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Chemical characterization of atmospheric particulate matter in Friuli Venezia Giulia (NE Italy) by exploratory data analysis with multisite and multivariate approach

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A Correction to this article was published on 28 November 2018

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Abstract

The chemical composition of atmospheric particulate (PM10) in the Friuli Venezia Giulia (FVG) region (NE Italy) has been characterized for the first time with the help of exploratory data analysis (EDA) techniques (uni-, bi-, and multivariated, i.e., principal components analysis), molecular and elemental diagnostic ratios, and seasonal trends. Despite that the available analytical data was limited to the parameters routinely analyzed on PM10 by ARPA FVG (11 elements and 16 PAH congeners), the large number of samples and of measured chemical parameters, together with the applied techniques of data analysis, allowed us to extract useful latent information from the dataset, resulting in a greater knowledge of both regional and local features. Specifically, we succeeded in matching data patterns to the known pollution sources of some sampling stations, both industrial (two secondary fusion steelworks and one coke oven) and urban (traffic and domestic heating), and in defining the mainly urban or mainly industrial feature of some questionable sampling stations. This is of paramount importance to check for possible industrial inputs in urban stations, allowing policymakers to implement the most appropriate response.

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Change history

  • 28 November 2018

    Unfortunately, we encountered an error with units of measure in reporting data in the last two columns of Table 3 (on page 28814 in the printed version), so that those data should be changed as reported in the following corrected version of the Table

Notes

  1. ARPA FVG AMCQA Lab is accredited by the Italian National Accreditation Body (Accredia) for the determination of BaP and the four compulsory metals in PM.

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Acknowledgments

We thank all colleagues that contributed to data sampling, collection, and validation, namely Marco Bellini, Valter Cecchin, Agostino Colla, Gianmaria Cossio, Ivano De Simon, Lorenzo Fragiacomo, Rossana Michelini, Angela Roman Rioni, and Marco Visintin. We thank Alessandro Acquavita (ARPA FVG) and Alan Colli (University of Cambridge) for useful insights on the manuscript preparation.

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Correspondence to Andrea Mistaro.

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Mistaro, A., Felluga, A., Moimas, F. et al. Chemical characterization of atmospheric particulate matter in Friuli Venezia Giulia (NE Italy) by exploratory data analysis with multisite and multivariate approach. Environ Sci Pollut Res 25, 28808–28828 (2018). https://doi.org/10.1007/s11356-018-1883-8

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