, Monteleone F, Severi M, Traversi R, Udisti R (2012) Evidence for heavy fuel oil combustion aerosols from chemical analyses at the island of Lampedusa: a possible large role of ships emissions in the Mediterranean. Atmos Chem Phys 12:3479–3492
Behymer TD, Hites RA (1988) Photolysis of polycyclic aromatic hydrocarbons adsorbed on fly ash. Environ Sci Technol 22:1311–1319
Bidleman TF, Billings WN, Foreman WT (1986) Vapor-particle partitioning of semivolatile organic compounds: estimates from field collections. Environ Sci Technol 20:1038–1043
Bourotte C, Forti M, Taniguchi S, Bicego M, Lotufo P (2005) A wintertime study of PAHs in fine and coarse aerosols in Sao Paulo city, Brazil. AtmosEnviron 39:3799–3811
Budzinski H, Jones I, Bellocq J, Pierard C, Garrigues P (1997) Evaluation of sediment contamination by polycyclic aromatic hydrocarbons in the Gironde estuary. Mar Chem 58:85–97
Burke S (2001) Missing values, outliers, robust statistics & non-parametric methods. LC.GC Europe Online Supplement, statistics and data analysis 2.0. RHM Technology Ltd, High Wycombe, Buckinghamshire, pp 19–24
Canepari S (2010) Influenza del traffico veicolare sull’inquinamento atmosferico in aree urbane: contributo delle sorgenti non combustive alle concentrazioni elementari nel particolato. In: VI Rapporto sulla qualità dell’ambiente urbano – Focus sulle buone pratiche. ISPRA, Roma, pp 137–150 (in Italian)
Cecinato A (1997) Polynuclear aromatic hydrocarbons (PAH), benz(a)pyrene (BaPY) and nitrated-PAH (NPAH) in suspended particulate matter. Ann Chim 87:483–496
ChattopadhyayK, JohnsonD, YoungJ, VieiraJ, BachenheimerS, KumarS (2014) Evaluation of air emissions in steel plants with focus on heavy metals emissions.https://www.researchgate.net/publication/285598959. Accessed November 2016
Chen SC, Liao CM (2006) Health risk assessment on human exposed to environmental polycyclic aromatic hydrocarbons pollution sources. Sci Total Environ 366:112–123
Costa HJ, Sauer JTC (2005) Forensic approaches and considerations in identifying PAH background. Environ Forens 6:9–16
Culhane F (1973)Air pollution control—electric arc melting furnace. In: Noll K, Duncan J (eds) Industrial air pollution control. Ann Arbor science pub., pp 139–152. https://doi.org/10.1021/ac60332a823
Daisey JM, Leyko MA, Kneip TJ (1979) Source identification and allocation of polynuclear aromatic hydrocarbon compounds in the New York City aerosol: methods and applications. In: Jones PW, Leber P (eds) Polynuclear aromatic hydrocarbons. 3rd International Symposium on Chemistry and Biology – Carcinogenesis and Mutagenesis, Ann Arbor Science, MI
Galarneau E (2008) Source specificity and atmospheric processing of airborne PAHs: implications for source apportionment. Atmos Environ 42(35):8139–8149
Goetz F (1980) The mechanism of BOF fume formation. Open Access Dissertations and Theses. Paper 2794. McMaster University, Hamilton, Ontario.http://hdl.handle.net/11375/7521. Accessed 10 Oct 2017
Hammer Ø, HarperDAT, PaulDR (2001) PAST: palaeontological statistics, software package for education and data analysis. Palaeontol Electron 4:9
HammerØ (2011) PAST paleontological statistics, version 2.06, reference manual
Huber PJ (2011) Robust statistics. Springer, Berlin, Heidelberg, pp 1248–1251
Iijima A, Sato K, Fujitani Y, Fujimori E, Saito Y, Tanabe K, Ohara T, Kozawa K, Furuta N (2009) Clarification of the predominant emission sources of antimony in airborne particulate matter and estimation of their effects on the atmosphere in Japan. Environ Chem 6(2):122–132. https://doi.org/10.1071/EN08107
Iijima A, Sato K, Yano K, Kato M, Kozawa K, Furuta N (2008) Emission factor for antimony in brake abrasion dusts as one of the major atmospheric antimony sources. Environ Sci Technol 42(8):2937–2942
Jung KH, Yan B, Chillrud SN, Perera FP, Whyatt R, Camann D, Kinney PL, Miller RL (2010) Assessment of benzo(a)pyrene-equivalent carcinogenicity and mutagenicity of residential indoor versus outdoor polycyclic aromatic hydrocarbons exposing young children in New York City. Int J Environ Res Public Health 7(5):1889–1900
Li YM, Pan YP, Wang YS, Wang YF, Li XR (2012) Chemical characteristics and sources of trace metals in precipitation collected from a typical industrial city in Northern China. Huan Jing Ke Xue 33(11):3712–3717 (in Chinese)
Lilliefors HW (1967) On the Kolmogorov-Smirnov test for normality with mean and variance unknown. J Am Stat Assoc 62(318):399–402
López JM, Callén MS, Murillo R, García T, Navarro MV, de la Cruz MT, Mastral AM (2005) Levels of selected metals in ambient air PM10 in an urban site of Zaragoza (Spain). Environ Res 99:58–67
Luckey TD, Venugopal B (1977) Metal toxicity in mammals. Plenum Press, New York
Mann HB, Whitney DR (1947) On a test of whether one of two random variables is stochastically larger than the other. Ann Math Stat 18(1):50–60
Mislin H, Ravera O (1986) Cadmium in the environment. Experientia Supplementum vol. 50. Birkhäuser, Basel
Mucci G (2012) Inquinamento da benzene in atmosfera urbana: evoluzione del fenomeno e distribuzione nella città di Trieste. Università degli Studi di Trieste, Trieste (in Italian)
Nisbet ICT, LaGoy PK (1992) Toxic equivalency factors (TEFs) for polycyclic aromatic hydrocarbons (PAHs). Regul Toxicol Pharmacol 16:290–300
Pandolfi M, Gonzalez-Castanedo Y, Alasuey A, de la Rosa JD, Mantilla E, Sanchez de la Campa A, Querol X, Pey J, Amato F, Moreno T (2011) Source apportionment of MP10 and PM2,5 at multiple sites in the strait of Gibraltar by PMF: impact of shipping emissions. Environ Sci Pollut Res 18(2):260–269
Peng C, Chen WP, Liao XL, Wang ME, Ouyang ZY, Jiao WT, Bai Y (2011) Polycyclic aromatic hydrocarbons in urban soils of Beijing: status, sources, distribution and potential risk. Environ Pollut 159:802–808
Pirovano G, Colombi C, Balzarini A, Riva GM, Gianelle V, Lonati G (2015) PM2.5 source apportionment in Lombardy (Italy): comparison of receptor and chemistry-transport modelling results. Atmos Environ 106:56–70
PM2016 (2016) 7th Atmospheric Particulate National Congress. Book of Abstracts. Roma (in Italian)
Poluzzi V, Trentini A, Scotto F, Ricciardelli I, Ferrari S, Maccone C, Bacco D, Zigola C, Bonafè G, Ugolini P, Bertacci G, Pietrogrande MC, Visentin M,Gilardoni S, Paglione M, Rinaldi M, Facchini MC (2015) Preliminary results of the project “Supersito” concerningthe atmospheric aerosolo composition in Emilia-Romagna region, Italy: PM source apportionment and aerosol size distribution. In: Sustainable Develpoment. WIT Press Wessex Institute of Technology, Ashurst, pp 689–698
Pongpiachan S, Bualert S, Sompongchaiyakul P, Kositanont C (2009) Factors affecting sensitivity and stability of polycyclic aromatic hydrocarbons determined by gas chromatography quadrupole ion trap mass spectrometry. Anal Lett 42:2106–2130
Pongpiachan S, Hattayanone M, Choochuay C, Mekmok N, Wuttjak N, Ketratanakul A (2015) Enhanced PM10 bounded PAHs from shipping emissions. Atmos Environ 108:13–19
Pongpiachan S, Iijima A (2016) Assessment of selected metals in the ambient air PM10 in urban sites of Bangkok (Thailand). Environ Sci Pollut Res 23:2948–2961
Pongpiachan S, Hattayanone M, Cao J (2017a) Effect of agricultural waste burning season on PM2.5-bound polycyclic aromatic hydrocarbons (PAH) levels in Northern Thailand. Atmos Pollut Res 8:1069–1080. https://doi.org/10.1016/j.apr.2017.04.009
Pongpiachan S, Hattayanone M, Suttinun O, Khumsup C, Kittikoon I, Hirunyatrakul P, Cao J (2017b) Assessing human exposure to PM10-bound polycyclic aromatic hydrocarbons during fireworks displays. Atmospheric Pollution Research 8:816–827
Pongpiachan S, Hattayanone M, Tipmanee D, Suttinun O, Khumsup C, Kittikoon I, Hirunyatrakul P (2017c) Chemical characterization of polycyclic aromatic hydrocarbons (PAHs) in 2013 Rayong oil spill-affected coastal areas of Thailand. Environ Pollut 233:992–1002. https://doi.org/10.1016/j.envpol.2017.09.096
Puxbaum H (1991) Metal compounds in the atmosphere. In: Merian E (ed) Metals and their compounds in the environment, Wiley-VHC, pp257–86
Ravindra K, Bencs L, Wauters E, Dehoog J, Deutsch F, Roekens E et al (2006) Seasonal and site-specific variation in vapour and aerosol phase PAHs over Flanders (Belgium) and their relation with anthropogenic activities. Atmos Environ 40:771–785
Ravindra K, Sokhi R, Vangrieken R (2008) Atmospheric polycyclic aromatic hydrocarbons: source attribution, emission factors and regulation. Atmos Environ 42:2895–2921
Rudnick RL, Gao S (2003) Composition of the continental crust. In: Treatise on geochemistry (vol. 3), Elsevier, pp. 1–64
Stogiannidis E, Laane R (2015) Source characterization of polycyclic aromatic hydrocarbons by using their molecular indices: an overview of possibilities. Rev Environ Contam Toxicol 234:49–134
Tricarico V (2005) Gradienti spazio-temporali delle concentrazioni del Benzo(a)Pirene ed altri sei IPA, della loro somma e composizione relativa. Misure condotte nell’area urbana di Firenze durante l’anno 2004. Boll Chim Igien 56:73–77 (in Italian)
Tolloi A, Briguglio SC, Barbieri G, Bellini M, Liguori L, Pellegrini I, Colugnati L, Pastrello A, Semec Bertocchi A, Bruno R, Mistaro A, Adami G, Licen S, Barbieri P (2015) OPC, anemology, gravimetric and speciative analyses for characterizing PM impacts on an inhabited area close to an industrial hot spot. European Aerosol Conference, Milano
Tositti L, Brattich E, Masiol M, Zappoli S (2014) Source apportionment of particulate matter in a large city of southeastern Po Valley (Bologna, Italy). Environ Sci Pollut Res 21:872–890
Tuttitalia (2017) http://www.tuttitalia.it/friuli-venezia-giulia/ (in Italian). Accessed 15 September 2017
UNI EN 12341:1999 Air Quality—determination of the PM10 fraction of suspended particulate matter—reference method and field test procedure to demonstrate reference equivalence of measurement methods
UNI EN 15549:2008 Air Quality—standard method for the measurement of the concentration of benzo[a]pyrene in ambient air
UNI EN 14902:2005 Ambient air quality—standard method for the measurement of Pb, Cd, As and Ni in the PM10 fraction of suspended particulate matter
USEPA NC EPA-600/R-93/089 (1993) Provisional guidance for quantitative risk assessment of polycyclic aromatic hydrocarbons. US Environmental Protection Agency, Research Triangle Park
Viana M, Amato F, Alastuey A, Querol X, Saul G, Herce-Garraleta D, Fernandez-Patier R (2009) Chemical tracers of particulate emissions from commercial shipping. Environ Sci Technol 43(19):7472–7477
Viana M, Hammingh P, Colette A, Querol X, Degraeuwe B, de Vlieger I, van Aardenne J (2014) Impact of transport emissions on coastal air quality in Europe. Atmos Environ 90:96–105
Wedepohl KH (1995) The composition of the continental crust. Geochem Cosmochim Acta 59(7):1217–1232
WHO (2017) Evolution of WHO air quality guidelines: past, present and future. WHO Regional Office for Europe, Copenhagen ISBN 9789289052306
Wilcoxon F, Wilcox RA (1964) Some rapid approximate statistical procedures. Lederle Laboratories
Wilson JG, Kingham S, Pearce J, Sturman AP (2005) A review of intraurban variations in particulate air pollution: implications for epidemiological research. Atmos Environ 39:6444–6462
Wilson JG, Kingham S, Pearce J, Sturman AP (2006) Intraurban variations of PM10 air pollution in Christchurch, New Zealand: implications for epidemiological studies. Sci Total Environ 367:559–572
Wongphatarakul V, Friedlander SK, Pinto JP (1998) A comparative study of PM2.5 ambient aerosol chemical databases. Environ Sci Technol 32:3926–3934
Yunker MB, Macdonald RW (1995) Composition and origin of polycyclic aromatic hydrocarbons in the Mackenzie River and on the Beaufort Sea shelf. Arctic 48:118–129
Yunker MB, Macdonald RW, Vingarzan R, Mitchell RH, Goyette D, Sylvestre S (2002) PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition. Org Geochem 33:489–515
Zhang H, Wang Z, Zhang Y, Ding M, Li L (2015) Identification of traffic related metals and the effects of different environments on their enrichment in roadside soils along the Qinghai-Tibet highway. Sci Total Environ 521-522C:160–172
Acknowledgments
We thank all colleagues that contributed to data sampling, collection, and validation, namely Marco Bellini, Valter Cecchin, Agostino Colla, Gianmaria Cossio, Ivano De Simon, Lorenzo Fragiacomo, Rossana Michelini, Angela Roman Rioni, and Marco Visintin. We thank Alessandro Acquavita (ARPA FVG) and Alan Colli (University of Cambridge) for useful insights on the manuscript preparation.
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Mistaro, A., Felluga, A., Moimas, F. et al. Chemical characterization of atmospheric particulate matter in Friuli Venezia Giulia (NE Italy) by exploratory data analysis with multisite and multivariate approach. Environ Sci Pollut Res 25, 28808–28828 (2018). https://doi.org/10.1007/s11356-018-1883-8
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DOI: https://doi.org/10.1007/s11356-018-1883-8