Tip-Enhanced Raman Spectroscopy Studies on Amorphous Carbon Films and Carbon Overcoats in Commercial Hard Disk Drives
- 172 Downloads
Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy were used to investigate 20-nm-thick amorphous carbon films and 3-nm-thick carbon overcoats of commercial hard disk drives. Enhancement of the Raman signal on both samples was observed indicating the activation of surface plasmons. The largest enhancement was found for the 3-nm-thick carbon overcoat of a commercial hard disk suggesting that the chemistry of nanometer-thick carbon films can be studied using tip-enhanced Raman spectroscopy with high sensitivity and resolution.
KeywordsHard disk drives Carbon overcoats Diamond-like carbon Tip-enhanced Raman spectroscopy
Andreas Rosenkranz acknowledges the Feodor Lynen Fellowship of the Alexander von Humboldt foundation. This work was supported by the National Science Foundation (NSF) (Grants CBET-1704085, DMR-1707641, ECCS-1405234 and ECCS-1507146) and the Cymer Corporation. This work was performed in part at the San Diego Nanotechnology Infrastructure (SDNI) of UCSD, a member of the National Nanotechnology Coordinated Infrastructure, which is supported by the NSF (Grant ECCS-1542148).
- 2.Blum, C., Opilik, L., Atkin, J.M., Braun, K., Kämmer, S.B., Kravstov, V., Kumar, N., Lemeshko, S., Li, J.F., Luszcz, K., Maleki, T., Meixner, A.J., Minne, S., Raschke, M.B., Ren, B., Rogalski, J., Roy, D., Stephanidis, B., Wang, X., Zhang, D., Zhong, J.H., Zenobi, R.: Tip-enhanced Raman spectroscopy—an interlaboratory reproducibility and comparison study. J. Raman Spectrosc. 45, 22–31 (2014)CrossRefGoogle Scholar
- 8.Chen, C., Hayazawa, N., Kawata, S.: A 1.7 nm resolution chemical analysis of carbon nanotubes by tip-enhanced Raman imaging in the ambient. Nat. Commun. 4, 1–5 (2014)Google Scholar
- 21.Xu, S., Sinha, S., Rismaniyazdi, E., Wolf, C., Dorsey, P., Knigge, B.: Effect of carbon overcoat on heat-assisted magnetic recording performance. IEEE Trans. Magn. 51, 3301805 (2015)Google Scholar