Skip to main content

Advertisement

Log in

Pollutant Removal Efficiency of Electrocoagulation Method from Industrial Wastewater: Comparison with Other Treatment Methods and Key Operational Parameters—a Comparative Study Review

  • Published:
Water, Air, & Soil Pollution Aims and scope Submit manuscript

Abstract

Various types of industries discharge their untreated contaminated water into the environment every year. This untreated water contains the pollutants that can negatively affect the environment and biosphere. Many methods are under practice at the moment to treat this wastewater. Among the variety of methods proposed and employed currently is the electrocoagulation (EC) method. This technique involves destabilizing the pollutants of the wastewater through the electric current flowing between the electrodes. The electrodes are mainly made of iron or aluminum. Over the past years, this technique has shown a great potential towards removal of different pollutant types from variety of wastewater. Like many other processes, the EC method is also governed and affected by various parameters such as pH, operation time, types of electrodes, and current density. It is important to keep these parameters under check and at the optimum desired value for the maximum pollutant removal. The optimum value depends upon the wastewater and the composition of the contaminants to be segregated. The present study reviews and compares the efficiency of EC with other methods in use so far. Compared to other methods, EC is shown to be energy efficient and reducing operation costs. The study also presents the challenges faced by this technique, such as electrode passivation, and the possible ways to deal with them in order to improve the overall performance effectiveness.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  • Acharya, S., Sharma, S. K., Chauhan, G., & Shree, D. (2018). Statistical optimization of electrocoagulation process for removal of nitrates using response surface methodology. Indian Chemical Engineer, 60, 269–284. https://doi.org/10.1080/00194506.2017.1365630.

    Article  CAS  Google Scholar 

  • Akyol, A., Can, O., Demirbas, E., et al. (2013). A comparative study of electrocoagulation and electro-Fenton for treatment of wastewater from liquid organic fertilizer plant. Elsevier

  • Alameen, M., Engineering NM-J of (2020) undefined (2019) Removal of cadmium from industrial wastewater using electrocoagulation process. iasj.net. https://doi.org/10.31026/j.eng.2020.01.03

  • Ali, I., protocols VG-N (2006). undefined Advances in water treatment by adsorption technology. nature.com

  • Ali, I., Asim, M., & Khan, T. A. (2013). Arsenite removal from water by electro-coagulation on zinc-zinc and copper-copper electrodes. International Journal of Environmental Science and Technology, 10, 377–384. https://doi.org/10.1007/s13762-012-0113-z.

  • Al-Raad, A.A., Hanafiah, M.M., Naje, A.S., et al. Treatment of saline water using electrocoagulation with combined electrical connection of electrodes. mdpi.com. https://doi.org/10.3390/pr7050242

  • Al-Shannag, M., Lafi, W., Bani-Melhem, K., et al. (2012). Reduction of COD and TSS from paper industries wastewater using electro-coagulation and chemical coagulation. Separation Science, Taylor Fr, 47, 700–708. https://doi.org/10.1080/01496395.2011.634474.

    Article  CAS  Google Scholar 

  • Arturi, T., Seijas, C., Heliyon, G.B., (2019) Undefined A comparative study on the treatment of gelatin production plant wastewater using electrocoagulation and chemical coagulation. Elsevier

  • Attour, A., Touati, M., Tlili, M., et al. (2014) Influence of operating parameters on phosphate removal from water by electrocoagulation using aluminum electrodes. Elsevier

  • Bener, S., Bulca, Ö., Palas, B., et al (2019) Electrocoagulation process for the treatment of real textile wastewater: Effect of operative conditions on the organic carbon removal and kinetic study. Elsevier

  • Bhagawan, D., Poodari, S., Pothuraju, T., et al. (2014). Effect of operational parameters on heavy metal removal by electrocoagulation. Environmental Science and Pollution Research, 21, 14166–14173. https://doi.org/10.1007/s11356-014-3331-8.

    Article  CAS  Google Scholar 

  • Bratby, J. (2016). Coagulation and flocculation in water and wastewater treatment

  • Chen, X., Ren, P., Li, T., et al. (2018). Zinc removal from model wastewater by electrocoagulation: Processing, kinetics and mechanism. Chemical Engineering Journal, 349, 358–367. https://doi.org/10.1016/j.cej.2018.05.099.

    Article  CAS  Google Scholar 

  • Chithra, M. J., Sathya, M., & Pushpanathan, K. (2015). Effect of pH on crystal size and photoluminescence property of zno nanoparticles prepared by chemical precipitation method. Acta Metallurgica Sinica (English Letters), 28, 394–404. https://doi.org/10.1007/s40195-015-0218-8.

    Article  CAS  Google Scholar 

  • Choudhary, M., Peter, C. N., Shukla, S. K., et al. (2020). Environmental issues: A challenge for wastewater treatment (pp. 1–12). Cham: Springer.

    Google Scholar 

  • Chow, H., materials AP-J of hazardous (2019). undefined Effective removal of silica and sulfide from oil sands thermal in-situ produced water by electrocoagulation. Elsevier

  • Da̧browski, A., Hubicki, Z., Podkościelny, P. et al. Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. Elsevier

  • Darban, A., Shahedi, A., … FT-CO in, (2020) undefined A review on industrial wastewater treatment via electrocoagulation processes. Elsevier

  • De, S., Hazra, T., & Dutta, A. (2019). Assessment of removal of mercury from landfill leachate by electrocoagulation. In Environmental biotechnology for soil and wastewater implications on ecosystems (pp. 21–27). Singapore: Springer.

    Chapter  Google Scholar 

  • Elimelech, M., Gregory, J., Jia, X. (2013). Particle deposition and aggregation: Measurement, modelling and simulation

  • Esfandyari, Y., Saeb, K., … AT-WS, (2019). undefined Effective removal of cefazolin from hospital wastewater by the electrocoagulation process. iwaponline.com

  • Eskibalci, M., & Engineering MO-M. (2018). undefined Comparison of conventional coagulation and electrocoagulation methods for dewatering of coal preparation plant. Elsevier.

  • Fekete, É., Lengyel, B., Cserfalvi, T., & Pajkossy, T. (2016). Electrochemical dissolution of aluminium in electrocoagulation experiments. Journal of Solid State Electrochemistry, 20, 3107–3114. https://doi.org/10.1007/s10008-016-3195-6.

    Article  CAS  Google Scholar 

  • Gaied, F., Louhichi, B., Bali, M., Jeday, M.R. (2019). Tertiary treatment of wastewater by electro-coagulation, electro-Fenton and advanced electro-oxidation processes: Comparative and economic study

  • Garcia-Segura, S., Eiband, M. M. S. G., de Melo, J. V., & Martínez-Huitle, C. A. (2017). Electrocoagulation and advanced electrocoagulation processes: A general review about the fundamentals, emerging applications and its association with other technologies. Journal of Electroanalytical Chemistry, 801, 267–299.

    Article  CAS  Google Scholar 

  • Ghanbari, F., Wu, J., Khatebasreh, M., et al. (2020) Efficient treatment for landfill leachate through sequential electrocoagulation, electrooxidation and PMS/UV/CuFe2O4 process. Elsevier

  • Hansen, H., Peña, S., Gutiérrez, C., et al. Selenium removal from petroleum refinery wastewater using an electrocoagulation technique. Elsevier

  • Hashim, K., Al Khaddar, R., Jasim, N., et al Electrocoagulation as a green technology for phosphate removal from river water. Elsevier

  • İrdemez, Ş., Demircioğlu, N., Materials YY-J of H (2006). undefined The effects of pH on phosphate removal from wastewater by electrocoagulation with iron plate electrodes. Elsevier

  • Kasmuri, N., Aliah, N., & Tarmizi, A. (2018). The treatment of landfill leachate by electrocoagulation to reduce heavy metals and ammonia-nitrogen. International Journal of Engineering and Technology, 7, 109–112. https://doi.org/10.14419/ijet.v7i3.11.15940.

    Article  CAS  Google Scholar 

  • Kim, T., Kim, T., Engineering KZ-J of WP (2020). undefined Removal mechanism of heavy metal (Cu, Ni, Zn, and Cr) in the presence of cyanide during electrocoagulation using Fe and Al electrodes. Elsevier

  • Lin, S., Shyu, C., & MS-W, R. (1998). undefined Saline wastewater treatment by electrochemical method. Elsevier.

  • López-Guzmán, M., … MA-H-S of the T, (2019). Undefined Simultaneous removal of fluoride and arsenic from well water by electrocoagulation. Elsevier

  • Maitlo, H., Kim, J., Kim, K., et al. (2019) Metal-air fuel cell electrocoagulation techniques for the treatment of arsenic in water. Elsevier

  • Manikandan, P., Palanisamy et al. (2017) A comparative study on the competitiveness of photo-assisted chemical oxidation (PACO) with electrocoagulation (EC) for the effective decolorization of reactive blue dye

  • MWH (2012). MWH’s water treatment: principles and design

  • Nariyan, E., Sillanpää, M., & Wolkersdorfer, C. (2018). Uranium removal from Pyhäsalmi/Finland mine water by batch electrocoagulation and optimization with the response surface methodology. Separation and Purification Technology, 193, 386–397. https://doi.org/10.1016/j.seppur.2017.10.020.

    Article  CAS  Google Scholar 

  • Nasrullah, M., Siddique, M., Chemistry AZ-AJ of, (2014). undefined Effect of high current density in electrocoagulation process for sewage treatment. core.ac.uk

  • Nouri, J., Mahvi, A. H., & Bazrafshan, E. (2010). Application of electrocoagulation process in removal of zinc and copper from aqueous solutions by aluminum electrodes. nternational Journal of Environmental Research, 4, 201–208. https://doi.org/10.22059/ijer.2010.10.

    Article  CAS  Google Scholar 

  • Nwabanne, J.T., Igwegbe, C.A., Nwabanne, J.T., et al. (2018). Removal of copper, nickel, and chromium from simulated wastewater using electrocoagulation technique. Evaluation of coagulant activities on wastewaters using natural materials and electrodes View project degradation View project Removal of Copper, Nickel, and Chromium from Simulated Wastewater using Electrocoagulation Technique

  • Oden, M., Protection HS-E-PS and E, (2018). Undefined Treatment of metal plating wastewater using iron electrode by electrocoagulation process: Optimization and process performance. Elsevier

  • Omranpour Shahreza, S., Mokhtarian, N., & Behnam, S. (2020). Optimization of Mn removal from aqueous solutions through electrocoagulation. Environmental Technology (United Kingdom), 41, 890–900. https://doi.org/10.1080/09593330.2018.1514071.

    Article  CAS  Google Scholar 

  • Padmaja, K., Cherukuri, J., Process MR-J of W, (2020). Undefined A comparative study of the efficiency of chemical coagulation and electrocoagulation methods in the treatment of pharmaceutical effluent. Elsevier

  • Prajapati, A., Chaudhari, P., … DP-J of W (2016). undefined Electrocoagulation treatment of rice grain based distillery effluent using copper electrode. Elsevier

  • Ramprasad, C., Sona, K., Afridhi, M., et al. (2019). Nature Environment and Pollution Technology: An International Quarterly Scientific Journal Comparative study on the treatment of landfill leachate by coagulation and electrocoagulation processes. neptjournal.com. 18:845–856

  • Rosenwinkel, K., … UA-H-E, (2005) Undefined Industrial wastewater sources and treatment strategies. Wiley Online Libr

  • Sandhwar, V. K., & Prasad, B. (2018). Comparison of electrocoagulation, peroxi-electrocoagulation and peroxi-coagulation processes for treatment of simulated purified terephthalic acid wastewater: Optimization, sludge and kinetic analysis. Korean Journal of Chemical Engineering, 35, 909–921. https://doi.org/10.1007/s11814-017-0336-2.

    Article  CAS  Google Scholar 

  • Sharma, D., Chaudhari, P. K., & Prajapati, A. K. (2020). Removal of chromium (VI) and lead from electroplating effluent using electrocoagulation. Separation Science and Technology, 55, 321–331. https://doi.org/10.1080/01496395.2018.1563157.

    Article  CAS  Google Scholar 

  • Vasudevan, S., Lakshmi, J. (2010). Electrochemistry MP-J of applied, 2010 undefined Electrocoagulation studies on removal of cadmium using magnesium electrode. Springer

  • Wang L, Hung Y, Shammas N (2005) Physicochemical treatment processes

  • Widhiastuti, F., Lin, J. Y., Shih, Y. J., & Huang, Y. H. (2018). Electrocoagulation of boron by electrochemically co-precipitated spinel ferrites. Chemical Engineering Journal, 350, 893–901. https://doi.org/10.1016/j.cej.2018.06.041.

    Article  CAS  Google Scholar 

  • Wiesner, M. R., Clark, M. M., & Mallevialle, J. (1989). Membrane filtration of coagulated suspensions. Journal of Environmental Engineering (United States), 115, 20–40. https://doi.org/10.1061/(ASCE)0733-9372(1989)115:1(20).

    Article  CAS  Google Scholar 

  • Xu, L., Xu, X., Cao, G., et al. (2018). Optimization and assessment of Fe–electrocoagulation for the removal of potentially toxic metals from real smelting wastewater. Journal of Environmental Management, 218, 129–138. https://doi.org/10.1016/j.jenvman.2018.04.049.

    Article  CAS  Google Scholar 

  • Zou, L., Luo, Y., Hooper, M., et al. Removal of VOCs by photocatalysis process using adsorption enhanced TiO2–SiO2 catalyst. Elsevier

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Faheem Akhter.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Akhter, F., Soomro, S.A., Siddique, M. et al. Pollutant Removal Efficiency of Electrocoagulation Method from Industrial Wastewater: Comparison with Other Treatment Methods and Key Operational Parameters—a Comparative Study Review. Water Air Soil Pollut 232, 93 (2021). https://doi.org/10.1007/s11270-021-05022-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11270-021-05022-5

Keywords

Navigation