Removal of Fluoride from Water by Locally Available Sand Modified with a Coating of Iron Oxides

  • Champa Gogoi
  • Jitu Saikia
  • Susmita Sarmah
  • Dipak Sinha
  • Rajib Lochan Goswamee
Article

Abstract

Locally available low-cost material viz. sand from the Kaliani river of Kanaighat area of Golaghat district Assam, India, was collected. The sand was fractionated and the different fractions were characterized by classical chemical analysis, powder XRD, SEM-EDXA, DTA-TGA, and by FT-IR. The chemical analysis of the size fraction of a 600–850-μm range gave more than 90% silica. This fractionated portion was modified by coating with iron oxide. Coating was carried out on the washed and separated sand by repeated treatment of Fe(NO3)3 at 110 and 600 °C, respectively. From FESEM analysis, formation of iron oxide coating over sand surface is clearly observed. The coated sand was used to remove toxic fluoride ion from the drinking water. Iron oxide-coated sand shows highly improved fluoride removal capacity compared to raw sand. The defluoridation capacity of coated sands rose up to 89% from 7% in uncoated raw sand. The effects of different parameters like adsorbent dose, contact time, temperature, initial fluoride concentration, and pH and the effects of different anions present in water along with arsenic on defluoridation capacity of the material were studied in a batch mode.

Keywords

Fluoride Fluorosis Kanaighat sand Iron oxide-coated sand Defluoridation 

Notes

Acknowledgements

Authors are very thankful to the Director, CSIR-NEIST, Jorhat, Assam, India, for providing facilities for the work and allowing to publish the work, Nagaland University for allowing to register under Ph.D. program, and CSIR project CSC 408 for the infrastructural facilities. Author CG is also grateful to Principal CNB College Bokakhat, Golaghat, Assam, for giving permission to carry out the work as a part of a faculty improvement of the Chemistry Department.

References

  1. Agarwal, M., Rai, K., Shrivastav, R., & Dass, S. (2003). Defluoridation of water using amended clay. J. Cleaner Produc., 11, 439–444.CrossRefGoogle Scholar
  2. Al-Rashed, S. M., & Al-Gaid, A. A. (2012). Kinetic and thermodynamic studies on the adsorption behavior of Rhodamine B dye on Duolite C-20 resin. Journal of Saudi Chemical Society, 16(2), 209–215.CrossRefGoogle Scholar
  3. Amalraj, A., & Pius, A. (2017). Removal of fluoride from drinking water using aluminum hydroxide coated activated carbon prepared from bark of Morinda tinctoria. Applied Water Science, 7, 2653–2665.CrossRefGoogle Scholar
  4. Apshankar Kruttika R., Goel, S.: 2017, Defluoridation of groundwater using electrocoagulation and filtration: efficiency and energy consumption. Journal of Enverionmental Engineering 143(2), February 2017.Google Scholar
  5. Azbar, N., & Turkman, A. (2000). Defluoridation in drinking waters. Water Science and Technology, 42, 403–407.Google Scholar
  6. Baruah, B., Mishra, M., Bhattacharjee, C. R., Nihalani, M. C., Mishra, S. K., Baruah, S. D., Phukan, P., & Goswami, R. L. (2013). The effect of particle size of clay on the viscocity bulid up property of mixed metal hydroxide (MMH) in the low solid-drilling and composition. Applied Clay Science, 80-81, 169–175.CrossRefGoogle Scholar
  7. Bejaoui, I., Mnif, A., & Hamroun, B. (2014). Performance of reverse osmosis and nanofiltration in the removal of fluoride from model water and metal packaging industrial effluent. Separation Science and Technology, 49(8), 1135–1145.CrossRefGoogle Scholar
  8. Benjamin, M. M., Sletten, R. S., Bailey, R. P., & Bennet, T. (1996). Sorption and filtration of metals using iron oxide coated sand. Water Research, 30(11), 2609–2620.CrossRefGoogle Scholar
  9. Brindha, K., Elango, L., 2011. Fluoride in groundwater: causes, implications and mitigation measures. In: Monroy, S.D. (Ed.), Fluoride properties applications and environmental management, 111–136.Google Scholar
  10. Browne, D., Whelton, H., & O’Mullane, D. (2005). Fluoride metabolism and fluorosis. Journal of Dentistry, 33(3), 177–186.CrossRefGoogle Scholar
  11. Bureau of Indian Standards (BIS) (1991). 10500:1991, Second Revision ICS No. 13.060.20. http://www.bis.org.in/sf/fad/FAD25(2047)C.pdf. Accessed 6 Jan 2010.
  12. Chai, L., Wang, Y., Zhao, N., Yang, W., & You, X. (2013). Sulfate-doped Fe3O4/Al2O3 nanoparticles as a novel adsorbent for fluoride removal from drinking water. Water Research, 47(12), 4040–4049.CrossRefGoogle Scholar
  13. Chen, N., Feng, C., & Li, M. (2014). Fluoride removal on Fe-Al-impregnated granular ceramic adsorbent from aqueous solution. Clean Technologies and Environmental Policy, 16(3), 609–617.CrossRefGoogle Scholar
  14. Chen, N., Zhang, Z., Fenga, C., Zhub, D., Yang, Y., & Sugiura, N. (2011). Preparation and characterization of porous granular ceramic containing dispersed aluminum and iron oxides as adsorbents for fluoride removal from aqueous solution. Journal of Hazardous Materials, 186(1), 863–868.CrossRefGoogle Scholar
  15. Cornell, R.M., Schwertmann, U.: 1996, The iron oxides, Weinheim (Germany), V C H Publishers. 573.Google Scholar
  16. Czarnowski, W., Wrzesniowska, K., & Krechniak, J. (1996). Fluoride in drinking water and human urine in Northern and Central Poland. Science of the Total Environment, 191, 177–184.CrossRefGoogle Scholar
  17. Daifullah, A., Yakout, S., & Elreefy, S. (2007). Adsorption of fluoride in aqueous solutions using KMnO4-modified activated carbon derived from steam pyrolysis of rice straw. Journal of Hazardous Materials, 147(1-2), 633–643.CrossRefGoogle Scholar
  18. Dissanayake, C. B. (1991). The fluoride problem in the groundwater of Sri Lanka—environmental management and health. International Journal of Environmental Studies, 19, 195–203.CrossRefGoogle Scholar
  19. Dutta, R. K., Saikia, G., Das, B., Bezboruah, C., Das, H. B., & Dube, S. N. (2006). Fluoride contamination in ground water of Central Assam, India. Asian Journal of Water Environment and Pollution, 2(3), 93–100.Google Scholar
  20. Edwards, M., & Benjamin, M. M. (1989). Adsorptive filtration using coated sand: a new approach for treatment of metal bearing wastes. Journal - Water Pollution Control Federation, 61(9), 1523–1533.Google Scholar
  21. Elazhar, E., Tahaikt, M., Zouahri, A., Taky, M., Hafsi, M., & Elmidaoui, A. (2013). Defluoridation of Moroccan groundwater by nanofiltration and electrodialysis: performances and cost comparison. World Applied Sciences Journal, 22(6), 844–850.Google Scholar
  22. Erdem, E., Karapinar, N., & Donat, R. (2004). The removal of heavy metal cations by natural zeolites. Journal of Colloid and Interface Science, 280, 309–314.CrossRefGoogle Scholar
  23. Fan, X., Parker, D. J., & Smith, M. D. (2003). Adsorption kinetics of fluoride on low cost materials. Water Research, 37, 4929–4937.CrossRefGoogle Scholar
  24. Ford, R. G., & Bertsch, P. M. (1999). Distinguishing between surface and bulk dehydration-dehydroxylation reactions in synthetic goethites by high-resolution thermogravimetric analysis. Clays and Clay Minerals, 47(3), 32–337.CrossRefGoogle Scholar
  25. Gandhi, N., Sirisha, D., Asthana, S., Manjusha, A., 2012. Adsorption studies of fluoride on multani matti and red soil. Res. Journal of Chemical Sciences 2, 32–37.Google Scholar
  26. Gandhia, M. R., Kalaivania, G., & Meenakshia, S. (2011). Sorption of chromate and fluoride onto duolite a 171 anion exchange resin—a comparative study. Pollution, 32, 2034–2040.Google Scholar
  27. Ganvir, V., & Das, K. (2011). Removal of fluoride from drinking water using aluminum hydroxide coated rice husk ash. Journal of Hazardous Materials, 185, 1287–1294.CrossRefGoogle Scholar
  28. Geethamani, C. K., Ramesh, S. T., Gandhimathi, R., & Nidheesh. (2013). Alkali-treated fly ash for the removal of fluoride from aqueous solutions. Desalination and Water Treatment, 52(19-21), 3466–3476.CrossRefGoogle Scholar
  29. Gupta, V. K., Lmran, A., & Sain, V. K. (2007). Defluoridation of wastewaters using waste carbon slurry. Water Research, 41(15), 3307–3316.CrossRefGoogle Scholar
  30. Hameed, B. H. (2009). Removal of cationic dye from aqueous solution using jackfruit peel as non-conventional low-cost adsorbent. Journal of Hazardous Materials, 162, 344–350.CrossRefGoogle Scholar
  31. Harrison, P. T. C. (2005). Fluoride in water: a UK perspective. Journal of Fluorine Chemistry, 126, 1448–1456.CrossRefGoogle Scholar
  32. Ho, Y. S., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34(5), 451–465.CrossRefGoogle Scholar
  33. Hu, C. Y., Lo, S. L., Kuan, W. H., & Lee, Y. D. (2005). Removal of fluoride from semiconductor wastewater by electrocoagulation-flotation. Water Research, 39, 895–901.CrossRefGoogle Scholar
  34. Indian Standard Methods of Sampling and Test for Water Used in Industry: 1964, 3025.Google Scholar
  35. Indian Standard Classification and Identification of Soils for General Engineering Purposes, First revision 1970, IS 1498.Google Scholar
  36. Jagtap, S., Yenkie, M. K., Labhsetwar, N., & Rayalu, S. (2012). Fluoride in drinking water and defluoridation of water. Chemical Reviews, 112, 2454–2466.CrossRefGoogle Scholar
  37. Jiménez, L. V., Fregozo, C. S., Beltrán, M. L. M., Coronado, O. G., & Vega, M. I. P. (2011). Effects of the fluoride on the central nervous system. Neurología, 26, 297–300.CrossRefGoogle Scholar
  38. Johnson, A. C., & Bretzler, A. (2015). Eawag, geogenic contamination handbook. Addressing arsenic and fluoride in drinking water. Dubendorf, Switzerland: Swiss federal Institute of Aquatic Science and Technology (Eawag).Google Scholar
  39. Kalkan, N. A., Aksoy, S., Aksoy, E. A., & Hasirci, N. (2012). Preparation of chitosan-coated magnetite nanoparticles and application for immobilization of laccase. Journal of Applied Polymer Science, 123, 707–716.CrossRefGoogle Scholar
  40. Kamaraj, R., & Vasudevan, S. (2015a). Decontamination of selenate from aqueous solution by oxidized multi-walled carbon nanotubes. Powder Technology, 274, 268–275.CrossRefGoogle Scholar
  41. Kamaraj, R., & Vasudevan, S. (2015b). Evaluation of electrocoagulation process for the removal of strontium and cesium from aqueous solution. Chemical Engineering Research and Design, 93, 522–530.CrossRefGoogle Scholar
  42. Khal, H. E., & Batis, N. H. (2015). Effects of temperature on the preparation and characteristics of hydroxyapatite and its adsorptive properties toward lead. New Journal of Chemistry, 39, 3597–3607.CrossRefGoogle Scholar
  43. Khan, S. A., Ali, N., & Srivastava, Y. (2015). Comparative study of defluoridation from water using waste materials as adsorbents—a review. IJIET, 6, 159–164.Google Scholar
  44. Kiczka, M., Wiederhold, J. G., Frommer, J., Voegelin, A., Kraemer, S. M., Bourdon, B., & Kretzschmar, R. (2011). Iron speciation and isotope fractionation during silicate weathering and soil formation in an alpine glacier forefield chronosequence. Geochimica et Cosmochimica Acta, 75, 5559–5573.CrossRefGoogle Scholar
  45. Kosmulski, M. (2003). A literature survey of the differences between the reported isoelectric points and their discussion. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 222, 113–118.CrossRefGoogle Scholar
  46. Ku, Y., & Chiou, H. M. (2002). The adsorption of fluoride ion from aqueous solution by activated alumina. Water, Air, and Soil Pollution, 133, 349–360.CrossRefGoogle Scholar
  47. Kumar, E., Bhatnagar, A., Ji, M., Jung, W., Lee, S. H., Kim, S. J., Lee, G., Song, H., Choi, J. Y., Yang, J. S., & Jeon, B. H. (2009). Defluoridation from aqueous solutions by granular ferric hydroxide (GFH). Water Research, 43, 490–498.CrossRefGoogle Scholar
  48. Kut, K. M. K., Sarswat, A., Srivastava, A., Charles, U., Pittman Jr., C. U., & Mohan, D. (2016). A review of fluoride in african groundwater and local remediation methods. Groundwater for Sustainable Development, 2-3, 190–212.CrossRefGoogle Scholar
  49. Lagergren, S. (1898). About the theory of so called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1–39.Google Scholar
  50. Lavecchia, R., Medici, F., Piga, L., Rinaldi, G., & Zuorro, A. (2012). Fluoride removal from water by adsorption on a high alumina content bauxite. Chemical Engineering Transactions, 26, 225–230.Google Scholar
  51. Loganathan, P., Vigneswaran, S., Kandasamy, J., & Naidu, R. (2013). Defluoridation of drinking water using adsorption processes. Journal of Hazardous Materials, 248–249, 1–19.CrossRefGoogle Scholar
  52. Malay, K.D., Salim, A.J.: 2011, Comparative study of batch adsorption of fluoride using commercial and natural adsorbent, Res. Journal of Chemical Sciences 1, 68–75.Google Scholar
  53. Mandinic, Z., Curcic, M., Antonijevic, B., Lekic, C. P., & Carevic, M. (2009). Relationship between fluoride intake in Serbian children living in two areas with different natural levels of fluorides and occurrence of dental fluorosis. Food and Chemical Toxicology, 47, 1080–1084.CrossRefGoogle Scholar
  54. Meenakshi, S., Sundaram, C. S., & Sukumar, R. (2008). Enhanced fluoride sorption by mechano-chemically activated kaolinites. Journal of Hazardous Materials, 153, 164–172.CrossRefGoogle Scholar
  55. Minju, N., Swaroop, K. V., Haribabu, K., Sivasubramanian, V., & Kumar, P. S. (2013). Removal of fluoride from aqueous media by magnesium oxide-coated nanoparticles. Desalination and Water Treatment, 53(11), 2905–2914.CrossRefGoogle Scholar
  56. Mohan, D., Singh, K. P., & Singh, V. K. (2008). Wastewater treatment using low cost activated carbons derived from agricultural byproducts—a case study. Journal of Hazardous Materials, 152, 1045–1053.CrossRefGoogle Scholar
  57. Nasr, A. B., Charcosset, C., Amar, R. B., & Walha, K. (2013). Defluoridation of water by nanofiltration. Journal of Fluorine Chemistry, 150, 92–97.CrossRefGoogle Scholar
  58. Rincon-Silva, N. G., Moreno-Piraján, J. C., Giraldo, L. G.: 2015, Thermodynamic study of adsorption of phenol, 4-chlorophenol, and 4-nitrophenol on activated carbon obtained from eucalyptus seed, Journal of Chemistry. 2015, Article ID 569403,  https://doi.org/10.1155/2015/569403
  59. Rudzinski, W., & Plazinski, W. (2007). Studies of the kinetics of solute adsorption at solid/solution interfaces: on the possibility of distinguishing between the diffusional and the surface reaction kinetic models by studying the pseudo-first-order kinetics. Journal of Physical Chemistry C, 111(41), 15100–15110.CrossRefGoogle Scholar
  60. Saikia, J., Sarmah, S., Ahmed, T. H., Kalita, P. J., & Goswamee, R. L. (2017). Removal of toxic fluoride ion from water using low cost ceramic nodules prepared from some locally available raw materials of Assam. Journal of Environmental Chemical Engineering, 5, 2488–2497.CrossRefGoogle Scholar
  61. Sarmah, S., Saikia, J., Bordoloi, D., & Goswamee, R. L. (2017). Surface modification of paddy husk ash by hydroxyl-alumina coating to develop an efficient water defluoridation media and the immobilization of the sludge by lime-silica reaction. Journal of Environmental Chemical Engineering.  https://doi.org/10.1016/j.jece.2017.08.032.
  62. Sasaki, K., Fukumoto, N., Moriyama, S., Yu, Q., & Hirajima, T. (2012). Chemical regeneration of magnesium oxide used as a sorbent for fluoride. Separation and Purification Technology, 9(8), 24–30.CrossRefGoogle Scholar
  63. Singh, B., Gaur, S., & Garg, V. K. (2007). Fluoride in drinking water and human urine in Southern Haryana, India. Journal of Hazardous Materials, 144, 147–151.CrossRefGoogle Scholar
  64. Shukla S. C. (2014) Development, Safety evaluation and comparative studies of low cost adsorbent technology for arsenic removal from drinking water Ph D Thesis, Hemwati Nandan Bahuguna Garhwal University; Srinagar (Garwahl); Uttaranchal.Google Scholar
  65. Thirunavukkarasu, O. S., Viraraghavan, T., & Subramanian, K. S. (2003). Arsenic removal from drinking water using iron oxide-coated sand. Water, Air, and Soil Pollution, 142, 95–111.CrossRefGoogle Scholar
  66. Umlong, I. M., Das, B., Devi, R. R., Borah, K., Saikia, L. B., Raul, P. K., & Singh, S. B. L. (2012). Defluoridation from aqueous solution using stone dust and activated alumina at a fixed ratio. Applied Water Science, 2, 29–36.CrossRefGoogle Scholar
  67. Viswanathan, N., & Meenakshi, S. (2008). Effect of metal ion loaded in a resin towards fluoride retention. Journal of Fluorine Chemistry, 129, 645–653.CrossRefGoogle Scholar
  68. Viswanathan, N., Prabhu, S. M., & Meenakshi, S. (2013). Development of amine functionalized co-polymeric resins for selective fluoride sorption. Journal of Fluorine Chemistry, 153, 143–150.CrossRefGoogle Scholar
  69. Waghmare, S. S., & Arfin, T. (2015). Fluoride removal from water by calcium materials: a state-of-the-art review. International Journal of Innovative Research in Science, Engineering and Technology, 4(9), 2347–6710.Google Scholar
  70. Wambu, E. W., Onindo, C. O., Ambusso, W., & Muthakia, G. K. (2012). Removal of fluoride from aqueous solutions by adsorption using a siliceous mineral of a Kenyan origin. Clean Soil, Air, Water, 41(4), 340–348.CrossRefGoogle Scholar
  71. Wan, S. L., He, F., Wu, J. Y., Wan, W. B., Gu, Y. W., & Gao, B. (2016). Rapid and highly selective removal of lead from water using graphene oxide-hydrated manganese oxide nanocomposites. Journal of Hazardous Materials, 314, 32–40.CrossRefGoogle Scholar
  72. Wang, B., Zheng, B., Zhai, C., Yu, G., & Liu, X. (2004). Relationship between fluorine in drinking water and dental health of residents in some large cities in China. Environment International, 30, 1067–1073.CrossRefGoogle Scholar
  73. Wang, W. Y., Li, R. B., Tan, J. A., Luo, K. L., Yang, L. S., Li, H. R., & Li, Y. H. (2002). Adsorption and leaching of fluoride in soils of China. Fluoride, 35, 122–129.Google Scholar
  74. Weber, W. J., & Morris, J. C. (1963). Kinetics of adsorption on carbon from solutions. Journal of the Sanitary Engineering Division American Society of Civil Engineers, 89(SA2), 31.Google Scholar
  75. Yadav, A. K., Kaushik, C. P., Haritash, A. K., Kansal, A., & Rani, N. (2006). Defluoridation of groundwater using brick powder as an adsorbent. Journal of Hazardous Materials, 128, 289–293.CrossRefGoogle Scholar
  76. Ying, X., & Lisa, A. (2005). Synthesis and characterization of iron oxide-coated silica and its effect on metal adsorption. Journal of Colloid and Interface Science, 282, 11–19.CrossRefGoogle Scholar
  77. Zhang, J., Chen, N., Tang, Z., Yu, Y., Hua, Q., & Feng, C. (2015). A study of the mechanism of fluoride adsorption from aqueous solutions onto Fe-impregnated chitosan. Physical Chemistry Chemical Physics, 17, 12041–12050.CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Champa Gogoi
    • 1
    • 2
    • 3
  • Jitu Saikia
    • 1
    • 4
  • Susmita Sarmah
    • 1
    • 4
  • Dipak Sinha
    • 2
  • Rajib Lochan Goswamee
    • 1
    • 4
  1. 1.Materials Science and Technology DivisionCSIR-North East Institute of Science and TechnologyJorhatIndia
  2. 2.Department of ChemistryNagaland UniversityLumamiIndia
  3. 3.Department of ChemistryCNB CollegeBokakhatIndia
  4. 4.Academy of Scientific and Innovative ResearchCSIR-NEIST Jorhat CampusJorhatIndia

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