Skip to main content
Log in

Photocatalytic Oxidation of Reactive Red 22 in Aqueous Solution Using La2Ti2O7 Photocatalyst

  • Published:
Water, Air, & Soil Pollution Aims and scope Submit manuscript

Abstract

This study was focused on the application of a highly doped layered perovskite, La2Ti2O7, as the photocatalyst for the photocatalytic decomposition of an azo dye, Reactive Red 22 (RR22). The temporal behavior of the photocatalytic decomposition of RR22 in aqueous solution by the UV/La2Ti2O7 with a batch photoreactor operated in a recirculation mode was studied under various operating conditions including solution pH, light intensity, and La2Ti2O7 loading. The decomposition of RR22 in aqueous solution by La2Ti2O7 photocatalytic process was found to be feasible. An empirical kinetic equation was developed for modeling the photocatalytic decomposition of RR22 in aqueous solution using UV/La2Ti2O7 photocatalytic processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Abe, R., Higashi, M., Sayama, K., Abe, Y., & Sugihara, H. (2006). Photocatalytic activity of R3MO7 and R2Ti2O7 (R = Y, Gd, La; M = Nb, Ta) for water splitting into H2 and O2. The Journal of Physical Chemistry. B, 110, 2219–2226.

    Article  CAS  Google Scholar 

  • Allen, N. S., Edge, M., Ortega, A., Liauw, C. M., Stratton, J., & McIntyre, R. B. (2006). Internal structure analysis of mica particles coated with metal oxide by transmission electron microscopy. Dyes and Pigments, 70, 192–195.

    Article  CAS  Google Scholar 

  • Chen, S., & Cao, G. (2005). Study on the photocatalytic reduction of dichromate and photocatalytic oxidation of dichlorvos. Chemosphere, 60, 1308–1315.

    Article  CAS  Google Scholar 

  • Florencio, M. H., Pires, E., Castro, A. L., Nunes, M. R., Borges, C., & Costa, F. M. (2004). Photodegradation of diquat and paraquat in aqueous solutions by titanium dioxide: evolution of degradation reactions and characterisation of intermediates. Chemosphere, 55, 345–355.

    Article  CAS  Google Scholar 

  • Fouad, O. A., Ismail, A. A., Zaki, Z. I., & Mohamed, R. M. (2006). Zinc oxide thin films prepared by thermal evaporation deposition and its photocatalytic activity. Applied Catalysis B: Environmental, 62, 144–149.

    Article  CAS  Google Scholar 

  • Gnanamani, A., Bhaskar, M., Ganga, R., Sekaran, G., & Sadulla, S. (2004). Chemical and enzymatic interactions of Direct Black 38 and Direct Brown 1 on release of carcinogenic amines. Chemosphere, 56, 833–841.

    Article  CAS  Google Scholar 

  • Hur, S. G., Kim, T. W., Hwang, S. J., & Choy, J. H. (2006). Influences of A- and B-site cations on the physicochemical properties of perovskite-structured A(In1/3Nb1/3B1/3)O3 (A = Sr, Ba; B = Sn, Pb) photocatalysts. Journal of Photochemistry and Photobiology A: Chemistry, 183, 176–181.

    Article  CAS  Google Scholar 

  • Kaneco, S., Katsumata, H., Suzuki, T., & Ohta, K. (2006). Titanium dioxide mediated photocatalytic degradation of dibutyl phthalate in aqueous solution—kinetics, mineralization and reaction mechanism. Chemical Engineering Journal, 125, 59–66.

    Article  CAS  Google Scholar 

  • Kato, H., & Kudo, A. (2003). Photocatalytic water splliting into H2 and O2 over various tantalate photocatalysts. Catalysis Today, 78, 561–569.

    Article  CAS  Google Scholar 

  • Li, G., Qu, J., Zhang, X., Liu, H., & Liu, H. (2006). Electrochemically assisted photocatalytic degradation of Orange II: influence of initial pH values. Journal of Molecular Catalysis A: Chemical, 259, 238–244.

    Article  CAS  Google Scholar 

  • Liu, C. C., Hsieh, Y. H., Lai, P. F., Li, C. H., & Kao, C. L. (2006). Photodegradation treatment of azo dye wastewater by UV/TiO2 process. Dyes and Pigments, 68, 191–195.

    Article  CAS  Google Scholar 

  • Ma, C. M., & Ku, Y. (2006). Photocatalytic oxidation of gaseous trichloroethylene by UV/TiO2 process. Reaction Kinetics and Catalysis Letters, 89, 293–301.

    Article  CAS  Google Scholar 

  • Ma, C. M., Ku, Y., Wang, W., & Jeng, F. T. (2008). A new optical fiber reactor for photocatalytic degradation of gaseous organic contaminant. Reaction Kinetics and Catalysis Letters, 94, 199–206.

    Article  CAS  Google Scholar 

  • Marugan, J., Hufschmidt, D., Sagawe, G., Selzer, V., & Bahnemann, D. (2006). Optical density and photonic efficiency of silica-supported TiO2 photocatalysts. Water Research, 40, 833–839.

    Article  CAS  Google Scholar 

  • Muruganandham, M., & Swaminathan, M. (2004). Solar photocatalytic degradation of a reactive azo dye in TiO2-suspension. Solar Energy Materials and Solar Cells, 81, 439–457.

    Article  CAS  Google Scholar 

  • Nishio, J., Tokumura, M., Znad, H. T., & Kawase, Y. (2006). Photocatalytic decolorization of azo-dye with zinc oxide powder in an external UV light irradiation slurry photoreactor. Journal of Hazardous Materials, 138, 106–115.

    Article  CAS  Google Scholar 

  • Park, H., & Choi, W. (2003). Visible light and Fe(III)-mediated degradation of Acid Orange 7 in the absence of H2O2. Journal of Photochemistry and Photobiology A: Chemistry, 159, 241–247.

    Article  CAS  Google Scholar 

  • Yeung, K. L., Yau, S. T., Maira, A. J., Coronado, J. M., Soria, J., & Yue, P. L. (2003). The influence of surface properties on the photocatalytic activity of nanostructured TiO2. Journal of Catalysis, 219, 107–116.

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This research was financially supported in part by Grant NSC-95-2221-E01-053 from National Science Council, Taiwan, Republic of China.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Young Ku.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ku, Y., Wang, LC., Ma, CM. et al. Photocatalytic Oxidation of Reactive Red 22 in Aqueous Solution Using La2Ti2O7 Photocatalyst. Water Air Soil Pollut 215, 97–103 (2011). https://doi.org/10.1007/s11270-010-0461-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11270-010-0461-6

Keyword

Navigation