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Environmental Science and Pollution Research

, Volume 24, Issue 30, pp 23488–23497 | Cite as

Improvement in rice straw pulp bleaching effluent quality by incorporating oxygen delignification stage prior to elemental chlorine-free bleaching

  • Daljeet Kaur
  • Nishi K. Bhardwaj
  • Rajesh Kumar Lohchab
Research Article

Abstract

Environmental degradation by industrial and other developmental activities is alarming for imperative environmental management by process advancements of production. Pulp and paper mills are now focusing on using nonwood-based raw materials to protect forest resources. In present study, rice straw was utilized for pulp production as it is easily and abundantly available as well as rich in carbohydrates (cellulose and hemicelluloses). Soda-anthraquinone method was used for pulp production as it is widely accepted for agro residues. Bleaching process during paper production is the chief source of wastewater generation. The chlorophenolic compounds generated during bleaching are highly toxic, mutagenic, and bioaccumulative in nature. The objectives of study were to use oxygen delignification (ODL) stage prior to elemental chlorine-free (ECF) bleaching to reduce wastewater load and to study its impact on bleached pulp characteristics. ODL stage prior to ECF bleaching improved the optical properties of pulp in comparison to only ECF bleaching. When ODL stage was incorporated prior to bleaching, the tensile index and folding endurance of the pulp were found to be 56.6 ± 1.5 Nm/g and 140, respectively, very high in comparison to ECF alone. A potential reduction of 51, 57, 43, and 53% in BOD3, COD, color, and AOX, respectively was observed on adding the ODL stage compared to ECF only. Generation of chlorophenolic compounds was reduced significantly. Incorporation of ODL stage prior to bleaching was found to be highly promising for reducing the toxicity of bleaching effluents and may lead to better management of nearby water resources.

Graphical abstract

Keywords

Bleaching Chlorophenol Delignification Rice straw Wastewater 

Notes

Acknowledgements

The authors acknowledge the Ministry of Minority Affairs (India) and University Grants Commission (India) for providing the financial support under Maulana Azad National Fellowship for Minority Students. First author is also highly thankful to the Director, Avantha Centre for Industrial Research and Development, for allowing to carry out research work, and also the Department of Environmental Science and Engg, Guru Jambeshwar University of Science and Technology, Hisar (India).

References

  1. Akbari M and Resalati H (2012) Use of agricultural waste in pulp and paper industry. Ist international and the 4th National Congress on recycling of organic waste in agriculture. IsfahanGoogle Scholar
  2. Berry RM, Luthe CE, Voss RH, & Wrist PE (1991) The effects of recent changes in bleached softwood kraft mill technology on organoflorine emissions: an international perspective. Pulp Pap Can 92(6):T155–T165Google Scholar
  3. Brumley CM, Haritos VS, Ahokas JT, Holdway DA (1996) Metabolites of chlorinated syringaldehydes in fish bile as biomarkers of exposure to bleached eucalyptus effluents. Ecotoxicol Environ Saf 33:253–260CrossRefGoogle Scholar
  4. Catalkaya EC, Kargi F (2007) Color, TOC and AOX removals from pulp mill effluent by advanced oxidation process: a comparative study. J Hazard Mater 139:244–225CrossRefGoogle Scholar
  5. Colodette JL, Gomide JL, Júnior DL, Gomes CM (2007) Effect of pulp delignification degree on fiber line performance and bleaching effluent load. Bioresources 2(2):223–234Google Scholar
  6. Dhir A, Prakash NT, Sud D (2011) Studies on coupled biological and photochemical treatment of soda pulp bleaching effluents from agro residue based pulp and paper mill. J Chem Technol Biotechnol 86(12):1508–1513CrossRefGoogle Scholar
  7. Dutt D, Tyagi CH, Upadhyaya JS, Anuj M (2009) Oxygen delignification: An effective back-end modification to reduce pollution load and improve mechanical strength properties prior to bleaching. Ippta 21(2): 151–153Google Scholar
  8. Freire CSR, Silvestre AJD, Neto CP (2003) Carbohydrate derived chlorinated compounds in ECF bleaching of hardwood pulps: formation, degradation and contribution to AOX in a bleached kraft pulp mill. Environ Sci Technol 37:811–814CrossRefGoogle Scholar
  9. Griggs BF, Thomas P, Pikulin A, and Rosen A, (1994) Environmentally improved process for bleaching lignocellulosic materials with oxygen, ozone and chlorine dioxide. U.S. Patent 5,296,099, issued March 22Google Scholar
  10. Guay DF, Cole BJW, Fort RC Jr, Genco JM, Hausman MC (2000) Mechanisms of oxidative degradation of carbohydrates during oxygen delignification. I. Reaction of methyl β-d-glucopyranoside with photochemically generated hydroxyl radicals. J Wood Chem Technol 20(4):375–394CrossRefGoogle Scholar
  11. Huang GX, Shi J, Langrish TAG (2007) NH4OH-KOH pulping mechanisms and kinetics of rice straw. Bioresour Technol 98:1218–1222CrossRefGoogle Scholar
  12. Kaur D, Bhardwaj NK, Lohchab RK (2016) Prospects of rice straw as a raw material for paper making. Waste Manage.  https://doi.org/10.1016/j.wasman.2016.08.001
  13. Kumar P (2012) Characterization and removal of chlorinated organics from pulp bleaching effluents. Ph.D thesis IIT RoorkeeGoogle Scholar
  14. Kumar A, Kumar S, Kumar S (2005) Biodegradation kinetics of phenol and catechol using Pseudomonas putida MTCC1194. Biochem Eng J 22:151–159CrossRefGoogle Scholar
  15. Liebergott N, Van Lierop B, Nolin A, Faubert M, Laflamme J (1991) Modifying the bleaching process to decrease AOX formation. Pulp Pap Can 92(3):85–89Google Scholar
  16. Lindström K, Nordin J (1976) Gas chromatography-mass spectrometry of chlorophenols in spent bleach liquors. J Chromatogr 128(1):13–26CrossRefGoogle Scholar
  17. Liu YL, Chen KF, Lin BP (2014) The use of Mg (OH)2 in the final peroxide bleaching stage of wheat straw pulp. Bioresources 9(1):161–170Google Scholar
  18. Mc Donough TJ (1996) Oxygen delignification. Eds. Pulp bleaching: principles and practices Dence, C. W., & Reeve, D. W. (1996)., 213–239Google Scholar
  19. Meenakshi, Singh G, Hoondal GS (2011) Biobleaching of wheat straw rich-soda pulp by the application of thermophilic mannanase from Bacillus sp. MG-33. International J of Env Sci 2(2):839–849Google Scholar
  20. Meuller L, Basta J, Holtinger L, Wane G (2003) ECF bleaching of softwood and eucalyptus pulps—a comparative study. TAPPI 57(6):8–18Google Scholar
  21. Mukherjee D, Bandyopadhyay N (1993) Oxygen delignification technology for improved product quality and pollution abatement in pulp and paper industry. IPPTA 5:27–27Google Scholar
  22. Navaee-Ardeh S, Mohammadi-Rovshandeh J, Khodadadi A, Pourjoozi M (2003) Pulp and paper characterization of rice straw produced from aqueous ethanol pulping. Cellul Chem Technol 37(5–6):405–413Google Scholar
  23. Pokhrel D, Viraraghavan T (2004) Treatment of pulp and paper mill wastewater—a review. Sci Total Environ 333(1):37–58CrossRefGoogle Scholar
  24. Rao NJ, Kumar S (1987) Toxic effluent from pulp and paper mill. Convention issues. IPPTA. 13(4):47–51.Google Scholar
  25. Requejo A, Rodríguez A, Colodette JL, Gomide JL, Jiménez L (2012) Optimization of ECF bleaching and refining of kraft pulping from olive tree pruning. Bioresources 7(3):4046–4055Google Scholar
  26. Rintala JA, Jain VK & Kettunen RH (1999) Comparative status of the worldwide commercially available anaerobic technologies adopted for bio-methanation of paper and pulp effluent. 4th International Exhibition and Conference on pulp and paper industry, PAPEREX-99. 14-16 DecemberGoogle Scholar
  27. Rodriguez A, Jimenez L, Ferrer JL (2007) Use of oxygen in the delignification and bleaching of pulps. Appita 60(1):17–22Google Scholar
  28. Rolf B, Christina J, Lars-Ake L, Yngve L (2009) Non wood pulping technologies present and future scenario. IPPTA 12(1):115–120Google Scholar
  29. Roy M, Chakrabarti SK, Bhardwaj NK, Chandra S, Kumar S, Singh S, Bajpai PK (2004) Characterization of chlorinated organic material in eucalyptus pulp bleaching effluents. J Sci Indus Res 63(2):527–535Google Scholar
  30. Ruuttunen K, Vuorinen T (2007) Concomitant usage of transition metal polyanions as catalysts in oxygen delignification: laboratory bleaching trials. Appita 60(3):235–240Google Scholar
  31. Selvam K, Arungandhi K (2013) Biobleaching and delignification of hard wood kraft pulp (HWKP) by Trametes sp., Ganoderma sp. and Poria sp. Int J Plant, Anim Environ Sci 3(3):96–100Google Scholar
  32. Sharma C, Mohanty S, Kumar S, Rao NJ (1996) Gas chromatographic analysis of chlorophenolic, resin and fatty acids in chlorination and caustic extraction stage effluent from Kahi-grass. Analyst 121(12):1963–1967CrossRefGoogle Scholar
  33. Singh S, Dutt D (2014) Mitigation of adsorbable organic halides in combined effluents of wheat straw soda-AQ pulp bleached with cellulase-poor crude xylanases of coprinellus disseminatus in elemental chlorine free bleaching. Cellul Chem Technol 48(1–2):127–135Google Scholar
  34. Singh R, Tiwari S, Srivastva M, Shukla A (2013) Performance study of combined microwave and acid pretreatment method for enhancing enzymatic digest ability of rice straw for bioethanol production. Plant Knowl J 2(4):157–162Google Scholar
  35. Singh R, Tiwari S, Srivastva M, Shukla A (2014) Microwave assisted alkali pretreatment of rice straw for enhancing enzymatic digestability. J Energy.  https://doi.org/10.1155/2014/483813
  36. Thapliyal BP, Tyagi S (2015) Water pinch analysis—an innovative approach towards water conservation in pulp and paper industry. IPPTA 27(3):59–66Google Scholar
  37. Thomas R, Singh SP, Subrahmanyam SV (2007) A study on oxygen delignification of Melocanna baccifera (Muli bamboo) kraft pulp. Bioresources 2(3):430–441Google Scholar
  38. Woodman J (1993) Pollution prevention technologies for the bleached kraft segment. EPA report 1993Google Scholar
  39. Yaqoob N, Stack K, Cheema KJ, Mateen B (2011) Oxidative delignification and bleaching of alkaline sulphite-anthraquinone wheat straw pulp. Asian J Chem 23(7):2845–2851Google Scholar

Copyright information

© Springer-Verlag GmbH Germany 2017

Authors and Affiliations

  • Daljeet Kaur
    • 1
    • 2
  • Nishi K. Bhardwaj
    • 1
  • Rajesh Kumar Lohchab
    • 2
  1. 1.Avantha Centre for Industrial Research & DevelopmentYamunanagarIndia
  2. 2.Department of Environmental Science & EngineeringGuru Jambheshwar University of Science & TechnologyHisarIndia

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