Abstract
Statistical analysis of data collected in field observations of river water quality in an urban area was used to recognize characteristic features of the distribution and relationships between concentrations of mineral nitrogen forms in polluted surface waters. The distribution of the relative mole fraction of nitrites in water is always unimodal, while other N forms can have bimodal distributions. Significant correlations between the concentrations of nitrites, nitrates, ammonium, and the total mineral nitrogen were found to exist in waters heavily polluted with nitrogen compounds. These correlations are interpreted based on a simple kinetic model of nitrification and denitrification processes. Denitrification processes are shown to play an important role in nitrogen balance in polluted waters. An estimate is proposed for the admissible level of river water pollution by nitrogen-containing compounds.
Similar content being viewed by others
REFERENCES
Bashkin, V.N., Agrogeokhimiya azota (Nitrogen Agrogeochemistry), Pushchino: ONTI NTsBI AN SSSR, 1987.
Garlend, Dzh.Kh.N., Nitrification in the Trent River, in Matematicheskie modeli kontrolya zagryazneniya vody (Mathematical Models of Water Quality Control), Moscow: Mir, 1981, pp. 201–228.
Dzhudi R.D. Jr., Improvement of Urban Water Quality by Controlling Nonpoint Pollution Sources in Denver, CO, in Vosstanovlenie i okhrana malykh rek. Teoriya i praktika (Rehabilitation and Protection of Small Rivers. Theory and Practice), Moscow: Agropromizdat, 1989.
Druzhinin, N.I. and Shishkin, A.I., Matematicheskoe modelirovanie i prognozirovanie zagryazneniya poverkhnostnykh vod sushi (Mathemarical Modeling and Prediction of Surface Water Pollution), Leningrad: Gidrometeoizdat, 1989.
Kurs fizicheskoi khimii (Course of Physical Chemistry) Gerasimov, Ya.I.., Ed., Moscow: Khimiya, 1973, vol. II.
Leonov, A.V. and Chicherina, O.V., Nutrient Transport into the White Sea with River Runoff, Vodn. Resur., 2004, vol. 31, no.2, pp. 170–192 [Water Resour. (Engl. Transl.), vol. 31, no. 2, pp. 152–173].
Lozanovskaya, I.N., Orlov, D.S., and Sadovnikova, L.K., Ekologiya i okhrana biosfery pri khimicheskom zagryaznenii (Ecology and Protection of the Biosphere against Chemical Pollution), Moscow: Vysshaya Shkola, 1998.
Orlov, D.S., Khimiya Pochv (Soil Chemistry), Moscow: Mosk. Gos. Univ., 1985.
Razumov, V.A. and Tyutyunova, F.I., Nitrite Contamination of the Moskva River: Causes and Effects, Vodn. Resur., 2001, vol. 28, no.3, pp. 356–366 [Water Resour. (Engl. Transl.), vol. 28, no. 2, pp. 324–334].
Rybal'skii N.G., Malyarova M.A., et al., Ekologiya i bezopasnost' (spravochnik) (Ecology and Safety (Handbook)), Rybal'skii, N.G., Ed., Moscow: VNIIPI, 1993, vol. 2.
Spozito, G., Termodinamika pochvennykh rastvorov (Thermodynamics of Soil Solutions), Leningrad: Gidrometeoizdat, 1984.
Comber, S. and Gardner, M., Chromium Redox Speciation in Natural Waters, J. Environ. Monit., 2003, vol. 5, no.3, pp. 410–413.
Hamilton, D.P. and Schladow, S.G., Prediction of Water Quality in Lakes and Reservoirs: Part I. Model Description, Ecol. Model., 1997, vol. 96, nos.1–3, pp. 91–110.
Schladow, S.G. and Hamilton, D.P., Prediction of Water Quality in Lakes and Reservoirs: Part II. Model Calibration, Sensitivity Analysis and Application, Ecol. Model., 1997, vol. 96, nos.1–3, pp. 111–123.
Author information
Authors and Affiliations
Additional information
__________
Translated from Vodnye Resursy, Vol. 32, No. 5, 2005, pp. 589–596.
Original Russian Text Copyright © 2005 by Laryushkin-Zheleznyi, Novikov.
Rights and permissions
About this article
Cite this article
Laryushkin-Zheleznyi, B.V., Novikov, A.V. On the Distribution of Mineral Nitrogen Forms in Polluted River Reaches in Urban Territories. Water Resour 32, 537–544 (2005). https://doi.org/10.1007/s11268-005-0068-2
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11268-005-0068-2