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Heavy metals mobility associated with the molybdenum mining-concentration complex in the Buryatia Republic, Germany

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An Erratum to this article was published on 17 February 2017

Abstract

Mining of Dzhida ore deposits in Russia has caused the formation of a large tailings dam with technogenic sands and contamination of nearby district soils. Geochemical fractions of technogenic sands were divided by a sequential extraction procedure. The sampling points with maximum concentration of Pb, Cu, and Zn were selected for investigation of heavy metal mobility. Two previously described methods of heavy metal fractionation using selective extraction were applied: a procedure developed by the Community Bureau of Reference of the Commission of the European Communities (BCR procedure) and Tessier’s fractionation scheme. Despite some differences in Pb extractions, the two procedures describe equally well the distribution of heavy metals on geochemical fractions. BCR procedure was chosen as a fast method of heavy metal mobile form estimation. For considered mining object, it is revealed that there are different characters of heavy metal mobility sequence in the soils Zn > Cu > Pb and technogenic sands Pb > Zn > Cu.

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References

  • Akcil A, Koldas S (2006) Acid mine drainage (AMD): causes, treatment and case studies. J Clean Prod 14:1139–1145

    Article  Google Scholar 

  • Bacon JR, Davidson CM (2008) Is there a future for sequential chemical extraction? Analyst 133:25–46

    Article  CAS  Google Scholar 

  • Beckhoff B, Kanngießer B, Langhoff N, Wedell R, Wolff H (2006) Handbook of practical X-ray fluorescence analysis. Springer-Verlag Berlin Heidelberg. ISBN 3-540-28603-9

  • Bhattacharya A, Routh J, Jacks G, Bhattacharya P, Mörth M (2006) Environmental quality assessment of abandoned mine tailings in Adak, Västerbotten district (northern Sweden). Appl Geochem 21:1760–1780

    Article  CAS  Google Scholar 

  • Doelsch E, Moussard G, Saint Macary H (2008) Fractionation of tropical soilborne heavy metals—comparison of two sequential extraction procedures. Geoderma 143:168–179

    Article  CAS  Google Scholar 

  • Duplay J, Semhi K, Errais E, Imfeld G, Babcsanyi I, Perrone T (2014) Copper, zinc, lead and cadmium bioavailability and retention in vineyard soils (Rouffach, France): the impact of cultural practices. Geoderma 230–231:318–328

    Article  Google Scholar 

  • García-Delgado M, Rodríguez-Cruz MS, Lorenzo LF, Arienzo M, Sánchez-Martín MJ (2007) Seasonal and time variability of heavy metal content and of its chemical forms in sewage sludges from different wastewater treatment plants. Sci Total Environ 382:82–92

    Article  Google Scholar 

  • GN 2.1.7.2041–06 Hygienic standards (2006) “Maximum admissible concentrations (MAC) of chemical matters in soil” (in Russian)

  • GOST 17.4.1.02-83 (1983) Nature protection. Soils. Classification of chemical for pollution control, Moskow (in Russian)

  • GOST R 50683-94 (1994) Soils. Determination of mobile compounds of copper and cobalt by Krupsky and Aleksndrova method modified by Central Research Institute of Agrochemical Service (CINAO), Moscow (in Russian)

  • GOST R 50686-94 Soils (1994) Determination of mobile compounds of zinc by Krupsky and Alexandrova method modified by Central Research Institute of Agrochemical Service (CINAO), Moscow (in Russian)

  • Greenway GM, Song QJ (2002) An ultrasound accelerated sequential extraction method and its application for element partitioning studies in compost from mixed waste streams. J Environ Monit 4:950–955

    Article  CAS  Google Scholar 

  • Gruszecka MA, Wdowin M (2013) Characteristics and distribution of analyzed metals in soil profiles in the vicinity of a postflotation waste site in the Bukowno region, Poland. Environ Monit Assess 185:8157–8168

    Article  CAS  Google Scholar 

  • Guerra P, Ahumada I, Carrasco A (2007) Effect of biosolid incorporation to mollisol soils on Cr, Cu, Ni, Pb, and Zn fractionation, and relationship with their bioavailability. Chemosphere 68:2021–2027

    Article  CAS  Google Scholar 

  • Halim MA, Majumder RK, Zaman MN, Hossain S, Rasul MG, Sasaki K (2013) Mobility and impact of trace metals in Barapukuria coal mining area, Northwest Bangladesh. Arab J Geosci 6:4593–4605

    Article  CAS  Google Scholar 

  • Ho MD, Evans GJ (1997) Operational speciation of cadmium, copper, lead and zinc in the NIST Standard Reference Materials 2710 and 2711 (Montana soil) by the BCR sequential extraction procedure and flame atomic absorption spectrometry. Analytical Communication 34:363–364

    Article  CAS  Google Scholar 

  • Instruction №155-ХС (1978) Chemical-spectral methods. Scientific council on analytical methods at All-Russian Research Institute for Geology and Mineral Resources. Moscow (in Russian)

  • Khodanovich PY (1995) Molibden-volframovie mestorozhdniya Dzhidinskogo rudnogo polya. T. 1. kn. 1. Geoinformmark, Moskva, p 149–163 (in Russian)

  • Lee P-K, Kang M-J, Jo HY, Choi S-H (2012) Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments. Environmental Earth Sciences 66:1909–1923

    Article  CAS  Google Scholar 

  • Li J, Lu Y, Shim H, Deng X, Lian J, Jia Z, Li J (2010) Use of the BCR sequential extraction procedure for the study of metal availability to plants. J Environ Monit 12:466–471

    Article  CAS  Google Scholar 

  • Oyeyiola AO, Olayinka KO, Alo BI (2011) Comparison of three sequential extraction protocols for the fractionation of potentially toxic metals in coastal sediments. Environ Monit Assess 172:319–327

    Article  CAS  Google Scholar 

  • Perez-Cid B, Lavilla I, Bendicho C (1996) Analytical assessment of two sequential extraction schemes for metal partitioning in sewage sludges. Analyst 121:1479–1484

    Article  CAS  Google Scholar 

  • Pueyo M, Mateu J, Rigol A, Vidal M, Lopez-Sanchez JF, Rauret G (2008) Use of the modified BCR three-step sequential extraction procedure for the study of trace element dynamics in contaminated soils. Environ Pollut 152(2):330–341

    Article  CAS  Google Scholar 

  • Quevauviller P, Rauret G, Muntau H, Ure AM, Rubio R, López Sánchez JF, Fiedler HD, Griepink B (1994) Evaluation of a sequential extraction procedure for the determination of extractable trace metal contents in sediments. Fresenius Journal of Analytical Chemistry 349:808–814

    Article  CAS  Google Scholar 

  • Rastvorova OG, Andreev DP, Gagarina EI, Kasatkin GA, Fedorova NN (1995) The chemical analysis of soils: the manual. St.-Petersburg University, St.-Petersburg (in Russian)

    Google Scholar 

  • Rauret G, López Sánchez JF, Sahuquillo A, Rubio R, Davidson C, Ure A, Quevauviller P (1999) Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials. J Environ Monit 1:57–61

    Article  CAS  Google Scholar 

  • Rauret G, Lopez-Sanchez JF, Lück D, Yli-Halla M, Muntau H, Quevauviller Ph (2001) The certification of the extractable contents (mass fractions) of Cd, Cr, Cu, Pb and Zn in freshwater sediment following a sequential extraction procedure BCR-701. European Commission, BCR information, Reference materials. EUR 19775 EN. 82 pp

  • Samuel NL, Phillips DJH (1988) Distribution, variability and impacts of trace elements in San Francisco Bay. Mar Pollut Bull 19:413–425

    Article  Google Scholar 

  • Schnitzer M, Khan S (1972) Humic substances in the environment. Marcel Dekker, New York 327 pp

    Google Scholar 

  • Smirnova OK, Sarapulova AE, Tsyrenova AA (2010) Features of heavy metal occurrence in geotechnogenic landscapes of Dzhidinsky tungsten-molybdate industrial complex. Geoecologiya Inzhenernaya geologiya Gidrogeologiya Geokriologiya 3:244–252 (in Russian)

    Google Scholar 

  • Stone M, Marsalek J (1996) Trace metal composition and speciation in street sediment: Sault Ste. Marie, Canada. Water Air and Soil Pollution 87:149–169

    Article  CAS  Google Scholar 

  • Svete P, Milacic R, Phihlar B (2001) Partitioning of Zn, Pb and Cd in river sediments from a lead and zinc mining area using the BCR three-step sequential extraction procedure. J Environ Monit 3:586–590

    Article  CAS  Google Scholar 

  • Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51:844–851

    Article  CAS  Google Scholar 

  • Tokalioglu S, Kartal S, Elci L (2000) Determination of heavy metals and their speciation in lake sediments by flame atomic absorption spectrometry after a four-stage sequential extraction procedure. Anal Chim Acta 413:33–40

    Article  CAS  Google Scholar 

  • Tokalioglu S, Kartal S, Birol G (2003) Comparison of three sequential extraction procedures for partitioning of heavy metals in car park dusts. J Environ Monit 5:468–476

    Article  CAS  Google Scholar 

  • Vrhovnik P, Šmuc NR, Dolenec T, Serafimovski T, Dolenec M (2013) Impact of Pb-Zn mining activity on surficial sediments of Lake Kalimanci (FYR Macedonia). Turk J Earth Sci 22:996–1009

    Article  CAS  Google Scholar 

  • Zhalsarayev BZ (1999) The device for the X-ray fluorescence analysis. Russian Federation Patent 2130604, issued May 20 (in Russian)

Download references

Acknowledgements

This work was supported by the complex integration project of the Siberian Branch of the Russian Academy of Science № 112 “Geochemical and biological factors of chemical elements migration in geosystems” and Russian Foundation for Basic Research, RFBR 16-05-01041 “Geo-ecological aspects of migration chemical elements in natural and technogenic systems of sulfide deposits of Transbaikalia”.

The authors are grateful to Zhalsarayev B. Zh. for the X-ray fluorescence analysis, Tsyrenova A. A. for the atomic absorption spectrometry at the Geological Institute SB RAS, and Johanna M. Blake from the University of New Mexico for the consultations.

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Correspondence to Angelina Sarapulova.

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Responsible editor: Philippe Garrigues

An erratum to this article is available at http://dx.doi.org/10.1007/s11356-017-8579-3.

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Sarapulova, A., Dampilova, B.V., Bardamova, I. et al. Heavy metals mobility associated with the molybdenum mining-concentration complex in the Buryatia Republic, Germany. Environ Sci Pollut Res 24, 11090–11100 (2017). https://doi.org/10.1007/s11356-016-8105-z

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