Skip to main content

Advertisement

Log in

Origin of Gypsum-rich Coatings on Historic Buildings

  • Published:
Water, Air, and Soil Pollution Aims and scope Submit manuscript

Abstract

Gypsum-rich coatings found on buildings constructed with granitic rock ashlars have been studied, from both an urban and a rural area of the NW of Spain. Previous works have attributed gypsum to rock weathering by atmospheric pollution. Mineralogical, chemical, and physical data of coatings have allowed us to distinguish six different types of coatings formed in several ways. In most cases, they are originated by the deterioration calcium-rich plaster building materials. Sulfation of Ca-rich coatings, in situ gypsum dissolution and precipitation, and deposition of air pollution particles are the most important agents related to genesis of coatings. In fact, remains of plasters practically intact were found in some studied buildings. Also, data from coatings and rock ashlars suggest that gypsum-rich coatings are not formed by environment–rock interaction. Coatings located on different parts and façades of the buildings and submitted to different environmental conditions decay in a different way.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Aranguren Iriarte, A. (1994). Estructura y cinemática del emplazamiento de los granitoides del Domo de Lugo y del Antiforme del Ollo de Sapo. A Coruña, Spain: O Castro.

    Google Scholar 

  • Begonha, A., & Sequeira Braga, M. A. (1996). Black crusts and thin black layers in granitic monuments: their characterization and the role of air pollution. Berlin, Germany: 8th International Congress on Deterioration and Conservation of Stone, p. 371–375.

  • Blázquez, F., García-Vallès, M., Krumbein, W., Sterflinger, K., & Vendrell-Saz, M. (1997). Microstromatolitic deposits on granitic monuments: development and decay. European Journal of Mineralogy, 9, 889–901.

    Google Scholar 

  • Carballeira, A., Devesa, C., Retuerto, R., Santillán, E., & Ucieda, F. (1983). Bioclimatología de Galicia. A Coruña, Spain: Fundación Pedro Barrié de la Maza.

    Google Scholar 

  • Casal Porto, M. (1983). Estudio de la alteración del granito en los edificios de interés histórico de la provincia de La Coruña. Santiago, Spain: PhD, University of Santiago.

    Google Scholar 

  • Chavas, A., & Lefèvre, R. (1996). Origine des constituants des croûtes sulfatées des monuments de Délos (Cyclades-Grèce). Berlin, Germany: 8th International Congress on Deterioration and Conservation of Stone, p. 415–422.

  • Chavas, A., & Jeannette, D. (2001). Weathering of marbles and granites in marine environment: petrophysical properties and special role of atmospheric salts. Environmental Geology, 40, 359–368. doi:10.1007/s002540000157.

    Article  Google Scholar 

  • Cultrone, G., De la Torre, M., Sebastian, J. E. M., & Cazalla, O. (2000). Behavior of brick samples in aggressive environments. Water, Air, and Soil Pollution, 119, 191–207. doi:10.1023/A:1005142612180.

    Article  CAS  Google Scholar 

  • De Vedia y Gossens, E. (1845). Historia y descripción de la ciudad de La Coruña. A Coruña, Spain: Imprenta Domingo Puga.

    Google Scholar 

  • Del Monte, M., & Sabbioni, C. (1984). Gypsum crusts and fly ash particles on carbonate outcrops, Archives for Meteorology. Geophysics and Bioclimatology Series B, 35, 105–111. doi:10.1007/BF02269413.

    Article  Google Scholar 

  • Dorn, R. I. (1998). Rock coatings. Amsterdam: Elsevier.

    Google Scholar 

  • MAGNA (1994). Mapa Geológico de España E 1:50000 La Coruña, 187. Madrid: IGME.

    Google Scholar 

  • Moreda-Piñeiro, J., Moscoso-Pérez, C., Piñeiro-Iglesias, M., López-Mahía, P., Muniategui-Lorenzo, S., Fernández-Fernández, E., et al. (2007). Aqueous and acidified slurry sampling approaches in the As, Sb and Sn determination of urban dust samples by HG-ETAAS. Atomic Spectroscopy, 28, 137–143.

    Google Scholar 

  • Pavía, S., & Caro, S. (2006). Origin of films on monumental stone. Studies in Conservation, 51, 177–188.

    Google Scholar 

  • Pye, K., & Schiavon, N. (1989). Cause of sulphate attack on concrete, render and stone indicated by sulphur isotope ratios. Nature, 342, 663–664. doi:10.1038/342663a0.

    Article  CAS  Google Scholar 

  • Sanjurjo Sánchez, J., Vidal Romaní, J. R., & Alves, C. A. S. (2004). Characterisation typology and origin of patinas in the church of Las Capuchinas, A Coruña (NW Spain) pp. 202–206. Lisbon, Portugal: 6th International Symposium on Conservation of Monuments in the Mediterranean Basin.

    Google Scholar 

  • Sanjurjo Sánchez, J., Vidal Romaní, J. R., Fernández Mosquera, D., & Alves, C. A. S. (2008). Study of origin and composition of coatings in a monument built with granitic rocks by SEM, XRD, XRF and DTA-TGA. X-Ray Spectrometry, 37, 346–354. doi:10.1002/xrs.1019.

    Article  Google Scholar 

  • Schiavon, N. (1993). Microfabrics of weathered granite in urban monuments. In M. J. Thiel (Ed.), Conservation of stone and other materials, vol I (pp. 271–278). London: E&FN Spon, Chapman & Hal.

    Google Scholar 

  • Schiavon, N., Chiavari, G., Fabbri, D., & Schiavon, G. (1994). Microscopical and chemical analysis of black patinas on granite pp. 93–99. Venice, Italy: 3rd International Symposium on Conservation of Monuments in the Mediterranean Basin.

    Google Scholar 

  • Smith, B. J., Magee, R. W., & Whalley, W. B. (1994). Breakdown patterns of quartz sandstone in a polluted urban environment, Belfast, Northern Ireland. In A. R. D. Robinson, & R. B. G. Williams (Eds.), Rock weathering and Landform evolution (pp. 131–150). Chichester, UK: Wiley.

    Google Scholar 

  • Varela Diaz, R. (2004). Contaminación atmosférica en Galiza: inventario de emissions de gases de efecto invernadoiro, gases acidificantes e dioxinas (ano 2000). A Coruña, Spain: Baía.

    Google Scholar 

  • Van Grieken, R., & Torfs, K. (1996). Atmospheric aerosols and deposition near historic buildings: chemistry, sources, interrelations and relevance. In F. Zezza (Ed.),Origin, mechanisms and effects of salts on degradation of monuments in marine and continental environments (pp. 24–35). Bari, Italy: European Commission, Research Workshop.

    Google Scholar 

Download references

Acknowledgments

The Centro de Investigação Geológica, Ordenamento e Valorização de Recursos (Universidade do Minho) receives support from Programa de Financiamento Plurianual de Unidades de Investigação of the Portuguese Fundação para a Ciência e a Tecnologia, funded by European Union FEDER and national budget of the Portuguese Republic.

Financial support is from FEDER.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. Sanjurjo Sánchez.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sanjurjo Sánchez, J., Alves, C.A.S., Vidal Romaní, J.R. et al. Origin of Gypsum-rich Coatings on Historic Buildings. Water Air Soil Pollut 204, 53–68 (2009). https://doi.org/10.1007/s11270-009-0025-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11270-009-0025-9

Keywords

Navigation