Abstract
In a solid waste containment facility, volatile organic contaminants (VOCs) can diffuse through the geomembrane and have a potential to pollute the underlying soil and groundwater. A compacted clay liner (CCL) is frequently adopted as a barrier to the pollution plume. In this study, a theoretical model is developed to describe the effect of trapped gas bubbles on the transport of dissolved VOCs in a saturated CCL. The present model couples the consolidation of the liner due to waste emplacement and the solute transport of the VOCs. The numerical results suggest that the gas partitioning between the aqueous phase and a trapped gas phase can greatly reduce the rates of transport of hydrophobic VOCs in the CCL. However, the mitigation effect due to un-saturation and vapor sorption for the hydrophilic VOCs is less significant, compared with the hydrophobic VOCs. The bubble wall is a promising barrier to the hydrophobic VOCs. For the hydrophilic VOCs, the effects of retardation is anticipated if the biotransformation process occurs due to presence of oxygen in occluded bubbles, which can be produced by certain agent admixture. Moreover, the influence of varying gas bubble volumes on the VOCs transit time can be negligible.
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Anderson, A., McBratney, A., & FitzPatrick, E. (1996). Soil mass, surface, and spectral fractal dimensions estimated from thin section photographs. Soil Science Society of America Journal, 60(4), 962–969.
Barry, D.A., & Sposito, G. (1988). Application of the convection–dispersion model to solute transport in finite soil columns. Soil Science Society of America Journal, 52, 3–9.
Bouhamra, W.S., Baker, C.G.J., Elkilani, A.S., Alkandari, A.A., & Al-Mansour, A.A.A. (2009). Adsorption of toluene and 1,1,1-trichloroethane on selected adsorbents under a range of ambient conditions Adsorption 15:461:C- 475.
Chen, Y.M., Xie, H.J., Ke, H., & Tang, X.W. (2006). Analytical solution of one-dimensional diffusion of volatile organic compounds (VOCS) through composite liners. Chinese Journal of Geotechnical Engineering, 28, 1076–1080.
COMSOL (2010). COMSOL Multiphysics, 3rd Edition.
Costanza, M.S., & Brusseau, M.L. (2000). Contaminant vapor adsorption at the gas-water interface in soils. Environmental Science & Technology, 34(1), 1–11.
Danckwerts, P.V. (1953). systems, Continuous flow: Distribution of residence times. Chemical Engineering Science, 2, 1–13. doi:10.1016/0009-2509(53)80001-1.
Edil, T.B., Berthouex, P.M., Park, J.K, Hargett, D.L., Sandstrom, L., & Zelmanowitz, S. (1991). Effects of volatile organic compounds on clay landfill liner performance. Waste Management and Research, 9, 171–187.
Fityus, S.G., Smith, D.W., & Booker, J.R. (1999). Contaminant transport through an unsaturated soil liner beneath a landfill. Canadian Geotechnical Journal, 36(2), 330–354.
Fredlund, D., & Rahardjo, H. (1993). Soil Mechanics for Unsaturated Soils: Wiley.
Fry, V.A., & Selker, J.S. (1997). Experimental investigations for trapping oxygen gas in saturated porous media for in situ bioremediation. Water Resource Research, 33, 2687–2696.
Fry, V.A., Istok, J.D, Semprini, L., O’Reilly, K.T., & Buscheck, T.E. (1995). Retardation of dissolved oxygen due to a trapped gas phase in porous media. Ground Water, 33(3), 391–398.
Guerrero, J., & Skaggs, T. (2010). Analytical solution for one-dimensional advection-dispersion transport equation with distance-dependent coefficients. Journal of Hydrology, 390(1-2), 57–65.
Lake, C.B., & Rowe, R.K. (2004). Volatile organic compound diffusion and sorption coefficients for a needle-punched GCL. Geosynthetics International, 11, 257–272.
Lee, J.J., Choi, J., & Park, J.W. (2002). Simultaneous sorption of lead and chlorobenzene by organobentonite. Chemosphere, 49, 1309–1315.
Li, Y.C., & Cleall, P.J. (2011). Analytical solutions for advectivedispersive solute transport in double-layered finite porous media. International Journal for Numerical and Analytical Methods in Geomechanics, 35(4), 438–460.
Marinas, M., Roy, J.W., & Smith, J.E. (2013). Changes in entrapped gas content and hydraulic conductivity with pressure. Ground Water, 51, 41–50.
McWatters, R.S., & Rowe, R.K. (2010). Diffusive transport of VOCS through LLDPE and two coextruded geomembranes. Journal of Geotechnical and Geoenviromental Engineering, 136, 1167–1177.
Park, J., & Nibras, M. (1993). Mass flux of organic chemicals through polyethylene geomembranes. Water Environment Research, 65(3), 227–237.
Peters, G.P., & Smith, D.W. (2002). Solute transport through a deforming porous medium. International Journal for Numerical and Analytical Methods in Geomechanics, 26(7), 683–717.
Petersen, L.W., Moldrup, P., El-Farhan, Y.H., Jacobsen, O.H., Yamaguchi, T., & Rolston, D.E (1995). The Effect of Moisture and Soil Texture on the Adsorption of Organic Vapors. Journal of Environmental Quality, 24(4), 752–759.
Prasad, T., Brown, K., & Thomas, J. (1994). Diffusion coefficients of organics in high density polyethylene (HDPE). Waste Management and Research, 12, 61–71.
Rowe, R.K., ASCE, M., & Booker, J.R. (1985). 1-d pollutant migration in soil of finite depth. Journal of Geotechnical Engineering, 111, 479–499.
Sangam, H.P., & Rowe, R.K. (2001). Migration of dilute aqueous organic pollutants through HDPE geomembranes. Geotextiles and Geomembranes, 19, 329–357.
Shonnard David, R., & Bell Richard, L. (1994). The effects of nonlinear sorption on the diffusion of volatile organic compounds from air-dry soils: A theoretical study. Journal of Hazardous Materials, 37(3), 397–414.
Tsai, T.L., Chang, K.C., & Huang, L.H. (2006). Body force effect on consolidation of porous elastic media due to pumping. Journal of Chinese Institute of Engineers, 29(1), 75–82.
Vanoudheusden, E., Sultan, N., & Cochonat, P. (2004). Mechanical behaviour of unsaturated marine sediments: Experimental and theoretical approaches. Marine Geology, 213, 323–342.
Wheeler, S.J. (1988). A conceptual model for soils containing large gas bubbles. Géotechnique, 38, 389–397.
Zhang, H., Jeng, D.-S., Barry, D., Seymour, B., & Li, L (2013). Solute transport in nearly saturated porous media under landfill clay liners: A finite deformation approach. Journal of Hydrology, 479, 189–199.
Zhang, H.J., Jeng, D.-S., Seymour, B.R., Barry, D.A., & Li, L. (2012). Solute transport in partially-saturated deformable porous media: Application to a landfill clay liner. Advances in Water Resources, 40, 1–10.
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Funding for this study was provided by the National Natural Science Foundation of China (Grant No. 51308259), the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Grant No. 13KJB610004), and the Foundation for Advanced Talent of Jiangsu University, PRC (Grant No. 13JDG060 and No. 14JDG023).
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Zhang, H., Jeng, DS. & Xu, H. Migration of Volatile Organic Contaminations Through a Deformable Clay Liner: Effects of Occluded Gas Bubbles. Water Air Soil Pollut 226, 152 (2015). https://doi.org/10.1007/s11270-015-2414-6
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DOI: https://doi.org/10.1007/s11270-015-2414-6