Abstract
Antibiotics are among the prominent class of pharmaceuticals considered emerging pollutants. This class of compounds has found its way into diverse arrays of water bodies in the environment due to their incomplete decomposition, and also the indiscriminate disposal of pharmaceutical waste from industries, farms, and medical centers. This is often through soluble reactive effluent, water run-offs due to rainfall on agricultural facilities and untreated sewages. Their concentration in the environment usually exceeds the permitted levels, which in turn leads to the possibilities of bio-magnifications and bioaccumulation in the food chain. Consequently, they constitute safety hazards and it is important to remove this class of compounds. Another concern is the development of resistance by the micro-organisms, which could render these drugs ineffective and useless if serious control is not put in place to regulate their usage and presence in the environment. Although different conventional methods are currently used in water treatment plants, the presence of pharmaceuticals, such as antibiotics, has been confirmed in different recycled water meant for consumption. Recently, advanced oxidation processes (AOPs) have emerged as a useful technique for the mineralization of these antibiotics in water via the use of heterogeneous photocatalysis. In this review, a background study on the origin and fate of pharmaceuticals such as antibiotics, and the usefulness of photocatalysis (a prominent method of advanced oxidation process (AOPs)) in the mineralization of this class of pharmaceuticals into less harmful compounds is assessed. The degradation pathway of different classes of antibiotics is also discussed using specific examples of compounds in each of the classes.
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References
Abellán, M. N., Giménez, J., & Esplugas, S. (2009). Photocatalytic degradation of antibiotics: The case of sulfamethoxazole and trimethoprim. Catalysis Today, 144, 131–136. https://doi.org/10.1016/j.cattod.2009.01.051
Abraham, E. P., & Chain, E. (1940). An Enzyme from Bacteria able to. Nature, 146, 837.
Aissani, T., Yahiaoui, I., Boudrahem, F., Yahia Cherif, L., Fourcad, F., Amrane, A., & Aissani-Benissad, F. (2020). Sulfamethazine degradation by heterogeneous photocatalysis with ZnO immobilized on a glass plate using the heat attachment method and its impact on the biodegradability. Reaction Kinetics, Mechanisms and Catalysis, 131, 471–487. https://doi.org/10.1007/s11144-020-01842-4
Ajiboye, T. O., Kuvarega, A. T., & Onwudiwe, D. C. (2020a). Recent strategies for environmental remediation of organochlorine pesticides. Applied Sciences, 10, 6286. https://doi.org/10.3390/APP10186286
Ajiboye, T. O., Kuvarega, A. T., & Onwudiwe, D. C. (2020b). Graphitic carbon nitride-based catalysts and their applications: A review. Nano-Structures & Nano-Objects, 24, 100577. https://doi.org/10.1016/j.nanoso.2020.100577
An, T., Yang, H., Song, W., Li, G., Luo, H., & Cooper, W. J. (2010). Mechanistic considerations for the advanced oxidation treatment of fluoroquinolone pharmaceutical compounds using TiO2 heterogeneous catalysis. Journal of Physical Chemistry A, 114, 2569–2575. https://doi.org/10.1021/jp911349y
Aram, M., Farhadian, M., Solaimany Nazar, A. R., Tangestaninejad, S., Eskandari, P., & Jeon, B.-H. (2020). Metronidazole and Cephalexin degradation by using of Urea/TiO2/ZnFe2O4/Clinoptiloite catalyst under visible-light irradiation and ozone injection. Journal of Molecular Liquids, 304, 112764. https://doi.org/10.1016/j.molliq.2020.112764
Askari, N., Beheshti, M., Mowla, D., & Farhadian, M. (2020). Fabrication of CuWO4/Bi2S3/ZIF67 MOF: A novel double Z-scheme ternary heterostructure for boosting visible-light photodegradation of antibiotics. Chemosphere, 251, 126453. https://doi.org/10.1016/j.chemosphere.2020.126453
Azizi-Toupkanloo, H., Karimi-Nazarabad, M., Shakeri, M., & Eftekhari, M. (2019). Photocatalytic mineralization of hard-degradable morphine by visible light-driven Ag@g-C3N4 nanostructures. Environmental Science and Pollution Research, 26, 30941–30953. https://doi.org/10.1007/s11356-019-06274-9
Bahareh, K., & Habibi, M. H. (2019). High photocatalytic activity of light-driven Fe2TiO5 nanoheterostructure toward degradation of antibiotic metronidazole. Journal of Industrial and Engineering Chemistry, 80, 292–300. https://doi.org/10.1016/j.jiec.2019.08.007
Bassi, M. N., Bayarri, B., Giménez, J., & Costa, J. (2007). Photocatalytic degradation of sulfamethoxazole in aqueous suspension of TiO2. Applied Catalysis b: Environmental, 74, 233–241. https://doi.org/10.1016/j.apcatb.2007.02.017
Baneshi, M.M., Jahanbin, S., Mousavizadeh, A., Sadat, S.A., Rayegan-Shirazi, A., Biglari, H., 2018. Gentamicin removal by photocatalytic process from aqueous solution. Polish J. Environ. Stud. 27, 1433–1440. https://doi.org/10.15244/pjoes/78042
Bassi, A. S., Zhu, J. X., Lan, Q., Margaritis, A., & Zheng, Y. (2006). Photocatalytic Degradation of Pharmaceutical Drugs and Dyes Using Visible Active Box Photocatalyst (patent). https://doi.org/10.1038/incomms1464
Batt, A. L., Kincaid, T. M., Kostich, M. S., Lazorchak, J. M., & Olsen, A. R. (2016). Evaluating the extent of pharmaceuticals in surface waters of the United States using a National-scale Rivers and Streams Assessment survey. Environmental Toxicology and Chemistry, 35, 874–881. https://doi.org/10.1002/etc.3161
Bedia, J., Muelas-Ramos, V., Peñas-Garzón, M., Gómez-Avilés, A., Rodríguez, J. J., & Belver, C. (2019). A review on the synthesis and characterization of metal organic frameworks for photocatalytic water purification. Catalysts. https://doi.org/10.3390/catal9010052
Beltrán, F. J., Aguinaco, A., García-Araya, J. F., & Oropesa, A. (2008). Ozone and photocatalytic processes to remove the antibiotic sulfamethoxazole from water. Water Research, 42, 3799–3808. https://doi.org/10.1016/j.watres.2008.07.019
Bethesda, 2012. LiverTox: Clinical and research information on drug-induced liver injury- gentamicin. Natl. Inst. Diabetes Dig. Kidney Dis.
Beydoun, D., Amal, R., & Low, G. (1999). Role of nanoparticles in photocatalysis. Journal of Nanoparticle Research., 1, 439–458. https://doi.org/10.1023/A:1010044830871
Biancullo, F., Moreira, N. F. F., Ribeiro, A. R., Manaia, C. M., Faria, J. L., Nunes, O. C., Castro-Silva, S. M., & Silva, A. M. T. (2019). Heterogeneous photocatalysis using UVA-LEDs for the removal of antibiotics and antibiotic resistant bacteria from urban wastewater treatment plant effluents. Chemical Engineering Journal, 367, 304–313. https://doi.org/10.1016/j.cej.2019.02.012
Bouafıa-Cherguı, S., Zemmourı, H., Chabanı, M., & Bensmaılı, A. (2016). TiO 2 -photocatalyzed degradation of tetracycline: Kinetic study, adsorption isotherms, mineralization and toxicity reduction. Desalination and Water Treatment, 57, 16670–16677. https://doi.org/10.1080/19443994.2015.1082507
Boy-Roura, M., Mas-Pla, J., Petrovic, M., Gros, M., Soler, D., Brusi, D., & Menció, A. (2018). Towards the understanding of antibiotic occurrence and transport in groundwater: Findings from the Baix Fluvià alluvial aquifer (NE Catalonia, Spain). Science of the Total Environment, 612, 1387–1406. https://doi.org/10.1016/j.scitotenv.2017.09.012
Briche, S., Derqaoui, M., Belaiche, M., El Mouchtari, E. M., Wong-Wah-Chung, P., & Rafqah, S. (2020). Nanocomposite material from TiO2 and activated carbon for the removal of pharmaceutical product sulfamethazine by combined adsorption/photocatalysis in aqueous media. Environmental Science and Pollution Research, 27, 25523–25534. https://doi.org/10.1007/s11356-020-08939-2
Calvo-flores, F.G., 2017. Overview of pharmaceutical products as emerging pollutants, in: Emerging Pollutants. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, pp. 57–101. https://doi.org/10.1002/9783527691203.ch4
Cao, J., Li, J., Chu, W., & Cen, W. (2020a). Facile synthesis of Mn-doped BiOCl for metronidazole photodegradation: Optimization, degradation pathway, and mechanism. Chemical Engineering Journal, 400, 125813. https://doi.org/10.1016/j.cej.2020.125813
Cao, M., Wang, P., Ao, Y., Wang, C., Hou, J., & Qian, J. (2016). Visible light activated photocatalytic degradation of tetracycline by a magnetically separable composite photocatalyst: Graphene oxide/magnetite/cerium-doped titania. Journal of Colloid and Interface Science, 467, 129–139. https://doi.org/10.1016/j.jcis.2016.01.005
Cao, S., Zhang, Y., He, N., Wang, J., Chen, H., & Jiang, F. (2020b). Metal-free 2D/2D heterojunction of covalent triazine-based frameworks/graphitic carbon nitride with enhanced interfacial charge separation for highly efficient photocatalytic elimination of antibiotic pollutants. Journal of Hazardous Materials, 391, 122204. https://doi.org/10.1016/j.jhazmat.2020.122204
Carabin, A., Drogui, P., & Robert, D. (2015). Photo-degradation of carbamazepine using TiO2 suspended photocatalysts. Journal of the Taiwan Institute of Chemical Engineers, 54, 109–117. https://doi.org/10.1016/j.jtice.2015.03.006
Chang, P., Jiang, W., Li, Z., Jean, J., Kuo, C., 2015. Pharmaceutical analysis antibiotic tetracycline in the environments — A review. Res. Rev. J. Pharm. Anal. 4, 15–40
Chankhanittha, T., & Nanan, S. (2021). Visible-light-driven photocatalytic degradation of ofloxacin (OFL) antibiotic and Rhodamine B (RhB) dye by solvothermally grown ZnO/Bi2MoO6 heterojunction. Journal of Colloid and Interface Science, 582, 412–427. https://doi.org/10.1016/j.jcis.2020.08.061
Chen, F., Yang, Q., Li, X., Zeng, G., Wang, D., Niu, C., Zhao, J., An, H., Xie, T., & Deng, Y. (2017). Hierarchical assembly of graphene-bridged Ag3PO4/Ag/BiVO4 (040) Z-scheme photocatalyst: An efficient, sustainable and heterogeneous catalyst with enhanced visible-light photoactivity towards tetracycline degradation under visible light irradiation. Applied Catalysis b: Environmental, 200, 330–342. https://doi.org/10.1016/j.apcatb.2016.07.021
Chen, S., Yuan, M., Feng, W., Liu, W., Zhang, W., Xu, H., Zheng, X., Shen, G., Guo, C., & Wang, L. (2020a). Catalytic degradation mechanism of sulfamethazine via photosynergy of monoclinic BiVO4and microalgae under visible-light irradiation. Water Research, 185, 116220. https://doi.org/10.1016/j.watres.2020.116220
Chen, Y., Zhang, X., Wang, L., Cheng, X., & Shang, Q. (2020b). Rapid removal of phenol/antibiotics in water by Fe-(8-hydroxyquinoline-7-carboxylic)/TiO2 flower composite: Adsorption combined with photocatalysis. Chemical Engineering Journal, 402, 126260. https://doi.org/10.1016/j.cej.2020.126260
Cheng, P., Wang, Y., Sarakha, M., & Mailhot, G. (2021). Enhancement of the photocatalytic activity of decatungstate, W10O324−, for the oxidation of sulfasalazine/sulfapyridine in the presence of hydrogen peroxide. Journal of Photochemistry and Photobiology, a: Chemistry, 404, 112890. https://doi.org/10.1016/j.jphotochem.2020.112890
Choi, K.-J., Kim, S.-G., Kim, C., & Kim, S.-H. (2007). Determination of antibiotic compounds in water by on-line SPE-LC/MSD. Chemosphere, 66, 977–984. https://doi.org/10.1016/j.chemosphere.2006.07.037
Christian, T., Schneider, R. J., Färber, H. A., Skutlarek, D., Meyer, M. T., & Goldbach, H. E. (2003). Determination of antibiotic residues in manure, soil, and surface waters. Acta Hydrochimica Et Hydrobiologica, 31, 36–44. https://doi.org/10.1002/aheh.200390014
Costanzo, S. D., Murby, J., & Bates, J. (2005). Ecosystem response to antibiotics entering the aquatic environment. Marine Pollution Bulletin, 51, 218–223. https://doi.org/10.1016/j.marpolbul.2004.10.038
Cui, J., Fu, L., Tang, B., Bin, L., Li, P., Huang, S., & Fu, F. (2020). Occurrence, ecotoxicological risks of sulfonamides and their acetylated metabolites in the typical wastewater treatment plants and receiving rivers at the Pearl River Delta. Science of the Total Environment, 709, 136192. https://doi.org/10.1016/j.scitotenv.2019.136192
Cuklev, F., Kristiansson, E., Fick, J., Asker, N., Förlin, L., & Larsson, D. G. J. (2011). Diclofenac in fish: Blood plasma levels similar to human therapeutic levels affect global hepatic gene expression. Environmental Toxicology and Chemistry, 30, 2126–2134. https://doi.org/10.1002/etc.599
Dantas, R. F., Contreras, S., Sans, C., & Esplugas, S. (2008). Sulfamethoxazole abatement by means of ozonation. Journal of Hazardous Materials, 150, 790–794. https://doi.org/10.1016/j.jhazmat.2007.05.034
Darwish, M., Mohammadi, A., & Assi, N. (2016). Integration of nickel doping with loading on graphene for enhanced adsorptive and catalytic properties of CdS nanoparticles towards visible light degradation of some antibiotics. Journal of Hazardous Materials, 320, 304–314. https://doi.org/10.1016/j.jhazmat.2016.08.043
Daughton, C. G., & Ternes, T. A. (1999). Pharmaceuticals and personal care products in the environment: agents of subtle change? Environmental Health Perspectives, 107, 907–938. https://doi.org/10.1289/ehp.99107s6907
De andrade, j.r., oliveira, m.f., da silva, m.g.c., vieira, m.g.a., 2018. Adsorption of pharmaceuticals from water and wastewater using nonconventional low-cost materials: A review. Industrial and Engineering Chemistry Research. https://doi.org/10.1021/acs.iecr.7b05137
Deblonde, T., Cossu-Leguille, C., & Hartemann, P. (2011). Emerging pollutants in wastewater: A review of the literature. International Journal of Hygiene and Environmental Health, 214, 442–448. https://doi.org/10.1016/j.ijheh.2011.08.002
Deng, Y., & Zhao, R. (2015). Advanced oxidation processes (AOPs) in wastewater treatment. Current Pollution Reports, 1, 167–176. https://doi.org/10.1007/s40726-015-0015-z
Dewil, R., Mantzavinos, D., Poulios, I., & Rodrigo, M. A. (2017). New perspectives for advanced oxidation processes. Journal of Environmental Management, 195, 93–99. https://doi.org/10.1016/j.jenvman.2017.04.010
Dimitrakopoulou, D., Rethemiotaki, I., Frontistis, Z., Xekoukoulotakis, N. P., Venieri, D., & Mantzavinos, D. (2012). Degradation, mineralization and antibiotic inactivation of amoxicillin by UV-A/TiO 2 photocatalysis. Journal of Environmental Management, 98, 168–174. https://doi.org/10.1016/j.jenvman.2012.01.010
Dong, S., Cui, L., Zhang, W., Xia, L., Zhou, S., Russell, C. K., Fan, M., Feng, J., & Sun, J. (2020). Double-shelled ZnSnO3 hollow cubes for efficient photocatalytic degradation of antibiotic wastewater. Chemical Engineering Journal, 384, 123279. https://doi.org/10.1016/j.cej.2019.123279
Du, L., & Liu, W. (2012). Occurrence, fate, and ecotoxicity of antibiotics in agro-ecosystems. A Review Agronomy fog Sustainable. Development, 32, 309–327. https://doi.org/10.1007/s13593-011-0062-9
Duan, Y., Deng, L., Shi, Z., Liu, X., Zeng, H., Zhang, H., & Crittenden, J. (2020). Efficient sulfadiazine degradation via in-situ epitaxial grow of Graphitic Carbon Nitride (g-C3N4) on carbon dots heterostructures under visible light irradiation: Synthesis, mechanisms and toxicity evaluation. Journal of Colloid and Interface Science, 561, 696–707. https://doi.org/10.1016/j.jcis.2019.11.046
Durán-Álvarez, J. C., Avella, E., Ramírez-Zamora, R. M., & Zanella, R. (2016). Photocatalytic degradation of ciprofloxacin using mono- (Au, Ag and Cu) and bi- (Au-Ag and Au-Cu) metallic nanoparticles supported on TiO2 under UV-C and simulated sunlight. Catalysis Today, 266, 175–187. https://doi.org/10.1016/j.cattod.2015.07.033
Elmolla, E. S., & Chaudhuri, M. (2010). Photocatalytic degradation of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution using UV/TiO2 and UV/H2O2/TiO2 photocatalysis. Desalination, 252, 46–52. https://doi.org/10.1016/j.desal.2009.11.003
Fouad, K., Gar Alalm, M., Bassyouni, M., & Saleh, M. Y. (2020). A novel photocatalytic reactor for the extended reuse of W-TiO2 in the degradation of sulfamethazine. Chemosphere, 257, 127270. https://doi.org/10.1016/j.chemosphere.2020.127270
Friedmann, I. (1948). Staphylococcal infection due to penicillin-resistant strains. BMJ, 1, 27–28. https://doi.org/10.1136/bmj.1.4539.27-c
Fu, S., Yuan, W., Liu, X., Yan, Y., Liu, H., Li, L., Zhao, F., & Zhou, J. (2020). A novel 0D/2D WS2/BiOBr heterostructure with rich oxygen vacancies for enhanced broad-spectrum photocatalytic performance. Journal of Colloid and Interface Science, 569, 150–163. https://doi.org/10.1016/j.jcis.2020.02.077
Gagné, F., Blaise, C., & André, C. (2006). Occurrence of pharmaceutical products in a municipal effluent and toxicity to rainbow trout (Oncorhynchus mykiss) hepatocytes. Ecotoxicology and Environmental Safety, 64, 329–336. https://doi.org/10.1016/j.ecoenv.2005.04.004
Gao, L., Shi, Y., Li, W., Niu, H., Liu, J., & Cai, Y. (2012). Occurrence of antibiotics in eight sewage treatment plants in Beijing, China. Chemosphere, 86, 665–671. https://doi.org/10.1016/j.chemosphere.2011.11.019
Gaynor, M., Mankin, A.S., 2012. Macrolide antibiotics: Binding site, mechanism of action, Resistance, in: Frontiers in Medicinal Chemistry - (Volume 2). BENTHAM SCIENCE PUBLISHERS, pp. 21–35. https://doi.org/10.2174/978160805205910502010021
Giri, P., Pal, C., 2014. Ecotoxicological aspects of pharmaceuticals on aquatic environment. American Journal Drug Discovery 1, 10–24
Glassmeyer, S.T., Koplin, D.W., Furlong, E.T., Focazio, M., 2008. Environmental presence and persistence of pharmaceuticals: An overview, in: Fate of Pharmaceuticals in the Environment and in Water Treatment Systems. CRC Press, Boca Raton, pp. 3–51.
Göbel, A., Thomsen, A., McArdell, C. S., Joss, A., & Giger, W. (2005). Occurrence and sorption behavior of sulfonamides, macrolides, and trimethoprim in activated sludge treatment. Environmental Science and Technology, 39, 3981–3989. https://doi.org/10.1021/es048550a
Gomes, J., Costa, R., Quinta-Ferreira, R.M., Martins, R.C., 2017. Application of ozonation for pharmaceuticals and personal care products removal from water. Science Total Environment . https://doi.org/10.1016/j.scitotenv.2017.01.216
Gulkowska, A., Leung, H. W., So, M. K., Taniyasu, S., Yamashita, N., Yeung, L. W. Y., Richardson, B. J., Lei, A. P., Giesy, J. P., & Lam, P. K. S. (2008). Removal of antibiotics from wastewater by sewage treatment facilities in Hong Kong and Shenzhen. China. Water Research, 42, 395–403. https://doi.org/10.1016/j.watres.2007.07.031
Hasan, N., Moon, G., hee, Park, Jeesu, Park, Jaehoon, & Kim, J. (2018). Visible light-induced degradation of sulfa drugs on pure TiO2 through ligand-to-metal charge transfer. Separation and Purification Technology, 203, 242–250. https://doi.org/10.1016/j.seppur.2018.04.030
Hawkey, P. M. (2003). Mechanisms of quinolone action and microbial response. Journal of Antimicrobial Chemotherapy, 51, 29–35. https://doi.org/10.1093/jac/dkg207
He, S., Zhai, C., Fujitsuka, M., Kim, S., Zhu, M., Yin, R., Zeng, L., & Majima, T. (2021). Femtosecond time-resolved diffuse reflectance study on facet engineered charge-carrier dynamics in Ag3PO4 for antibiotics photodegradation. Applied Catalysis b: Environmental, 281, 119479. https://doi.org/10.1016/j.apcatb.2020.119479
Hu, L., Flanders, P. M., Miller, P. L., & Strathmann, T. J. (2007). Oxidation of sulfamethoxazole and related antimicrobial agents by TiO2 photocatalysis. Water Research, 41, 2612–2626. https://doi.org/10.1016/j.watres.2007.02.026
Hu, X. Y., Zhou, K., Chen, B. Y., & Chang, C. T. (2016). Graphene/TiO 2 /ZSM-5 composites synthesized by mixture design were used for photocatalytic degradation of oxytetracycline under visible light: Mechanism and biotoxicity. Applied Surface Science, 362, 329–334. https://doi.org/10.1016/j.apsusc.2015.10.192
Huo, P., Zhou, M., Tang, Y., Liu, X., Ma, C., Yu, L., & Yan, Y. (2016). Incorporation of N-ZnO/CdS/Graphene oxide composite photocatalyst for enhanced photocatalytic activity under visible light. Journal of Alloys and Compounds, 670, 198–209. https://doi.org/10.1016/j.jallcom.2016.01.247
Ian, C., & Marilyn, R. (2001). Tetracycline antibiotics: Mode of action, applications, molecular biology, and epidemiology of bacterial resistance. Microbiology and Molecular Biology Reviews, 65, 232–260. https://doi.org/10.1128/MMBR.65.2.232
Jelic, A., Fatone, F., Di Fabio, S., Petrovic, M., Cecchi, F., & Barcelo, D. (2012). Tracing pharmaceuticals in a municipal plant for integrated wastewater and organic solid waste treatment. Science of the Total Environment, 433, 352–361. https://doi.org/10.1016/j.scitotenv.2012.06.059
Jelic, A., Gros, M., Ginebreda, A., Cespedes-Sánchez, R., Ventura, F., Petrovic, M., & Barcelo, D. (2011). Occurrence, partition and removal of pharmaceuticals in sewage water and sludge during wastewater treatment. Water Research, 45, 1165–1176. https://doi.org/10.1016/j.watres.2010.11.010
Jia, A., Wan, Y., Xiao, Y., & Hu, J. (2012). Occurrence and fate of quinolone and fluoroquinolone antibiotics in a municipal sewage treatment plant. Water Research, 46, 387–394. https://doi.org/10.1016/j.watres.2011.10.055
Jiahu, G., Yucun, L., Hui, M., Tao, C., Weimin, L., Jun, D., Lunchao, Z., & Sadeghzadeh, S. M. (2020). Nanostructured silica-Nd2Sn2O7 hybrid using fibrous nanosilica as photocatalysts for degradation of metronidazole in simulated wastewater. Catal. Letters, 150, 2003–2012. https://doi.org/10.1007/s10562-019-03010-3
Kandi, D., Behera, A., Sahoo, S., & Parida, K. (2020). CdS QDs modified BiOI/Bi2MoO6 nanocomposite for degradation of quinolone and tetracycline types of antibiotics towards environmental remediation. Separation and Purification Technology, 253, 117523. https://doi.org/10.1016/j.seppur.2020.117523
Karimi-Nazarabad, M., & Goharshadi, E. K. (2017). Highly efficient photocatalytic and photoelectrocatalytic activity of solar light driven WO3/g-C3N4 nanocomposite. Solar Energy Materials and Solar Cells, 160, 484–493. https://doi.org/10.1016/j.solmat.2016.11.005
Karthik, R., Vinoth Kumar, J., Chen, S. M., Karuppiah, C., Cheng, Y. H., & Muthuraj, V. (2017). A study of electrocatalytic and photocatalytic activity of cerium molybdate nanocubes decorated graphene oxide for the sensing and degradation of antibiotic drug chloramphenicol. ACS Applied Materials & Interfaces, 9, 6547–6559. https://doi.org/10.1021/acsami.6b14242
Kato, H., & Kudo, A. (2002). Visible-light-response and photocatalytic activities of TiO 2 and SrTiO 3 photocatalysts codoped with antimony and chromium. The Journal of Physical Chemistry B, 106, 5029–5034. https://doi.org/10.1021/jp0255482
Kim, S., Park, C. M., Jang, A., Jang, M., Hernández-Maldonado, A. J., Yu, M., Heo, J., & Yoon, Y. (2019). Removal of selected pharmaceuticals in an ultrafiltration-activated biochar hybrid system. Journal of Membrane Science, 570–571, 77–84. https://doi.org/10.1016/j.memsci.2018.10.036
Klementova, S., Kahoun, D., Doubkova, L., Frejlachova, K., Dusakova, M., & Zlamal, M. (2017). Catalytic photodegradation of pharmaceuticals – homogeneous and heterogeneous photocatalysis. Photochemical & Photobiological Sciences, 16, 67–71. https://doi.org/10.1039/C6PP00164E
Kraemer, S. A., Ramachandran, A., & Perron, G. G. (2019). Antibiotic pollution in the environment: From microbial ecology to public policy. Microorganisms, 7, 180. https://doi.org/10.3390/microorganisms7060180
Krishnan, S., Rawindran, H., Sinnathambi, C.M., Lim, J.W., 2017. Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants. IOP Conference Series Materials Science and Engineering 206. https://doi.org/10.1088/1757-899X/206/1/012089
Kulkarni, R. M., Malladi, R. S., Hanagadakar, M. S., Doddamani, M. R., & Bhat, U. K. (2016). Ag-TiO2 nanoparticles for photocatalytic degradation of lomefloxacin. Desalination and Water Treatment, 57, 16111–16118. https://doi.org/10.1080/19443994.2015.1076352
Kümmerer, K. (2009). Antibiotics in the aquatic environment – A review – Part I. Chemosphere, 75, 417–434. https://doi.org/10.1016/j.chemosphere.2008.11.086
Kurt, A., Mert, B.K., Özengin, N., Sivrioğlu, Ö., Yonar, T., 2017. Treatment of antibiotics in wastewater using advanced oxidation processes (AOPs), in: Physico-Chemical Wastewater Treatment and Resource Recovery. InTech, p. 13. https://doi.org/10.5772/67538
Lee, P. R., & PhilipLin, R. C. (2003). The antibiotic paradox: How the misuse of antibiotics destroys their curative powers (review). Perspectives in Biology and Medicine, 46, 603–604. https://doi.org/10.1353/pbm.2003.0088
Lee, Y., & von Gunten, U. (2010). Oxidative transformation of micropollutants during municipal wastewater treatment: Comparison of kinetic aspects of selective (chlorine, chlorine dioxide, ferrateVI, and ozone) and non-selective oxidants (hydroxyl radical). Water Research. https://doi.org/10.1016/j.watres.2009.11.045
Li, G., Wang, B., Zhang, J., Wang, R., & Liu, H. (2019a). Rational construction of a direct Z-scheme g-C 3 N 4 /CdS photocatalyst with enhanced visible light photocatalytic activity and degradation of erythromycin and tetracycline. Applied Surface Science, 478, 1056–1064. https://doi.org/10.1016/j.apsusc.2019.02.035
Li, J., Wu, N., 2015. Semiconductor-based photocatalysts and photoelectrochemical cells for solar fuel generation: A review. Catalysis Sciences & Technology . https://doi.org/10.1039/c4cy00974f
Li, Q., Jia, R., Shao, J., & He, Y. (2019b). Photocatalytic degradation of amoxicillin via TiO2 nanoparticle coupling with a novel submerged porous ceramic membrane reactor. Journal of Cleaner Production, 209, 755–761. https://doi.org/10.1016/j.jclepro.2018.10.183
Lim, K. T., Shukor, M. Y., & Wasoh, H. (2014). Physical, chemical, and biological methods for the removal of arsenic compounds. BioMed Research International, 2014, 1–9. https://doi.org/10.1155/2014/503784
Lin, A. Y. C., Yu, T. H., & Lateef, S. K. (2009). Removal of pharmaceuticals in secondary wastewater treatment processes in Taiwan. Journal of Hazardous Materials, 167, 1163–1169. https://doi.org/10.1016/j.jhazmat.2009.01.108
Liu, B., Nie, X., Liu, W., Snoeijs, P., Guan, C., & Tsui, M. T. K. (2011). Toxic effects of erythromycin, ciprofloxacin and sulfamethoxazole on photosynthetic apparatus in Selenastrum capricornutum. Ecotoxicology and Environmental Safety, 74, 1027–1035. https://doi.org/10.1016/j.ecoenv.2011.01.022
Liu, P., Zhang, H., Feng, Y., Shen, C., & Yang, F. (2015). Integrating electrochemical oxidation into forward osmosis process for removal of trace antibiotics in wastewater. Journal of Hazardous Materials. https://doi.org/10.1016/j.jhazmat.2015.04.048
Liu, Q., Tian, H., Dai, Z., Sun, H., Liu, J., Ao, Z., Wang, S., Han, C., & Liu, S. (2020a). Nitrogen-doped carbon nanospheres-modified graphitic carbon nitride with outstanding photocatalytic activity. Nano-Micro Letters, 12, 24. https://doi.org/10.1007/s40820-019-0358-x
Liu, W., He, T., Wang, Y., Ning, G., Xu, Z., Chen, X., Hu, X., Wu, Y., Zhao, Y., 2020. Synergistic adsorption-photocatalytic degradation effect and norfloxacin mechanism of ZnO/ZnS@BC under UV-light irradiation. Sci. Rep. 10. https://doi.org/10.1038/s41598-020-68517-x
Löffler, D., & Ternes, T. A. (2003). Analytical method for the determination of the aminoglycoside gentamicin in hospital wastewater via liquid chromatography-electrospray-tandem mass spectrometry. Journal of Chromatography A, 1000, 583–588. https://doi.org/10.1016/S0021-9673(03)00059-1
Lou, W., Kane, A., Wolbert, D., Rtimi, S., Assadi, A.A., 2017. Study of a photocatalytic process for removal of antibiotics from wastewater in a falling film photoreactor: Scavenger study and process intensification feasibility. Chemical Engineering and Processing: Process Intensification. https://doi.org/10.1016/j.cep.2017.10.010
Low, J., Cheng, B., & Yu, J. (2017). Surface modification and enhanced photocatalytic CO2 reduction performance of TiO2: A review. Applied Surface Science, 392, 658–686. https://doi.org/10.1016/j.apsusc.2016.09.093
Lu, Z. Y., Ma, Y. L., Zhang, J. T., Fan, N. S., Huang, B. C., & Jin, R. C. (2020). A critical review of antibiotic removal strategies: Performance and mechanisms. Journal of Water Process Engineering, 38, 101681. https://doi.org/10.1016/j.jwpe.2020.101681
Lv, C., Lan, X., Wang, L., Dai, X., Zhang, M., Cui, J., Yuan, S., Wang, S., Shi, J., 2019. Rapidly and highly efficient degradation of tetracycline hydrochloride in wastewater by 3D IO-TiO 2 -CdS nanocomposite under visible light. Environmental Technology 0, 1–11. https://doi.org/10.1080/09593330.2019.1629183
Lv, X., Yan, D. Y. S., Lam, F.L.-Y., Ng, Y. H., Yin, S., & An, A. K. (2020). Solvothermal synthesis of copper-doped BiOBr microflowers with enhanced adsorption and visible-light driven photocatalytic degradation of norfloxacin. Chemical Engineering Journal, 401, 126012. https://doi.org/10.1016/j.cej.2020.126012
Lyssimachou, A., & Arukwe, A. (2007). Alteration of brain and interrenal StAR protein, P450 scc, and Cyp11β mRNA levels in atlantic salmon after nominal waterborne exposure to the synthetic pharmaceutical estrogen ethynylestradiol. Journal of Toxicology Environment Health Part A, 70, 606–613. https://doi.org/10.1080/10937400600882905
Malesic Eleftheriadou, N., Ofrydopoulou, A., Papageorgiou, M., & Lambropoulou, D. (2020). Development of novel polymer supported nanocomposite GO/TiO2 films, based on poly(L-lactic acid) for photocatalytic applications. Applied Sciences, 10, 2368. https://doi.org/10.3390/app10072368
Mao, W., Zhang, L., Liu, Y., Wang, T., Bai, Y., & Guan, Y. (2021). Facile assembled N, S-codoped corn straw biochar loaded Bi2WO6 with the enhanced electron-rich feature for the efficient photocatalytic removal of ciprofloxacin and Cr(VI). Chemosphere, 263, 127988. https://doi.org/10.1016/j.chemosphere.2020.127988
Martínez, J.L., 2019. Mechanisms of action and of resistance to quinolones, in: Antibiotic Drug Resistance. Wiley, pp. 39–55. https://doi.org/10.1002/9781119282549.ch2
Mayyahi, A. A., & Al-asadi, H. A. A. (2018). Advanced oxidation processes ( AOPs ) for wastewater treatment and reuse : A brief review. Asian Journal Applied Science Technology, 2, 18–30.
Mecha, A. C., & Chollom, M. N. (2020). Photocatalytic ozonation of wastewater: a review. Environmental Chemistry Letters, 18, 1491–1507. https://doi.org/10.1007/s10311-020-01020-x
Mehinto, A. C., Hill, E. M., & Tyler, C. R. (2010). Uptake and biological effects of environmentally relevant concentrations of the nonsteroidal anti-inflammatory pharmaceutical diclofenac in rainbow trout (Oncorhynchus mykiss). Environmental Science and Technology, 44, 2176–2182. https://doi.org/10.1021/es903702m
Mestre, A. S., & Carvalho, A. P. (2019). Photocatalytic degradation of pharmaceuticals carbamazepine, diclofenac, and sulfamethoxazole by semiconductor and carbon materials: A review. Molecules, 24, 3702. https://doi.org/10.3390/molecules24203702
Milić, N., Milanović, M., Letić, N. G., Sekulić, M. T., Radonić, J., Mihajlović, I., & Miloradov, M. V. (2013). Occurrence of antibiotics as emerging contaminant substances in aquatic environment. International Journal of Environmental Health Research, 23, 296–310. https://doi.org/10.1080/09603123.2012.733934
Naushad, M. (2019). A new generation material graphene: Applications in water technology, a new generation material graphene: Applications in water technology. Springer International Publishing, Cham. https://doi.org/10.1007/978-3-319-75484-0
Ni, M., Leung, M. K. H., Leung, D. Y. C., & Sumathy, K. (2007). A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production. Renewable and Sustainable Energy Reviews, 11, 401–425. https://doi.org/10.1016/j.rser.2005.01.009
Omrani, N., & Nezamzadeh-Ejhieh, A. (2020). A novel quadripartite Cu2O-CdS-BiVO4-WO3 visible-light driven photocatalyst: Brief characterization and study the kinetic of the photodegradation and mineralization of sulfasalazine. Journal of Photochemistry and Photobiology, a: Chemistry, 400, 112726. https://doi.org/10.1016/j.jphotochem.2020.112726
Ounnar, A., Favier, L., Bouzaza, A., Bentahar, F., & Trari, M. (2016). Kinetic study of spiramycin removal from aqueous solution using heterogeneous photocatalysis. Kinetics and Catalysis, 57, 200–206. https://doi.org/10.1134/S0023158416020087
Persson, M., Sabelström, E., & Gunnarsson, B. (2009). Handling of unused prescription drugs — knowledge, behaviour and attitude among Swedish people. Environment International, 35, 771–774. https://doi.org/10.1016/j.envint.2008.10.002
Pradhan, G. K., Sahu, N., & Parida, K. M. (2013). Fabrication of S, N co-doped α-Fe2O3 nanostructures: Effect of doping, OH radical formation, surface area, [110] plane and particle size on the photocatalytic activity. RSC Advances. https://doi.org/10.1039/c3ra23088k
Roberts, P., & Thomas, K. (2006). The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of the lower Tyne catchment. Science of the Total Environment, 356, 143–153. https://doi.org/10.1016/j.scitotenv.2005.04.031
Rodrigues-Silva, C., Porto, R.S., dos Santos, S.G., Schneider, J., Rath, S., 2019. Fluoroquinolones in hospital wastewater: Analytical method, occurrence, treatment with ozone and residual antimicrobial activity evaluation. J. Braz. Chem. Soc. 30, 1447–1457. https://doi.org/10.21577/0103-5053.20190040
Savage, N. (2009). Nanotechnology applications for clean water solutions for improving water quality micro and nano technologies. William andrew inc.
Schwaiger, J., Ferling, H., Mallow, U., Wintermayr, H., & Negele, R. D. (2004). Toxic effects of the non-steroidal anti-inflammatory drug diclofenac. Aquatic Toxicology, 68, 141–150. https://doi.org/10.1016/j.aquatox.2004.03.014
Serna-Galvis, E. A., Silva-Agredo, J., Giraldo, A. L., Flórez, O. A., & Torres-Palma, R. A. (2016). Comparison of route, mechanism and extent of treatment for the degradation of a β-lactam antibiotic by TiO2 photocatalysis, sonochemistry, electrochemistry and the photo-Fenton system. Chemical Engineering Journal, 284, 953–962. https://doi.org/10.1016/j.cej.2015.08.154
Sharma, M., Jain, T., Singh, S., & Pandey, O. P. (2012). Photocatalytic degradation of organic dyes under UV–Visible light using capped ZnS nanoparticles. Solar Energy, 86, 626–633. https://doi.org/10.1016/j.solener.2011.11.006
Shemer, H., Kunukcu, Y.K., Linden, K.G., 2006. Degradation of the pharmaceutical Metronidazole via UV, Fenton and photo-Fenton processes. Chemosphere. https://doi.org/10.1016/j.chemosphere.2005.07.029
Song, J., Xu, Z., Liu, W., & Chang, C. T. (2016). KBr O3 and graphene as double and enhanced collaborative catalysts for the photocatalytic degradation of amoxicillin by UVA/TiO2 nanotube processes. Materials Science in Semiconductor Processing, 52, 32–37. https://doi.org/10.1016/j.mssp.2016.04.011
Tacic, A., Nikolic, V., Nikolic, L., Savic, I., 2017. Antimicrobial sulfonamide drugs. Advanced Technology 6, 58–71. https://doi.org/10.5937/savteh1701058T
Tamaddon, F., Mosslemin, M. H., Asadipour, A., Gharaghani, M. A., & Nasiri, A. (2020). Microwave-assisted preparation of ZnFe2O4@methyl cellulose as a new nano-biomagnetic photocatalyst for photodegradation of metronidazole. International Journal of Biological Macromolecules, 154, 1036–1049. https://doi.org/10.1016/j.ijbiomac.2020.03.069
Tang, R., Ding, R.L., Zheng, S.Y., 2019. Preparation of phosphorus doped graphitic carbon nitride and its visible-light photocatalytic performance on sulfathiazole degradation. Journal of Ecology and Rural Environment 35, 377–384. https://doi.org/10.19741/j.issn.1673-4831.2018.0278
Tang, Y., Liu, X., Ma, C., Zhou, M., Huo, P., Yu, L., Pan, J., Shi, W., & Yan, Y. (2015). Enhanced photocatalytic degradation of tetracycline antibiotics by reduced graphene oxide-CdS/ZnS heterostructure photocatalysts. New Journal of Chemistry, 39, 5150–5160. https://doi.org/10.1039/c5nj00681c
Tassalit, D., Chekir, N., Benhabiles, O., Bentahar, F., & Laoufi, N. A. (2016). Photocatalytic degradation of Tylosin and spiramycin in water by using TiO2 and ZnO catalysts under UV radiation. Green Energy Technology. https://doi.org/10.1007/978-3-319-30127-3_51
Tran, M. L., Nguyen, C. H., Fu, C.-C., & Juang, R.-S. (2019). Hybridizing Ag-Doped ZnO nanoparticles with graphite as potential photocatalysts for enhanced removal of metronidazole antibiotic from water. Journal of Environmental Management, 252, 109611. https://doi.org/10.1016/j.jenvman.2019.109611
Van Boeckel, T. P., Brower, C., Gilbert, M., Grenfell, B. T., Levin, S. A., Robinson, T. P., Teillant, A., & Laxminarayan, R. (2015). Global trends in antimicrobial use in food animals. Proceedings of the National Academy of Sciences, 112, 5649–5654. https://doi.org/10.1073/pnas.1503141112
Vannini, C., Domingo, G., Marsoni, M., De Mattia, F., Labra, M., Castiglioni, S., & Bracale, M. (2011). Effects of a complex mixture of therapeutic drugs on unicellular algae Pseudokirchneriella subcapitata. Aquatic Toxicology, 101, 459–465. https://doi.org/10.1016/j.aquatox.2010.10.011
Vignesh, K., Rajarajan, M., & Suganthi, A. (2014). Photocatalytic degradation of erythromycin under visible light by zinc phthalocyanine-modified titania nanoparticles. Materials Science in Semiconductor Processing, 23, 98–103. https://doi.org/10.1016/j.mssp.2014.02.050
Wang, N., Li, X., Yang, Y., Zhou, Z., Shang, Y., Zhuang, X., & Zhang, T. (2020a). Two-stage calcination composite of Bi2O3-TiO2 supported on powdered activated carbon for enhanced degradation of sulfamethazine under solar irradiation. Journal of Water Process Engineering, 35, 101220. https://doi.org/10.1016/j.jwpe.2020.101220
Wang, P., Xu, S., Wang, J., & Liu, X. (2020b). Photodeposition synthesis of CdS QDs-decorated TiO2 for efficient photocatalytic degradation of metronidazole under visible light. Journal of Materials Science: Materials in Electronics. https://doi.org/10.1007/s10854-020-04504-2
Wang, X., Wang, A., Lu, M., & Ma, J. (2018). Synthesis of magnetically recoverable Fe0/graphene-TiO2 nanowires composite for both reduction and photocatalytic oxidation of metronidazole. Chemical Engineering Journal, 337, 372–384. https://doi.org/10.1016/j.cej.2017.12.090
Watkinson, A. J., Murby, E. J., & Costanzo, S. D. (2007). Removal of antibiotics in conventional and advanced wastewater treatment: Implications for environmental discharge and wastewater recycling. Water Research, 41, 4164–4176. https://doi.org/10.1016/j.watres.2007.04.005
Watkinson, A. J., Murby, E. J., Kolpin, D. W., & Costanzo, S. D. (2009). The occurrence of antibiotics in an urban watershed: From wastewater to drinking water. Science of the Total Environment, 407, 2711–2723. https://doi.org/10.1016/j.scitotenv.2008.11.059
WHO, 2011. Pharmaceuticals in drinking water: Public health and environment. Water, Sanitation, Hygiene and Health. Journal of the American Pharmaceutical Association. https://doi.org/10.1331/JAPhA.2010.09186
Williamson, R., Collatz, E., & Gutmann, L. (1986). Mechanisms of action of beta-lactam antibiotics and mechanisms of non-enzymatic resistance. Presse Medicale (paris, France: 1983), 15, 2282–2289.
Wilson, B. A., Smith, V. H., DeNoyelles, F., & Larive, C. K. (2003). Effects of three pharmaceutical and personal care products on natural freshwater algal assemblages. Environmental Science and Technology, 37, 1713–1719. https://doi.org/10.1021/es0259741
Wu, S., Li, X., Tian, Y., Lin, Y., & Hu, Y. H. (2021). Excellent photocatalytic degradation of tetracycline over black anatase-TiO2 under visible light. Chemical Engineering Journal, 406, 126747. https://doi.org/10.1016/j.cej.2020.126747
Xie, Y., Zhang, C., Miao, S., Liu, Z., Ding, K., Miao, Z., An, G., & Yang, Z. (2008). One-pot synthesis of ZnS/polymer composites in supercritical CO2-ethanol solution and their applications in degradation of dyes. Journal of Colloid and Interface Science, 318, 110–115. https://doi.org/10.1016/j.jcis.2007.09.076
Xiong, H., Zou, D., Zhou, D., Dong, S., Wang, J., & Rittmann, B. E. (2017). Enhancing degradation and mineralization of tetracycline using intimately coupled photocatalysis and biodegradation (ICPB). Chemical Engineering Journal, 316, 7–14. https://doi.org/10.1016/j.cej.2017.01.083
Xu, Y., Yifeng, E., & Wang, G. (2019). Controlled growth of “cookie-like” ZnIn2S4 nanoparticles on g-C3N4 for enhanced visible light photocatalytic activity. Inorganic Chemistry Communications, 108, 107485. https://doi.org/10.1016/j.inoche.2019.107485
Xue, Y. N., Sun, Y. S., Liu, J. K., Wang, Y. Y., Wang, X. G., & Yang, X. H. (2019). Construction, enhanced visible-light photocatalytic activity and application of multiple complementary Ag dots decorated onto Ag2MoO4/AZO hybrid nanocomposite. Research on Chemical Intermediates, 45, 873–892. https://doi.org/10.1007/s11164-018-3649-9
Yang, Y., Li, X. J., Chen, J. T., & Wang, L. Y. (2004). Effect of doping mode on the photocatalytic activities of Mo/TiO2. Journal of Photochemistry and Photobiology, a: Chemistry. https://doi.org/10.1016/j.jphotochem.2004.02.008
Zammouri, L., Aboulaich, A., Capoen, B., Bouazaoui, M., Sarakha, M., Stitou, M., & Mahiou, R. (2018). Enhancement under UV–visible and visible light of the ZnO photocatalytic activity for the antibiotic removal from aqueous media using Ce-doped Lu3Al5O12 nanoparticles. Materials Research Bulletin, 106, 162–169. https://doi.org/10.1016/j.materresbull.2018.05.039
Zhang, D., Qi, J., Ji, H., Li, S., Chen, L., Huang, T., Xu, C., Chen, X., & Liu, W. (2020a). Photocatalytic degradation of ofloxacin by perovskite-type NaNbO3 nanorods modified g-C3N4 heterojunction under simulated solar light: Theoretical calculation, ofloxacin degradation pathways and toxicity evolution. Chemical Engineering Journal, 400, 125918. https://doi.org/10.1016/j.cej.2020.125918
Zhang, H., Nengzi, L., Wang, Z., Zhang, X., Li, B., & Cheng, X. (2020b). Construction of Bi2O3/CuNiFe LDHs composite and its enhanced photocatalytic degradation of lomefloxacin with persulfate under simulated sunlight. Journal of Hazardous Materials, 383, 121236. https://doi.org/10.1016/j.jhazmat.2019.121236
Zhang, H., Yamada, H., & Tsuno, H. (2008). Removal of endocrine-disrupting chemicals during ozonation of municipal sewage with brominated byproducts control. Environmental Science and Technology, 42, 3375–3380. https://doi.org/10.1021/es702714e
Zhang, Q., Cheng, J., & Xin, Q. (2015). Effects of tetracycline on developmental toxicity and molecular responses in zebrafish (Danio rerio) embryos. Ecotoxicology, 24, 707–719. https://doi.org/10.1007/s10646-015-1417-9
Zhang, Q., Peng, Y., Lin, Y., Wu, S., Yu, X., & Yang, C. (2021a). Bisphenol S-doped g-C3N4 nanosheets modified by boron nitride quantum dots as efficient visible-light-driven photocatalysts for degradation of sulfamethazine. Chemical Engineering Journal, 405, 126661. https://doi.org/10.1016/j.cej.2020.126661
Zhang, W., Bian, Z., Xin, X., Wang, L., Geng, X., & Wang, H. (2021b). Comparison of visible light driven H2O2 and peroxymonosulfate degradation of norfloxacin using Co/g-C3N4. Chemosphere, 262, 127955. https://doi.org/10.1016/j.chemosphere.2020.127955
Zhang, Y., Yuan, Y., Chen, W., Fan, J., Lv, H., & Wu, Q. (2019). Integrated nanotechnology of synergism-sterilization and removing-residues for neomycin through nano-Cu2O. Colloids Surfaces B Biointerfaces, 183, 110371. https://doi.org/10.1016/j.colsurfb.2019.110371
Zhao, J., He, Q., Zhang, X., Guo, X., Song, Q., Liu, Y., Yao, B., Zhang, Q., & Dionysiou, D. D. (2020). Fabrication of CQDs/Bi5Nb3O15 nanocomposites for photocatalytic degradation of veterinary pharmaceutical sarafloxacin. Catalysis Today, 355, 716–726. https://doi.org/10.1016/j.cattod.2019.05.006
Zhao, J., Zhao, L., & Wang, X. (2008). Preparation and characterization of ZnO/ZnS hybrid photocatalysts via microwave-hydrothermal method. Frontiers of Environmental Science & Engineering in China, 2, 415–420. https://doi.org/10.1007/s11783-008-0056-2
Zhao, Z., Fan, J., Deng, X., & Liu, J. (2019). One-step synthesis of phosphorus-doped g-C 3 N 4 /Co 3 O 4 quantum dots from vitamin B12 with enhanced visible-light photocatalytic activity for metronidazole degradation. Chemical Engineering Journal, 360, 1517–1529. https://doi.org/10.1016/j.cej.2018.10.239
Zheng, L., Zheng, Y., Chen, C., Zhan, Y., Lin, X., Zheng, Q., & Wei, K. (2012). Facile one-pot synthesis of ZnO/SnO2 heterojunction photocatalysts with excellent photocatalytic activity and photostability. ChemPlusChem, 77, 217–223. https://doi.org/10.1002/cplu.201100066
Zheng, X., Xu, S., Wang, Y., Sun, X., Gao, Y., & Gao, B. (2018). Enhanced degradation of ciprofloxacin by graphitized mesoporous carbon (GMC)-TiO2 nanocomposite: Strong synergy of adsorption-photocatalysis and antibiotics degradation mechanism. Journal of Colloid and Interface Science, 527, 202–213. https://doi.org/10.1016/j.jcis.2018.05.054
Zhuang, X., Li, X., Yang, Y., Wang, N., Shang, Y., Zhou, Z., Li, J., & Wang, H. (2020). Enhanced sulfamerazine removal via adsorption–photocatalysis using Bi2O3–TiO2/PAC ternary nanoparticles. Water, 12, 2273. https://doi.org/10.3390/w12082273
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Adeyemi, J.O., Ajiboye, T. & Onwudiwe, D.C. Mineralization of Antibiotics in Wastewater Via Photocatalysis. Water Air Soil Pollut 232, 219 (2021). https://doi.org/10.1007/s11270-021-05167-3
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DOI: https://doi.org/10.1007/s11270-021-05167-3