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Effects of binding materials on microaggregate size distribution in bauxite residues

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Abstract

It is recognized that for successful establishment of a vegetation cover on bauxite residue disposal areas, soil formation and a greater understanding of the processes of soil development are crucial. The stability of microaggregates is a very important physical property that prevents erosion in bauxite residues. Samples were collected from a disposal area in Central China to determine not only the mechanism of aggregation but also clay dispersion. Colloidal stability was assessed by determining organic matter, carbonate, electrolyte, clay mineral, and iron-aluminum oxide forms, as these would contribute to their stability. Organic matter improved microaggregate stability by combining with clay particles and polyvalent cations to form macroaggregates. Polyvalent cations such as calcium had a positive effect on particle flocculation, while organic molecules were more effective at stabilizing microaggregates. Removal of salinity dispersed silt-size aggregates into clay-size aggregates and reduced microaggregate stability. Calcium improved particle aggregation, while sodium had the reverse effect. Quartz powder was added to the residues but did not show any cementing effect, while free and amorphous iron-aluminum oxides were effective binding agents for microaggregate formation. We propose that the presence of organic matter and polyvalent cations, together with incorporation of organic carbon and calcium minerals, may enhance the stability of this material and prove beneficial toward improving its physical condition.

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References

  • Alperovitch N, Shainberg I, Keren R (1981) Specific effect of magnesium on the hydraulic conductivity of sodic soils. Eur J Soil Sci 32:543–554

    Article  CAS  Google Scholar 

  • Amézketa E (1999) Soil aggregate stability: a review. J Sustain Agr 14:83–151

    Article  Google Scholar 

  • Amézketa E, Carranza R, Urgel B, Lafarga RA (2003) Chemical, spontaneous and mechanical dispersion of clays in arid-zone soils. Span J Agric Res 1(4):95–107

    Article  Google Scholar 

  • Armstrong ASB, Tanton TW (1992) Gypsum applications to aggregated saline-sodic clay topsoils. Eur J Soil Sci 43:249–260

    Article  CAS  Google Scholar 

  • Arora HS, Coleman NT (1979) The influence of electrolyte concentration on flocculation of clay suspensions. Soil Sci 127:134–189

    Article  CAS  Google Scholar 

  • Bronick CJ, Lal R (2005) Soil structure and management: a review. Geoderma 124:3–22

    Article  CAS  Google Scholar 

  • Cammeraat LH, Imeson AC (1998) Deriving indicators of soil degradation from soil aggregation studies in southeastern Spain and southern France. Geomorphology 23:307–321

    Article  Google Scholar 

  • Chan KY, Heenan DP (1998) Effect of lime (CaCO3) application on soil structural stability of a red earth. Soil Res 36(1):73–86

    Article  Google Scholar 

  • Chauhan S, Ganguly A (2011) Standardizing rehabilitation protocol using vegetation cover for bauxite waste (red mud) in eastern India. Ecol Eng 37:504–510

    Article  Google Scholar 

  • Chen YY, Zhao WJ, Jia YG, Xu GH (2009) Effects of clay and organic matter on sediment microaggregate composition and its stability in tidal zone of Yellow River estuary. Mar Geol Quat Geol 29(1):31–37 in Chinese

    Article  Google Scholar 

  • Clough A, Skjemstad JO (2000) Physical and chemical protection of soil organic carbon in three agricultural soils with different contents of calcium carbonate. Aust J Soil Res 38:1005–1016

    Article  CAS  Google Scholar 

  • Courtney R, Kirwan L (2012) Gypsum amendment of alkaline bauxite residue—plant available aluminium and implications for grassland restoration. Ecol Eng 42:279–282

    Article  Google Scholar 

  • Courtney RG, Jordan SN, Harrington T (2009) Physico-chemical changes in bauxite residue following application of spent mushroom compost and gypsum. Land Degrad Dev 20(5):572–581

    Article  Google Scholar 

  • Courtney R, Harrington T, Byrne KA (2013) Indicators of soil formation in restored bauxite residues. Ecol Eng 58:63–68

    Article  Google Scholar 

  • Duiker SW, Rhoton FE, Torrent J, Smeck NE, Lal R (2003) Iron (hydr)oxide crystallinity effects on soil aggregation. Soil Sci Soc Am J 67:606–611

    Article  CAS  Google Scholar 

  • Gräfe M, Klauber C (2011) Bauxite residue issues: IV. Old obstacles and new pathways for in situ residue bioremediation. Hydrometallurgy 108:46–59

    Article  Google Scholar 

  • Hind AR, Bhargava SK, Grocott SC (1999) The surface chemistry of Bayer process solids: a review. Colloid Surface A 146:359–374

    Article  CAS  Google Scholar 

  • Huang L, Wang CY, Tan WF, HQ H, Cai CF, Wang MK (2010) Distribution of organic matter in aggregates of eroded Ultisols, Central China. Soil Till Res 108:59–67

    Article  Google Scholar 

  • Igwe CA, Zarei M, Stahr K (2009) Colloidal stability in some tropical soils of southeastern Nigeria as affected by iron and aluminium oxides. Catena 77:232–237

    Article  CAS  Google Scholar 

  • Jones BEH, Haynes RJ (2011) Bauxite processing residue: a critical review of its formation, properties, storage, and revegetation. Crit Rev Env Sci Tec 41:271–315

    Article  CAS  Google Scholar 

  • Jones BEH, Haynes RJ, Phillips IR (2011) Influence of organic waste and residue mud additions on chemical, physical and microbial properties of bauxite residue sand. Environ Sci Pollut R 18:199–211

    Article  CAS  Google Scholar 

  • Klauber C, Gräfe M, Power G (2011) Bauxite residue issues: II. Options for residue utilization. Hydrometallurgy 108(1–2):11–32

    Article  CAS  Google Scholar 

  • Levy GL, Stern R, Agassi M, Smith HJC (1993) Microaggregate stability of kaolinitic and illitic soils determined by ultrasonic energy. Soil Sci Soc Am J 57:803–808

    Article  CAS  Google Scholar 

  • Liu S, Kang Y, Wan S, Wang Z, Liang Z, Sun X (2011) Water and salt regulation and its effects on Leymus chinensis growth under drip irrigation in saline-sodic soils of the Songnen Plain. Agr Water. Manage 98:1469–1476

    Google Scholar 

  • Liu WC, Chen XQ, Li WX, YF Y, Yan K (2014) Environmental assessment, management and utilization of red mud in China. J Clean Prod 84:606–610

    Article  CAS  Google Scholar 

  • Mbagwu JSC, Auerswald K (1999) Relationship of percolation stability of soil aggregates to land use, selected properties, structural indices and simulated rainfall erosion. Soil Till Res 50:197–206

    Article  Google Scholar 

  • Metreveli G, Philippe A, Schaumann GE (2014) Disaggregation of silver nanoparticle homoaggregates in a river water matrix. Sci Total Environ 535:35–44

    Article  Google Scholar 

  • Miller WP, Frenkel H, Newman KD (1990) Flocculation concentration and sodium/calcium exchange of kaolinitic soil clays. Soil Sci Soc Am J 54(2):346–351

    Article  CAS  Google Scholar 

  • Opara CC (2009) Soil microaggregates stability under different land use types in southeastern Nigeria. Catena 79:103–112

    Article  CAS  Google Scholar 

  • Piccolo A, Mbagwu JSC (1990) Effects of different organic waste amendments on soil microaggregates stability and molecular sizes of humic substances. Plant Soil 123:27–37

    CAS  Google Scholar 

  • Pinheiro-Dick D, Schwertmann U (1996) Microaggregates from Oxisols and Inceptisols: dispersion through selective dissolutions and physicochemical treatments. Geoderma 74:49–63

    Article  CAS  Google Scholar 

  • Power G, Gräfe M, Klauber C (2011) Bauxite residue issues: I. Current management, disposal and storage practices. Hydrometallurgy 108:33–45

    Article  CAS  Google Scholar 

  • Qadir M, Schubert S (2002) Degradation processes and nutrient constraints in sodic soils. Land Degrad Dev 13:275–294

    Article  Google Scholar 

  • Santini TC, Fey MV (2013) Spontaneous vegetation encroachment upon bauxite residue (red mud) as an indicator and facilitator of in situ remediation processes. Environ Sci Technol 47:12089–12096

    Article  CAS  Google Scholar 

  • Santini TC, Kerr JL, Warren LA (2015) Microbially-driven strategies for bioremediation of bauxite residue. J Hazard Mater 293:131–157

    Article  CAS  Google Scholar 

  • Six J, Bossuyt H, Degryze S, Denef K (2004) A history of research on the link between (micro)aggregates, soil biota, and soil organic matter dynamics. Soil Till Res 79:7–31

    Article  Google Scholar 

  • Sochan A, Bieganowski A, Ryżak M, Dobrowolski R, Bartmiński P (2012) Comparison of soil texture determined by two dispersion units of Mastersizer 2000. Int Agrophys 26:99–102

    Article  Google Scholar 

  • Tarchitzky J, Chen Y, Banin AS (1993) Humic substances and pH effects on sodium and calcium-montmorillonite flocculation and dispersion. Soil Sci Soc Am J 57:367–372

    Article  CAS  Google Scholar 

  • Ternan JL, Elmes A, Williams AG, Hartley R (1996) Aggregate stability of soils in Central Spain and the role of land management. Earth Surf Proc Land 21:181–193

    Article  Google Scholar 

  • Tisdall JM, Oades JM (1982) Organic matter and water-stable aggregates in soils. Eur J Soil Sci 33:141–163

    Article  CAS  Google Scholar 

  • Wang F, Pan G, Li L (2009) Effects of free iron oxyhydrates and soil organic matter on copper sorption-desorption behavior by size fractions of aggregates from two paddy soils. J Environ Sci (China) 21:618–624

    Article  CAS  Google Scholar 

  • Xue SG, Zhu F, Kong XF, Wu C, Huang L, Huang N, Hartley W (2016) A review of the characterization and revegetation of bauxite residues (red mud). Environ Sci Pollut R 23:1120–1132

    Article  CAS  Google Scholar 

  • Zanuzzi A, Arocena JM, van Mourik JM, Faz Cano A (2009) Amendments with organic and industrial wastes stimulate soil formation in mine tailings as revealed by micromorphology. Geoderma 154:69–75

    Article  CAS  Google Scholar 

  • Zhang XC, Norton LD (2002) Effect of exchangeable Mg on saturated hydraulic conductivity, disaggregation and clay dispersion of disturbed soils. J Hydrol 260:194–205

    Article  CAS  Google Scholar 

  • Zhang S, Li Q, Zhang X, Wei K, Chen L, Liang W (2012) Effects of conservation tillage on soil aggregation and aggregate binding agents in black soil of Northeast China. Soil Till Res 124:196–202

    Article  Google Scholar 

  • Zheng FL (2006) Effect of vegetation changes on soil erosion on the loess plateau. Pedosphere 16:420–427

    Article  Google Scholar 

  • Zhu F, Xue SG, Hartley W, Huang L, Wu C, Li X (2016a) Novel predictors of soil genesis following natural weathering processes of bauxite residues. Environ Sci Pollut R 23:2856–2863

    Article  CAS  Google Scholar 

  • Zhu F, Zhou JY, Xue SG, Hartley W, Wu C, Guo Y (2016b) Aging of bauxite residue in association of regeneration: a comparison of methods to determine aggregate stability & erosion resistance. Ecol Eng 92:47–54

    Article  Google Scholar 

Download references

Acknowledgments

Financial supports from Environmental protection’s special scientific research for Chinese public welfare industry (No. 201509048) and National Natural Science Foundation of China (No. 41371475) are gratefully acknowledged.

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Authors and Affiliations

  1. School of Metallurgy and Environment, Central South University, Changsha, 410083, People’s Republic of China

    Feng Zhu, Nan Huang, Shengguo Xue, Yiwei Li & Qi Zou

  2. South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou, 510655, China

    Feng Zhu

  3. Crop and Environment Sciences Department, Harper Adams University, Newport, Shropshire, TF10 8NB, UK

    William Hartley

Authors
  1. Feng Zhu
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  2. Nan Huang
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  3. Shengguo Xue
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  4. William Hartley
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  5. Yiwei Li
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  6. Qi Zou
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Correspondence to Shengguo Xue.

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Responsible editor: Philippe Garrigues

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Zhu, F., Huang, N., Xue, S. et al. Effects of binding materials on microaggregate size distribution in bauxite residues. Environ Sci Pollut Res 23, 23867–23875 (2016). https://doi.org/10.1007/s11356-016-7626-9

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  • DOI: https://doi.org/10.1007/s11356-016-7626-9

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