Abstract
Sr-doped CuBi2O4 micro-particles were successively synthesized via a solid-state technique and were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), and UV–vis diffuse reflectance spectroscopy (UV–vis-DRS) techniques. Results show that Sr-doped CuBi2O4 was crystallized with a spinel-type structure and tetragonal crystal system, and the band gap energy was about 1.35 eV. The as-prepared Sr-doped CuBi2O4 treated at 573 °C for 12 h exhibited the highest efficiency, as a result of 97.22 % of CR degradation within 220 min, which is approximately 31 times greater than CR photodegradation when catalyzed by CuBi2O4 (3.13 %) and about 2.3 times superior than that catalyzed by the untreated Sr–doped CuBi2O4 sample (42.08 %). Pseudo-first-order kinetic model gave the best fit, with highest correlation coefficients (R 2 = 0.94–0.97). The Sr–doping and extending reaction time up to 12 h could be effective in producing Sr-doped CuBi2O4 materials that delay electron–hole recombination, thereby increasing the lifetime of the electron electron–hole separation and support the charge carrier transfer to the catalyst surface. On the basis of the calculated energy band positions, superoxide radical anions (O2 •–) were the main oxidative species responsible for the photocatalytic degradation of CR dye solution.
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Abdulkarem AM, Li J, Aref AA, Ren L, Elssfah EM, Wang H, Ge Y, Yu Y (2011) CuBi2O4 single crystal nanorods prepared by hydrothermal method: growth mechanism and optical properties. Mater Res Bull 46:1443–1450
Anandan S, Lee G, Yang CK, Ashokkumar Wub JJ (2012) Sonochemical synthesis of Bi2CuO4 nanoparticles for catalytic degradation of nonylphenol ethoxylate. Chem Eng J 183:46–52
Anandan S, Pugazhenthiran N, Lee GJ, Wu JJ (2013) Photocatalytic degradation of ceftiofur sodium using auloaded Bi2CuO4 nanoparticles. J Mol Catal A Chem 379:112–116
Arai T, Yanagida M, Konishi Y, Iwasaki Y, Sugihara H, Sayama K (2007) Efficient complete oxidation of acetaldehyde into CO2 over CuBi2O4/WO3 composite photocatalyst under visible and UV light irradiation. J Phys Chem C 111:7574–7577
Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293:269–271
Azàroff LV (1968) Elements of X-ray crystallography. McGraw-Hill, New York
Bauer JC (2009) Nanoparticles as reactive precursors: synthesis of alloys, intermetallic compounds and multi-metal oxides through low-temperature annealing and conversion chemistry. Thesis. Texas A&M University, USA
Berglund SP, Lee HC, Nún˜ez PD, Bardb AJ, Mullins CB (2013) Screening of transition and post-transition metals to incorporate into copper oxide and copper bismuth oxide for photoelectrochemical hydrogen evolution. Phys Chem Chem Phys 15:4554–4565
Boivin JC, Trehoux J, Thomas D, Daniel T (1976) Etude structurale de CuBi2O4. Bull Soc Fr Minéral Cristallogr 99:193–196
Chae WS, Ko JH, Choi KH, Jung JS, Kim YR (2010) Photocatalytic efficiency analysis of CdS nanoparticles with modified electronic states. J Anal Sci Technol 1:25–29
Chen XL, Liang JK, Liu Y, Xing XY, Qiao XY, Lan YC, Zhang YL, Ma Y, Che GC, Liu GD (1999) Structural transformations of Bi2CuO4 induced by mechanical deformation. J Appl Phys 85:3155–3158
Chen S, Zhao W, Liu W, Zhang H, Yu X, Chen Y (2009a) Preparation, characterization and activity evaluation of p–n junctionphotocatalyst p-CaFe2O4/n-Ag3VO4 under visible light irradiation. J Hazard Mater 172:1415–1423
Chen XY, Ma C, Li XX, Chen P, Fang JG (2009b) Hierarchical Bi2CuO4 microspheres: hydrothermal synthesis and catalytic in wet oxidation of methylene blue. Catal Commun 10:1020–1024
Choi YH., Kim DH, Joo W, Han BS, Shin SS, Yoo HI, Hong SH, Hong KS (2013) Synthesis and structural characteristics of p-type semiconducting CuBi2O4 as a new gas sensor material. International Symposium on Defects, Transport and Related Phenomena, Materials Science and Technology
Cullity B D (1956) Elements of X-ray diffraction. Edition Addison-Wesley Publishing Co, 1956: 98–99
Curkovic L, Ljubas D, Juretic H (2010) Photocatalytic decolorization kinetics of diazo dye Congo Red aqueous solution by UV/TiO2 nanoparticles. React Kinet Mech Catal 99:201–208
Deng Y, Chen Y, Chen B, Ma J (2013) Preparation, characterization and photocatalytic activity of CuBi2O4/NaTaO3 coupled photocatalysts. J Alloys Compd 559:116–122
Doi A, Obata K, Matsushima S (2013) Preparation and characterization of CuBi2O4 powders by organic acid complex method . Research report, Kitakyushu National College, 46: 39–42
Ebisuki (2009) Thermodynamic study on TiO2 photocatalytic activity and synthesis of TiO2(SrTiO3)-CuBi2O4 composite photocatalyst, UDC, 10497. Master's thesis, Wuhan University of Technology
Elaziouti A (2014) Preparation and characterization of semiconductor mixed oxides p n heterojunctions type: photocatalysis application. Thesis. Mohamed Boudiaf University, Algeria
Elaziouti A, Laouedj N, Bekka A (2011) ZnO-assisted photocatalytic degradation of congo Red and benzopurpurine 4B in aqueous solution. J Chem Eng Process Technol 2:1–9
Elaziouti A, Laouedj N, Bekka A (2012) Synthesis, characterization and UV-A light photocatalytic activity of 20 wt%SrO–CuBi2O4 composite. Appl Surf Sci 258:5010–5024
Elaziouti A, Laouedj N, Bekka A, Vannier RN (2014) Preparation and characterization of p–n heterojunction CuBi2O4/CeO2 and its photocatalytic activities under UVA light irradiation. Sci Technol A 39:9–22
Elaziouti A, Laouedj N, Bekka A (2015a) Preparation and characterization of novel CuBi2O4/SnO2 p–n heterojunction with enhanced photocatalytic performance under UVA light irradiation. J King Saud Univ 27:76–91
Elaziouti A, Laouedj N, Bekka A, Vannier RN (2015b) Preparation and characterization of p–n heterojunction CuBi2O4/CeO2 and its photocatalytic activities under UVA light irradiation. J King Saud Univ 27:120–135
Frame FA, Carroll EC, Larsen DS, Sarahan M, Browningb ND, Osterloh FE (2008) First demonstration of CdSe as a photocatalyst for hydrogen evolution from water under UV and visible light. Chem Commun 2008:2206–2208
Fu HB, Pan CS, Yao WQ, Zhu YF (2005) Visible-light-induced degradation of Rhodamine B by nanosized Bi2WO6. J Phys Chem B 109:22432–22439
Fumiaki A, Eri I, Akira Y (2013) Effect of particle size on the photocatalytic activity of WO3 particles for water oxidation. J Phys Chem C 117:22584–22590
Garcia-Munoz JL, Rodriguez-Carvajal J, Sapina F, Sanchis MJ, Ibanez R, Beltran-Porter J (1990) Crystal and magnetic structures of Bi2CuO4. J Phys Condens Matter 2:2205–2214
Hahn NT, Holmberg VC, Korgel BA, Mullins CB (2012) Electrochemical synthesis and characterization of p-CuBi2O4 thin film photocathodes. J Phys Chem C 116:6459–6466
Hameeda A, Aslama M, Ismaila Iqbal MI, Chandrasekarana S, Kadib MW, Gondald MA (2014) Sunlight assisted photocatalytic mineralization of nitrophenolisomers over W6+impregnated ZnO. Appl Catal B Environ 160–161:227–239
Harish BM, Chakravarthy BP, Ramakrishnan PA, Levasseur A, Rao KJ (2000) Microwave synthesis of electrode materials for lithium batteries. Bull Mater Sci 23:461–466
Henry N, Mentre O, Boivin JC, Abraham F (2001) Local perturbation in CuBi2O4: hydrothermal synthesis, crystal structure, and characterization of the new Bi2 (Cu1−2xMx) O4 M(=Bi, Pb). Chem Mater 13:543–551
Herak M, Miljak M, Guy D (2010) Revcolevschi A. Easy plane anisotropy in Bi2CuO4. J Phys Condens Matter 22:1–13
Ho C, Yu JC, Kwong T, Mak AC, Lai S (2005) Morphology-controllable synthesis of mesoporous CeO2 nano and microstructures. Chem Mater 17:4514–4522
Janson O, Rosner H (2007) Electronic structure and magnetic properties of Bi2CuO4. Physica C 460–462:458–459
Karunakaran C, Panneerselvam SM, Gomathisankar P (2009) Photoreduction of chromium(VI) on ZrO2 and ZnS surfaces. Monatsh Chem 140:1269–1274
Karunakaran C, Dhanalakshmi R, Gomathisankar P (2010) Photomineralization of phenol on Al2O3: synergistic photocatalysis by semiconductors. Res Chem Intermed 36:361–371
Kohtani S, Koshiko M, Kudo A, Tokumura K, Ishigaki Y, Toriba A, Hayakawa K, Nakagaki R (2003) Photodegradation of 4-alkylphenols using BiVO4 photocatalyst under irradiation with visible light from a solar simulator. Appl Catal B Environ 46:573–586
Kovalenko MV, Bodnarchuk MI, Stroyuk AL, Kuchmii SY (2004) Spectral, optical, and photocatalytic characteristics of quantum-sized particles of CdTe. Theor Exp Chem 40:220–225
Laidani N, Bartali R, Gottardi G, Anderle M, Cheyssac P (2008) Optical absorption parameters of amorphous carbon films from forouhi-bloomer and tauc-lorentz models: a comparative study. J Phys Condens Matter 20:015216.1–015216.8
Lam SM, Sin JC, Satoshi I, Zuhairi Abdullah A, Mohamed A (2014) Enhanced sunlight photocatalytic performance over Nb2O5/ZnO nanorod composites and the mechanism study. Appl Catal A Gen 471:126–135
Lam SM, Sin JC, Zuhairi AA, Mohamed A (2015) Sunlight responsive WO3/ZnO nanorods for photocatalytic degradation and mineralization of chlorinated phenoxyacetic acid herbicides in water. J Colloid Interface Sci 450:34–44
Laouedj N, Elaziouti A, Bekka A (2011) Photodegradation study of Congo Red in aqueous solution using ZnO/UV-a: effect of pH and band gap of other semiconductor groups. J Chem Eng Process Technol 2:1–9
Lee EJH, Ribeiro C, Giraldi TR, Longo E, Leitea ER (2004) Photoluminescence in quantum-confined SnO2 nanocrystals: evidence of free exciton decay. Appl Phys Lett 84:1745–1747
Liu S (2011) Preparation and property research of TiO2-based photocatalyst and CuBi2O4 thin films. Thesis, china
Liu W, Chen S, Zhang S, Zhao W, Zhang H, Yu X (2010) Preparation and characterization of p–n heterojunction photocatalyst p-CuBi2O4/n-TiO2 with high photocatalytic activity under visible and UV light irradiation. J Nano Res 2:1355–1366
Liu W, Chen S, Zhang H, Yu X (2011) Preparation, characterisation of p-n heterojunction photocatalyst CuBi2O4/Bi2WO6 and its photocatalytic activities. J Exp Nanosci 6:102–120
Lyskov NV, Metlin YG, Belousov VV, Tretyakov YD (2004) Microstructure evolution and conductivity of Bi2CuO4-Bi2O3 composites nearby the eutectic point. Solid State Ionics 173:135–139
Manzoor U, Islam M, Tabassam L, Ur Rahman S (2009) Quantum confinement effect in ZnO nanoparticles by co-precipitate method. Physica E 41:1669–1672
Mora-Sero I, Bisquert J, Dittrich T, Belaidi A, Susha AS, Rogach AL (2007) Photosensitization of TiO2 layers with CdSe quantum dots: correlation between light absorption and photoinjection. J Phys Chem C 111:14889–14892
Nakabayashi Y, Nishikawa M, Nosaka Y (2014) Fabrication of CuBi2O4 photocathode through novel anodic electrodeposition for solar hydrogen production. Electrochim Acta 125:191–198
Nishikawa M, Hiura S, Mitani Y, Nosaka Y (2013) Enhanced photocatalytic activity of BiVO4 by co-grafting of metal ions and combining with CuBi2O4. J Photochem Photobiol A Chem 262:52–56
Oh WD, Lua SK, Dong Z, Lim TT (2015) A novel three-dimensional spherical CuBi2O4 consisting of nanocolumn arrays with persulfate and peroxymonosulfate activation functionalities for 1H- benzotriazole removal. Nanoscale 7:8149–8158
Patil R, Kelkar S, Rounak N, Ogale S (2014) Low temperature grown CuBi2O4 with flower morphology and its composite with CuO nanosheets for photoelectrochemical water splitting. J Mater Chem A 2:3661–3668
Phoka S, Laokul P, Swatsitang E, Promarack V (2009) Synthesis, structural and optical properties of CeO2 nanoparticles synthesized by a simple polyvinyl pyrrolidone (PVP) solution route. Mater Chem Phys 115:423–428
Pouretedal HR, Hosseini M (2010) Bleaching kinetic and mechanism study of Congo Red catalyzed by ZrO2 nanoparticles prepared by usinga simple precipitation method. Acta Chim Slov 57:415–423
Rengaraj S, Kezhen Q, Al-Kindy SMZ, MikaS YK, Tai C-W (2014) A simple hydrothermal route for the preparation of HgS nanoparticles and their photocatalytic activities. RSC Adv 4:15371–15376
Sangami G, Dharmaraj N (2012) UV–visible spectroscopic estimation of photodegradation of rhodamine- B dye using tin(IV) oxide nanoparticles. Spectrochim Acta A Mol Biomol Spectrosc 97:847–852
Saravanan R, Shankara H, Prakasha T, Narayananb V, Stephena A (2011) ZnO/CdO composite nanorods for photocatalytic degradation of methylene blue under visible light. Mater Chem Phys 125:277–280
Saravanan R, Karthikeyan S, Gupta VK, Sekaran G, Narayanan V, Stephen A (2013a) Enhanced photocatalytic activity of ZnO/CuO nanocomposite for the degradation of textile dye on visible light illumination. Mater Sci Eng C 33:91–98
Saravanan R, Gupta VK, Prakash T, Narayanan V, Stephen A (2013b) Synthesis, characterization and photocatalytic activity of novel Hg doped ZnO nanorods prepared by thermal decomposition method. J Mol Liq 178:88–93
Saravanan R, Thirumal E, Gupta VK, Narayanan V, Stephen A (2013c) The photocatalytic activity of ZnO prepared by simple thermal decomposition method at various temperatures. J Mol Liq 177:394–401
Saravanan R, Gupta VK, Narayanan V, Stephen A (2014) Visible light degradation of textile effluent using novel catalyst ZnO/g-Mn2O3. J Taiwan Inst Chem Eng 45:1910–1917
Saravanan R, Gupta VK, Mosquera E, Gracia F, Khan MM, Narayanan V, Stephen A (2015a) ZnO/Ag/Mn2O3 nanocomposite for visible lightinduced industrial textile effluent degradation, uric acid and ascorbic acid sensing and antimicrobial activity. RSC Adv 5:34645–34651
Saravanan R, Gupta VK, Mosquera E, Gracia F, Khan MM, Narayanan V, Stephen A (2015b) ZnO/Ag/CdO nanocomposite for visible light-induced photocatalytic degradation of industrial textile effluents. J Colloid Interface Sci 452:126–133
Seiji K, Toshiyuki A (2009) Photocatalysis for water oxidation by Fe2O3 nanoparticles embedded in clay compound: correlation between its polymorphs and their photocatalytic activities. J Mater Sci 44:2890–2898
Sharma PK, Ramanab A, Vasanthacharya NY (1996) Low-temperature synthesis of bismuth cuprates. Mater Res Bull 31:913–917
Shimodaira Y, Kato H, Kobayashi H, Kudo A (2006) Photophysical properties and photocatalytic activities of bismuth molybdates under visible light irradiation. J Phys Chem B 110:17790–17797
Sobanska S, Wignacourt JP, Conflant P, Drachem M, Bulimestru I, Gulea A (1996) A new CuBi2O4 precursor : synthesis, crystal structure and thermal behaviour of Cu(BiEDTA)2, 9H2O. Eur J Solid State Inorg Chem 33:701–712
Soboleva NM, Nosovich AA, Goncharuk VV (2007) The heterogeneous photocatalysis in water treatment process. J Water Chem Technol 29:72–89
Streit HC, Kramer J, Suta M, Wickleder C (2013) Red, green, and blue photoluminescence of Ba2SiO4:M (M = Eu3+, Eu 2+, Sr2+) nanophosphors. Materials 6:3079–3093
Strejc A, Sedmidubsky D, Rusika K, Leitner J (2003) Thermochemical properties of Bi2CuO4. Thermochim Acta 402:69–74
Tang JW, Zou ZG, Ye JH (2004) Efficient photocatalytic decomposition of organic contaminants over CaBi2O4 under visible-light irradiation. Angew Chem Int Ed 43:4463–4466
Tnunekawa S, Fukuda T, Kasuya A (2000) Blue shift in ultraviolet absorption spectra of monodisperse CeO2-x nanoparticles. J Appl Phys 87:1318–1321
Torres-Martínez LM, MA R-G, Figueroa-Torres MZ, Juárez-Ramírez I, Moctezuma E (2012) Sm2FeTaO7 photocatalyst for degradation of indigo carmine dye under solar light irradiation. Int J Photoenergy 2012:7
Truffault L, Ta MT, Devers T, Konstantinov K, Harel V, Simmonard C, Andreazza C, Nevirkovets IP, Pineau A, Veron O, Blondeau JP (2010) Application of nanostructured Ca doped CeO2 for ultraviolet filtration. Mater Res Bull 45:527–535
Vasanth Kumar K, Porkodi K, Rocha F (2008) Langmuir–Hinshelwood kinetics—a theoretical study. Catal Commun 9:82–84
Vora JJ, Chauhan SK, Parmar KC, Vasava SB, Sharma S, Bhutadiya LS (2009) Kinetic study of application of ZnO as a photocatalyst in heterogeneous medium. E-J Chem 6:531–536
Wang JH, Zou ZG, Ye JH (2005) Surface modification and photocatalytic activity of distorted pyrochlore- type Bi2M(M = In, Ga and Fe)TaO7 photocatalysts. J Phys Chem Solids 66:349–355
Wang C, Thompson RL, Ohodnicki P, Baltrus J, Matranga C (2011) Size-dependent photocatalytic reduction of CO2 with PbS quantum dot sensitized TiO2 heterostructured photocatalysts. J Mater Chem 21:13452–13457
Werner L, Eriksson M, Treor W (1985) A semi-exhaustie trial-and-error powder indexing program for all symmetries. J Appl Crystallogr 18:367–370
Woodhouse M, Parkinson BA (2008) Combinatorial discovery and optimization of a complex oxide with water photoelectrolysis activity. Chem Mater 20:2495–2502
Xiaoning W, Jinping J, Yalin W (2011) Degradation of C.I. Reactive Red 2 through photocatalysis coupled with water jet cavitation. J Hazard Mater 185:315–321
Xie Y, Zhang Y, Yang G, Liu C, Wang J (2013) Hydrothermal synthesis of CuBi2O4 nanosheets and their photocatalytic behavior under visible light irradiation. Mater Lett 107:291–294
Xu Y, Schoonen MAA (2000) The absolute energy positions of conduction and bands of selected semiconducting Minerals. Am Mineral 85:543–556
Yamada K, Hashzumze T, Yamamoto K, Sonoda T, Taniguchi M (2011) Study on visible-light activity of photocatalytic composites composed of foreign semiconductors. Rapport de recherche, Kitakyushu Collège national
Yang X, Xu L, Yu X, Li W, Li K, Huo M, Guo Y (2008) Enhanced photocatalytic activity of Eu2O3/Ta2O5 mixed oxides on degradation of rhodamine B and 4-nitrophenol. Colloids Surf A Physicochem Eng Asp 320:61–67
Yao WF, Xu XH, Wang H, Zhou JT, Yang XN, Zhang Y, Shang SX, Huang BB (2004) Photocatalytic property of perovskite bismuth titanate. Appl Catal B Environ 52:109–116
Yongchuan W, Xingxing S, Feng C (2014) Improving the catalytic activity of CeO2/H2O2 system by sulfation pretreatment of CeO2. J Mol Catal A Chem 381:38–45
Yoshii K, Fukuda T, Akahama H, Kano J, Kambe T, Ikeda N (2011) Magnetic and dielectric study of Bi2CuO4. Phys C 471:766–769
Zhang J, Jiang Y (2015) Preparation, characterization and visible photocatalytic activity of CuBi2 O4 photocatalyst by a novel sol–gel method. J Mater Sci Mater Electron 26:4308–4312
Zhang C, Zhu YF (2005) Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts. Chem Mater 17:3537–3545
Zhang GK, Yang JL, Zhang SM, Xiong Q, Huang BB, Wang JT, Gong WQ (2009) Preparation of nanosized Bi3NbO7 and its visible-light photocatalytic property. J Hazard Mater 172:986–992
Zhang Y, Xie Y, Li J, Yang G, Bai T, Wanga J (2013) Effects of synthetic conditions on the morphology and catalytic properties of hierarchical CuBi2O4 nanoflowers grown by low-temperature solution process. J Alloys Compd 580:172–175
Zhong C, Xueqiang C, Lixian S, He Y (2011) Photocatalytic activity of Bi2O3 prepared by different precipitants. Adv Mater Res 239–242:998–1001
Zou ZG, Ye JH, Sayama K, Arakawa H (2001a) Photocatalytic and photophysical properties of a novel series of solid photocatalysts, BiTa1−xNbxO4 (0 ≤ x ≤ 1). Chem Phys Lett 343:303–308
Zou ZG, Ye JH, Sayama K, Arakawa H (2001b) Photocatalytic and photophysical properties of a novel series of solid photocatalysts, Bi2MNbO7 (M = Al3+, Ga3+ and In3+). Chem Phys Lett 333:57–62
Acknowledgments
We are greatly indebted to the University of Science and Technology of Oran (Mohamed Boudiaf) and the University of Science and Technology of Saida (Moulay Tahar), Algeria for their material support. We gratefully acknowledge the support for X-ray diffraction (XRD), scanning electron microscopy (SEM), and UV–vis diffuse reflectance spectroscopy (DRS) by Mrs. Professor Rose-Noëlle Vannier of the Unit of Catalysis and Solid State Chemistry of Lille 1 University, France.
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Elaziouti, A., Laouedj, N. & Bekka, A. Synergetic effects of Sr-doped CuBi2O4 catalyst with enhanced photoactivity under UVA– light irradiation. Environ Sci Pollut Res 23, 15862–15876 (2016). https://doi.org/10.1007/s11356-015-4946-0
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DOI: https://doi.org/10.1007/s11356-015-4946-0