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Bulk Atmospheric Deposition in the Southern Po Valley (Northern Italy)

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Abstract

A study on pH and chemical composition of precipitation was carried out in two Italian sites, one urban (site 1) and one rural (site 2), located approximately 30 km far from Bologna, during a 3-year period. No significative site variation was found. In both locations, bulk deposition pH ranged from slightly acid to slightly alkaline, despite the volume weighted mean concentration of acidic species, NO −3 and SO 2−4 (67.4 and 118.4 μeq l−1 in site 1 and 88.7 and 103.8 μeq l−1 in site 2), that were similar to those of typical acidic rainfall region. This might be ascribed to the neutralization reaction of the Ca2+, attributed to the calcareous soil and the frequent dusty air mass intrusion from the Sahara. The pair correlation matrix and the analysis of the main components suggested also ammonium and other crustal elements as neutralization agents. The depositional rate of SO 2−4 and NO −3 , chemical elements of agricultural interest, amounted to 38 and 28 and 32 and 35 kg ha−1 for site 1 and site 2, respectively. These supplies of nutrient were not negligible and had to be considered on cultivated lands. NH +4 deposition rate on site 2 was 7 kg ha−1, 23% over site 1, probably due to nitrogen fertilization in the fields around the monitoring station. In site 1, SO 2−4 presented a seasonal trend, indicating that its principal source was the residential heating. Results emphasized that the entity of the bulk deposition acidification is linked not only to the ions local emission sources (fossil fuel combustions, heating, and fertilizers) but also to the surrounding territory and the prevalent wind that transports through kilometers air masses which may contain acidic and alkaline species.

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References

  • Akkoyunlu, B. O., & Tayanç, M. (2003). Analyses of wet and bulk deposition in four different regions of Istanbul, Turkey. Atmospheric Environment, 37, 3571–3579.

    Article  CAS  Google Scholar 

  • Alastuey, A., Querol, X., Chaves, A., Ruiz, C. R., Carratala, A., & Lopez-Soler, A. (1999). Bulk deposition in a rural area located around a large coal fired power station, northeast Spain. Environmental Pollution, 106, 359–367.

    Article  CAS  Google Scholar 

  • Al-Khashman, O. A. (2005). Study of chemical composition in wet atmospheric precipitation in Eshidiya area, Jordan. Atmospheric Environment, 39, 6175–6183.

    Article  CAS  Google Scholar 

  • Al-Momani, I. F., Ataman, O. Y., Anwari, M. A., Tuncel, S., Köse, C., & Tuncel, G. (1995). Chemical composition of precipitation near an industrial area at Izmir, Tukey. Atmospheric Environment, 29, 1131–1143.

    Article  CAS  Google Scholar 

  • Avila, A., Alarcon, M., & Queralt, I. (1998). The chemical composition of dust transported in red rain—its contribution to the biogeochemical cycle of a Holm oak forest in Catalonia (Spain). Atmospheric Environment, 32, 179–191.

    Article  CAS  Google Scholar 

  • Balasubramanian, R., Victor, T., & Chun, N. (2001). Chemical and statistical analysis of precipitation in Singapore. Water, Air, and Soil Pollution, 130, 451–456.

    Article  Google Scholar 

  • Balestrini, R., Galli, L., & Tartari, G. (2000). Wet and dry atmospheric deposition at prealpine and alpine sites in northern Italy. Atmospheric Environment, 34, 1455–1470.

    Article  CAS  Google Scholar 

  • Beverland, I. J., & Crowther, J. M. (1992). On the interpretation of event and sub-event rainfall chemistry. Environmental Pollution, 75, 163–174.

    Article  CAS  Google Scholar 

  • Bo Kyoung, L., Seung, H. H., & Dong, S. L. (2000). Chemical composition of precipitation and wet deposition of major ions on the Korean peninsula. Atmospheric Environment, 34, 563–575.

    Article  Google Scholar 

  • Dinelli, G., Di Martino, E., & Vicari, A. (1998). Multi-determination of mineral ions in environmental water samples by capillary electrophoresis. Recent Research Developments in Agricultural & Food Chemistry, 2, 435–442.

    Google Scholar 

  • DiSTA Servizio Agrometeorologico Università di Bologna. (2008) http://www.dista.unibo.it/meteo/index.php.

  • Draxel, R., & Rolph, G. (2003). HYSLIP model (Hybrid Single-Particle Lagrangian Integrated Trajectory). Silver Spring: NOAA Air Resources Laboratory. http://www.arl.noaa.gov/ready/hyslpit4.html.

  • ENEL (1991). Le piogge acide. I quaderni dell’energia, 19.

  • Fenn, M. E., & Poth, M. A. (1999). Temporal and spatial trends in streamwater nitrate concentrations in the San Bernardino Mountains, southern California. Journal of Environmental Quality, 28, 822–836.

    Article  CAS  Google Scholar 

  • Fenn, M. E., Poth, M. A., & Johnson, D. W. (1996). Evidence for nitrogen saturation in the San Bernardino Mountains in southern California. Forest Ecology and Management, 82, 211–230.

    Article  Google Scholar 

  • Fenn, M. E., Haebuer, R., Tonnesen, G. S., Baron, J. S., Grossman-Clarke, S., Hope, D., et al. (2003). Nitrogen emissions, deposition and monitoring in the western United States. BioScience, 53, 391–403.

    Article  Google Scholar 

  • Flues, M., Hama, P., Lemes, M. J. L., Dantas, E. S. K., & Fornaro, A. (2002). Evaluation of the rainwater acidity of a rural region due to a coal-fired power plant in Brazil. Atmospheric Environment, 36(14), 2397–2404.

    Article  CAS  Google Scholar 

  • Francaviglia, R., Costantini, A., & Morselli, L. (1995). Long term monitoring of atmospheric depositions in a Po valley station. Evaluation of environmental effect. Chemosphere, 30(8), 1513–1525.

    Article  CAS  Google Scholar 

  • Harman, H. H. (1968). Modern factor analysis, 2nd edition (revised). Chicago: The University of Chicago Press.

    Google Scholar 

  • Hopke, P. K., Glandney, E. S., Gordon, G. E., Zoller, W. H., & Jones, A. G. (1976). The use of multivariate analysis to identify sources of selected elements in the Boston urban aerosol. Atmospheric Environment, 10, 1015–1025.

    Article  CAS  Google Scholar 

  • Huang, K., Zhuang, G., Xu, C., Wang, Y., & Tang, A. (2008). The chemistry of the severe acidic precipitation in Shanghai, China. J Atmos Res, 89(1–2), 149–160.

    Article  CAS  Google Scholar 

  • Hughes, L., Allen, J. O., Salmon, L. G., Mayo, P. R., Johnson, R. J., & Cass, G. R. (2002). Evolution of nitrogen species air pollutants along trajectories crossing the Los Angeles area. Environmental Science and Technology, 36, 3928–3935.

    Article  CAS  Google Scholar 

  • INEA (2004). L’agricoltura italiana conta (Report on Italian agriculture). Roma: Istituto Nazionale di Economia Agraria. http://www.inea.it/pubbl/itaco.cfm. Accessed Jan 2009.

  • Israelevich, P. L., Levin, Z., Joseph, J. H., & Ganor, E. (2002). Desert aereosol transport in the Mediterranean region as inferred from the TOMS aereosol index. Journal of Geophysical Research, 107(D21), 4572.

    Article  Google Scholar 

  • Kaya, G., & Tuncel, G. (1997). Trace elements and major ion composition of wet and dry deposition in Ankara, Turkey. Atmospheric Environment, 31, 3958–3998.

    Article  Google Scholar 

  • Khawaja, H. A., & Husain, L. (1990). Chemical characterization of acid precipitation in Albany, New York. Atmospheric Environment, 24A, 1869–1882.

    Google Scholar 

  • Khemani, L. T. (1992). The role of alkaline particulates on pH of rain water and implications of control of acid rain. In H. W. Ellasesser (Ed.), Global 2000 revisited: mankinds impact on spaceship earth (pp. 87–123). New York: Pargon.

    Google Scholar 

  • Kulshrestha, U. C., Sarkar, A. K., Srivastava, S. S., & Parashar, D. C. (1995). Wet-only and bulk deposition studies at New Delhi (India). Water, Air, and Soil Pollution, 85, 2143–2148.

    Article  CAS  Google Scholar 

  • Lara, L. B., Artaxo, L. S., Martinelli, L. A., Victoria, R. L., Camargo, P. B., Krusche, A., et al. (2001). Chemical composition of rainwater and anthropogenic influences in the piracicaba river basin, southeast Brazil. Atmospheric Environment, 38, 4937–4945.

    Article  Google Scholar 

  • Le Bolloch, O., & Guerzoni, S. (1995). Acid and alkaline deposition in precipitation on the western coast of Sardinia, central Mediterranean (40° N, 8° E). Water, Air, and Soil Pollution, 85, 2155–2160.

    Article  Google Scholar 

  • Lee, B. K., Hong, S. H., & Lee, D. S. (2000). Chemical composition of precipitation and wet deposition of major ions on the Korean peninsula. Atmospheric Environment, 34, 563–575.

    Article  CAS  Google Scholar 

  • Loye-Pilot, M. D., Martin, J. M., & Morelli, J. (1986). Influence of Saharan dust on the rain acidity and atmospheric input to the Mediterranean. Nature, 321, 427–428.

    Article  Google Scholar 

  • Mosello, R. (1993) Rapporto sull’attività della rete RIDEP nel quinquennio 1988–1992. Documenta Istituto Italiano Idrobiologia, pp. 44–118.

  • Mosello, R., Barbieri, A., Brizzio, M. C., Calderoni, A., Marchetto, A., Passera, S., et al. (2001). Nitrogen budget of Lago Maggiore: The relative importance of atmospheric deposition and catchment sources. Journal of Limnology, 60, 27–40.

    Google Scholar 

  • Moulin, C., Lambert, C. E., Dayan, U., Masson, V., Ramonet, M., Bousquet, P., et al. (1998). Satellite climatology of African dust transport in the Mediterranean atmosphere. Journal of Geophysical Research, 103(D11), 13,138–13,144.

    Article  Google Scholar 

  • Noll, K. E., & Khalili, E. (1998). Dry deposition of sulfate associated with pollen. Atmospheric Environment, 22(3), 601–604.

    Google Scholar 

  • Pelicho, A. F., Martins, L. D., Nomi, S. N., & Solci, M. C. (2006). Integrated and sequential bulk and wet only samplings of atmospheric precipitation in Londrina, south Brazil (1998–2002). Atmospheric Environment, 40, 6827–6835.

    Article  CAS  Google Scholar 

  • Prospero, J. M., Ginoux, P., Torres, O., Nicholson, S. E., & Gill, T. E. (2002). Environmental characterization of global sources of atmospheric soil dust identified with the NINBUS 7 Total ozone mapping Spectrometer (TOMS) absorbing aerosol product. Reviews of Geophysics, 40, 1002. doi:10.1029/2000RG00095.

    Article  Google Scholar 

  • Rao, G., Momin, P., Safai, A., & Khemani, L. (1995). Rain water and through fall chemistry in the silent valley forest in the south India. Atmospheric Environment, 29, 2025–2029.

    Article  CAS  Google Scholar 

  • Sequi, P. (1991). Chimica del suolo. Bologna: Patron Ed.

    Google Scholar 

  • Tanner, P. A. (1999). Analysis of Hong Kong daily bulk and wet deposition data from 1994 to 1995. Atmospheric Environment, 33, 1757–1766.

    Article  CAS  Google Scholar 

  • Topcu, S., Incecik, S., & Atimtay, A. (2002). Chemical composition of rainwater at EMEP station in Ankara, Turkey. Atmospheric Research, 65(1–2), 77–92.

    Article  CAS  Google Scholar 

  • Tuncer, B., Bayer, B., Yesilyurt, C., & Tuncel, G. (2001). Ionic composition of precipitation at the central Anatolia, Turkey. Atmospheric Environment, 35, 5989–6002.

    Article  CAS  Google Scholar 

  • Vong, R. J., Larson, T. V., Covert, A. P., & Waggoner, A. P. (1985). Measurement and modelling of western Washington precipitation chemistry. Water, Air, and Soil Pollution, 26, 71–84.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The study was conducted thanks to the financial support of Progetto Strategico di Ateneo FINqUER and Ecosearch S.r.e.

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Authors and Affiliations

  1. Department of Agroenvironmental Science and Technology, University of Bologna, Viale Fanin 44, 40127, Bologna, Italy

    Linda Pieri, Philipp Matzneller, Nicola Gaspari, Ilaria Marotti, Giovanni Dinelli & Paola Rossi

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  1. Linda Pieri
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  2. Philipp Matzneller
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  3. Nicola Gaspari
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  4. Ilaria Marotti
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  5. Giovanni Dinelli
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Correspondence to Linda Pieri.

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Pieri, L., Matzneller, P., Gaspari, N. et al. Bulk Atmospheric Deposition in the Southern Po Valley (Northern Italy). Water Air Soil Pollut 210, 155–169 (2010). https://doi.org/10.1007/s11270-009-0238-y

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