Abstract
Two water-soluble N-containing additives without sulfur and phosphorus, hexanamide with tetraethylenepentamine (EEHA) and benzotriazole amide with diethylenetriamine (BTAA), were synthesized and used as additives in the oil-in-water emulsion to investigate the effect of amino and benzotriazole ring on the tribological properties of the emulsion. The results showed that EEHA/BTAA exhibited wear resistance under all tested conditions. This may be attributed to the basic amino-functional groups in the additives which reduce the corrosive wear of the base emulsion. BTAA-emulsion showed the best friction-reducing and anti-wear performance under the 3 N loading condition, which may be attributed to its benzotriazole ring, which cannot be easily decomposed and could form self-assembled layers through π–π stacking. This π–π stacking may effectively compensate for the low chemical reactivity of the benzotriazole ring, and serve as a better protective film to exert tribological properties.
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The authors would like to thank the financial support from Shanghai University of Engineering Science and the National Natural Science Foundation of China (51965020). The authors are also grateful to the Beijing synchrotron radiation facility and Shanghai Jiao tong University for their technical support.
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Wu, Y., van der Heide, E., He, Z. et al. Explore the Tribological Effects of Two N-Containing Functional Groups on O/W Emulsion. Tribol Lett 70, 52 (2022). https://doi.org/10.1007/s11249-022-01594-3
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DOI: https://doi.org/10.1007/s11249-022-01594-3