Abstract
In this study, the adsorption kinetic of cesium, strontium, and rubidium radionuclides was investigated using ferritin magnetic molecules. Kinetic investigation of synthetic and natural wastes was carried out and the results were compared. Pseudo first-order, pseudo second-order, Elovich, double-exponential, and intraparticle diffusion models were the kinetic models used in the fitting of experimental data. The kinetic study of synthetic waste revealed that the double-exponential model demonstrated excellent fitting. Coefficient of determination resulting from fitting of cesium, strontium, and rubidium radionuclide’s adsorption results via the double-exponential model are 0.9938, 0.9905, and 0.9863, respectively. In the experiments conducted on natural wastes, too, all of the five kinetic models were investigated. Results indicated that the double-exponential model matched greatly with the experimental data, and cesium, strontium, and rubidium radionuclide’s coefficients of determination were 0.9742, 0.9613, and 0.9442, respectively. Comparison of the results of natural and synthetic wastes showed that matching with the model and recovery of target elements were more prominent in experiments with synthetic waste (unicomponent) rather than natural waste (multicomponent).
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Abd El-Latif, M. M., & Elkady, M. F. (2011). Kinetics study and thermodynamic behavior for removing cesium, cobalt and nickel ions from aqueous solution using nano-zirconium vanadate ion exchanger. Desalination, 271, 41–54.
Anzai, K., Ban, N., Ozawa, T., & Tokonami, S. (2012). Fukushima Daiichi nuclear power plant accident: facts, environmental contamination, possible biological effects and counter measures. Journal of Clinical Biochemistry and Nutrition, 50, 2–8.
Casiday, R., & Frey, R. (2007). Iron use and storage in the body: ferritin. Department of Chemistry, Washington University, p. 1–12.
Chegrouche, S., Mellah, A., & Barkat, M. (2009). Removal of strontium from aqueous solutions by adsorption onto activated carbon: kinetic and thermodynamic studies. Desalination, 235, 306–318.
Chiron, N., Guilet, R., & Deydier, E. (2003). Adsorption of Cu (II) and Pb (II) into a grafted silica: isotherms and kinetic model. Water Research, 13, 3079–3086.
Dinesh, M., Charles, U. P. J., & Philip, H. S. (2006). Single, binary and multi-component adsorption of copper and cadmium from aqueous solutions on Kraft lignin—a biosorbent. Journal of Colloid and Interface Science, 297, 489–504.
Ding, D., Lei, Z., Yang, Y., Feng, C., & Zhang, Z. (2013a). Nickel oxide grafted andic soil for efficient cesium removal from aqueous solution: adsorption behavior and mechanisms. ACS Applied Materials and Interfaces, 5(20), 10151–10158.
Ding, D., Zhao, Y., Yang, S., Shi, W., Zhang, Z., Lei, Z., & Yang, Y. (2013b). Adsorption of cesium from aqueous solution using agricultural residue walnut shell: equilibrium, kinetic and thermodynamic modeling studies. Water Research, 47, 2563–2571.
El-Naggar, I. M., Zakaria, E. S., Ali, I. M., Khalil, M., & El-Shahat, M. F. (2012). Kinetic modeling analysis for the removal of cesium ions from aqueous solutions using polyaniline titanotungstate. Arabian Journal of Chemistry, 5, 109–119.
Faghihian, H., Moayed, M., Firooz, A., & Iravani, M. (2013a). Synthesis of a novel magnetic zeolite nanocomposite for removal of Cs+ and Sr2+ from aqueous solution: kinetic, equilibrium, and thermodynamic studies. Journal of Colloid and Interface Science, 393, 445–451.
Faghihian, H., Iravani, M., Moayed, M., & Ghannadi-Maragheh, M. (2013b). Preparation of a novel PAN–zeolite nanocomposite for removal of Cs+ and Sr2+ from aqueous solutions: kinetic, equilibrium, and thermodynamic studies. Chemical Engineering Journal, 222, 41–48.
Fulekar, M. H., & Gavrilescu, M. (2009). Bioremediation technology (pp. 39–43). Churchill: Springer, London.
Hassan, H. S., Attallah, M. F., & Yakout, S. M. (2010). Sorption characteristics of an economical sorbent material used for removal radioisotopes of cesium and europium. Journal of Radioanalytical and Nuclear Chemistry, 286, 17–26.
Liu, X., Chen, G. R., Lee, D. J., Kawamoto, T., Tanaka, H., Chen, M. L., & Luo, Y. K. (2014). Adsorption removal of cesium from drinking waters: a mini review on use of biosorbents and other adsorbents. Bioresource Technology, 160, 142–149.
Majidnia, Z., & Idris, A. (2015). Evaluation of cesium removal from radioactive waste water using maghemite PVA–alginate beads. Chemical Engineering Journal, 262, 372–382.
Nabavi Larimi, Y., Mallah, M. H., Moosavian, M. A., & Safdari, J. (2014). Kinetic and equilibrium study of selenium removal from wastewater in mag-molecular process. Desalination and Water Treatment, 45, 1–16.
Ofomaja, A. E., Pholosi, A., & Naidoo, E. B. (2014). Kinetics and competitive modeling of cesium biosorption onto iron (III) hexacyanoferrate modified pine cone powder. International Biodeterioration and Biodegradation, 92, 71–78.
Ofomaja, A. E., Pholosi, A., & Naidoo, E. B. (2015). Application of raw and modified pine biomass material for cesium removal from aqueous solution. Ecological Engineering, 82, 258–266.
Park, Y., Lee, Y. C., Sik Shin, W., & Sang-June, C. (2010). Removal of cobalt, strontium and cesium from radioactive laundry wastewater by ammonium molybdophosphate–polyacrylonitrile (AMP–PAN). Chemical Engineering Journal, 162, 685–695.
Qiu, H., Lv, L., Pan, B. C., Zhang, Q. J., Zhang, W. M., & Zhang, Q. X. (2009). Critical review in adsorption kinetic models. Journal of Zhejiang University. Science. A, 10(5), 716–724.
Rooygar, A. A., Mallah, M. H., Abolghasemi, H., & Safdari, J. (2014). New “magmolecular” process for the separation of antimony (III) from aqueous solution. Journal of Chemical and Engineering Data, 59(11), 3545–3554.
Tranter, T. J., Herbst, R. S., Todd, T. A., Olson, A. L., & Eldredge, H. B. (2003). Application of a second order kinetic model for the preliminary design of an adsorption bed system using ammonium molybdophosphate–polyacrylonitrile for the removal of Cs137 from acidic nuclear waste solutions. Advances in Environmental Research, 7, 913–923.
Warner, C. L., Addleman, R. S., Cinson, A. D., Droubay, T. C., Engelhard, M. H., Nash, M. A., Yantasee, W., & Warner, M. G. (2010). High-performance, superparamagnetic, nanoparticle based heavy metal sorbents for removal of contaminants from natural waters. ChemSusChem, 3, 749–757.
Xiushen, Y., Zhijian, W., Haining, L., Quan, L., Binju, Q., Min, G., & Fei, G. (2009). Rubidium and cesium ion adsorption by an ammonium molybdophosphate–calcium alginate composite adsorbent. Colloids and Surfaces, A, 342, 76–83.
Yusuf Miah, M., Volchek, K., Kuang, W., & Handan Tezel, F. (2010). Kinetic and equilibrium studies of cesium adsorption on ceiling tiles from aqueous solutions. Journal of Hazardous Materials, 183, 712–717.
Zhicheng, C., Junsheng, L., & Chengliang, H. (2015). Removal of strontium ions from aqueous solution using hybrid membranes: kinetics and thermodynamics. Chinese Journal of Chemical Engineering, 23(10), 1620–1626.
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Tangestani, F., Rashidi, A. & Mallah, MH. The Kinetic Study of Cesium, Strontium, and Rubidium Radionuclide’s Adsorption from Synthetic and Natural Wastes via the Mag-molecular Process. Water Air Soil Pollut 228, 16 (2017). https://doi.org/10.1007/s11270-016-3201-8
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DOI: https://doi.org/10.1007/s11270-016-3201-8