Abstract
Subsurface contamination by nonaqueous phase liquids, such as 1,2,4-trichlorobenzene, is a widespread problem at numerous sites. In this work, the behaviour of 1,2,4-trichlorobenzene in the saturated zone was investigated using two natural porous media. To this end, cylindrical columns were packed with different materials and the initial water saturation was displaced by loading a constant level of trichlorobenzene on top of the porous bed. The experiments were carried out with different configurations to simulate natural media with several stratigraphic units. Also, the effect of pressure gradient on nonaqueous phase liquid flow was investigated. Both the pressure gradient and the configuration of the layers of porous media have shown a strong effect on water recoveries and fluxes through the column.
Similar content being viewed by others
References
Amott, E.: 1959, ‘Observations relating to the wettability of porous rock’, Trans. AIME 216, 156–162.
Black, C. A.: 1965, Methods of Soil Analysis, Part I, Agronomy, No. 9., American Society of Agronomy, Madison, Wiscosin.
Buckley, S. E. and Leverett, M. C.: 1942, ‘Mechanism of fluid displacement in sands’, Trans. AIME 146, 107–116.
Guigard, S., Stiver, W. H. and Zytner, R. G.: 1996, ‘The infiltration and movement of immiscible chemicals in unsaturated soil’, Environ. Technol. 17(10), 1123–1130.
Hofstee, C., Oostrom, M., Dane, J. H. and Walker, R. C.: 1998, ‘Infiltration and redistribution of perchloroethylene en partially saturated, stratified porous media’, J. Contam. Hydrol. 34, 293–313.
Johnson, E. F., Bossler, D. P. and Naumann, V. O.: 1959, ‘Calculation of relative permeability from displacement experiments’, Trans. AIME 216, 370–372.
Lenormand, R., Zarcone, C. and Sarr, A.: 1983, ‘Mechanisms of displacements of one fluid by another in a network of capillary ducts’, J. Fluid Mech. 16, 3365–3376.
Middeldorp, P. J. M., de Wolf, J., Zehnder, A. J. B. and Schraa, G.: 1997, ‘Enrichment and properties of a 1,2,4-Trichlorobenzene-dechlorinating methanogenic microbial consortium’, Applied and Environmental Microbiology. 63(4), 1225–1229.
Oostrom, M., Hofstee, C., Lenhard, R. J. and Wietsma, T. W.: 2003, ‘Flow behavior and residual saturation formation of liquid carbon tetrachloride in unsaturated heterogeneous porous media’, J. Contam. Hydrol. 64, 93–112.
Radojević, M. and Bashkin, V. N.: 1999, Practical Environmental Analysis, Royal Society of Chemistry. UK
Spiteri, E. J. and Juanes, R.: 2004, ‘Impact of relative permeability hysteresis on the numerical simulation of WAG injection’, SPE Annual Technical Conference and Exhibition Houston, Texas, U.S.A., September 2004, pp. 26–29.
Tang, G. and Firoozabadi, A.: 2001, ‘Effect of pressure gradient an initial water saturation on water injection in water-wet and mixed-wet fractured porous media’, SPE Reservoir Evaluation and Engineering 4(6), 516–524.
Toth, J., Bodi, T., Szucs, P. and Civan, F.: 2002, ‘Convenient formulae for determination of relative permeability from unsteady-state fluid displacements in core plugs’, J. Pet. Sci. Eng. 36, 33–44.
Toxics Release Inventory EPA Database (http://www.epa.gov/tri/index.htm)
U.S. EPA. Subsurface Contamination Reference Guide, EPA/540/2-90/011, October, 1990).
Zhou, X., Morrow, N. R. and Ma, S.: 2000, ‘Interrelationship of wettability, initial water saturation, aging time, and oil recovery by spontaneous imbibition and waterflooding’, SPE Journal 5(2) 199–207.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Díaz, J., Rendueles, M. & Díaz, M. 1,2,4-Trichlorobenzene Flow Characteristics in Saturated Homogeneous and Stratified Porous Media. Water Air Soil Pollut 177, 3–17 (2006). https://doi.org/10.1007/s11270-005-9019-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11270-005-9019-4