Abstract
Direct ceramic microfiltration (DCMF) is an effective technology to pre-concentrate organic matter (OM) for the subsequent anaerobic energy-recovering processes and a fast, cost-effective, easy treatment process for municipal wastewater. The major problem in DCMF is the rapid fouling of the membrane. In this study, to maximize OM recovery rates and prevent membrane fouling, the DCMF process was alternately paired with dosing of a cationic polyacrylamide (PAM) flocculant and chemically enhanced primary sedimentation (CEPS). The DCMF process tested in three stages: (i) optimization of flocculant concentration (0.5, 1, 1.5, and 2 mg/L PAM) and dosing point, (ii) optimization of operational conditions (pH, filtration/backwash duration, flux, and recovery rate) to control membrane fouling, and (iii) long-term operation of the DCMF process. The influence of PAM dosage points on DCMF fouling behavior was explored, and system operating parameters in terms of OM recovery and TMP change were optimized. The CEPS + DCMF setup was discovered to be a potential option for overcoming fouling. The highest chemical oxygen demand (COD) was 520 ± 20 mg/L in the concentrated wastewater using CEPS + DCMF experiments for 0.5 mg/L PAM. The highest OM pre-concentration was achieved at 90% recovery rate. After the optimization, COD concentration in the concentrate of the DCMF process reached 822 mg/L for the long-term (20 days) operation. The net potential energy production was calculated as 0.28 kWh/m3 considering the theoretical COD of 1432 mg/L in the concentrate stream. As a novel approach, the CEPS + DCMF process can be used in place of conventional municipal wastewater treatment processes due to its acceptable OM removal performance, simple operation, small footprint, and potential energy generation.
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Data Availability
The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
Aguilar, M. I., Sáez, J., Lloréns, M., Soler, A., & Ortuño, J. F. (2002). Nutrient removal and sludge production in the coagulation–flocculation process. Water Research, 36(11), 2910–2919.
Ahmad, A., Ismail, S., & Bhatia, S. (2005). Optimization of coagulation− flocculation process for palm oil mill effluent using response surface methodology. Environmental Science & Technology, 39(8), 2828–2834.
Ahmad, A., Wong, S., Teng, T., & Zuhairi, A. (2008). Improvement of alum and PACl coagulation by polyacrylamides (PAMs) for the treatment of pulp and paper mill wastewater. Chemical Engineering Journal, 137(3), 510–517.
Aiyuk, S., Amoako, J., Raskin, L., van Haandel, A., & Verstraete, W. (2004). Removal of carbon and nutrients from domestic wastewater using a low investment, integrated treatment concept. Water Research, 38(13), 3031–3042.
Alengebawy, A., Jin, K., Ran, Y., Peng, J., Zhang, X., & Ai, P. (2021). Advanced pre-treatment of stripped biogas slurry by polyaluminum chloride coagulation and biochar adsorption coupled with ceramic membrane filtration. Chemosphere, 267, 129197.
Amuda, O., & Alade, A. (2006). Coagulation/flocculation process in the treatment of abattoir wastewater. Desalination, 196(1–3), 22–31.
APHA (2005). Standard methods for the examination of water and wastewater. American Public Health Association (APHA), Washington, DC, USA 21.
Arhin, S. G., Banadda, N., Komakech, A. J., Kabenge, I., Wanyama, J., Arhin, S. G., Banadda, N., Komakech, A. J., Kabenge, I., & Wanyama, J. (2016). Membrane fouling control in low pressure membranes, a review on pretreatment techniques for fouling abatement. Environmental Engineering Research, 21(2), 109–120.
Bezirgiannidis, A., Plesia-Efstathopoulou, A., Ntougias, S., & Melidis, P. (2019). Combined chemically enhanced primary sedimentation and biofiltration process for low cost municipal wastewater treatment. Journal of Environmental Science and Health, Part A, 54(12), 1227–1232.
Bielefeldt, A. R. (2009). Water Treatment, Industrial. Encyclopedia of Microbiology (Third Edition). M. Schaechter. Oxford, Academic Press, 569-586.
Campinas, M., Viegas, R. M. C., Silva, C., Lucas, H., & Rosa, M. J. (2021). Operational performance and cost analysis of PAC/ceramic MF for drinking water production, exploring treatment capacity as a new indicator for performance assessment and optimization. Separation and Purification Technology, 255, 117443.
Chakraborty, T., Balusani, D., Smith, S., Santoro, D., Walton, J., Nakhla, G., & Ray, M. B. (2020). Reusability of recovered iron coagulant from primary municipal sludge and its impact on chemically enhanced primary treatment. Separation and Purification Technology, 231, 115894.
Chong, M. F. (2012). Direct flocculation process for wastewater treatment. Advances in water treatment and pollution prevention, Springer, 201–230.
Czerwionka, K., Wilinska, A., & Tuszynska, A. (2020). The use of organic coagulants in the primary precipitation process at wastewater treatment plants. Water, 12(6), 1650.
Dai, W., Xu, X., Liu, B., & Yang, F. (2015). Toward energy-neutral wastewater treatment, a membrane combined process of anaerobic digestion and nitritation–anammox for biogas recovery and nitrogen removal. Chemical Engineering Journal, 279, 725–734.
Dang, T. T. H., Li, C.-W., & Choo, K.-H. (2016). Comparison of low-pressure reverse osmosis filtration and polyelectrolyte-enhanced ultrafiltration for the removal of Co and Sr from nuclear plant wastewater. Separation and Purification Technology, 157, 209–214.
De Feo, G., De Gisi, S., & Galasso, M. (2008). Definition of a practical multi-criteria procedure for selecting the best coagulant in a chemically assisted primary sedimentation process for the treatment of urban wastewater. Desalination, 230(1), 229–238.
Du, Y., Pennock, W. H., Weber-Shirk, M. L., & Lion, L. W. (2019). Observations and a geometric explanation of effects of humic acid on flocculation. Environmental Engineering Science, 36(5), 614–622.
Gong, H., Jin, Z., Wang, X., & Wang, K. (2015). Membrane fouling controlled by coagulation/adsorption during direct sewage membrane filtration (DSMF) for organic matter concentration. Journal of Environmental Sciences, 32, 1–7.
Gruskevica, K., & Mezule, L. (2021). Cleaning methods for ceramic ultrafiltration membranes affected by organic fouling. Membranes, 11(2), 131.
Guven, H., Dereli, R. K., Ozgun, H., Ersahin, M. E., & Ozturk, I. (2019). Towards sustainable and energy efficient municipal wastewater treatment by up-concentration of organics. Progress in Energy and Combustion Science, 70, 145–168.
Hafuka, A., Takahashi, T., & Kimura, K. (2020). Anaerobic digestibility of up-concentrated organic matter obtained from direct membrane filtration of municipal wastewater. Biochemical Engineering Journal, 161, 107692.
Hennecke, D., Bauer, A., Herrchen, M., Wischerhoff, E., & Gores, F. (2018). Cationic polyacrylamide copolymers (PAMs), environmental half life determination in sludge-treated soil. Environmental Sciences Europe, 30(1), 1–13.
Hofs, B., Ogier, J., Vries, D., Beerendonk, E. F., & Cornelissen, E. R. (2011). Comparison of ceramic and polymeric membrane permeability and fouling using surface water. Separation and Purification Technology, 79(3), 365–374.
Hög, A., Ludwig, J., & Beery, M. (2015). The use of integrated flotation and ceramic membrane filtration for surface water treatment with high loads of suspended and dissolved organic matter. Journal of Water Process Engineering, 6, 129–135.
Huang, J.-C., & Li, L. (2000). An innovative approach to maximize primary treatment performance. Water Science and Technology, 42(12), 209–222.
Huang, B.-C., Guan, Y.-F., Chen, W., & Yu, H.-Q. (2017). Membrane fouling characteristics and mitigation in a coagulation-assisted microfiltration process for municipal wastewater pretreatment. Water Research, 123, 216–223.
Hube, S., Eskafi, M., Hrafnkelsdóttir, K. F., Bjarnadóttir, B., Bjarnadóttir, M. Á., Axelsdóttir, S., & Wu, B. (2020). Direct membrane filtration for wastewater treatment and resource recovery, A review. Science of the Total Environment, 710, 136375.
Ismail, I. M., Fawzy, A. S., Abdel-Monem, N. M., Mahmoud, M. H., & El-Halwany, M. A. (2012). Combined coagulation flocculation pre treatment unit for municipal wastewater. Journal of Advanced Research, 3(4), 331–336.
Jin, L., Ong, S. L., & Ng, H. Y. (2010). Comparison of fouling characteristics in different pore-sized submerged ceramic membrane bioreactors. Water Research, 44(20), 5907–5918.
Jin, Z., Gong, H., Temmink, H., Nie, H., Wu, J., Zuo, J., & Wang, K. (2016). Efficient sewage pre-concentration with combined coagulation microfiltration for organic matter recovery. Chemical Engineering Journal, 292, 130–138.
Jin, Z., Meng, F., Gong, H., Wang, C., & Wang, K. (2017). Improved low-carbon-consuming fouling control in long-term membrane-based sewage pre-concentration, the role of enhanced coagulation process and air backflushing in sustainable sewage treatment. Journal of Membrane Science, 529, 252–262.
Jordao, E., & Volschan, I. (2004). Cost-effective solutions for sewage treatment in developing countries-the case of Brazil. Water Science and Technology, 50(7), 237–242.
Kacprzak, M., Neczaj, E., Fijałkowski, K., Grobelak, A., Grosser, A., Worwag, M., Rorat, A., Brattebo, H., Almås, Å., & Singh, B. R. (2017). Sewage sludge disposal strategies for sustainable development. Environmental Research, 156, 39–46.
Kalboussi, N., Harmand, J., Rapaport, A., Bayen, T., Ellouze, F., & Amar, N. B. (2018). Optimal control of physical backwash strategy-towards the enhancement of membrane filtration process performance. Journal of Membrane Science, 545, 38–48.
Kim, J., Kim, K., Ye, H., Lee, E., Shin, C., McCarty, P. L., & Bae, J. (2011). Anaerobic fluidized bed membrane bioreactor for wastewater treatment. Environmental Science & Technology, 45(2), 576–581.
Kimura, K., Honoki, D., & Sato, T. (2017). Effective physical cleaning and adequate membrane flux for direct membrane filtration (DMF) of municipal wastewater, up-concentration of organic matter for efficient energy recovery. Separation and Purification Technology, 181, 37–43.
Kimura, K., M. Yamakawa and A. Hafuka (2021). Direct membrane filtration (DMF) for recovery of organic matter in municipal wastewater using small amounts of chemicals and energy. Chemosphere, 130244.
Lateef, S. K., Soh, B. Z., & Kimura, K. (2013). Direct membrane filtration of municipal wastewater with chemically enhanced backwash for recovery of organic matter. Bioresource Technology, 150, 149–155.
Lee, C. S., Robinson, J., & Chong, M. F. (2014). A review on application of flocculants in wastewater treatment. Process Safety and Environmental Protection, 92(6), 489–508.
Li, C., Sun, W., Lu, Z., Ao, X., & Li, S. (2020a). Ceramic nanocomposite membranes and membrane fouling. A Review. Water Research, 175, 115674.
Li, Y. Y., Lin, L., & Li, X. Y. (2020b). Chemically enhanced primary sedimentation and acidogenesis of organics in sludge for enhanced nitrogen removal in wastewater treatment. Journal of Cleaner Production, 244, 118705.
Lin, L., Li, R.-H., Li, Y., Xu, J., & Li, X.-Y. (2017). Recovery of organic carbon and phosphorus from wastewater by Fe-enhanced primary sedimentation and sludge fermentation. Process Biochemistry, 54, 135–139.
Liu, T., Lian, Y., Graham, N., Yu, W., Rooney, D., & Sun, K. (2017). Application of polyacrylamide flocculation with and without alum coagulation for mitigating ultrafiltration membrane fouling, Role of floc structure and bacterial activity. Chemical Engineering Journal, 307, 41–48.
Liu, Z., Zhu, X., Liang, P., Zhang, X., Kimura, K., & Huang, X. (2019). Distinction between polymeric and ceramic membrane in AnMBR treating municipal wastewater, in terms of irremovable fouling. Journal of Membrane Science, 588, 117229.
Malkoske, T. A., Bérubé, P. R., & Andrews, R. C. (2020). Coagulation/flocculation prior to low pressure membranes in drinking water treatment, a review Environmental Science. Water Research & Technology, 6(11), 2993–3023.
McCarty, P. L., Bae, J., & Kim, J. (2011). Domestic wastewater treatment as a net energy producer–can this be achieved? Environmental Science & Technology, 45, 7100–7106.
Mei, X., Quek, P. J., Wang, Z., & Ng, H. Y. (2017). Alkali-assisted membrane cleaning for fouling control of anaerobic ceramic membrane bioreactor. Bioresource Technology, 240, 25–32.
Meng, F., Chae, S.-R., Drews, A., Kraume, M., Shin, H.-S., & Yang, F. (2009). Recent advances in membrane bioreactors (MBRs), membrane fouling and membrane material. Water Research, 43(6), 1489–1512.
Mudhoo, A., & Kumar, S. (2013). Effects of heavy metals as stress factors on anaerobic digestion processes and biogas production from biomass. International Journal of Environmental Science and Technology, 10(6), 1383–1398.
Nair, A. T., & Ahammed, M. M. (2015). The reuse of water treatment sludge as a coagulant for post-treatment of UASB reactor treating urban wastewater. Journal of Cleaner Production, 96, 272–281.
Nascimento, T. A., Mejía, F. R., Fdz-Polanco, F., & Peña Miranda, M. (2017). Improvement of municipal wastewater pretreatment by direct membrane filtration. Environmental Technology, 38(20), 2562–2572.
Nascimento, T. A. and M. P. Miranda (2021). Control strategies for the long-term operation of direct membrane filtration of municipal wastewater. Journal of Environmental Chemical Engineering, 105335.
Oh, H., Takizawa, S., Ohgaki, S., Katayama, H., Oguma, K., & Yu, M. (2007). Removal of organics and viruses using hybrid ceramic MF system without draining PAC. Desalination, 202(1–3), 191–198.
Panepinto, D., Fiore, S., Zappone, M., Genon, G., & Meucci, L. (2016). Evaluation of the energy efficiency of a large wastewater treatment plant in Italy. Applied Energy, 161, 404–411.
Seib, M., Berg, K., & Zitomer, D. (2016). Low energy anaerobic membrane bioreactor for municipal wastewater treatment. Journal of Membrane Science, 514, 450–457.
Shewa, W. A., & Dagnew, M. (2020). Revisiting chemically enhanced primary treatment of wastewater, a review. Sustainability, 12(15), 5928.
Sills, D. L., Wade, V. L., & DiStefano, T. D. (2016). Comparative life cycle and technoeconomic assessment for energy recovery from dilute wastewater. Environmental Engineering Science, 33(11), 861–872.
Taboada-Santos, A., Rivadulla, E., Paredes, L., Carballa, M., Romalde, J., & Lema, J. M. (2020). Comprehensive comparison of chemically enhanced primary treatment and high-rate activated sludge in novel wastewater treatment plant configurations. Water Research, 169, 115258.
Wan, J., Gu, J., Zhao, Q., & Liu, Y. (2016). COD capture, a feasible option towards energy self-sufficient domestic wastewater treatment. Scientific Reports, 6(1), 1–9.
Wang, S., Liu, C., & Li, Q. (2011). Fouling of microfiltration membranes by organic polymer coagulants and flocculants, controlling factors and mechanisms. Water Research, 45(1), 357–365.
Wang, S., Jena, U., & Das, K. C. (2018). Biomethane production potential of slaughterhouse waste in the United States. Energy Conversion and Management, 173, 143–157.
Wang, H., I. A. Fotidis and I. Angelidaki (2015). Ammonia effect on hydrogenotrophic methanogens and syntrophic acetate-oxidizing bacteria. FEMS microbiology ecology, 91(11).
Xu, S., Zhang, L., Huang, S., Zeeman, G., Rijnaarts, H., & Liu, Y. (2018). Improving the energy efficiency of a pilot-scale UASB-digester for low temperature domestic wastewater treatment. Biochemical Engineering Journal, 135, 71–78.
Xue, J., Zhang, Y., Liu, Y., & El-Din, M. G. (2016). Treatment of oil sands process-affected water (OSPW) using a membrane bioreactor with a submerged flat-sheet ceramic microfiltration membrane. Water Research, 88, 1–11.
Zhao, Y.-X., Li, P., Li, R.-H., & Li, X.-Y. (2019). Direct filtration for the treatment of the coagulated domestic sewage using flat-sheet ceramic membranes. Chemosphere, 223, 383–390.
Zhao, Y.-X., Li, P., Li, R.-H., & Li, X.-Y. (2020). Characterization and mitigation of the fouling of flat-sheet ceramic membranes for direct filtration of the coagulated domestic wastewater. Journal of Hazardous Materials, 385, 121557.
Zielińska, M., & Galik, M. (2017). Use of ceramic membranes in a membrane filtration supported by coagulation for the treatment of dairy wastewater. Water, Air, & Soil Pollution, 228(5), 1–12.
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The Scientific and Technological Research Council of Turkey provided financial support (Project No.: 119Y134).
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Ozcan, O., Sahinkaya, E. & Uzal, N. Pre-concentration of Municipal Wastewater Using Flocculation-Assisted Direct Ceramic Microfiltration Process: Optimization of Operational Conditions. Water Air Soil Pollut 233, 420 (2022). https://doi.org/10.1007/s11270-022-05872-7
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DOI: https://doi.org/10.1007/s11270-022-05872-7