Abstract
The present work investigates the potential use of metal hydroxides sludge (MHS) generated from hot dipping galvanizing plant for adsorption of Congo Red and Naphthol Green B dyes from aqueous solutions. Characterization of MHS included infrared and X-ray fluorescence analysis. The effect of shaking time, initial dye concentration, temperature, adsorbent dosage and pH has been investigated. The results of adsorption experiments indicate that the maximum capacity of Congo Red and Naphthol Green B dyes at equilibrium (q e) and percentage of removal at pH 6 are 40 mg/g, 93 %, and 10 mg/g, 52 %, respectively. Some kinetic models were used to illustrate the adsorption process of Congo Red and Naphthol Green B dyes using MHS waste. Thermodynamic parameters such as (ΔG, ΔS, and ΔH) were also determined.
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Ali I, Gupta VK (2007) Advances in water treatment by adsorption technology. Nat Protoc 1(6):2661–2667
Asfour HM, Fadali OA, Nassar MM, El-Geundi MS (1985) Equilibrium studies on adsorption of basic dyes on hardwood. Chem Technol Biotechnol 35A:21
Chatterjee S, Chatterjee S, Chatterjee BP, Guha AK (2007) Adsorptive removal of Congo Red, a carcinogenic textile dye by chitosan hydrobeads: binding mechanism, equilibrium and kinetics. Colloids Surf A Physicochem Eng Asp 299:146–152
Chiou MS, Li HY (2003) Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads. Chemosphere 50:1095–1105
Fu Y, Viraraghavan T (2002) Removal of Congo Red from an aqueous solution by fungus Aspergillus niger. Adv Env Res 7:239
Géraud E, Bouhent M, Derriche Z, Leroux F, Prévot V, Forano C (2007) Texture effect of layered double hydroxides on chemisorption of Orange II. J Phys Chem Solids 68:818–823
Gharbani P, Tabatabaii SM, Mehrizad A (2008) Removal of Congo Red from textile wastewater by ozonation. Int J Environ Sci Tech 5(4):495–500
Giles CH, Greczek JJ (1962) A review of methods of purifying and analyzing water-soluble dyes. Text Res J 32:506
Golder AK, Samanta AN, Ray S (2006) Anionic reactive dye removal from aqueous solution using a new adsorbent—sludge generated in removal of heavy metals by electrocoagulation. Chem Eng J 122(1–2):107–115
Gupta VK, Ali I (2008) Removal of endosulfan and methoxychlor from water on carbon slurry. Environ Sci Technol 42:766–770
Gupta VK, Rastogi A (2008) Equilibrium and kinetic modelling of cadmium(II) biosorption by nonliving algal biomass Oedogonium sp. from aqueous phase. J Hazard Mater 153(1–2):759–766
Gupta VK, Rastogi A (2009) Biosorption of hexavalent chromium by raw and acid-treated green alga Oedogonium hatei from aqueous solutions. J Hazard Mater 163:396–402
Gupta VK, Mittal A, Gajbe V, Mittal J (2006a) Removal and recovery of the hazardous azo dye acid orange 7 through adsorption over waste materials: bottom ash and de-oiled soya. Ind Eng Chem Res 45:1446–1453
Gupta VK, Mittal A, Jain R, Mathur M, Sikarwar S (2006b) Adsorption of Safranin-T from wastewater using waste materials- activated carbon and activated rice husks. J Colloid Interface Sci 303(1):80–86
Gupta VK, Mittal A, Kurup L, Mittal J (2006c) Adsorption of a hazardous dye, erythrosine, over hen feathers. J Colloid Interface Sci 304(1):52–57
Gupta VK, Ali I, Saini VK (2007a) Adsorption studies on the removal of Vertigo Blue 49 and Orange DNA13 from aqueous solutions using carbon slurry developed from a waste material. J Colloid Interface Sci 315(1):87–93
Gupta VK, Ali I, Saini VK (2007b) Defluoridation of wastewaters using waste carbon slurry. Water Res 41(15):3307–3316
Gupta VK, Jain R, Varshney S (2007c) Electrochemical removal of the hazardous dye Reactofix Red 3 BFN from industrial effluents. J Colloid Interface Sci 312:292–296
Gupta VK, Jain R, Varshney S (2007d) Removal of Reactofix golden yellow 3 RFN from aqueous solution using wheat husk—an agricultural waste. J Hazard Mater 142(1–2):443–448
Gupta VK, Jain R, Mittal A, Mathur M, Sikarwar S (2007e) Photochemical degradation of the hazardous dye Safranin-T using TiO2 catalyst. J Colloid Interface Sci 309(2):464–469
Gupta VK, Mittal A, Gajbe V, Mittal J (2008) Adsorption of basic Fuchsin using waste materials—bottom ash and de-oiled soya as adsorbents. J Colloid Interface Sci 319:30–39
Gupta VK, Goyal RN, Sharma RA (2009) Novel PVC membrane based alizarin sensor and its application; determination of vanadium, zirconium and molybdenum. Int J Electrochem Sci 4(1):156–172
Gupta VK, Rastogi A, Nayak A (2010) Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material. J Colloid Interface Sci 342(1):135–141
Gupta VK, Ali I, Saleh TA, Nayak A, Agarwal S (2012) Chemical treatment technologies for waste-water recycling—an overview. RSC Adv. doi:10.1039/C2RA20340E
Hameed BH (2008) Equilibrium and kinetic studies of methyl violet sorption by agricultural waste. J Hazard Mater 154:204–212
Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451
Hou M, Baughman GL (1992) Predicting the precipitation of acid and direct dyes in natural waters. Dyes Pigments 18:35
Hu Z, Chen H, Ji F, Yuan S (2010) Removal of Congo Red from aqueous solution by cattail root. J Hazard Mater 173:292–297
Lagergren S (1898) Zur theorie der sogenannten adsorption gelöster stoffe, Kungliga Svenska Vetenskapsakademiens. Handlingar 24(4):1–39
Lee CK, Low KS, Chow SW (1996) Chrome sludge as an adsorbent for colour removal. Environ Technol 17:1023
Lee J-W, Choi S-P, Thiruvenkatachari R, Shim W-G, Moon H (2006) Evaluation of the performance of adsorption and coagulation processes for the maximum removal of reactive dyes. Dyes Pigments 69:196–203
Legrouri A, Lakraimi M, Barroug A, De Roy A, Besse JP (2005) Removal of herbicide 2,4-dichlorophenoxyacetate from water to zinc–aluminium-chloride layered double hydroxides. Water Res 21:217–226
Li Y, Gao B, Wu T, Wang B, Li X (2009) Adsorption properties of aluminum magnesium mixed hydroxide for the model anionic dye Reactive Brilliant Red K-2BP. J Hazard Mater 164:1098–1110
Lorenc-Grabowska E, Gryglewicz G (2007) Adsorption characteristics of Congo Red on coal-based mesoporous activated carbon. Dyes Pigments 74:34–40
McMullan G, Meehan C, Conneely A, Kirby N, Robinson T, Nigam P, Banat IM, Marchant R, Smyth WF (2001) Microbial decolourisation and degradation of textile dyes. Appl Microbiol Biotechnol 56(1/2):81–87
Mittal A (2006) Removal of the dye. Amaranth from wastewater using hen feathers. Electron J Environ Agric Food Chem 5(2):1296–1305
Mittal AK, Gupta SK (1996) Biosorption of cationic dyes by dead macro fungus Fomitopsis carnea: batch studies. Water Sci Technol 34:81–87
Mittal A, Gupta VK (2010) Adsorptive removal and recovery of the azo dye Eriochrome Black T. Toxicol Environ Chem 92(10):1813–1823
Mittal A, Mittal J, Malviya A, Gupta VK (2009) Adsorptive removal of hazardous anionic dye “Congo Red” from wastewater using waste materials and recovery by desorption. J Colloid Interface Sci 340(1):16–26
Mittal A, Jain R, Mittal J, Varshney S, Sikarwar S (2010a) Removal of Yellow ME 7 GL from industrial effluent using electrochemical and adsorption techniques. Int J Environ Pollut 43(4):308–323
Mittal A, Mittal J, Malviya A, Gupta VK (2010b) Removal and recovery of Chrysoidine Y from aqueous solutions by waste materials. J Colloid Interface Sci 344:497–507
Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK (2010c) Decoloration treatment of a hazardous triarylmethane dye, Light Green SF (Yellowish) by waste material adsorbents. J Colloid Interface Sci 342(2):518–527
Mittal A, Thakur V, Gajbe V (2012a) Adsorptive removal of toxic azo dye Amido Black 10B by hen feather. Environ Sci Pollut Res. doi:10.1007/s11356-012-0843-y
Mittal A, Thakur V, Gajbe V (2012b) Evaluation of adsorption characteristics of an anionic azo dye Brilliant Yellow onto hen feathers in aqueous solutions. Environ Sci Pollut Res. doi:10.1007/s11356-012-0756-9
Nakamoto K (1978) Infrared and raman spectroscopy of inorganic and coordination compounds. Wiley, New York
Namasivayam C, Jeyakumar R, Yamuna RT (1994) Dye removal from wastewater by adsorption on waste Fe(III)/Cr(III) hydroxide. Waste Manage 14(7):643–648
Netpradit S, Thiravetyan P, Towprayoon S (2003) Application of ‘waste’ metal hydroxide sludge for adsorption of azo reactive dyes. Water Res 37(4):763–772
Netpradit S, Thiravetyan P, Towprayoon S (2004) Adsorption of three azo reactive dyes by metal hydroxide sludge: effect of temperature, pH, and electrolytes. J Colloid Interface Sci 270(2):255–261
Ni ZM, Xia SJ, Wang LG, Xing FF, Pan GX (2007) Treatment of methyl orange by calcined layered double hydroxides in aqueous solution: adsorption property and kinetic studies. J Colloid Interface Sci 316:284–291
O’Neill C, Hawkes FR, Hawkes DL, Esteves S, Wilcox SJ (2000) Anaerobic-aerobic biotreatment of simulated textile effluent containing varied ratios of starch and azo dye. Water Res 34:2355–2361
Out EO, Westland AD (1991) Solvent extraction with sulphonic acids. Solvent Extr Ion Exch 9:875
Ozcan S, Erdem B, Özcan A (2004) Adsorption of acid Blue 193 from aqueous solutions onto Na-bentonite and DTMA-bentonite. J Colloid Interface Sci 280:44–54
Ozdemir Y, Dogan M, Alkan M (2006) Adsorption of cationic dyes from aqueous solutions by sepiolite. Microporous Mesoporous Mater 96:419–427
Packter A, Dhillon HS (1981) The dissolution and crystallisation of amphoteric metal hydroxides from sodium hydroxide solutions: ionic equilibria, crystalline phases and crystallisation mechanisms. Cryst Res Technol 16:567
Papić S, Koprivanac N, Božič AL, Meteš A (2004) Removal of some reactive dyes from synthetic wastewater by combined Al(III) coagulation/carbon adsorption process. Dyes Pigments 62:291–298
Pascuta P, Vladescu A, Borodi G, Culea E, Tetean R (2011) Structural and magnetic properties of zinc ferrite incorporated in amorphous matrix. Ceram Int 37:3343–3349
Raghu S, Ahmed Basha C (2007) Chemical or electrochemical techniques, followed by ion exchange, for recycle of textile dye wastewater. J Hazard Mater 149:324–330
Saiah FBD, Su BL, Bettahar N (2009) Nickel–iron layered double hydroxide (LDH): textural properties upon hydrothermal treatments and application on dye sorption. J Hazard Mater 165:206–217
Saleh TA, Gupta VK (2012) Column with CNT/magnesium oxide composite for lead(II) removal from water. Environ Sci Pollut Res. doi:10.1007/s11356-011-0670-6
Santos SCR, Vilar VJP, Boaventura RAR (2008) Waste metal hydroxide sludge as adsorbent for a reactive dye. J Hazard Mater 153:999–1008
Sawhney R, Kumar A (2011) Congo Red (Azo dye) decolourization by local isolate VTII inhabiting dye effluent exposed soil. Int J Environ Sci 1(6):1261–1267
Sharma J, Janveja B (2008) A study on removal of Congo Red dye from the effluents of textile industry using rice husk carbon activated by steam. Rasayan J Chem 1(4):936–942
Staurt B (1996) Modern infrared spectroscopy. Wiley, West Sussex
Stumm W (1992) Chemistry of the solid–water interface. Wiley, New York
Swaminathan K, Sandhya S, Sophia AC, Pachhade K, Subrahmanyam YV (2003) Decolorization and degradation of H-acid and other dyes using ferrous-hydrogen peroxide system. Chemosphere 50:619–625
Vimonses V, Lei SM, Jin B, Chowd CWK, Saint C (2009) Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials. Chem Eng J 148:354–364
Wong YC, Szeto YS, Cheung WH, McKay G (2003) Equilibrium studies for acid dye adsorption onto chitosan. Langmuir 19:7888
You Y, Zhao H, Vance GF (2002) Adsorption of dicamba (3,6-dichloro-2-methoxy benzoic acid) in aqueous solution by calcined-layered double hydroxide. Appl Clay Sci 21:217–226
Zollinger H (1991) Color chemistry. Synthesis, properties and applications of organic dyes and pigments, 2nd revised edn. VCH, New York
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Attallah, M.F., Ahmed, I.M. & Hamed, M.M. Treatment of industrial wastewater containing Congo Red and Naphthol Green B using low-cost adsorbent. Environ Sci Pollut Res 20, 1106–1116 (2013). https://doi.org/10.1007/s11356-012-0947-4
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DOI: https://doi.org/10.1007/s11356-012-0947-4