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Reactive Black 5 dye degradation using filters of smuggled cigarette modified with Fe3+

  • AOPs: Recent Advances to Overcome Barriers in the Treatment of Water, Wastewater and Air
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Abstract

This study presents an attempt to solve two serious environmental problems: the generation of toxic effluents and solid waste disposal. The work proposes recycling cigarette filters with the purpose of degrading reactive dyes, which are used in the textile industry. Filters of smuggled cigarettes were recycled through Fe3+ immobilization on their surface. The material obtained was characterized through Fourier transform infrared spectroscopy (FTIR), atomic absorption spectroscopy (AAS), scanning electron microscopy–energy-dispersive spectroscopy (SEM-EDS), and ultraviolet–visible spectroscopy (UV–vis). The factorial design revealed that the most suitable conditions for the degradation of Reactive Black 5 dye were obtained by using 1 g of material at pH 3.0 in a 100 mg L−1 hydrogen peroxide solution. The material showed excellent performance in the Reactive Black 5 dye degradation process; in 60 min, 99.09 % dye was removed. At pH 7.0, the dye degradation was 72.67 %, indicating that the material prepared can be used at pH values greater than 3.0 without the occurrence of hydrated Fe3+ oxide precipitation. Furthermore, the material showed no loss of catalytic activity after three degradation studies.

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Acknowledgments

LPG is indebted to CAPES for the fellowship and PJC is indebted to PET Química/UEPG–CAPES for the fellowship. STF is indebted to CAPES, Fundação Araucária, and CNPq for financial support. The authors are also indebted to CLABMU/UEPG for AAS, FTIR, SEM-EDS analysis and the Internal Revenue Service for providing of smuggled cigarettes.

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Authors and Affiliations

  1. Departamento de Química, Universidade Estadual de Ponta Grossa, 84030-900, Ponta Grossa, PR, Brazil

    Letícia Polli Glugoski, Paloma de Jesus Cubas & Sérgio Toshio Fujiwara

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  1. Letícia Polli Glugoski
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  2. Paloma de Jesus Cubas
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  3. Sérgio Toshio Fujiwara
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Correspondence to Sérgio Toshio Fujiwara.

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Responsible editor: Philippe Garrigues

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Glugoski, L.P., de Jesus Cubas, P. & Fujiwara, S.T. Reactive Black 5 dye degradation using filters of smuggled cigarette modified with Fe3+ . Environ Sci Pollut Res 24, 6143–6150 (2017). https://doi.org/10.1007/s11356-016-6820-0

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