The presence of some anionic species, such as nitrate, nitrite, chloride, sulfide, fluoride, and cyanide, in water supplies may represent a serious environmental problem. In this work, the main sources and harmful effects of their bioaccumulation on living organisms are reviewed, as well as the most adopted technologies for their uptake. The major advantages and disadvantages of each methodology are also listed. In general, ion-exchange has been elucidated as the most suitable removal process. In view of that the most promising materials used to remove anionic pollutants from aqueous solutions are highlighted in this review. In particular, the major efforts towards the development of low-cost and easily available effective sorbents for water decontamination are covered. For instance, natural waste solid materials and derivatives have emerged as promising low-cost exchangers for selective anions uptake. Besides, a number of structural modifications including the introduction of more suitable surface functional groups or compensation species into the sorbent matrix have been investigated in order to enhance sorbents selectivity and capacity for anionic pollutants. The influence of speciation and removal conditions is also focused.
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- C :
Concentration in solution
- C 0 :
Initial concentration in solution
European Drinking Water Directive
Fe(III)-loaded ligand exchange cotton cellulose adsorbent
Granular red mud
Layered double hydroxides
Mixed metal oxide
- t :
- T :
Total anodic compartment
World Health Organization
- X :
Dimensionless concentration in solution
- Y :
Dimensionless concentration in the solid phase
Afkhami, A., Madrakian, T., & Karimi, Z. (2007). The effect of acid treatment of carbon cloth on the adsorption of nitrite and nitrate ions. Journal of Hazardous Materials, 144(1–2), 427–431.
Arora, M., Eddy, N. K., Mumford, K. A., Baba, Y., Perera, J. M., & Stevens, G. W. (2010). Surface modification of natural zeolite by chitosan and its use for nitrate removal in cold regions. Cold Regions Science and Technology, 62(2–3), 92–97.
Ateya, B. G., AlKharafi, F. M., & Al-Azab, A. S. (2003). Electrodeposition of sulfur from sulfide contaminated brines. Electrochemical and Solid-State Letters, 6(9), C137–C140.
Behnamfard, A., & Salarirad, M. M. (2009). Equilibrium and kinetic studies on free cyanide adsorption from aqueous solution by activated carbon. Journal of Hazardous Materials, 170, 127–133.
Berbar, Y., Amara, M., & Kerdjoudj, H. (2008). Anion exchange resin applied to a separation between nitrate and chloride ions in the presence of aqueous soluble polyelectrolyte. Desalination, 223, 238–242.
Bhakat, P. B., Gupta, A. K., & Ayoob, S. (2007). Feasibility analysis of As(III) removal in a continuous flow fixed bed system by modified calcined bauxite (MCB). Journal of Hazardous Materials, 139(2), 286–292.
Bhatnagar, A., Ji, M., Choi, Y. H., Jung, W., Lee, S. H., Kim, S. J., et al. (2008). Removal of nitrate from water by adsorption onto zinc chloride treated activated carbon. Separation Science and Technology, 43(4), 886–907.
Biçak, N., & Filiz Şenkal, B. (1998). Removal of nitrite ions from aqueous solutions by cross-linked polymer of ethylenediamine with epichlorohydrin. Reactive and Functional Polymers, 36(1), 71–77.
Biswas, K., Gupta, K., Goswami, A., & Ghosh, U. C. (2010). Fluoride removal efficiency from aqueous solution by synthetic iron(III)-aluminum (III)-chromium(III) ternary mixed oxide. Desalination, 255, 44–51.
Bogoczek, R., Kociolek-Balawejder, E., & Stanislawska, E. (2006). A macromolecular oxidant, the N,N-dichlorosulfonamide for removal of residual nitrites from aqueous media. Reactive and Functional Polymers, 66(6), 609–617.
Bulusu, K. R., & Nawlakhe, W. G. (1988). Defluoridation of water with activated alumina: batch operations. Indian Journal of Environmental Health, 30(3), 262–299.
Camel, V. (2003). Solid phase extraction of trace elements. Spectrochimica Acta: Part B Atomic Spectroscopy, 58(7), 1177–1233.
Carmona, M., Perez, A., de Lucas, A., Rodriguez, L., & Rodriguez, J. F. (2008). Removal of chloride ions from an industrial polyethylenimine flocculant shifting it into an adhesive promoter using the anion exchange resin Amberlite IRA-420. Reactive and Functional Polymers, 68, 1218–1224.
Chabani, M., & Bensmaili, A. (2005). Kinetic modelling of the retention of nitrates by Amberlite IRA 410. Desalination, 185(1–3), 509–515.
Chabani, M., Amrane, A., & Bensmaili, A. (2006). Kinetic modelling of the adsorption of nitrates by ion exchange resin. Chemical Engineering Journal, 125, 111–117.
Chanda, M., & Rempel, G. L. (1995). Sorption of sulfide on a macroporous, quaternized poly(4-vinyl pyridine) in alkaline medium. Reactive Polymers, 24, 203–212.
Chatterjee, S., & Woo, S. H. (2009). The removal of nitrate from aqueous solutions by chitosan hydrogel beads. Journal of Hazardous Materials, 164(2–3), 1012–1018.
Chen, G. (2004). Electrochemical technologies in wastewater treatment. Separation and Purification Technology, 38(1), 11–41.
Cheng, I. F., Muftikian, R., Fernando, Q., & Korte, N. (1997). Reduction of nitrate to ammonia by zero-valent iron. Chemosphere, 35(11), 2689–2695.
Cheng, X. W., Zhong, Y., Wang, J., Guo, J., Huang, Q., & Long, Y. C. (2005). Studies on modification and structural ultra-stabilization of natural STI zeolite. Microporous and Mesoporous Materials, 83(1–3), 233–243.
Cumbal, L., Greenleaf, J., Leun, D., & SenGupta, A. K. (2003). Polymer supported inorganic nanoparticles: characterization and environmental applications. Reactive and Functional Polymers, 54(1–3), 167–180.
Dabrowski, A., Hubicki, Z., Podkoscielny, P., & Robens, E. (2004). Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. Chemosphere, 56(2), 91–106.
Dai, X., & Breuer, P. L. (2009). Cyanide and copper cyanide recovery by activated carbon. Minerals Engineering, 22, 469–476.
Daifullah, A. A. M., Yakout, S. M., & Elreefy, S. A. (2007). Adsorption of fluoride in aqueous solutions using KMnO4-modified activated carbon derived from steam pyrolysis of rice straw. Journal of Hazardous Materials, 147, 633–643.
Das, D. P., Das, J., & Parida, K. (2003). Physicochemical characterization and adsorption behavior of calcined Zn/Al hydrotalcite-like compound (HTlc) towards removal of fluoride from aqueous solution. Journal of Colloid and Interface Science, 261(2), 213–220.
Das, N., Pattanaik, P., & Das, R. (2005). Defluoridation of drinking water using activated titanium rich bauxite. Journal of Colloid and Interface Science, 292(1), 1–10.
Dash, R. R., Gaur, A., & Balomajumder, C. (2009). Review cyanide in industrial wastewaters and its removal: a review on biotreatment. Journal of Hazardous Materials, 163, 1–11.
de Heredia, J. B., Dominguez, J. R., Cano, Y., & Jimenez, I. (2006). Nitrate removal from groundwater using Amberlite IRN-78: Modelling the system. Applied Surface Science, 252, 6031–6035.
Deganello, F., Liotta, L. F., Macaluso, A., Venezia, A. M., & Deganello, G. (2000). Catalytic reduction of nitrates and nitrites in water solution on pumice-supported Pd–Cu catalysts. Applied Catalysis B: Environmental, 24(3–4), 265–273.
DeMarco, M. J., SenGupta, A. K., & Greenleaf, J. E. (2003). Arsenic removal using a polymeric/inorganic hybrid sorbent. Water Research, 37(1), 164–176.
Deveci, H., Yazıcı, E. Y., Alp, I., & Uslu, T. (2006). Removal of cyanide from aqueous solutions by plain and metal-impregnated granular activated carbons. International Journal of Mineral Processing, 79, 198–208.
Dubey, S. K., & Holmes, D. S. (1995). Biological cyanide destruction mediated by microorganisms. World Journal of Microbiology and Biotechnology, 11(3), 257–265.
Durmaz, F., Kara, H., Cengeloglu, Y., & Ersoz, M. (2005). Fluoride removal by Donnan dialysis with anion exchange membranes. Desalination, 177(1–3), 51–57.
Dutta, P. K., Rabaey, K., Yuan, Z., & Keller, J. (2008). Spontaneous electrochemical removal of aqueous sulfide. Water Research, 42(20), 4965–4975.
Dutta, P. K., Rabaey, K., Yuan, Z., Rozendal, R. A., & Keller, J. (2010). Electrochemical sulfide removal and recovery from paper mill anaerobic treatment effluent. Water Research, 44, 2563–2571.
Erdem, M., Altundogan, H. S., & Tumen, F. (2004). Removal of hexavalent chromium by using heat-activated bauxite. Minerals Engineering, 17(9–10), 1045–1052.
Ettouney, H. M., El-Dessouky, H. T., Faibish, R. S., & Gowin, P. J. (2002). Evaluating the economics of desalination. Chemical Engineering Progress, 98(12), 32–39.
Fan, X., Parker, D. J., & Smith, M. D. (2003). Adsorption kinetics of fluoride on low cost materials. Water Research, 37, 4929–4937.
Ganczarczyk, J. J., Takoaka, P. T., & Ohashi, D. A. (1985). Application of polysulfide for pretreatment of spent cyanide liquors. Journal of the Water Pollution Control Federation, 57(11), 1089–1093.
Gao, W., Chen, J., Guan, X., Jin, R., Zhang, F., & Guan, N. (2004). Catalytic reduction of nitrite ions in drinking water over Pd–Cu/TiO2 bimetallic catalyst. Catalysis Today, 93–95, 333–339.
Gao, B.-Y., Xu, X., Wang, Y., Yue, Q.-Y., & Xu, X.-M. (2009). Preparation and characteristics of quaternary amino anion exchanger from wheat residue. Journal of Hazardous Materials, 165(1–3), 461–468.
Gärtner, R. S., & Witkamp, G. J. (2005). Regeneration of mixed solvent by ion exchange resin: selective removal of chloride and sulfate. Separation Science and Technology, 40(12), 2391–2410.
Gärtner, R. S., Wilhelm, F. G., Witkamp, G. J., & Wessling, M. (2005). Regeneration of mixed solvent by electrodialysis: selective removal of chloride and sulfate. Journal of Membrane Science, 250, 113–133.
Guan, H. D., Bestland, E., Zhu, C. Y., Zhu, H. L., Albertsdottir, D., Hutson, J., et al. (2010). Variation in performance of surfactant loading and resulting nitrate removal among four selected natural zeolites. Journal of Hazardous Materials, 183(1–3), 616–621.
Guo, Z., Zheng, Z., Gu, C., & Zheng, Y. (2008). Gamma irradiation-induced removal of low-concentration nitrite in aqueous solution. Radiation Physics and Chemistry, 77(6), 702–707.
Hichour, M., Persin, F., Sandeaux, J., & Gavach, C. (2000). Fluoride removal from waters by Donnan dialysis. Separation and Purification Technology, 18, 1–11.
Honn, K. V., & Chavin, W. (1976). Utility of ozone treatment in the maintenance of water quality in a closed marine system. Marine Biology, 34(3), 201–209.
Hradil, J., Králová, E., & Benes, M. J. (1997). Methacrylate anion exchangers with enhanced affinity for nitrates. Reactive and Functional Polymers, 33, 263–273.
Hu, H.-Y., Goto, N., & Fujie, K. (2001). Effect of ph on the reduction of nitrite in water by metallic iron. Water Research, 35(11), 2789–2793.
Islam, M., & Patel, R. (2010). Synthesis and physicochemical characterization of Zn/Al chloride layered double hydroxide and evaluation of its nitrate removal efficiency. Desalination, 256, 120–128.
Kabay, N., Arar, O., Samatya, S., Yuksel, U., & Yuksel, M. (2008). Separation of fluoride from aqueous solution by electrodialysis: effect of process parameters and other ionic species. Journal of Hazardous Materials, 153(1–2), 107–113.
Kagne, S., Jagtap, S., Dhawade, P., Kamble, S. P., Devotta, S., & Rayalu, S. S. (2008). Hydrated cement: a promising adsorbent for the removal of fluoride from aqueous solution. Journal of Hazardous Materials, 154, 88–95.
Kameda, T., Miyano, Y., Yoshioka, T., Uchida, M., & Okuwaki, A. (2000). New treatment methods for waste water containing chloride ion using magnesium-aluminum oxide. Chemistry Letters, 10, 1136–1137.
Kameda, T., Yabuuchi, F., Yoshioka, T., Uchida, M., & Okuwaki, A. (2003a). New method of treating dilute mineral acids using magnesium-aluminum oxide. Water Research, 37(7), 1545–1550.
Kameda, T., Yoshioka, T., Mitsuhashi, T., Uchida, M., & Okuwaki, A. (2003b). The simultaneous removal of calcium and chloride ions from calcium chloride solution using magnesium–aluminum oxide. Water Research, 37, 4045–4050.
Kenfield, C. F., Qin, R., Semmens, M. J., & Cussler, E. L. (1988). Cyanide recovery across hollow fiber gas membranes. Environmental Science and Technology, 22(10), 1151–1155.
Khani, A., & Mirzaei, M. (2008). Comparative study of nitrate removal from aquous solution using powder activated carbon and carbon nanotubes. Paper presented at the 2nd International IUPAC Conference in Green Chemistry.
Kim, J., & Benjamin, M. M. (2004). Modeling a novel ion exchange process for arsenic and nitrate removal. Water Research, 38, 2053–2062.
Kim, Y., Kim, C., Choi, I., Rengaraj, S., & Yi, J. (2004). Arsenic removal using mesoporous alumina prepared via a templating method. Environmental Science and Technology, 38(3), 924–931.
Krüner, G., & Rosenthal, H. (1983). Efficiency of nitrification in trickling filters using different substrates. Aquacultural Engineering, 2(1), 49–67.
Lahnid, S., Tahaikt, M., Elaroui, K., Idrissi, I., Hafsi, M., Laaziz, I., et al. (2008). Economic evaluation of fluoride removal by electrodialysis. Desalination, 230(1–3), 213–219.
Lehman, S. G., Badruzzaman, M., Adham, S., Roberts, D., & Clifford, D. A. (2008). Perchlorate and nitrate treatment by ion exchange integrated with biological brine treatment. Water Research, 42, 969–976.
Li, J., Qiu, J., Sun, Y. J., & Long, Y. C. (2000). Studies on natural STI zeolite: modification, structure, adsorption and catalysis. Microporous and Mesoporous Materials, 37(3), 365–378.
Lin, S. H., & Wu, C. L. (1996). Removal of nitrogenous compounds from aqueous solution by ozonation and ion exchange. Water Research, 30(8), 1851–1857.
Lopes, C. B., Lito, P. F., Cardoso, S. P., Pereira, E., Duarte, A. C., & Silva, C. M. (2012). Metal recovery, separation and/or concentration. In S. Inamuddin & M. Luqman (Eds.), Ion-exchange technology: theory, materials and applications. Berlin: Springer.
Lüdtke, K., Peinemann, K. V., Kasche, V., & Behling, R. D. (1998). Nitrate removal of drinking water by means of catalytically active membranes. Journal of Membrane Science, 151(1), 3–11.
Lv, L., He, J., Wei, M., Evans, D. G., & Duan, X. (2006a). Factors influencing the removal of fluoride from aqueous solution by calcined Mg–Al–CO3 layered double hydroxides. Journal of Hazardous Materials B, 133, 119–128.
Lv, L., He, J., Wei, M., Evans, D. G., & Duan, X. (2006b). Uptake of chloride ion from aqueous solution by calcined layered double hydroxides: equilibrium and kinetic studies. Water Research, 40, 735–743.
Lv, L., Sun, P., Gu, Z., Du, H., Pang, X., Tao, X., et al. (2009). Removal of chloride ion from aqueous solution by ZnAl–NO3 layered double hydroxides as anion-exchanger. Journal of Hazardous Materials, 161, 1444–1449.
Ma, J., & Dasgupta, P. K. (2010). Recent developments in cyanide detection: a review. Analytica Chimica Acta, 673, 117–125.
Mandal, S., & Mayadevi, S. (2008). Cellulose supported layered double hydroxides for the adsorption of fluoride from aqueous solution. Chemosphere, 72(6), 995–998.
Meenakshi, S., & Viswanathan, N. (2007). Identification of selective ion-exchange resin for fluoride sorption. Journal of Colloid and Interface Science, 308, 438–450.
Mena-Duran, C. J., Kou, M. R. S., Lopez, T., Azamar-Barrios, J. A., Aguilar, D. H., Dominguez, M. I., et al. (2007). Nitrate removal using natural clays modified by acid thermoactivation. Applied Surface Science, 253(13), 5762–5766.
Mohapatra, M., Anand, S., Mishra, B. K., Giles, D. E., & Singh, P. (2009). Review of fluoride removal from drinking water. Journal of Environmental Management, 91(1), 67–77.
Namasivayam, C., & Sangeetha, D. (2005). Removal and recovery of nitrate from water by ZnCl2 activated carbon from coconut coir pith, an agricultural solid waste. Indian Journal of Chemical Technology, 12(5), 513–521.
Ndiayea, P. I., Moulin, P., Dominguez, L., Millet, J. C., & Charbit, F. (2005). Removal of fluoride from electronic industrial effluent by RO membrane separation. Desalination, 173(1), 25–32.
Oh, T.-K., & Chikushi, J. (2010). Fluoride adsorption on water treatment sludge processed by polyaluminium chloride. Journal of Food, Agriculture & Environment, 8(1), 358–362.
Onyango, M. S., Kojima, Y., Aoyi, O., Bernardo, E. C., & Matsuda, H. (2004). Adsorption equilibrium modeling and solution chemistry dependence of fluoride removal from water by trivalent-cation-exchanged zeolite F-9. Journal of Colloid and Interface Science, 279(2), 341–350.
Onyango, M. S., Kojima, Y., Kuchar, D., Osembo, S. O., & Matsuda, H. (2005). Diffusion kinetic modeling of fluoride removal from aqueous solution by charge-reversed zeolite particles. Journal of Chemical Engineering of Japan, 38(9), 701–710.
Onyango, M. S., Kojima, Y., Kumar, A., Kuchar, D., Kubota, M., & Matsuda, H. (2006). Uptake of fluoride by Al3 + pretreated low–silica synthetic zeolites: adsorption equilibrium and rate studies. Separation Science and Technology, 41(4), 683–704.
Orlando, U. S., Baes, A. U., Nishijima, W., & Okada, M. (2002). A new procedure to produce lignocellulosic anion exchangers from agricultural waste materials. Bioresource Technology, 83, 195–198.
Orlando, U. S., Okuda, T., Baes, A. U., Nishijima, W., & Okada, M. (2003). Chemical properties of anion-exchangers prepared from waste natural materials. Reactive and Functional Polymers, 55(3), 311–318.
Osathaphan, K., Boonpitak, T., Laopirojana, T., & Sharma, V. K. (2008). Removal of cyanide and zinc-cyanide complex by an ion-exchange process. Water, Air, and Soil Pollution, 194, 179–183.
Öztürk, N., & Köse, T. E. (2008). A kinetic study of nitrite adsorption onto sepiolite and powdered activated carbon. Desalination, 223, 174–179.
Panswad, T., & Anan, C. (1999). Impact of high chloride wastewater on an anaerobic/anoxic/aerobic process with and without inoculation of chloride acclimated seeds. Water Research, 33(5), 1165–1172.
Parrish, J. R. (1977). Macroporous resins as supports for a chelating liquid ion-exchanger in extraction chromatography. Analytical Chemistry, 49(8), 1189–1192.
Pikaar, I., Rozendal, R. A., Yuan, Z., Keller, J., & Rabaey, K. (2011a). Electrochemical sulfide oxidation from domestic wastewater using mixed metal-coated titanium electrodes. Water Research, 45(45), 5381–5388.
Pikaar, I., Rozendal, R. A., Yuan, Z., Keller, J., & Rabaey, K. (2011b). Electrochemical sulfide removal from synthetic and real domestic wastewater at high current densities. Water Research, 45, 2281–2289.
Pintar, A., & Batista, J. (2006). Improvement of an integrated ion-exchange/catalytic process for nitrate removal by introducing a two-stage denitrification step. Applied Catalysis B: Environmental, 63(1–2), 150–159.
Pintar, A., Batista, J., & Levec, J. (2001). Integrated ion exchange/catalytic process for efficient removal of nitrates from drinking water. Chemical Engineering Science, 56(4), 1551–1559.
Rabaey, K., Van de Sompel, K., Maignien, L., Boon, N., Aelterman, P., Clauwaert, P., et al. (2006). Microbial fuel cells for sulfide removal. Environmental Science and Technology, 40(17), 5218–5224.
Rajeshwar, K., Ibanez, J. G., & Swain, G. M. (1994). Electrochemistry and the environment. Journal of Applied Electrochemistry, 24(11), 1077–1091.
Reimers, C. E., Girguis, P., Stecher Iii, H. A., Tender, L. M., Ryckelynck, N., & Whaling, P. (2006). Microbial fuel cell energy from an ocean cold seep. Geobiology, 4(2), 123–136.
Rivas, B. L., & del Carmen Aguirre, M. (2007). Nitrite removal from water using water-soluble polymers in conjunction with liquid-phase polymer-based retention technique. Reactive and Functional Polymers, 67(12), 1487–1494.
Ruixia, L., Jinlong, G., & Hongxiao, T. (2002). Adsorption of fluoride, phosphate, and arsenate ions on a new type of ion exchange fiber. Journal of Colloid and Interface Science, 248, 268–274.
Samatya, S., Kabay, N., Yuksel, U., Arda, M., & Yuksel, M. (2006). Removal of nitrate from aqueous solution by nitrate selective ion exchange resins. Reactive and Functional Polymers, 66, 1206–1214.
Samatya, S., Yuksel, U., Yuksel, M., & Kabay, N. (2007). Removal of fluoride from water by metal ions (Al3+, La3+ and ZrO2+) loaded natural zeolite. Separation Science and Technology, 42(9), 2033–2047.
Samatya, S., Mizuki, H., Ito, Y., Kawakita, H., & Uezu, K. (2010). The effect of polystyrene as a porogen on the fluoride ion adsorption of Zr(IV) surface-immobilized resin. Reactive and Functional Polymers, 70(1), 63–68.
Saremi, M., & Mahallati, E. (2002). A study on chloride-induced depassivation of mild steel in simulated concrete pore solution. Cement and Concrete Research, 32, 1915–1921.
Sarkar, S., & SenGupta, A. K. (2008). A new hybrid ion exchange-nanofiltration (HIX-NF) separation process for energy-efficient desalination: process concept and laboratory evaluation. Journal of Membrane Science, 324, 76–84.
Sivasankar, V., Ramachandramoorthy, T., & Chandramohan, A. (2010). Fluoride removal from water using activated and MnO2-coated tamarind fruit (tamarindus indica) shell: batch and column studies. Journal of Hazardous Materials, 177, 719–729.
Solangi, I. B., Memon, S., & Bhanger, M. I. (2010). An excellent fluoride sorption behavior of modified amberlite resin. Journal of Hazardous Materials, 176, 186–192.
Soldatov, V. S., Sokolova, V. I., Medyak, G. V., Shunkevich, A. A., & Akulich, Z. I. (2007). Binary ion exchange equilibria in systems containing NO−, Cl− and SO2 − on fibrous anion exchangers with tetraalkylammomium groups. Reactive and Functional Polymers, 67, 1530–1539.
Spiegler, K. S., & El-Sayed, Y. M. (2001). The energetics of desalination processes. Desalination, 134(1–3), 109–128.
Strukul, G., Pinna, F., Marella, M., Meregalli, L., & Tomaselli, M. (1996). Sol–gel palladium catalysts for nitrate and nitrite removal from drinking water. Catalysis Today, 27(1–2), 209–214.
Sujana, M. G., & Anand, S. (2011). Fluoride removal studies from contaminated ground water by using bauxite. Desalination, 267(2–3).
Sun, Y. B., Fang, Q. H., Dong, J. P., Cheng, X. W., & Xu, J. Q. (2011). Removal of fluoride from drinking water by natural stilbite zeolite modified with Fe(III). Desalination, 277(1–3), 121–127.
Suzuki, T., Akizawa, Y., Ono, N., Masuda, H., Shindo, T., Nagamachi, M., et al. (1991). The transfer of mofezolac into the inflammatory site and the hypothalamus in rats. Japanese Pharmacology and Therapeutics, 19(1), 33–40.
Swain, S. K., Dey, R. K., Islam, M., Patel, R. K., Jha, U., Patnaik, T., et al. (2009). Removal of fluoride from aqueous solution using aluminum-impregnated chitosan biopolymer. Separation Science and Technology, 44, 2096–2116.
Tahaikt, M., El Habbania, R., Haddou, A. A., Acharya, I., Amora, Z., Takya, M., et al. (2007). Fluoride removal from groundwater by nanofiltration. Desalination, 212(1–3), 46–53.
Tahaikt, M., Haddou, A. A., El Habbani, R., Amor, Z., Elhannouni, F., Taky, M., et al. (2008). Comparison of the performances of three commercial membranes in fluoride removal by nanofiltration. Continuous operations. Desalination, 225(1–3), 209–219.
Tang, Y., Guan, X., Su, T., Gao, N., & Wang, J. (2009). Fluoride adsorption onto activated alumina: modeling the effects of pH and some competing ions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 337, 33–38.
Tchobanoglous, G., Burton, F. L., & Stensel, H. D. (2003). Wastewater engineering: treatment and reuse. New York: McGraw-Hill.
Tokunaga, S., Haron, M. J., Wasay, S. A., Wong, K. F., Laosangthum, K., & Uchiumi, A. (1995). Removal of fluoride ions from aqueous solutions by multivalent metal compounds. International Journal of Environmental Studies, 48(1 Sect.A), 17–28.
Tor, A., Danaoglu, N., Arslan, G., & Cengeloglu, Y. (2009). Removal of fluoride from water by using granular red mud: batch and column studies. Journal of Hazardous Materials, 164, 271–278.
Tsuji, M., & Abe, M. (1986). Possible radiochemical separations of anionic radionuclides by amorphous hydrous titanium dioxide. Journal of Radioanalytical and Nuclear Chemistry Articles, 102(2), 283–294.
Tsuji, M., & Abe, M. (1991). Selective uptake of toxic elements by an amorphous titanium dioxide ion exchanger. Journal of Radioanalytical and Nuclear Chemistry, 149(1), 109–118.
Vaiopoulou, E., Melidis, P., & Aivasidis, A. (2005). Sulfide removal in wastewater from petrochemical industries by autotrophic denitrification. Water Research, 39(17), 4101–4109.
Viswanathan, N., & Meenakshi, S. (2010). Enriched fluoride sorption using alumina/chitosan composite. Journal of Hazardous Materials, 178, 226–232.
Wajima, T., Umeta, Y., Narita, S., & Sugawara, K. (2009). Adsorption behavior of fluoride ions using a titanium hydroxide-derived adsorbent. Desalination, 249(1), 323–330.
Warshawsky, A. (1974). Polystyrene impregnated with β-diphenylglyoxime, a selective reagent for palladium. Talanta, 21(6), 624–626.
Wild, S. R., Rudd, T., & Neller, A. (1994). Fate and effects of cyanide during wastewater treatment processes. Science of the Total Environment, 156(2), 93–107.
Yang, H., & Cheng, H. (2007). Controlling nitrite level in drinking water by chlorination and chloramination. Separation and Purification Technology, 56(3), 392–396.
Zhang, Z., & Pinnavaia, T. J. (2002). Mesostructured γ-Al2O3 with a lathlike framework morphology. Journal of the American Chemical Society, 124(41), 12294–12301.
Zhang, L., De Schryver, P., De Gusseme, B., De Muynck, W., Boon, N., & Verstraete, W. (2008). Chemical and biological technologies for hydrogen sulfide emission control in sewer systems: a review. Water Research, 42(1–2), 1–12.
Zhang, J., Xie, S., & Ho, Y.-S. (2009). Removal of fluoride ions from aqueous solution using modified attapulgite as adsorbent. Journal of Hazardous Materials, 165, 218–222.
Zhao, Y., Li, X., Liu, L., & Chen, F. (2008). Fluoride removal by Fe(III)-loaded ligand exchange cotton cellulose adsorbent from drinking water. Carbohydrate Polymers, 72, 144–150.
Zhu, P., Wang, H., Sun, B., Deng, P., Hou, S., & Yu, Y. (2009). Adsorption of fluoride from aqueous solution by magnesia-amended silicon dioxide granules. Journal of Chemical Technology and Biotechnology, 84, 1449–1455.
Patrícia F. Lito wishes to thank grant provided by Fundação para a Ciência e Tecnologia (SFRH/BPD/63214/2009; Portugal). José P.S. Aniceto would like to acknowledge the funding from the European Community’s Seventh Framework Programme FP7/2007-2013 under grant agreement No. CP-IP 228589-2 AFORE. Authors thank Pest-C/CTM/LA0011/2011 for CICECO funding. The authors thank Simão P. Cardoso for figures support.
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Lito, P.F., Aniceto, J.P.S. & Silva, C.M. Removal of Anionic Pollutants from Waters and Wastewaters and Materials Perspective for Their Selective Sorption. Water Air Soil Pollut 223, 6133–6155 (2012). https://doi.org/10.1007/s11270-012-1346-7
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