Skip to main content
Log in

Ultrafiltration Combined with Coagulation/Flocculation/Sedimentation Using Moringa oleifera as Coagulant to Treat Dairy Industry Wastewater

  • Published:
Water, Air, & Soil Pollution Aims and scope Submit manuscript

Abstract

Direct ultrafiltration and its combination with pretreatment by coagulation/flocculation/sedimentation using Moringa oleifera as coagulant to treat dairy industry wastewater were investigated. A single-channel tubular ceramic membrane with an average porosity of 0.1 μm was used at transmembrane pressures of 1, 2, and 3 bars, using the cross-flow filtration principle in a membrane filtration unit. Process efficiency was evaluated in terms of chemical oxygen demand (COD), apparent color, and turbidity removal, along with major requirements such as average permeate flux, percentage of fouling, and contribution of different resistances (resistances in series model) to the total resistance of the membrane. The highest removals for the evaluated parameters occurred in the combined coagulation/flocculation/sedimentation/ultrafiltration process. At a pressure of 2 bar, the removal of turbidity and apparent color was 99.9 % and that of COD was 98.5 %. For the combined process, the lowest percentage of fouling was 59.8 %, which occurred at 1 bar. The fraction of resistance due to fouling, which may indicate irreversible damage of the membrane, was lower in the process of coagulation/flocculation/sedimentation using M. oleifera as coagulant followed by ultrafiltration than in the process that treated dairy wastewater with direct ultrafiltration for all pressures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • APHA. (1994). Standard methods for the examination of water and wastewater. New York: American Public Health Association.

    Google Scholar 

  • Balannec, B., Gesan-Guiziou, G., Chaufer, B., Rabiller-Baudry, M., & Daufin, G. (2002). Treatment of dairy process waters by membrane operations for water reuse and milk constituents concentration. Desalination, 147, 89–94.

    Article  CAS  Google Scholar 

  • Beltrán-Heredia, J., & Sánchez-Martín, J. (2009). Removal of sodium lauryl sulphate by coagulation/flocculation with Moringa oleifera seed extract. Journal of Hazardous Materials, 164, 713–719.

    Article  Google Scholar 

  • Bergamasco, R., Bouchard, C., Silva, F. V., Reis, M. H. M., & Fagundes-Klen, M. R. (2009). An application of chitosan as a coagulant/flocculant in a microfiltration process of natural water. Desalination, 245, 205–213.

    Article  CAS  Google Scholar 

  • Bergamasco, R., Konradt-Moraes, L. C., Vieira, M. F., Fagundes-Klen, M. R., & Vieira, A. M. S. (2011). Performance of a coagulation-ultrafiltration hybrid process for water supply treatment. Chemical Engineering Journal, 166, 483–489.

    Article  CAS  Google Scholar 

  • Bhatia, S., Othman, Z., & Ahmad, A. B. (2007). Pretreatment of palm oil mill effluent (POME) using Moringa oleifera seeds as natural coagulant. Journal of Hazardous Materials, 145, 120–126.

    Article  CAS  Google Scholar 

  • Bhuptawat, H., Folkard, G. K., & Chaudhari, S. (2007). Innovative physico-chemical treatment of wastewater incorporating Moringa oleifera seed coagulant. Journal of Hazardous Materials, 142(1–2), 477–482.

    Article  CAS  Google Scholar 

  • Guo, X., Shao, H., Hu, W., Gao, W., & Chen, X. (2010). Tannin and polyacrylic acid polarity and structure influence on the performance of polyvinylchloride ultrafiltration membrane. Desalination, 250, 740–744.

    Article  CAS  Google Scholar 

  • Guo, X., Zhang, Z., Fang, L., & Su, L. (2009). Study on ultrafiltration for surface water by a polyvinylchloride hollow fiber membrane. Desalination, 238, 183–191.

    Article  CAS  Google Scholar 

  • Katayon, S., Noor, M. J. M. M., Tat, W. K., Halim, G. A., Thamer, A. M., & Badronisa, Y. (2007). Effect of natural coagulant application on microfiltration performance in treatment of secondary oxidation pond effluent. Desalination, 204, 204–212.

    Article  CAS  Google Scholar 

  • Kushwaha, J. P., Srivastava, V. C., & Mall, I. D. (2010). Treatment of dairy wastewater by commercial activated carbon and bagasse fly ash: parametric, kinetic and equilibrium modelling, disposal studies. Bioresource Technology, 101, 3474–3483.

    Article  CAS  Google Scholar 

  • László, Z., Kertész, S., Beszédes, S., Hovorka-Horváth, Z., Szabó, G., & Hodúr, C. (2009). Effect of preozonation on the filterability of model dairy waste water in nanofiltration. Desalination, 240, 170–177.

    Article  Google Scholar 

  • Lee, B.-B., Choo, K.-H., Chang, D., & Choi, S.-J. (2009). Optimizing the coagulant dose to control membrane fouling in combined coagulation/ultrafiltration systems for textile wastewater reclamation. Chemical Engineering Journal, 155, 101–107.

    Article  CAS  Google Scholar 

  • Muyibi, S. A., & Evison, L. M. (1995). Moringa oleifera seeds for softening hard water. Water Research, 29, 1099–1105.

    Article  CAS  Google Scholar 

  • Ndabigengesere, A., Narasiah, K. S., & Talbot, B. G. (1995). Active agents and mechanism of coagulation of the turbid waters using Moringa oleifera. Water Research, 29, 703–710.

    Article  CAS  Google Scholar 

  • Okuda, T., Baes, A. U., Nishijima, W., & Okada, M. (2001). Isolation and characterization of coagulant extracted from Moringa oleifera seed by salt solution. Water Research, 35, 405–410.

    Article  CAS  Google Scholar 

  • Ravazzini, A. M., van Nieuwenhuijzen, A. F., & van-der Graff, J. H. M. J. (2005). Direct ultrafiltration of municipal wastewater: comparison between filtration of raw sewage and primary clarifier effluent. Desalination, 178, 51–62.

    Article  CAS  Google Scholar 

  • Reddy, A. V. R., Trivedi, J. J., Devmurari, C. V., Mohan, D. J., Singh, P., Rao, A. P., et al. (2005). Fouling resistant membranes in desalination and water recovery. Desalination, 183, 301–306.

    Article  CAS  Google Scholar 

  • Sánchez-Sánchez, A., Garrido, J. M., & Méndez, R. (2010). A comparative study of tertiary membrane filtration of industrial wastewater treated in a granular and a flocculent sludge SBR. Desalination, 250, 810–814.

    Article  Google Scholar 

  • Sarkar, B., Chakrabarti, P. P., Vijaykumar, A., & Kale, V. (2006). Wastewater treatment in dairy industries—possibility of reuse. Desalination, 195, 141–152.

    Article  CAS  Google Scholar 

  • Sengil, I. A., & Özacar, M. (2006). Treatment of dairy wastewaters by electrocoagulation using mild steel electrodes. Journal of Hazardous Materials, 137, 1197–1205.

    Article  CAS  Google Scholar 

  • Stoller, M. (2009). On the effect of flocculation as pretreatment process and particle size distribution for membrane fouling reduction. Desalination, 240, 209–217.

    Article  CAS  Google Scholar 

  • Tchamango, S., Nanseu-Njiki, C. P., Ngameni, E., Hadjiev, D., & Darchen, A. (2010). Treatment of dairy effluents by electrocoagulation using aluminium electrodes. Science of the Total Environment, 408, 947–952.

    Article  CAS  Google Scholar 

  • Turan, M. (2004). Influence of filtration conditions on the performance of nanofiltration and reverse osmosis membranes in dairy wastewater treatment. Desalination, 170, 83–90.

    Article  CAS  Google Scholar 

  • Vieira, A. M. S., Vieira, M. F., Silva, G. F., Araújo, A. A., Fagundes-Klen, M. R., Veit, M. T., et al. (2010). Use of Moringa oleifera seed as a natural adsorbent for wastewater treatment. Water, Air, and Soil Pollution, 206, 273–281.

    Article  Google Scholar 

  • Vourch, M., Balannec, B., Chaufer, B., & Dorange, G. (2008). Treatment of dairy industry wastewater by reverse osmosis for water reuse. Desalination, 219, 190–202.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank CNPq–National Council for Scientific and Technological Development and Araucaria Foundation for Support to Scientific and Technological Development of Paraná for the financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Angélica Marquetotti Salcedo Vieira.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Formentini-Schmitt, D.M., Alves, Á.C.D., Veit, M.T. et al. Ultrafiltration Combined with Coagulation/Flocculation/Sedimentation Using Moringa oleifera as Coagulant to Treat Dairy Industry Wastewater. Water Air Soil Pollut 224, 1682 (2013). https://doi.org/10.1007/s11270-013-1682-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11270-013-1682-2

Keywords

Navigation