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Environmental Science and Pollution Research

, Volume 21, Issue 1, pp 568–583 | Cite as

Fate of para-toluenesulfonamide (p-TSA) in groundwater under anoxic conditions: modelling results from a field site in Berlin (Germany)

  • Raffaella Meffe
  • Claus Kohfahl
  • Enrico Hamann
  • Janek Greskowiak
  • Gudrun Massmann
  • Uwe Dünnbier
  • Asaf Pekdeger
Research Article

Abstract

This article reports on a field modelling study to investigate the processes controlling the plume evolution of para-toluenesulfonamide (p-TSA) in anoxic groundwater in Berlin, Germany. The organic contaminant p-TSA originates from the industrial production process of plasticisers, pesticides, antiseptics and drugs and is of general environmental concern for urban water management. Previous laboratory studies revealed that p-TSA is degradable under oxic conditions, whereas it appears to behave conservatively in the absence of oxygen (O2). p-TSA is ubiquitous in the aquatic environment of Berlin and present in high concentrations (up to 38 μg L−1) in an anoxic aquifer downgradient of a former sewage farm, where groundwater is partly used for drinking water production. To obtain refined knowledge of p-TSA transport and degradation in an aquifer at field scale, measurements of p-TSA were carried out at 11 locations (at different depths) between 2005 and 2010. Comparison of chloride (Cl) and p-TSA field data showed that p-TSA has been retarded in the same manner as Cl. To verify the transport behaviour under field conditions, a two-dimensional transport model was setup, applying the dual-domain mass transfer approach in the model sector corresponding to an area of high aquifer heterogeneity. The distribution of Cl and p-TSA concentrations from the site was reproduced well, confirming that both compounds behave conservatively and are subjected to retardation due to back diffusion from water stagnant zones. Predictive simulations showed that without any remediation measures, the groundwater quality near the drinking water well galleries will be affected by high p-TSA loads for about a hundred years.

Keywords

p-TSA Microorganic pollutants Wastewater irrigation Transport modelling Emerging contaminants Dual-domain mass transfer approach 

Notes

Acknowledgements

The authors want to thank Dr. Malaak Kallache of the Imdea-Water Institute (Madrid, Spain) for her advices and help in data processing.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2013

Authors and Affiliations

  • Raffaella Meffe
    • 1
  • Claus Kohfahl
    • 2
    • 3
  • Enrico Hamann
    • 3
  • Janek Greskowiak
    • 4
  • Gudrun Massmann
    • 4
  • Uwe Dünnbier
    • 5
  • Asaf Pekdeger
    • 3
  1. 1.Instituto Madrileño de Estudios AvanzadoAlcalá de HenaresSpain
  2. 2.Instituto Geológico y MineroSevillaSpain
  3. 3.Institute of Geological SciencesFreie Universität BerlinBerlinGermany
  4. 4.Department of Biology and Environmental SciencesCarl von Ossietzky Universität OldenburgOldenburgGermany
  5. 5.Department of LaboratoriesBerliner WasserbetriebeBerlinGermany

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