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Fe3O4/SiO2/TiO2 nanoparticles for photocatalytic degradation of 2-chlorophenol in simulated wastewater

Environmental Science and Pollution Research volume 22, pages 3149–3157 (2015)Cite this article

Abstract

Photocatalysis has emerged as an advance and environmental-friendly process for breakdown of organic contaminants in wastewater. This work reports facile synthesis and characterization of stable magnetic core-shell-shell Fe3O4/SiO2/TiO2 nanoparticles and their effectiveness for photocatalysis. The surface morphology, crystal structure, and chemical properties of the photocatalyst were characterized by using scanning electron microscope (SEM), energy-dispersive X-ray (EDX), X-ray diffraction (XRD), and nitrogen physisorption. Stability of synthesized nanoparticles in aqueous medium was tested by leaching test. The photocatalytic degradation of 2-chlorophenol was investigated and reaction parameters for best catalyst performance were optimized. Catalyst dose of 0.5 g/L under optimized conditions produced complete degradation of 25 mg/L 2-chlorophenol (2-CP) within 130 min of 100-W ultraviolet (UV) irradiation while 97.2 % degradation of 50 mg/L 2-CP was achieved within 3 h. The rate of photocatalytic degradation was determined by considering pseudo first-order kinetics and Hugul’s kinetic equations. The Hugul’s kinetics was found to provide a better interpretation of the experimental results than the generally adopted pseudo first-order reaction kinetics.

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References

  • Abramson S, Srithammavanh L, Siaugue J-M, Horner O, Xu X, Cabuil V (2009) Nanometric core-shell-shell γ-Fe2O3/SiO2/TiO2 particles. J Nanoparticle Res 11:459–465

    CAS  Article  Google Scholar 

  • Anju SG, Yesodharan S, Yesodharan EP (2012) Zinc oxide mediated sonophotocatalytic degradation of phenol in water. Chem Eng J 189–190:84–93

    Article  Google Scholar 

  • Asenjo NG, Santamaria R, Blanco C, Granda M, Alvarez P, Menendez R (2013) Correct use of the Langmuir–Hinshelwood equation for proving the absence of a synergy effect in the photocatalytic degradation of phenol on a suspended mixture of titania and activated carbon. Carbon 55:62–69

    CAS  Article  Google Scholar 

  • Barakat MA, Al-Hutailah RI, Qayyum E, Rashid J, Kuhn JN (2013) Pt/TiO2 nanoparticles for photocatalytic degradation of phenols in wastewater. J Environ Technol 35:137–144

    Article  Google Scholar 

  • Chalasani R, Vasudevan S (2013) Cyclodextrin-functionalized Fe3O4@TiO2: reusable, magnetic nanoparticles for photocatalytic degradation of endocrine-disrupting chemicals in water supplies. ACS Nano 7:4093–4104

    CAS  Article  Google Scholar 

  • Directive on Environmental Quality Standards (Directive 2008/105/EC). http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2008:348:0084:0097:EN:PDF

  • EPA, Code of Federal Regulations (2014) Appendix A to 40 CFR, Part 423–126 Priority Pollutants. http://www.epa.gov/region1/npdes/permits/generic/prioritypollutants.pdf

  • Gad-Allah TA, Kat S, Satokawa S, Kojima T (2009) Treatment of synthetic dyes wastewater utilizing a magnetically separable photocatalyst (TiO2/SiO2/Fe3O4): parametric and kinetic studies. Desalination 244:1–11

    CAS  Article  Google Scholar 

  • Gao Y, Chen B, Li H, Ma Y (2003) Preparation and characterization of a magnetically separated photocatalyst and its catalytic properties. Mater Chem Phys 80:348–355

    CAS  Article  Google Scholar 

  • Hugul M, Ercag E, Apak R (2006) Kinetic studies on UV-photodegradation of some chlorophenols using TiO2 catalyst. J Environ Sci Health A 37:365–383

    Article  Google Scholar 

  • Lin SH, Chiou CH, Chang CK, Juang RS (2011) Photocatalytic degradation of phenol on different phases of TiO2 particles in aqueous suspensions under UV irradiation. J Environ Manag 92:3098–3104

    CAS  Article  Google Scholar 

  • Luo X, Zhang S, Lin X (2013) New insights on degradation of methylene blue using thermocatalytic reactions catalyzed by low-temperature excitation. J Hazard Mater 260:112–121

    CAS  Article  Google Scholar 

  • Naeem K, Feng O (2009) Parameters effect on heterogeneous photocatalysed degradation of phenol in aqueous dispersion of TiO2. J Environ Sci 21:527–533

    Article  Google Scholar 

  • Ruzmanova Y, Stoller M, Recine G, Hochepied J F, Maury D, Chianese A (2014) Production and characterization of magnetic core nanoparticles for photocatalysis. Proceedings of ISIC19, Toulouse 17-19 Sept. (2014), accepted for publication

  • Santra S, Tapec R, Theodoropoulou N, Dobson J, Hebard A, Tan W (2001) Synthesis and characterization of silica-coated iron oxide nanoparticles in microemulsion: the effect of nonionic surfactants. Langmuir 17:2900–2906

    CAS  Article  Google Scholar 

  • Shaban YA, El-Sayed MA, El-Maradny AA, Al-Farawati RK, Al-Zobidi MI (2013) Photocatalytic degradation of phenol in natural seawater using visible light active carbon modified (CM)-n-TiO2 nanoparticles under UV light and natural sunlight illuminations. Chemosphere 91:307–313

    CAS  Article  Google Scholar 

  • Sin JC, Lam SM, Mohamed AR, Lee KT (2012) Degrading endocrine disrupting chemicals from wastewater by TiO2 photocatalysis: a review. Int J Photoenergy 2012:1–23

    Article  Google Scholar 

  • Tu W, Lin Y-P, Bai R (2013) Removal of phenol in aqueous solutions by novel buoyant composite photocatalysts and the kinetics. Sep Purif Technol 115:180–189

    CAS  Article  Google Scholar 

  • Xu J, Wang F, Liu W, Cao W (2013) Nanocrystalline N-doped TiO2 powders: mild hydrothermal synthesis and photocatalytic degradation of phenol under visible light irradiation. Int J Photoenergy 2013:1–7

    Google Scholar 

  • Ye M, Zhang Q, Hu Y, Ge J, Lu Z, He L, Chen Z, Yin Y (2010) Magnetically recoverable core–shell nanocomposites with enhanced photocatalytic activity. Chem Eur J 16:6243–6250

    CAS  Article  Google Scholar 

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Affiliations

  1. Department of Environmental Sciences, Faculty of Meteorology and Environment, King Abdulaziz University (KAU), Jeddah, Saudi Arabia

    Jamshaid Rashid & M. A. Barakat

  2. Central Metallurgical R & D Institute, Cairo, 11421, Helwan, Egypt

    M. A. Barakat

  3. Center of Excellence in Environmental Studies (CEES), King Abdulaziz University (KAU), Jeddah, Saudi Arabia

    M. A. Barakat

  4. Department of Chemical Material Environmental Engineering, Sapienza University of Rome, Rome, Italy

    Y. Ruzmanova & A. Chianese

Authors
  1. Jamshaid Rashid
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  2. M. A. Barakat
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  3. Y. Ruzmanova
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  4. A. Chianese
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Corresponding author

Correspondence to A. Chianese.

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Responsible editor: Philippe Garrigues

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Rashid, J., Barakat, M.A., Ruzmanova, Y. et al. Fe3O4/SiO2/TiO2 nanoparticles for photocatalytic degradation of 2-chlorophenol in simulated wastewater. Environ Sci Pollut Res 22, 3149–3157 (2015). https://doi.org/10.1007/s11356-014-3598-9

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  • DOI: https://doi.org/10.1007/s11356-014-3598-9

Keywords

  • Photocatalysis
  • Magnetic
  • Core-shell-shell nanoparticles
  • Separation
  • 2-chlorophenol
  • Wastewater