Abstract
Water pollution in response to accelerated land-use/land cover changes has drawn concerns because of public health and environmental impacts. The study was conducted to evaluate the impact of land use/land cover changes, seasonal, and location on water quality of streams within the Wheeler Lake Watershed basin in northern Alabama. Temporal water samples from 18 sheppard streams were randomly collected in 2000 and 2001, processed and analyzed for pH, and total nitrogen (TN), dissolved (Dp), particulate (Pp) and total phosphorus (Tp), dissolved oxygen (DO) and soluble lead (Pb) concentration, employing standard methods of analysis. The data were normalized and integrated into a simple index (WQCIndex) to evaluate stream water quality. Results showed that the urban proportion of the total watershed basin had increased from 2.9 to 14.7% with an associated loss of agricultural (8.9%) and wetland (4.8%) covers from 1992 to 2000. A change in land-use/land covers in association with seasonal and location variation significantly affected stream water quality. Total nitrogen concentration in stream water had a peak during the summer at 34% above the annual mean. While both Pp and Tp concentrations peaking during the summer at 24% above the annual mean and about 25% below the annual mean during spring, the DO concentrations were 46% above the annual mean during the fall and 18 to 26% below annual mean during summer. The WQCIndex had responded very seasonal and showed significant identical trends, with 21% degradation in water quality during the summer above the annual mean and improvement during the spring at 20% above the annual mean. Upstream water had a significantly greater Pp and Tp (21 to 28%) concentration than at down- and middle streams water. Location and seasonal variations had significant interactive effects on Pp, Tp and DO concentration of stream water. Total amount of seasonal rainfall significantly accounted 99.6% of the variations in WQCIndex. Increasing seasonal mean relative humidity, air and soil temperature, evaporation and solar radiation had positive relationship with the variations in WQCIndex. Among the water quality parameters, both Pp and Tp were correlated (r 2 = 0.998∗*∗) to each other, and accounted for more than 80% variability of the WQCIndex. Highly significant positive linear relationship between Pp and Tp concentration suggested that 99.8% of the P in stream water is in Pp form which probably transported with sediments in surface runoff. In other words, Pp is the main pollutant responsible for degradation of stream water quality in the Wheeler lake basin. Routine measurement of either Pp or Tp concentration could be used as sensitive and early indicator of temporal changes in stream water quality even when the other parameters changed negligibly or remain unchanged.
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References
Abelho, M.: 2001, From litterfall to breakdown in streams: A review. The Scientific World 1: 656–680.
Alabama Department of Environmental Management: 1998, ADEM's Strategy for Sampling Environmental Indicators Surface Water Quality Status.
Alabama Department of Environmental Management: 1999, Office of Water: Alabama Surface Water Quality. http://www.epa.gov/OW/resources/9698/al/html
Anderson, D. G.: 1970, Effects of Urban Development of Floods in Northern Virginia. US Geol. Sur. Water Supp. Paper 2001-C:26.
Berg, R. D. and Carter, D. L.: 1980, ‘Furrow erosion and sediment losses on irrigated cropland’, J. Soil Water Conserv. 35, 267–270.
Brett, M. T., Arhonditsis, G. B., Mueller, S. E., Hartley, D. M., Frodge, J. D. and Funke, D. E.: 2005, ‘Non-point source impacts of stream nutrient concentrations along a forest to urban gradient’, Environ. Mang. 35, 330–342.
Carpenter, S. R., Caraco, N. F., Correll, D. L., Howarth, R. W., Sharpley, A. N. and Smith, V. H.: 1998, ‘Nonpoint pollution of surface waters with phosphorus and nitrogen’, Ecological Applications 8, 559–568.
Carter, W. R.: 1961, Magnitude and frequency of floods in suburban areas. US Geol. Sur. Professional Paper 424-B: B9-11.
Chichester, F. W. 1977, ‘Effects of increased fertilizer rates on nitrogen content of runoff and percolate from monolith lysimeters’, J. Environ. Qual. 6, 211–217.
Cole, J. T., Baird, J. H., Basta, N. T., Huhnke, R. L., Storm, D. E., Johnson, G. V., Payton, M. E., Smolen, M. D., Martin, D. L. and Cole, J. C.: 1997, ‘Influence of buffers on pesticide and nutrient runoff from bermudagrass turf’, J. Environ. Qual’ 26, 1589–1598.
David, M. B. and Gentry, L. E.: 2000, ‘Anthropogenic inputs of nitrogen and phosphorus and riverine export for Illinois, USA’, Journal of Environmental Quality 29, 494–508.
Dillon, P. J. and Kirchner, W. B.: 1975, ‘The effects of geology and land use on the export of phosphorus from watersheds’, Water Res. 9(2), 135–148.
Ferber, D., Herring, H. and Mlot, C.: 2004, ‘New life on the Mississippi’, Nature Conser 54, 24–33.
Gilliam, F. S., May, J. D., Fisher, M. A. and Evans, D. K.: 1999, ‘Short-term changes in soil nutrients during wetland creation’, Wetlands Ecology and Management 6, 203–208.
Goolsby, D. A., Battaglin, W. A., Lawrence, G. B., Artz, R. S., Aulenbach, B. T., Hooper, R. P., Keeney, D. R. and Stensland, G. J.: 1999, Flux and Sources of Nutrients in the Mississippi-Atchafalaya River Basin. Topic 3. Report of the Integrated Assessment on Hypoxia in the Gulf of Mexico. NOAA Coastal Ocean Program Decision Analysis Series No. 17. NOAA Coastal Ocean Program, Silver Spring, MD.
Gove, N. E., Edwards, R. T. and Conquest, L. L.: 2001, ‘Effects of scale on land use and water quality relationships. J. Amer’, Water Res. Asso. 37, 1721–1734.
Keeney, D. R. and DeLuca, T. H.: 1993, ‘Des Moines river nitrate in relation to watershed agricultural practices: 1945 versus 1980's’, J. Environ. Qual. 22, 267–272.
Kroening, S. E. and Fallon, J. D.: 1996, Sources and Sinks for Nitrogen and Phosphorus in Part of the Upper Mississippi River Basin, Minnesota and Wisconsin, 1991–1993 [Abstract] in Minnesota Water ‘96–Changing Patterns of Power and Responsibility: Implications for Water Policy, Fifth Biennial Conference on Water Resources in Minnesota, University of Minnesota, Water Resources Research Center, May 20–21, 1996, p. 96.
Larson, W. E. and Pierce, F.: 1996, ‘Conservation and Enhancement of Soil Quality; The Soil Quality Concept; pp. 11–34. USDA-NRCS-SQI. Lewis Publishers; Boca raton, New York.
Lazaro, R. R.: 1990, Urban Hydrology, a Multidisciplinary Perspective. Technomic Pub. Comp., Lncaster.
Moscrip, A. L. and Montgomery, D. R.: 1997, ‘Urbanization flood, frequency and salmon abundance in Puget Lowlan streams’, J. Amer. Water Res. Asso, 33, 247–260.
Murphy, J. and Riley, J.: 1962, ‘A Modified single solution method for the determination of phosphate in natural waters’, Anal. Chem. Acta. 27, 31–36.
NOAA (National Climatic Data Center), 1993–1996, Monthly Summaries of Local Climatological Data, Portland International Jetport, Portland, Maine Smith, C. L., 1997, Bluff Recession Rates and Processes at Sebago Lake, Maine. Bowdoin College Senior Thesis, Brunswick, Maine.
Pote, D. H., Daniel, T. C., Sharpley, A. N., Moore, P. A. Jr., Edwards, D. R. and Nichols, D. J.: 1996, ‘Relating extractable phosphorus to P losses in runoff’, Soil Sci. Soc. Am. J. 60, 855–859.
Power, J. F., Flowerday, A. D., Wiess, R. A. and Watts, D. G.: 1998, ‘Agricultural nitrogen management to protect water quality’, IDEA no. 4. Pp. 2–4. USDA.
Raloff, J.: 2004, ‘Dead waters’, Sceince News 165, 360–362.
Schueler, T.: 1995, Environmental Land Planning Series: Site Planning for Urban Streams Protection. Center for Watershed Protection Pub. No. 95708. Metropolitan Washington Council of Governments, Washington, DC.
Sharpley, A. N., Gburek, W. J., Folmar, G. J. and Pionke, H. B.: 1999b, ‘Sources of phosphorus exported from an agricultural watershed in Pennsylvania. Agric’, Water Manage 41, 77–89.
Sharpley, A. N. and Moyer, B.: 2000, ‘Phosphorus forms in manure and compost and their release during simulated rainfall’, J. Environ. Qual. 29, 1462–1469.
Sharpley, A. N. and Tunney, H.: 2000, ‘Phosphorus research strategies to meet agricultural and environmental challenges of the 21st century’, J. Environ. Qual. 29, 176–181.
Tang, Z., Engel, B. A., Pijanowski, B. C. and Lim, K. J.: 2005, ‘Eorecasting land use change and its environmental impact at a watershed scale’, J. Environ. Qual. 76, 35–45.
Tsegaye, T. D., Spencer, D., Golson, K., Sheppard, D., Long, S. and Abdi, I.: 2002, Monitoring water quality in Flint River and Flint Creek Watersheds. In Proceedings of the Alabama Water Resource Conference. Perdido Beach Resort, 3–6 September 2002, Orange Beach, AL.
Schindler, D. W.: 1977, ‘Evolution of phosphorus limitation in lakes’, Science, 195, 260–262.
U. S. Census: 2000, U. S. Census of population (Summary File 1).
USEPA: 1996, Environmental indicators of water quality in the United States. EPA Report 841-R-96-002. EPA, Washington, DC.
USEPA: 2001, Our built and national environments: A technical review of the interactions between land-use, transportation, and environmental quality 2001. p. 4.
USGS-NAWQA: 2000, Nutrients in the Nation's Water: The Major Influences on Nutrient Concentrations in water. Cir. 1136.
USGS-NAWQA Mobil River Basin: 2001, http://tenn.er.usgs.gov/MOBL/basin-description.html
Vos, de, J. A.: 2001, ‘Monitoring nitrate leaching from submerged drains’, J. Environ. Qual. 30, 1092–1096.
Wahl, M. H., McKellar, H. N. and Williams, T. M.: 1997, ‘Patterns of nutrient loading in forested and urbanized coastal streams’, J. Expt. Marine Biol. Ecol. 213, 111–131.
Welch, E. B.: 1992, Ecological Effects of Wastewater, 2nd ed. Chapman & Hall, London.
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Tsegaye, T., Sheppard, D., Islam, K.R. et al. Development of Chemical Index as a Measure of In-Stream Water Quality in Response to Land-Use and Land Cover Changes. Water Air Soil Pollut 174, 161–179 (2006). https://doi.org/10.1007/s11270-006-9090-5
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DOI: https://doi.org/10.1007/s11270-006-9090-5