Skip to main content
Log in

UV–Vis Spectroscopy Applied in the Determination of the Degradation Time of Abelmoschus esculentus Moench Solution Used as Natural Flocculant

  • Published:
Water, Air, & Soil Pollution Aims and scope Submit manuscript

Abstract

Coagulation and flocculation are two of the steps in the water treatment process in which chemical coagulants based on iron salts or aluminum are used. In order to replace the aluminum or to reduce the concentration of the metal, several natural alternatives to assist in the coagulation/flocculation process have been evaluated, including the use of Abelmoschus escuentus Moench (okra) as a flocculating agent. To determine the degradation time of the okra solution, spectral measurements were performed on the UV–Vis region. The coagulation/flocculation tests were carried out in a jar test equipment, using aluminum polychoride as a coagulant, 1-mgL−1 okra solution as a flocculation aid, and the alkalinizing hydroxide of calcium. Through the spectral measurements and the test in the jar test, it was possible to verify that the solution of the okra remains stable only until the time of 24 h, and after this time, begins the degradation process of the constituents of the okra that promote the flocculation of it. In addition, satisfactory results were obtained in the treatment of water in 24 h, allowing the use of okra as flocculation aid and aluminum polychloride coagulant, as in effluent color removal, with an efficiency of 91 to 96%, and organic matter removal, with an efficiency of 92 to 93.5%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

Data Availability

All data generated or analyzed during this study are included in this published article.

Code Availability

Not applicable.

References

  • Ahmad, T., Ahmad, K., & Alam, M. (2016). Characterization of water treatment plant’s sludge and its safe disposal options. Procedia Environmental Sciences, 35, 950–955.

    Article  CAS  Google Scholar 

  • Almeida, M. M. C., Francisco, C. R. L., Oliveira, A., Campos, S. S., Bilck, A. P., Fuchs, R. H. B., Gonçalves, O. H., Valderrama, P., Genena, A. K., & Leimann, F. V. (2018). Textural, color, hygroscopic, lipid oxidation, and sensory properties of cookies containing free and microencapsulated chia oil. Food and Bioprocess Technology, 11(5), 926–939. https://doi.org/10.1007/s11947-018-2057-x

    Article  CAS  Google Scholar 

  • Anastasakis, K., Kalderis, D., & Diamadopoulos, E. (2009). Flocculation behavior of mallow and okra mucilage in treating wastewater. Desalination, 249(2), 786–791. https://doi.org/10.1016/j.desal.2008.09.013

    Article  CAS  Google Scholar 

  • Bade, A., Joshi, M., & Kulkarni, V. S. (2014). Screening of certain herbs for turbidity removal and antimicrobial activity for wastewater treatment. International Journal of Chemical and Life Sciences, 3, 1289–1293.

    Google Scholar 

  • Bazzo, F. P., Pironato, N. B., Março, P. H., Valderrama, P., Peron, A. P., & Medeiros, F. V. S. (2021). Multivariate optimization approach applied to natural polymers from Ceratonia siliqua L. and Moringa oleifera Lam as coagulating/flocculating agents. Environmental Technology (in press)

  • Bondy, S. C. (2010). The neurotoxicity of environmental aluminum is still an issue. Neurotoxicology, 31(5), 575–581. https://doi.org/10.1016/j.neuro.2010.05.009

    Article  CAS  Google Scholar 

  • Carneiro-Marra, L., Sad, L., & Silva-Batista, M. (2019). Evaluation of mucilage and powder of okra as bio-flocculant in water treatment. Revista Ion, 32(2), 53–58.

    Article  Google Scholar 

  • Casale, M., Abajo, M. J. S., Sáiz, J. M. G., Pizarro, C., & Forina, M. (2006). Study of the aging and oxidation processes of vinegar samples from different origins during storage by near-infrared spectroscopy. Analytica Chimica Acta, 557(1–2), 360–366. https://doi.org/10.1016/j.aca.2005.10.063

    Article  CAS  Google Scholar 

  • Domingues, J. A., Consolin-Filho, N., Souza, L. A. G., & Silva-Medeiros, F. V. (2020). Coagulation activity of the seed extract from Zygia cauliflora (WILLD.) KILLIP applied in Water Treatment. Revista Ambiente & Água, 15(6), e2611.

    Google Scholar 

  • Edzwald, J. K., & Kaminski, G. S. (2008). A practical method for water plants to select coagulant dosing. Journal New England Water Works Association – NEWWA, 2008. Available from: <http://www.cec-online.com/site/technical/coagdose.pdf>. Access in 10 de maio de 2021

  • Freitas, T. K. F. S., Oliveira, V. M., Souza, M. T. F., Geraldino, H. C. L., Almeida, V. C., Fávaro, S. L., & Garcia, J. C. (2015). Optimization of coagulation-flocculation process for treatment of industrial textile wastewater using okra (A. esculentus) mucilage as natural coagulant. Industrial Crops and Products, 76(15), 558–544. https://doi.org/10.1016/j.indcrop.2015.06.027

    Article  CAS  Google Scholar 

  • Gupta, S., Jain, R., Kachhwaha, S., & Kothari, S. L. (2018). Nutritional and medicinal applications of Moringa oleifera Lam.—Review of current status and future possibilities. Journal of Herbal Medicine, 11, 1–11.

    Article  Google Scholar 

  • Jatav, K. A., Gawas, S., Yadav, S., Parmar, A., & Kadam, P. (2016). Coagulation efficiency of okra seed extract for surface water treatment. International Journal of Science and Research, 5(3), 2100–2102.

    Google Scholar 

  • Khan, S., Yaoguo, W., Xiaoyan, Z., Youning, X., Jianghua, Z., & Sihai, H. (2014). Estimation of concentration of dissolved organic matter from sediment by using UV–Visible spectrophotometer. International Journal of Environmental Pollution and Remediation, 2(1), 24–29. https://doi.org/10.11159/ijepr.2014.004

    Article  CAS  Google Scholar 

  • Koplík R. Advanced strategies in food analysis [homepage on the Internet]. Czech Republic: Ultraviolet and visible spectrometry. Available from: http://web.vscht.cz/~poustkaj/EN%20ASFA%20AU%20Koplík%20UV_VIS_spectrometry.pdf

  • Lee, C. S., Robinson, J., & Chong, M. F. (2014). A review on application of flocculants in wastewater treatment. Process Safety and Environmental Protection, 92(6), 489–508. https://doi.org/10.1016/j.psep.2014.04.010

    Article  CAS  Google Scholar 

  • Lee, C. S., Chong, M. F., Robinson, J., & Binner, E. (2015). Optimization of extraction and sludge dewatering efficiencies of bio-flocculants extracted from Abelmoschus esculentus (okra). Journal of Environmental Management, 157(1), 320–325. https://doi.org/10.1016/j.jenvman.2015.04.028

    Article  CAS  Google Scholar 

  • Lima, P. R., Almeida, I. V., & Vicentini, V. E. P. (2020). The different types of natural coagulants for water treatment: a review. Evidência, 1–14. (in portuguese). https://doi.org/10.18593/eba.24704

  • Madrona, G. S., Branco, I. G., Seolin, V. J., de Abreu Alves Filho, B., Fagundes-Klen, M. R., & Bergamasco, R. (2012). Evaluation of extracts of Moringa oleifera Lam seeds obtained with NaCl and their effects on water treatment. Acta Scientiarum. Technology, 34(3), 289–293.

    Article  CAS  Google Scholar 

  • Matilainen, A., Vepsäläinen, M., & Sillanpää, M. (2010). Natural organic matter removal by coagulation during drinking water treatment: A review. Advances in Colloid and Interface, 159(2), 189–197. https://doi.org/10.1016/j.cis.2010.06.007

    Article  CAS  Google Scholar 

  • Moreira, I., & Scarminio, I. S. (2013). Chemometric discrimination of genetically modified Coffea arábica cultivars using spectroscopic and chromatographic fingerprints. Talanta, 107, 416–422. https://doi.org/10.1016/j.talanta.2013.01.053

    Article  CAS  Google Scholar 

  • Mota, W., F. (2008). Mineral composition of fruits of four okra cultivars. Ciência Agrotecnológica, 32(3), 762–767.

  • Muniz, G. L., Borges, A. C., & Silva, T. C. F. (2020). Performance of natural coagulants obtained from agro-industrial wastes in dairy wastewater treatment using dissolved air flotation. Journal of Water Process Engineering, 37, 101453.

    Article  Google Scholar 

  • Nogueira, F., C., B. (2012) Sementes de moringa e pó de quiabo no tratamento de efluente sanitário. Master Dissertation) - Universidade José do Rosário Vellano, Alfenas, 2012.

  • Thakur, S. S., & Choubey, S. (2014). Assessment of coagulation efficiency of Moringa oleifera and okra for treatment of turbid water. Applied Science Research, 6(2), 24–30.

    Google Scholar 

  • Van Dyke, N., et al. (2021). Association between aluminum in drinking water and incident Alzheimer’s disease in the Canadian Study of Health and Aging cohort. Neurotoxicology, 83, 157–165.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Contributions

Dominique Martins Sala, conducted experiments with okra. Patricia Valderrama and Ana Paula Peron, co-supervisors of the work and helped in the written part. Flávia Vieira da Silva Medeiros, oriented the work and wrote the manuscript.

Corresponding author

Correspondence to Flávia Vieira da Silva-Medeiros.

Ethics declarations

Ethics Approval

Not applicable.

Consent for Publication

All authors read and approved the final manuscript, and all authors agreed to submit the work to Water, Air, and Soil Pollution.

Conflict of Interest

The authors declare no competing interests.

Additional Declarations for Articles in Life Science Journals That Report the Results of Studies Involving Humans and/or Animals

Not applicable.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sala, D.M., Valderrama, P., Peron, A.P. et al. UV–Vis Spectroscopy Applied in the Determination of the Degradation Time of Abelmoschus esculentus Moench Solution Used as Natural Flocculant. Water Air Soil Pollut 232, 368 (2021). https://doi.org/10.1007/s11270-021-05307-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11270-021-05307-9

Keywords

Navigation