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Biochar as an adsorbent for inorganic nitrogen and phosphorus removal from water: a review

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Abstract

Biochar is the solid product of biomass pyrolysis that can be used for carbon sequestration, soil amendment, and pollution remediation. The use of biochar as an adsorbent for the removal of water contaminants has elicited increasing interest due to the multifunctional properties of this material. The application of biochar in the adsorption of inorganic nutrients from eutrophic water has not been reviewed. This review focuses on recent research on the use of biochar for the adsorption of inorganic nitrogen (ammonium and nitrate) and phosphorus (phosphate) from water, especially for the main influence factors and mechanisms for nitrogen and phosphorus adsorption on biochar.

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References

  • Ahmad M, Lee SS, Lim JE, Lee SE, Cho JS, Moon DH, Hashimoto Y, Ok YS (2014) Speciation and phytoavailability of lead and antimony in a small arms range soil amended with mussel shell, cow bone and biochar: EXAFS spectroscopy and chemical extractions. Chemosphere 95:433–441

    Article  CAS  Google Scholar 

  • Ahmedna M, Johns MM, Clarke SJ, Marshall WE, Rao RM (1997) Potential of agricultural by-product-based activated carbons for use in raw sugar decolourisation. J Sci Food Agric 75:117–124

    Article  CAS  Google Scholar 

  • Altundoğan HS, Tümen F (2002) Removal of phosphates from aqueous solutions by using bauxite. I: effect of pH on the adsorption of various phosphates. J Chem Technol Biotechnol 77:77–85

    Article  CAS  Google Scholar 

  • Arias CA, Del Bubba M, Brix H (2001) Phosphorus removal by sands for use as media in subsurface flow constructed reed beds. Water Res 35:1159–1168

    Article  CAS  Google Scholar 

  • Berge ND, Ro KS, Mao J, Flora JRV, Chappell MA, Bae S (2011) Hydrothermal carbonization of municipal waste streams. Environ Sci Technol 45:5696–5703

    Article  CAS  Google Scholar 

  • Boesch D, Burreson E, Dennison W, Houde E, Kemp M, Kennedy V, Newell R, Paynter K, Orth R, Ulanowicz R (2001) Factors in the decline of coastal ecosystems. Science 293:1589–1591

    Article  CAS  Google Scholar 

  • Cantrell KB, Hunt PG, Uchimiya M, Novak JM, Ro KS (2012) Impact of pyrolysis temperature and manure source on physicochemical characteristics of biochar. Bioresour Technol 107:419–428

    Article  CAS  Google Scholar 

  • Cao XD, Ma LN, Liang Y, Gao B, Harris W (2011a) Simultaneous immobilization of lead and atrazine in contaminated soils using dairy-manure biochar. Environ Sci Technol 45:4884–4889

    Article  CAS  Google Scholar 

  • Cao XY, Ro KS, Chappell M, Li YA, Mao JD (2011b) Chemical structures of swine-manure chars produced under different carbonization conditions investigated by advanced solid-state 13C nuclear magnetic resonance (NMR) spectroscopy. Energy Fuel 25:388–397

    Article  CAS  Google Scholar 

  • Cao X, Pignatello JJ, Li Y, Lattao C, Chappell MA, Chen N, Miller LF, Mao J (2012) Characterization of wood chars produced at different temperatures using advanced solid-state 13C NMR spectroscopic techniques. Energy Fuel 26:5983–5991

    Article  CAS  Google Scholar 

  • Cao X, Ro KS, Libra JA, Kammann CI, Lima I, Berge N, Li L, Li Y, Chen N, Yang J (2013) Effects of biomass types and carbonization conditions on the chemical characteristics of hydrochars. J Agric Food Chem 61:9401–9411

    Article  CAS  Google Scholar 

  • Cavendish H, Planta J (2011) Adsorption of nitrate and Cr(VI) by cationic polymer-modified granular activated carbon. Chem Eng J 175:298–305

    Article  CAS  Google Scholar 

  • Chen JG, Kong HN, DY W, Chen XC, Zhang DL, Sun ZH (2007) Phosphate immobilization from aqueous solution by fly ashes in relation to their composition. J Hazard Mater 139:293–300

    Article  CAS  Google Scholar 

  • Chen BL, Zhou DD, Zhu LZ (2008) Transitional adsorption and partition of nonpolar and polar aromatic contaminants by biochars of pine needles with different pyrolytic temperatures. Environ Sci Technol 42:5137–5143

    Article  CAS  Google Scholar 

  • Chen BL, Chen ZM, Lv SF (2011a) A novel magnetic biochar efficiently sorbs organic pollutants and phosphate. Bioresour Technol 102:716–723

    Article  CAS  Google Scholar 

  • Chen XC, Chen GC, Chen LG, Chen YX, Lehmann J, McBride MB, Hay AG (2011b) Adsorption of copper and zinc by biochars produced from pyrolysis of hardwood and corn straw in aqueous solution. Bioresour Technol 102:8877–8884

    Article  CAS  Google Scholar 

  • Chen T, Zhang YX, Wang HT, WJ L, Zhou ZY, Zhang YC, Ren LL (2014) Influence of pyrolysis temperature on characteristics and heavy metal adsorptive performance of biochar derived from municipal sewage sludge. Bioresour Technol 164:47–54

    Article  CAS  Google Scholar 

  • Cheng CH, Lehmann J (2009) Ageing of black carbon along a temperature gradient. Chemosphere 75:1021–1027

    Article  CAS  Google Scholar 

  • Cheng CH, Lehmann J, Thies JE, Burton SD, Engelhard MH (2006) Oxidation of black carbon by biotic and abiotic processes. Org Geochem 37:1477–1488

    Article  CAS  Google Scholar 

  • Cheng CH, Lehmann J, Engelhard MH (2008) Natural oxidation of black carbon in soils: changes in molecular form and surface charge along a climosequence. Geochim Cosmochim Acta 72:1598–1610

    Article  CAS  Google Scholar 

  • Chernyakhovskii VA (1985) Technology of unfired periclase-spinel parts with a phosphate binder. Refractories 26:41–44

    Article  Google Scholar 

  • Dai L, Wu B, Tan F, He M, Wang W, Qin H, Tang X, Zhu Q, Pan K, Hu Q (2014) Engineered hydrochar composites for phosphorus removal/recovery: lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw. Bioresour Technol 161:327–332

    Article  CAS  Google Scholar 

  • De-Bashan LE, Bashan Y (2004) Recent advances in removing phosphorus from wastewater and its future use as fertilizer (1997-2003). Water Res 38:4222–4246

    Article  CAS  Google Scholar 

  • Demirbas A, Arin G (2010) An overview of biomass pyrolysis. Energy Sources 24:471–482

    Article  Google Scholar 

  • Diaz RJ, Rosenberg R (2008) Spreading dead zones and consequences for marine ecosystems. Science 321:926–929

    Article  CAS  Google Scholar 

  • Eberhardt TL, Min SH (2008) Biosorbents prepared from wood particles treated with anionic polymer and iron salt: effect of particle size on phosphate adsorption. Bioresour Technol 99:626–630

    Article  CAS  Google Scholar 

  • Eberhardt TL, Min SH, Han JS (2006) Phosphate removal by refined aspen wood fiber treated with carboxymethyl cellulose and ferrous chloride. Bioresour Technol 97:2371–2376

    Article  CAS  Google Scholar 

  • Enders A, Hanley K, Whitman T, Joseph S, Lehmann J (2012) Characterization of biochars to evaluate recalcitrance and agronomic performance. Bioresour Technol 114:644–653

    Article  CAS  Google Scholar 

  • Fang C, Zhang T, Li P, Jiang RF, Wang YC (2014) Application of magnesium modified corn biochar for phosphorus removal and recovery from swine wastewater. Int J Environ Res Public Health 11:9217–9237

    Article  CAS  Google Scholar 

  • Gao F, Xue YW, Deng PY, Cheng XR, Yang K (2015) Removal of aqueous ammonium by biochars derived from agricultural residuals at different pyrolysis temperatures. Chem Speciat Bioavailab 27:92–97

    Article  CAS  Google Scholar 

  • Genz A, Kornmuller A, Jekel M (2004) Advanced phosphorus removal from membrane filtrates by adsorption on activated aluminium oxide and granulated ferric hydroxide. Water Res 38:3523–3530

    Article  CAS  Google Scholar 

  • Guo YJ, Tang H, Li GD, Xie DT (2014) Effects of cow dung biochar amendment on adsorption and leaching of nutrient from an acid yellow soil irrigated with biogas slurry. Water Air Soil Pollut 225:1–13

    Article  CAS  Google Scholar 

  • Han X, Liang CF, Li TQ, Wang K, Huang HG, Yang XE (2013) Simultaneous removal of cadmium and sulfamethoxazole from aqueous solution by rice straw biochar. J Zhejiang Univ Sci B 14:640–649

    Article  CAS  Google Scholar 

  • Harvey OR, Herbert BE, Rhue RD, Kuo LJ (2011) Metal interactions at the biochar-water interface: energetics and structure-sorption relationships elucidated by flow adsorption microcalorimetry. Environ Sci Technol 45:5550–5556

    Article  CAS  Google Scholar 

  • Hema M, Arivoli S (2007) Comparative study on the adsorption kinetics and thermodynamics of dyes onto acid activated low cost carbon. Int J Phys Sci 2:10–17

    Google Scholar 

  • Hollister CC, Bisogni JJ, Lehmann J (2013) Ammonium, nitrate, and phosphate sorption to and solute leaching from biochars prepared from corn stover (Zea mays L.) and oak wood (Quercus spp.) J Environ Qual 42:137–144

    Article  CAS  Google Scholar 

  • Huang HM, Xiao XM, Yan B, Yang LP (2010) Ammonium removal from aqueous solutions by using natural Chinese (Chende) zeolite as adsorbent. J Hazard Mater 175:247–252

    Article  CAS  Google Scholar 

  • Iida T, Amano Y, Machida M, Imazeki F (2013) Effect of surface property of activated carbon on adsorption of nitrate ion. Chem Pharm Bull 61:1173

    Article  CAS  Google Scholar 

  • Ismadji S, Tong DS, Soetaredjo FE, Ayucitra A, WH Y, Zhou CH (2016) Bentonite hydrochar composite for removal of ammonium from Koi fish tank. Appl Clay Sci 119:146–154

    Article  CAS  Google Scholar 

  • Jung KW, Ahn KH (2016) Fabrication of porosity-enhanced MgO/biochar for removal of phosphate from aqueous solution: application of a novel combined electrochemical modification method. Bioresour Technol 200:1029–1032

    Article  CAS  Google Scholar 

  • Jung KW, Hwang MJ, Ahn KH, Ok YS (2015a) Kinetic study on phosphate removal from aqueous solution by biochar derived from peanut shell as renewable adsorptive media. Int J Environ Sci Technol 12:3363–3372

    Article  CAS  Google Scholar 

  • Jung KW, Hwang MJ, Jeong TU, Ahn KH (2015b) A novel approach for preparation of modified-biochar derived from marine macroalgae: dual purpose electro-modification for improvement of surface area and metal impregnation. Bioresour Technol 191:342–345

    Article  CAS  Google Scholar 

  • Jung KW, Jeong TU, Hwang MJ, Kim K, Ahn KH (2015c) Phosphate adsorption ability of biochar/Mg-Al assembled nanocomposites prepared by aluminum-electrode based electro-assisted modification method with MgCl2 as electrolyte. Bioresour Technol 198:603–610

    Article  CAS  Google Scholar 

  • Jung KW, Kim K, Jeong TU, Ahn KH (2016) Influence of pyrolysis temperature on characteristics and phosphate adsorption capability of biochar derived from waste-marine macroalgae (Undaria pinnatifida roots). Bioresour Technol 200:1024–1028

    Article  CAS  Google Scholar 

  • Kambo HS, Dutta A (2015) A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications. Renew Sust Energ Rev 45:359–378

    Article  CAS  Google Scholar 

  • Keiluweit M, Kleber M (2009) Molecular-level interactions in soils and sediments: the role of aromatic pi-systems. Environ Sci Technol 43:3421–3429

    Article  CAS  Google Scholar 

  • Kizito S, SB W, Kirui WK, Lei M, QM L, Bah H, Dong RJ (2015) Evaluation of slow pyrolyzed wood and rice husks biochar for adsorption of ammonium nitrogen from piggery manure anaerobic digestate slurry. Sci Total Environ 505:102–112

    Article  CAS  Google Scholar 

  • Kong HL, He J, Gao YZ, HF W, Zhu XZ (2011) Cosorption of phenanthrene and mercury(II) from aqueous solution by soybean stalk-based biochar. J Agric Food Chem 59:12116–12123

    Article  CAS  Google Scholar 

  • Krishnan KA, Haridas A (2008) Removal of phosphate from aqueous solutions and sewage using natural and surface modified coir pith. J Hazard Mater 152:527–535

    Article  CAS  Google Scholar 

  • Lehmann J (2007a) A handful of carbon. Nature 447:143–144

    Article  CAS  Google Scholar 

  • Lehmann J (2007b) Bio-energy in the black. Front Ecol Environ 5:381–387

    Article  Google Scholar 

  • Lehmann J, Joseph S (2009) Biochar for environmental management: an introduction. Biochar for Environmental Management Science and Technology. Earthscans, UK, pp 1–12

  • Lehmann J, Gaunt J, Rondon M (2006) Bio-char sequestration in terrestrial ecosystems – a review. Mitig Adapt Strateg Glob Chang 11:395–419

    Article  Google Scholar 

  • Li X, Shen Q, Zhang D, Mei X, Ran W, Xu Y, Yu G (2013) Functional groups determine biochar properties (pH and EC) as studied by two-dimensional 13C NMR correlation spectroscopy. PLoS One 8:e65949

    Article  CAS  Google Scholar 

  • Liang B, Lehmann J, Solomon D, Kinyangi J, Grossman J, O'Neill B, Skjemstad JO, Thies J, Luizao FJ, Petersen J, Neves EG (2006) Black carbon increases cation exchange capacity in soils. Soil Sci Soc Am J 70:1719–1730

    Article  CAS  Google Scholar 

  • Liu HW, Dong YH, Wang HY, Liu Y (2010) Ammonium adsorption from aqueous solutions by strawberry leaf powder: equilibrium, kinetics and effects of coexisting ions. Desalination 263:70–75

    Article  CAS  Google Scholar 

  • Liu X, Zhang Y, Li ZF, Feng R, Zhang YZ (2014) Characterization of corncob-derived biochar and pyrolysis kinetics in comparison with corn stalk and sawdust. Bioresour Technol 170:76–82

    Article  CAS  Google Scholar 

  • Liu FL, Zuo JE, Chi T, Wang P, Yang B (2015) Removing phosphorus from aqueous solutions by using iron-modified corn straw biochar. Front Environ Sci Eng 9:1066–1075

    Article  CAS  Google Scholar 

  • Lǚ J, Liu H, Liu R, Zhao X, Sun L, Qu J (2013) Adsorptive removal of phosphate by a nanostructured Fe–Al–Mn trimetal oxide adsorbent. Powder Technol 233:146–154

    Article  CAS  Google Scholar 

  • Ma ZH, Li Q, Yue QY, Gao BY, Li WH, Xu X, Zhong QQ (2011) Adsorption removal of ammonium and phosphate from water by fertilizer controlled release agent prepared from wheat straw. Chem Eng J 171:1209–1217

    Article  CAS  Google Scholar 

  • Mangun CL, Debarr JA, Economy J (2001) Adsorption of sulfur dioxide on ammonia-treated activated carbon fibers. Carbon 39:1689–1696

    Article  CAS  Google Scholar 

  • Maurer M, Abramovich D, Siegrist H, Gujer W (1999) Kinetics of biologically induced phosphorus precipitation in waste-water treatment. Water Res 33:484–493

    Article  CAS  Google Scholar 

  • Meyer S, Glaser B, Quicker P (2011) Technical, economical, and climate-related aspects of biochar production technologies: a literature review. Environ Sci Technol 45:9473–9483

    Article  CAS  Google Scholar 

  • Mizuta K, Matsumoto T, Hatate Y, Nishihara K, Nakanishi T (2004) Removal of nitrate-nitrogen from drinking water using bamboo powder charcoal. Bioresour Technol 95:255–257

    Article  CAS  Google Scholar 

  • Mukherjee A, Zimmerman AR, Harris W (2011) Surface chemistry variations among a series of laboratory-produced biochars. Geoderma 163:247–255

    Article  CAS  Google Scholar 

  • Nguyen BT, Lehmann J (2009) Black carbon decomposition under varying water regimes. Org Geochem 40:846–853

    Article  CAS  Google Scholar 

  • Novak JM, Busscher WJ, Watts DW, Laird DA, Ahmedna MA, Niandou MAS (2010) Short-term CO2 mineralization after additions of biochar and switchgrass to a Typic Kandiudult. Geoderma 154:281–288

    Article  CAS  Google Scholar 

  • Özacar M (2003) Equilibrium and kinetic modelling of adsorption of phosphorus on calcined alunite. Adsorption 9:125–132

    Article  Google Scholar 

  • Paerl HW (2009) Controlling eutrophication along the freshwater–marine continuum: dual nutrient (N and P) reductions are essential. Estuar Coasts 32:593–601

    Article  CAS  Google Scholar 

  • Park JH, Choppala G, Lee SJ, Bolan N, Chung JW, Edraki M (2013) Comparative sorption of Pb and Cd by biochars and its implication for metal immobilization in soils. Water Air Soil Pollut 224:1711

    Article  CAS  Google Scholar 

  • Park JH, Ok YS, Kim SH, Cho JS, Heo JS, Delaune RD, Seo DC (2015) Evaluation of phosphorus adsorption capacity of sesame straw biochar on aqueous solution: influence of activation methods and pyrolysis temperatures. Environ Geochem Health 37:969–983

    Article  CAS  Google Scholar 

  • Parks GA (1965) The isoelectric points of solid oxides, solid hydroxides, and aqueous hydroxo complex systems. Chem Rev 65:177–198

    Article  CAS  Google Scholar 

  • Regmi P, Garcia Moscoso JL, Kumar S, Cao X, Mao J, Schafran G (2012) Removal of copper and cadmium from aqueous solution using switchgrass biochar produced via hydrothermal carbonization process. J Environ Manag 109:61–69

    Article  CAS  Google Scholar 

  • Ren J, Li N, Li L, An JK, Zhao L, Ren NQ (2015) Granulation and ferric oxides loading enable biochar derived from cotton stalk to remove phosphate from water. Bioresour Technol 178:119–125

    Article  CAS  Google Scholar 

  • Šafařík I, Nymburská K, Šafaříková M (1997) Adsorption of water-soluble organic dyes on magnetic charcoal. J Chem Technol Biotechnol 69:1–4

    Article  Google Scholar 

  • Sarkhot DV, Ghezzehei TA, Berhe AA (2013) Effectiveness of biochar for sorption of ammonium and phosphate from dairy effluent. J Environ Qual 42:1545–1554

    Article  CAS  Google Scholar 

  • Sica M, Duta A, Teodosiu C, Draghici C (2014) Thermodynamic and kinetic study on ammonium removal from a synthetic water solution using ion exchange resin. Clean Techn Environ Policy 16:351–359

    Article  CAS  Google Scholar 

  • Silber A, Levkovitch I, Graber ER (2010) pH-dependent mineral release and surface properties of cornstraw biochar: agronomic implications. Environ Sci Technol 44:9318–9323

    Article  CAS  Google Scholar 

  • Smith VH (2003) Eutrophication of freshwater and coastal marine ecosystems a global problem. Environ Sci Pollut Res 10:126–139

    Article  CAS  Google Scholar 

  • Takaya CA, Fletcher LA, Singh S, Anyikude KU, Ross AB (2016) Phosphate and ammonium sorption capacity of biochar and hydrochar from different wastes. Chemosphere 145:518–527

    Article  CAS  Google Scholar 

  • Verheijen FGA, Jeffery S, Bastos AC, van der Velde M, Diafas I (2009) Biochar application to soils-a critical scientific review of effects on soil properties, processes and functions. EUR 24099 EN, Office for Official Publications of the European Communities, Luxembourg, p 149

  • Volceanov E, Georgescu M, Volceanov A, Mihalache F (2001) Zirconium phosphate binder for periclase refractories. Key Eng Mater 206-213:1677–1680

    Article  Google Scholar 

  • Wahab M, Jellali S, Jedidi N (2010) Ammonium biosorption onto sawdust: FTIR analysis, kinetics and adsorption isotherms modeling. Bioresour Technol 101:5070–5075

    Article  CAS  Google Scholar 

  • Wang ZH, Guo HY, Shen F, Yang G, Zhang YZ, Zeng YM, Wang LL, Xiao H, Deng SH (2015) Biochar produced from oak sawdust by lanthanum (La)-involved pyrolysis for adsorption of ammonium (NH+ 4), nitrate (NO− 3), and phosphate (PO3- 4). Chemosphere 119:646–653

    Article  CAS  Google Scholar 

  • Yao Y, Gao B, Inyang M, Zimmerman AR, Cao XD, Pullammanappallil P, Yang LY (2011a) Removal of phosphate from aqueous solution by biochar derived from anaerobically digested sugar beet tailings. J Hazard Mater 190:501–507

    Article  CAS  Google Scholar 

  • Yao Y, Gao B, Inyang M, Zimmerman AR, Cao XD, Pullammanappallil P, Yang LY (2011b) Biochar derived from anaerobically digested sugar beet tailings: characterization and phosphate removal potential. Bioresour Technol 102:6273–6278

    Article  CAS  Google Scholar 

  • Yao Y, Gao B, Chen JJ, Yang LY (2013a) Engineered biochar reclaiming phosphate from aqueous solutions: mechanisms and potential application as a slow-release fertilizer. Environ Sci Technol 47:8700–8708

    Article  CAS  Google Scholar 

  • Yao Y, Gao B, Chen JJ, Zhang M, Inyang M, Li YC, Alva A, Yang LY (2013b) Engineered carbon (biochar) prepared by direct pyrolysis of Mg-accumulated tomato tissues: characterization and phosphate removal potential. Bioresour Technol 138:8–13

    Article  CAS  Google Scholar 

  • Yoon SY, Lee CG, Park JA, Kim JH, Kim SB, Lee SH, Choi JW (2014) Kinetic, equilibrium and thermodynamic studies for phosphate adsorption to magnetic iron oxide nanoparticles. Chem Eng J 236:341–347

    Article  CAS  Google Scholar 

  • Zach-Maor A, Semiat R, Shemer H (2011) Synthesis, performance, and modeling of immobilized nano-sized magnetite layer for phosphate removal. J Colloid Interface Sci 357:440–446

    Article  CAS  Google Scholar 

  • Zeng Z, Zhang SD, Li TQ, Zhao FL, He ZL, Zhao HP, Yang XE, Wang HL, Zhao J, Rafiq MT (2013) Sorption of ammonium and phosphate from aqueous solution by biochar derived from phytoremediation plants. J Zhejiang Univ Sci B 14:1152–1161

    Article  CAS  Google Scholar 

  • Zhang JS, Wang QQ (2016) Sustainable mechanisms of biochar derived from brewers’ spent grain and sewage sludge for ammonia-nitrogen capture. J Clean Prod 112:3927–3934

    Article  CAS  Google Scholar 

  • Zhang GS, JH Q, Liu HJ, Cooper AT, RC W (2007) CuFe2O4/activated carbon composite: a novel magnetic adsorbent for the removal of acid orange II and catalytic regeneration. Chemosphere 68:1058–1066

    Article  CAS  Google Scholar 

  • Zhang T, Li Q, Ding L, Ren H, Xu K, Wu Y, Sheng D (2011) Modeling assessment for ammonium nitrogen recovery from wastewater by chemical precipitation. J Environ Sci 23:881–890

    Article  CAS  Google Scholar 

  • Zhang M, Gao B, Yao Y, Xue YW, Inyang M (2012) Synthesis of porous MgO-biochar nanocomposites for removal of phosphate and nitrate from aqueous solutions. Chem Eng J 210:26–32

    Article  CAS  Google Scholar 

  • Zhang M, Gao B, Yao Y, Inyang MD (2013) Phosphate removal ability of biochar/MgAl-LDH ultra-fine composites prepared by liquid-phase deposition. Chemosphere 92:1042–1047

    Article  CAS  Google Scholar 

  • Zhang M, Gao B, Fang J, Creamer AE, Ullman JL (2014a) Self-assembly of needle-like layered double hydroxide (LDH) nanocrystals on hydrochar: characterization and phosphate removal ability. RSC Adv 4:28171–28175

    Article  CAS  Google Scholar 

  • Zhang Y, Li ZF, Mahmood IB (2014b) Recovery of NH+ 4 by corn cob produced biochars and its potential application as soil conditioner. Front Environ Sci Eng 8:825–834

    Article  CAS  Google Scholar 

  • Zheng W, Guo MX, Chow T, Bennett DN, Rajagopalan N (2010) Sorption properties of greenwaste biochar for two triazine pesticides. J Hazard Mater 181:121–126

    Article  CAS  Google Scholar 

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 51506054), Hebei Provincial Natural Science Foundation (No. E2016502089), and the Fundamental Research Funds for the Central Universities (No. 2015MS118).

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Yin, Q., Zhang, B., Wang, R. et al. Biochar as an adsorbent for inorganic nitrogen and phosphorus removal from water: a review. Environ Sci Pollut Res 24, 26297–26309 (2017). https://doi.org/10.1007/s11356-017-0338-y

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