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Adsorption of Rare Earth Elements onto the Phosphogypsum a Waste Byproduct

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Abstract

Phosphogypsum (PG), the waste byproduct resulting from wet process phosphoric acid production, is employed as a selective and effective adsorbent for total rare earth elements (REEs) from aqueous solution and leach liquor. The elaboration of PG adsorbent complemented after some physical treatments. Adsorption and elution studies carried out in experimental batches, including the effect of pH, adsorbent dose, initial REE concentration, and equilibrium time. Adsorption of REEs onto PG fitted well with Langmuir isotherm with a theoretical capacity surpassed 357 mg/g. REEs were effectively eluted from loaded PG with 2 mol L−1 HCl acid with an efficiency of 94%. PG showed an outstanding selectivity towards REEs in the presence of many cations and anions, for instance (Fe3+, UO22+, Ca2+, SO42−, NO3−). Different qualitative techniques such as EDS, SEM, and FTIR used to emphasize the adsorption of REEs onto PG. The film diffusion model was the preponderant adsorption mechanism for REEs; also, the adsorption process has a good accordance with pseudo-second-order kinetic model.

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References

  • Ahmad, R., & Kumar, R. (2011). Adsorption of Amaranth dye onto alumina reinforced polystyrene. Clean – Soil, Air, Water, 39(1), 74–82.

    Article  CAS  Google Scholar 

  • Ang, K. L., Li, D., & Nikoloski, A. N. (2017). The effectiveness of ion exchange resins in separating uranium and thorium from rare earth elements in acidic aqueous sulfate media. Part 1. Anionic and cationic resins, Hydrometallurgy, 174, 147–155.

    Article  CAS  Google Scholar 

  • Azizian, S., Eris, S., & Wilson, L. D. (2018). Re-evaluation of the century-old Langmuir isotherm for modeling adsorption phenomena in solution. Chemical Physics, 513, 99–104.

    Article  CAS  Google Scholar 

  • Barnes, P., & Bensted, J. (2001). Structure and Performance of Cements (p. 259). Spon Press.

  • Bouchaud, B., Balmain, J., Bonnet, G., & Pedraza, F. (2012). pH-distribution of cerium species in aqueous systems. Journal of Rare Earths, 30(6), 559–562.

    Article  CAS  Google Scholar 

  • Cánovas, C. R., Chapron, S., Arrachart, G., & Pellet-Rostaing, S. (2019). Leaching of rare earth elements (REEs) and impurities from phosphogypsum: A preliminary insight for further recovery of critical raw materials. Journal of Cleaner Production, 219, 225–235.

    Article  Google Scholar 

  • Chen, Q., Ma, X., Zhang, X., Liu, Y., & Yu, M. (2018). Extraction of rare earth ions from phosphate leach solution using emulsion liquid membrane in concentrated nitric acid medium. Journal of Rare Earths, 36(11), 1190–1197.

    Article  CAS  Google Scholar 

  • Coey, J. M. D. (2019). 2019, perspective and prospects for rare earth permanent magnets. Engineering, In press, Available online. https://doi.org/10.1016/j.eng.2018.11.034.

  • Crini, G., Peindy, H. N., Gimbert, F., & Robert, C. (2007). Removal of basic green 4 (malachite green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: Kinetic and equilibrium studies. Separation and Purification Technology, 53, 97–110.

    Article  CAS  Google Scholar 

  • El Afifi, E. M., Hilal, M. A., Attallah, M. F., & EL-Reefy, S. A. (2009). Characterization of phosphogypsum wastes associated with phosphoric acid and fertilizers production. Journal of Environmental Radioactivity, 100, 407–412.

    Article  Google Scholar 

  • El-Didamony, H., Gado, H. S., Awwad, N. S., Fawzy, M. M., & Attallah, M. F. (2013). Treatment of phosphogypsum waste produced from phosphate ore processing. Journal of Hazardous Materials, 244-245, 596–602.

    Article  CAS  Google Scholar 

  • Forsyth, M., & Hinton, B. (2014). Rare earth-based corrosion inhibitors. In T. Behrsing, G. B. Deacon, & P. C. Junk (Eds.), The chemistry of rare earth metals, compounds, and corrosion inhibitors (pp. 2–37). Woodhead Publishing Series- Elsevier Ltd..

  • Goodenough, K. M., Wall, F., & Merriman, D. (2018). The rare earth elements: Demand, Global Resources, and Challenges for Resourcing Future Generations. Natural Resourses Research, 27, 201.

    Article  CAS  Google Scholar 

  • Gupta, S. S., & Bhattacharyya, K. G. (2011). Kinetics of adsorption of metal ions on inorganic materials: A review. Advances in Colloid and Interface Science, 162, 39–58.

    Article  Google Scholar 

  • Gupta, N. K., Gupta, A., Ramteke, P., Sahoo, H., & Sengupta, A. (2019). Biosorption-a green method for the preconcentration of rare earth elements (REEs) from waste solutions: A review. Journal of Molecular Liquids, 274, 148–164. https://doi.org/10.1016/j.molliq.2018.10.134

    Article  CAS  Google Scholar 

  • Hagag, M.SA., 2019, Comparative study of fabricated composites based on phosphogypsum and Al-hydroxide for uranium separation from aqueous and waste solutions, https://doi.org/10.1080/03067319.2019.1670826.

  • Hentati, O., Abrantes, N., Caetano, A. L., Bouguerra, S., Gonçalves, F., Römbke, J., & Pereiraef, R. (2015). Phosphogypsum as a soil fertilizer: Ecotoxicity of amended soil and elutriates to bacteria, invertebrates, algae and plants. Journal of Hazardous Materials, 294, 80–89.

    Article  CAS  Google Scholar 

  • Hiskey, J. B., & Copp, R. G. (2018). Solvent extraction of yttrium and rare earth elements from copper pregnant leach solutions using Primene JM-T. Minerals Engineering, 125, 265–270.

    Article  CAS  Google Scholar 

  • Hunter, A., 1989, Use of Phosphogypsum fortified with other selected essential elements as a soil amendment on low Cation exchange soils. Final report, FIPR publication no. 01-034-081.

  • Idris, S., Alotaibi, K. M., Peshkur, T. A., Anderson, P., Morris, M., & Gibson, L. T. (2013). Adsorption kinetics: Effect of adsorbent pore size distribution on the rate of Cr(VI) uptake. Microporous and Mesoporous Materials, 165, 99–105.

    Article  CAS  Google Scholar 

  • Islam, G. M. S., Chowdhury, F. H., Raihan, M. T., Amit, S. K. S., & Islam, M. R. (2017). Effect of Phosphogypsum on the properties of Portland cement. Procedia Engineering, 171, 744–751.

    Article  CAS  Google Scholar 

  • Jebali, R., Triki, M., Alomair, N.A., Kochkar, H., 2019, From adsorption of rare earth elements on TiO2 nanotubes to preconcentration column application microchemical journal, 149, 104.

  • Kandila, A. T., Cheira, M. F., Gado, H. S., Soliman, M. H., & Akl, M. H. (2017). Ammonium sulfate preparation from phosphogypsum waste. Journal of Radiation Research and Applied Sciences, 10(1), 24–33.

    Article  Google Scholar 

  • Karge, H., Geidel, E., & Weitkamp, J. (2004). Mol. Sieves science and technology-characterization I. Vibrational Spectroscopy, 72.

  • Li, L., Lu, W., Ding, D., Dai, Z., Cao, C., Liu, L., & Chen, T. (2019). Adsorption properties of pyrene-functionalized nano-Fe3O4 mesoporous materials for uranium. Journal of Solid State Chemistry, 270, 666–673.

    Article  CAS  Google Scholar 

  • Ma, L., Du, Y., Niu, X., Zheng, S., & Zhang, W. (2012). Thermal and kinetic analysis of the process of thermochemical decomposition of Phosphogypsum with CO and additives. Industrial and Engineering Chemistry Research, 51, 6680–6685.

    Article  CAS  Google Scholar 

  • Manjit, S. (2007). Treating waste phosphogypsum for cement and plaster manufacture. Cement and Concrete Research, 32(7), 1033–1038.

    Google Scholar 

  • Marczenko, Z. (1976). spectrophotometric determination of elements. Harwood, New York: John Wiley and Sons. 1976

  • Mosai, A. K., Chimuka, L., Cukrowska, E. M., Kotzé, I. A., & Tutu, H. (2019). The recovery of rare earth elements (REEs) from aqueous solutions using natural zeolite and Bentonite. Water, Air, and Soil Pollution, 230, 188.

    Article  Google Scholar 

  • Newbury, D. E., & Ritchie, N. W. M. (2013). Is scanning Electron microscopy/energy dispersive X-ray spectrometry (SEM/EDS) quantitative? Scanning, 35, 141–168. https://doi.org/10.1002/sca.21041

    Article  Google Scholar 

  • Nosov, V. N., Frolova, N. G., & Kamyshov, V. F. (1976). IR spectra of calcium sulfate semihydrates. Journal of Applied Spectroscopy, 24, 509.

    Article  Google Scholar 

  • Pacheco-Torgal, F., Jalali, S., & Fucic, A. (2012). Toxicity of building materials (p. 221). Woodhead Publishing Limited.

  • Pacheco-Torgal, F., Shi, C., & Sanchez, A. P. (2018). Carbon dioxide sequestration in Cementitious construction materials (p. 199). Elsevier.

  • Qi, D. (2018). Hydrometallurgy of Rare Earths: Extraction and Separation (p. 701). Elsevier.

  • Ramasamy, D. L., Puhakka, V., Doshi, B., Iftekhar, S., & Sillanpää, M. (2019). Fabrication of carbon nanotubes reinforced silica composites with improvedrare earth elements adsorption performance. Chemical Engineering Journal, 365, 291–304.

    Article  CAS  Google Scholar 

  • Rychkov, V. N., Kirillov, E. V., Kirillov, S. V., Semenishchev, V. S., Bunkov, G. M., Botalov, M. S., Smyshlyaev, D. V., & Malyshev, A. S. (2018). Recovery of rare earth elements from phosphogypsum. Journal of Cleaner Production, 196, 674–681.

    Article  CAS  Google Scholar 

  • Singh, B. P., Gupta V. K., and Passari, A. K. (2018). New and Future Developments in Microbial Biotechnology and Bioengineering Actinobacteria: Diversity and Biotechnological Applications,Chapter 18- Ashok Bankar and Geetha Nagaraja1, Elsevier B.V. Recent Trends in Biosorption of Heavy, Metals by Actinobacteria, Chapter 18, pp 265.

  • Siyal, A. A., Shamsuddin, M. R., Khan, M. I., Rabat, N. K., Zulfiqar, M., Man, Z., Siame, J., & Azizli, K. A. (2018). A review on geopolymers as emerging materials for the adsorption of heavy metals and dyes. Journal of Environmental Management, 224, 327.

    Article  CAS  Google Scholar 

  • Smith, Y. R., Bhattacharyya, D., Willhard, T., & Mano Misra, M. (2016). Adsorption of aqueous rare earth elements using carbon black derived from recycled tires. Chemical Engineering Journal, 296, 102–111.

    Article  CAS  Google Scholar 

  • Speight, J. G. (2017). Environmental Inorganic Chemistry for Engineers , Elsevier Inc., pp 149.

  • Szpadt, R., & Augustyn, Z. (1991). Environmental Pollution in the Vicinity of a Waste-Gypsum Landfill. In L. Pawlowski, W. J. Lacy, & J. J. Dlugosz (Eds.), Chemistry for the Protection of the Environment. Environmental Science Research (Vol. 42, pp. 387–399). Springer.

  • Tanabe, S. (2015). Glass and Rare-Earth Elements: A Personal Perspective. International Journal of Applied Glass Science, 6(4), 305–328.

    Article  CAS  Google Scholar 

  • Ul-Hamid, A. (2018). A Beginners' guide to scanning electron microscopy (pp. 4–6). Switzerland: Springer Nature Switzerland AG.

    Book  Google Scholar 

  • Vijayakumar, G., Dharmendirakumar, M., Renganathan, S., Sivanesan, S., Baskar, G., & Elango, P. (2009). Removal of Congo red from aqueous solutions by perlite. CLEAN - Soil Air Water, 37(4–5), 355–364.

    Article  CAS  Google Scholar 

  • Wu, S., Zhao, L., Wang, L., Huang, X., Zhang, Y., Feng, Z., & Cui, D. (2019). Simultaneous Recovery of Rare Earth Elements and Phosphorus from Phosphate rock. Phosphoric Acid Leaching and Selective Precipitation: Towards Green Process, 37(6), 652–658.

    CAS  Google Scholar 

  • Xu, X., Jiang, X., Jiao, F., Chen, X., & Yu, J. (2018). Tunable assembly of porous three-dimensional graphene oxide-corn zein composites with strong mechanical properties for adsorption of rare earth elements. Journal of the Taiwan Institute of Chemical Engineers, 85, 106–114.

    Article  CAS  Google Scholar 

  • Yaoguang, Y. U., Chen, G., Zhou, Y., & Han, Z. (2015). Recent advances in rare-earth elements modification of inorganic semiconductor-based photocatalysts for efficient solar energy conversion: A review. Journal of Rare Earths, 33(5), 453–462. https://doi.org/10.1016/S1002-0721(14)60440-3.

    Article  CAS  Google Scholar 

  • Youssef, W. M., Hagag, M. S., & Ali, A. H. (2018). Synthesis, characterization and application of composite derived from rice husk ash with aluminium oxide for sorption of uranium. Adsorption Science and Technology, 36(5–6), 1274–1293. https://doi.org/10.1177/026361741876892.

    Article  CAS  Google Scholar 

  • Youssef, L., Morci, A., & Hagag, M. S. (2019). Uranium ions adsorption from acid leach liquor using acid cured phosphate rock: Kinetic, equilibrium and thermodynamic studies. Separation Science and Technology.

  • Yu, Z., Meng, X., Zheng, Z., Lu, Chen, H., Huang, C., Sun, H., Liang, K., Ma, Z., Qia, Y., & Zhang, T. (2019). Room temperature multiferroic properties of rare-earth-substituted Aurivillius phase Bi5Ti3Fe0.7Co0.3O15. Materials Research Bulletin, 115, 235–241.

    Article  CAS  Google Scholar 

  • Zhao, F., Repo, E., Meng, Y., Wang, X., Yin, D., & Sillanpää, M. (2016). An EDTA-b-cyclodextrin material for the adsorption of rare earth elements and its application in preconcentration of rare earth elements in seawater. Journal of Colloid and Interface Science, 465, 215–224.

    Article  CAS  Google Scholar 

  • Zhou, J., Yi, Y., Shu, Z., Wang, Y., Yakubu, Y., Zhao, Y., & Li, X. (2019). Enhancing waterproof performance of phosphogypsum non-fired ceramics by coating silane-coupled unsaturated polyester resin. Materials Letters, 252, 52–55.

    Article  CAS  Google Scholar 

  • Znajdek, K., Szczecińska, N., Sibiński, M., Wiosna-Sałyga, G., & Przymęcki, K. (2018). Luminescent layers based on rare earth elements for thin-film flexible solar cells applications. Optik, 165, 200–209.

    Article  CAS  Google Scholar 

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  1. Nuclear Materials Authority, P.O. Box 530, Maadi, Cairo, Egypt

    M. S. Hagag, A. M. A. Morsy, A. H. Ali & A. S. El-Shiekh

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  1. M. S. Hagag
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  2. A. M. A. Morsy
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  3. A. H. Ali
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Hagag, M.S., Morsy, A.M.A., Ali, A.H. et al. Adsorption of Rare Earth Elements onto the Phosphogypsum a Waste Byproduct. Water Air Soil Pollut 230, 308 (2019). https://doi.org/10.1007/s11270-019-4362-z

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