Abstract
Amorphous mesoporous titania (AM-TiO2) was prepared through the solvothermal-assisted sol–gel method. AM-TiO2 exhibited a large specific surface area (675 m2/g) and a high adsorption capacity (252.7 ± 5.6 mg/g) for the removal of Sb(III) from aqueous solution, which was beyond the majority of previously reported Sb(III) adsorbent. The isotherms and kinetics studies indicated that the adsorption followed the Langmuir isotherm model and pseudo-second-order kinetics equation. Choosing N, N-dimethylformamide (DMF) as the solvent, as-synthesized AM-TiO2 exhibited a remarkably enhanced adsorption capacity of Sb(III) compared with other solvents including acetone (209.6 mg/g), methyl alcohol (195.5 mg/g), ethyl alcohol (180.5 mg/g), and water (106.7 mg/g). Furthermore, the background ionic such as CO32−, Cl−, SO42−, and NO3− had a negligible impact on the adsorption properties of AM-TiO2. The synergy among negative surface charge, large specific surface area, and abundant hydroxyl groups facilitates the adsorption of Sb(III). AM-TiO2 was further utilized to the removal of Sb(III) in real polluted textile wastewater; meanwhile, Mn and chemical oxygen demand (COD) in the textile wastewater were simultaneously reduced as well.
Graphical abstract
Similar content being viewed by others
Data Availability
The datasets supporting the conclusions of this article are included within the article and its supplementary information files.
References
Abramian, L., & El-Rassy, H. (2009). Adsorption kinetics and thermodynamics of azo-dye Orange II onto highly porous titania aerogel. Chemical Engineering Journal, 150, 403–410. https://doi.org/10.1016/j.cej.2009.01.019
Bastakoti, B. P., Sakka, Y., Wu, K. C. W., & Yamauchi, Y. (2015). ’ Synthesis of highly photocatalytic TiO2 microflowers based on solvothermal approach using N,N-Dimethylformamide. Journal of Nanoscience and Nanotechnology, 15, 4747–4751. https://doi.org/10.1166/jnn.2015.9694
Bergmann, M. E., & Koparal, A. S. (2011). Electrochemical antimony removal from accumulator acid: Results from removal trials in laboratory cells. Journal of Hazardous Materials, 196, 59–65. https://doi.org/10.1016/j.jhazmat.2011.08.073
Chen, D., Cao, L., Huang, F., Imperia, P., Cheng, Y. B., & Caruso, R. A. (2010). Synthesis of monodisperse mesoporous titania beads with controllable diameter, high surface areas, and variable pore diameters (14–23 nm). Journal of the American Chemical Society, 132, 4438–4444. https://doi.org/10.1021/ja100040p
Cheng, K., Wu, Y.-N., Zhang, B., & Li, F. (2020). New insights into the removal of antimony from water using an iron-based metal-organic framework: Adsorption behaviors and mechanisms. Colloids and Surfaces a: Physicochemical and Engineering Aspects, 602,. https://doi.org/10.1016/j.colsurfa.2020.125054
Chu, Y., Zhang, X., Yu, X., Yan, C., Yang, Y., Shen, G., Wang, X., Tao, S., & Wang, X. (2021). Antimony removal by a magnetic TiO2/SiO2/Fe3O4 nanosphere and influence of model dissolved organic matter. Chemical Engineering Journal, 420,. https://doi.org/10.1016/j.cej.2021.129783
Fan, H. T., Sun, W., Jiang, B., Wang, Q. J., Li, D. W., Huang, C. C., Wang, K. J., Zhang, Z. G., & Li, W. X. (2016). Adsorption of antimony(III) from aqueous solution by mercapto-functionalized silica-supported organic–inorganic hybrid sorbent: Mechanism insights. Chemical Engineering Journal, 286, 128–138. https://doi.org/10.1016/j.cej.2015.10.048
Fan, Y., Zheng, C., Liu, H., He, C., Shen, Z., & Zhang, T. C. (2020). Effect of pH on the adsorption of arsenic(V) and antimony(V) by the black soil in three systems: Performance and mechanism. Ecotoxicology and Environmental Safety, 191, 110145. https://doi.org/10.1016/j.ecoenv.2019.110145
Feng, M., Zhang, P., Zhou, H. C., & Sharma, V. K. (2018a). Water-stable metal-organic frameworks for aqueous removal of heavy metals and radionuclides: A review. Chemosphere, 209, 783–800. https://doi.org/10.1016/j.chemosphere.2018.06.114
Feng, Q. G., Cai, H. D., Lin, H. Y., Qin, S. Y., Liu, Z., Ma, D. C., & Ye, Y. Y. (2018b). Synthesis and structural characteristics of high surface area TiO2 aerogels by ultrasonic-assisted sol-gel method. Nanotechnology, 29, 075702. https://doi.org/10.1088/1361-6528/aaa1d1
Gurgul, J., Rinke, M. T., Schellenberg, I., & Pöttgen, R. (2013). The antimonide oxides REZnSbO and REMnSbO (RE = Ce, Pr) – An XPS study. Solid State Sciences, 17, 122–127. https://doi.org/10.1016/j.solidstatesciences.2012.11.014
Han, Y. S., Seong, H. J., Chon, C. M., Park, J. H., Nam, I. H., Yoo, K., & Ahn, J. S. (2018). Interaction of Sb(III) with iron sulfide under anoxic conditions: Similarities and differences compared to As(III) interactions. Chemosphere, 195, 762–770. https://doi.org/10.1016/j.chemosphere.2017.12.133
He, X., Min, X., & Luo, X. (2017). Efficient removal of antimony (III, V) from contaminated water by amino modification of a zirconium metal–organic framework with mechanism study. Journal of Chemical & Engineering Data, 62, 1519–1529. https://doi.org/10.1021/acs.jced.7b00010
Ho, Y. S., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34, 451–465. https://doi.org/10.1016/S0032-9592(98)00112-5
Jia, T., Zhang, J., Wu, J., Wang, D., Liu, Q., Qi, Y., Hu, B., He, P., Pan, W., & Qi, X. (2020). Synthesis amorphous TiO2 with oxygen vacancy as carriers transport channels for enhancing photocatalytic activity. Materials Letters, 265,. https://doi.org/10.1016/j.matlet.2020.127465
Lee, C. G., Javed, H., Zhang, D., Kim, J. H., Westerhoff, P., Li, Q., & Alvarez, P. J. J. (2018). Porous electrospun fibers embedding TiO2 for adsorption and photocatalytic degradation of water pollutants. Environmental Science & Technology, 52, 4285–4293. https://doi.org/10.1021/acs.est.7b06508
Li, H., Zhou, M., Guan, E., & Li, Z. (2021). Preparation of wheat bran-titanium dioxide (TiO2) composite and its application for selenium adsorption. Journal of Cereal Science, 99,. https://doi.org/10.1016/j.jcs.2021.103230
Li, J., Wang, C., Zheng, P., Zhang, L., Chen, G., Tang, C., & Wu, T. (2017). Solvothermal preparation of micro/nanostructured TiO2 with enhanced lithium storage capability. Materials Chemistry and Physics, 190, 202–208. https://doi.org/10.1016/j.matchemphys.2016.12.049
Li, W., Fu, F., Ding, Z., & Tang, B. (2018). Zero valent iron as an electron transfer agent in a reaction system based on zero valent iron/magnetite nanocomposites for adsorption and oxidation of Sb(III). Journal of the Taiwan Institute of Chemical Engineers, 85, 155–164. https://doi.org/10.1016/j.jtice.2018.01.032
Li, Y., Yang, Y., Yang, P., Jiang, L., Wang, W., He, J., Chen, Y., & Wang, J. (2020). Tungstate doped TiO2-SiO2 aerogels for preferential photocatalytic degradation of methamphetamine in seizure samples containing caffeine under simulated sunlight. Catalysis Communications, 145,. https://doi.org/10.1016/j.catcom.2020.106121
Lin, W. H., Chen, C. Y., Chang, T. F. M., Hsu, Y. J., & Sone, M. (2016). Effects of pressure in cathodic deposition of TiO2 and SnO2 with supercritical CO2 emulsified electrolyte. Electrochimica Acta, 208, 244–250. https://doi.org/10.1016/j.electacta.2016.04.088
Liu, B., Jian, M., Wang, H., Zhang, G., Liu, R., Zhang, X., & Qu, J. (2018). Comparing adsorption of arsenic and antimony from single-solute and bi-solute aqueous systems onto ZIF-8. Colloids and Surfaces a: Physicochemical and Engineering Aspects, 538, 164–172. https://doi.org/10.1016/j.colsurfa.2017.10.068
Liu, C., Li, Y., Wang, X., Li, B., Zhou, Y., Liu, D., Liu, D., & Liu, S. (2020). Efficient extraction of antimony(III) by titanate nanosheets: Study on adsorption behavior and mechanism. Ecotoxicology and Environmental Safety, 207, 111271. https://doi.org/10.1016/j.ecoenv.2020.111271
Liu, Y., Lou, Z., Yang, K., Wang, Z., Zhou, C., Li, Y., Cao, Z., & Xu, X. (2019). Coagulation removal of Sb(V) from textile wastewater matrix with enhanced strategy: Comparison study and mechanism analysis. Chemosphere, 237, 124494. https://doi.org/10.1016/j.chemosphere.2019.124494
Long, X., Wang, X., Guo, X., & He, M. (2020). A review of removal technology for antimony in aqueous solution. Journal of Environmental Sciences, 90, 189–204. https://doi.org/10.1016/j.jes.2019.12.008
Lu, X., Li, M., Hoang, S., Suib, S. L., & Gao, P. X. (2021). Solvent effects on the heterogeneous growth of TiO2 nanostructure arrays by solvothermal synthesis. Catalysis Today, 360, 275–283. https://doi.org/10.1016/j.cattod.2020.02.044
Luo, J., Hu, C., Meng, X., Crittenden, J., Qu, J., & Peng, P. (2017). Antimony removal from aqueous solution using novel α-MnO2 nanofibers: Equilibrium, kinetic, and density functional theory studies. ACS Sustainable Chemistry & Engineering, 5, 2255–2264. https://doi.org/10.1021/acssuschemeng.6b02583
Ma, B., Wang, X., Liu, R., Jefferson, W. A., Lan, H., Liu, H., & Qu, J. (2017). Synergistic process using Fe hydrolytic flocs and ultrafiltration membrane for enhanced antimony(V) removal. Journal of Membrane Science, 537, 93–100. https://doi.org/10.1016/j.memsci.2017.05.022
Madurai Ramakrishnan, V., Pitchaiya, S., Muthukumarasamy, N., Kvamme, K., Rajesh, G., Agilan, S., Pugazhendhi, A., & Velauthapillai, D. (2020). Performance of TiO2 nanoparticles synthesized by microwave and solvothermal methods as photoanode in dye-sensitized solar cells (DSSC). International Journal of Hydrogen Energy, 45, 27036–27046. https://doi.org/10.1016/j.ijhydene.2020.07.018
MiarAlipour, S., Friedmann, D., Scott, J., & Amal, R. (2018). TiO2/porous adsorbents: Recent advances and novel applications. Journal of Hazardous Materials, 341, 404–423. https://doi.org/10.1016/j.jhazmat.2017.07.070
Mohamed, M. A., Wan Salleh, W. N., Jaafar, J., Rosmi, M. S., MohdHir, Z. A., Abd Mutalib, M., Ismail, A. F., & Tanemura, M. (2017). Carbon as amorphous shell and interstitial dopant in mesoporous rutile TiO2: Bio-template assisted sol-gel synthesis and photocatalytic activity. Applied Surface Science, 393, 46–59. https://doi.org/10.1016/j.apsusc.2016.09.145
Qi, P., Wang, Y., Zeng, J., Sui, K., & Zhao, J. (2021). Progress in antimony capturing by superior materials: Mechanisms, properties and perspectives. Chemical Engineering Journal, 419,. https://doi.org/10.1016/j.cej.2021.130013
Riveros, P. A., Dutrizac, J. E., & Lastra, R. (2013). A Study of the ion exchange removal of antimony(III) and antimony(V) from copper electrolytes. Canadian Metallurgical Quarterly, 47, 307–316. https://doi.org/10.1179/cmq.2008.47.3.307
Sarkar, A., & Paul, B. (2021). Synthesis, characterization of iron-doped TiO2(B) nanoribbons for the adsorption of As(III) from drinking water and evaluating the performance from the perspective of physical chemistry. Journal of Molecular Liquids, 322,. https://doi.org/10.1016/j.molliq.2020.114556
Tang, Y. C., Wu, C. N., Huang, X. H., Zhang, H. P., Yu, H. Q., Li, X., & Peng, Y. (2012). Arsenic(III) removal from low-arsenic water by adsorption with amorphous mesoporous TiO2. Desalination and Water Treatment, 49, 359–367. https://doi.org/10.1080/19443994.2012.719465
Wang, W., Zhang, C., Shan, J., & He, M. (2020). Comparison of the reaction kinetics and mechanisms of Sb(III) oxidation by reactive oxygen species from pristine and surface-oxidized pyrite. Chemical Geology, 552,. https://doi.org/10.1016/j.chemgeo.2020.119790
Xi, J., He, M., & Lin, C. (2011). Adsorption of antimony(III) and antimony(V) on bentonite: Kinetics, thermodynamics and anion competition. Microchemical Journal, 97, 85–91. https://doi.org/10.1016/j.microc.2010.05.017
Xue, G., Wang, Q., Qian, Y., Gao, P., Su, Y., Liu, Z., Chen, H., Li, X., & Chen, J. (2019). Simultaneous removal of aniline, antimony and chromium by ZVI coupled with H2O2: Implication for textile wastewater treatment. Journal of Hazardous Materials, 368, 840–848. https://doi.org/10.1016/j.jhazmat.2019.02.009
Yan, L., Song, J., Chan, T., & Jing, C. (2017). Insights into antimony adsorption on 001 TiO2: XAFS and DFT study. Environmental Science & Technology, 51, 6335–6341. https://doi.org/10.1021/acs.est.7b00807
Yan, Z., He, Z., Li, M., Zhang, L., Luo, Y., He, J., Chen, Y., & Wang, J. (2020). Curcumin doped SiO2/TiO2 nanocomposites for enhanced photocatalytic reduction of Cr (VI) under visible light. Catalysts, 10,. https://doi.org/10.3390/catal10080942
Yang, H., Jiang, L., Li, Y., Li, G., Yang, Y., He, J., Wang, J., & Yan, Z. (2018). Highly efficient red cabbage anthocyanin inserted TiO2 aerogel nanocomposites for photocatalytic reduction of Cr(VI) under visible light. Nanomaterials, 8,. https://doi.org/10.3390/nano8110937
Yang, K., Liu, Y., Li, Y., Cao, Z., Zhou, C., Wang, Z., Zhou, X., Baig, S. A., & Xu, X. (2019). Applications and characteristics of Fe-Mn binary oxides for Sb(V) removal in textile wastewater: Selective adsorption and the fixed-bed column study. Chemosphere, 232, 254–263. https://doi.org/10.1016/j.chemosphere.2019.05.194
Yang, X., Shi, Z., Yuan, M., & Liu, L. (2015). Adsorption of trivalent antimony from aqueous solution using graphene oxide: Kinetic and thermodynamic studies. Journal of Chemical & Engineering Data, 60, 806–813. https://doi.org/10.1021/je5009262
Yue, X., Xiang, J., Chen, J., Li, H., Qiu, Y., & Yu, X. (2020). High surface area, high catalytic activity titanium dioxide aerogels prepared by solvothermal crystallization. Journal of Materials Science & Technology, 47, 223–230. https://doi.org/10.1016/j.jmst.2019.12.017
Zhang, X., Xie, N., Guo, Y., Niu, D., Sun, H. B., & Yang, Y. (2021). Insights into adsorptive removal of antimony contaminants: Functional materials, evaluation and prospective. Journal of Hazardous Materials, 418, 126345. https://doi.org/10.1016/j.jhazmat.2021.126345
Zhu, D. L., Sun, X. M., Han, Y., Li, J. J., Zhang, W., Duan, D. L., He, J., & Wang, J. Q. (2017). Adsorption of Pb(II) ions from aqueous solution by surfactant-templated titania aerogels. Desalination and Water Treatment, 75, 85–93. https://doi.org/10.5004/dwt.2017.20155
Zulfiqar, M., Sufian, S., Rabat, N. E., & Mansor, N. (2020). Photocatalytic degradation and adsorption of phenol by solvent-controlled TiO2 nanosheets assisted with H2O2 and FeCl3: Kinetic, isotherm and thermodynamic analysis. Journal of Molecular Liquids, 308,. https://doi.org/10.1016/j.molliq.2020.112941
Acknowledgements
This work was supported by the National Natural Science Foundation of China (22062026), the Industrialization Cultivation Project (2016CYH04), the Yunling Scholar (K264202012420), the Kunming Science and Technology Project (2019-1-N-25318000002603), and the Key Laboratory of Advanced Materials for Wastewater Treatment of Kunming. The authors thank the Advanced Analysis and Measurement Center of Yunnan University for the sample testing service.
Author information
Authors and Affiliations
Contributions
Yepeng Yang, Liang Jiang, and Jiaqiang Wang conceived and designed the experiments. Mi Li, Qinyuan Tang, and Peiwen Xu performed the experiments. Daomei Chen, Jiao He, and Yongjuan Chen analyzed the data. Yepeng Yang, Liang Jiang, and Jiaqiang Wang analyzed the data and contributed to writing the manuscript. All authors provided critical feedback and helped shape the research, analysis, and manuscript.
Corresponding authors
Ethics declarations
Competing Interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Highlights
• Amorphous mesoporous titania (AM-TiO2) was prepared through the solvothermal-assisted sol–gel method.
• AM-TiO2 synthesized by using DMF as solvent showed highly efficient adsorption activity for Sb(III).
• AM-TiO2 could simultaneously remove Sb, Mn, and chemical oxygen demand in actual industrial textile wastewater.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Yang, Y., Jiang, L., Tang, Q. et al. Solvothermal-assisted Sol–Gel method Synthesized Amorphous Mesoporous Titania for Efficient Adsorption of Sb(III) in Aqueous Solution. Water Air Soil Pollut 233, 61 (2022). https://doi.org/10.1007/s11270-022-05526-8
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11270-022-05526-8