Environmental Science and Pollution Research

, Volume 25, Issue 10, pp 10090–10101 | Cite as

Iron doped fibrous-structured silica nanospheres as efficient catalyst for catalytic ozonation of sulfamethazine

Research Article

Abstract

Sulfonamide antibiotics are ubiquitous pollutants in aquatic environments due to their large production and extensive application. In this paper, the iron doped fibrous-structured silica (KCC-1) nanospheres (Fe-KCC-1) was prepared, characterized, and applied as a catalyst for catalytic ozonation of sulfamethazine (SMT). The effects of ozone dosage, catalyst dosage, and initial concentration of SMT were examined. The experimental results showed that Fe-KCC-1 had large surface area (464.56 m2 g−1) and iron particles were well dispersed on the catalyst. The catalyst had high catalytic performance especially for the mineralization of SMT, with mineralization ratio of about 40% in a wide pH range. With addition of Fe-KCC-1, the ozone utilization increased nearly two times than single ozonation. The enhancement of SMT degradation was mainly due to the surface reaction, and the increased mineralization of SMT was due to radical mechanism. Fe-KCC-1 was an efficient catalyst for SMT degradation in catalytic ozonation system.

Keywords

Catalytic ozonation Sulfamethazine PPCPs Catalyst AOPs 

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Collaborative Innovation Center for Advanced Nuclear Energy Technology, INETTsinghua UniversityBeijingPeople’s Republic of China
  2. 2.School of Water Resources and EnvironmentChina University of GeosciencesBeijingChina
  3. 3.Beijing Key Laboratory of Radioactive Waste Treatment, INETTsinghua UniversityBeijingPeople’s Republic of China

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