Abstract
We present a methodology that allows one to identify the interfacial properties as a function of confinement. Rheology, viscosity as well as elasticity, in both directions (normal and tangential), and static and dynamic forces can be simultaneously measured in situ for the same set of surfaces/liquid as the confinement increases, from bulk (few μm) to highly confined (down to few 0.1 nm) regimes. The tribological behaviour of confined layers for steady-state and/or transient conditions can also be addressed.
Similar content being viewed by others
References
Campana, M., Teichert, A., Clarke, S., Steitz, R., Webster, J.R.P., Zarbakhsh, A.: Surfactant adsorption at the metal–oil interface. Langmuir 27(10), 6085–6090 (2011)
Campen, S., Green, J.H., Lamb, G.D., Spikes, H.A.: In situ study of model organic friction modifiers using liquid cell AFM; Saturated and mono-unsaturated carboxylic acids. Tribol. Lett. 57(2), 1–20 (2015)
Doig, M., Warrens, C.P., Camp, P.J.: Structure and friction of stearic acid and oleic acid films adsorbed on iron oxide surfaces in squalane. Langmuir 30(1), 186–195 (2014)
Tabor, D., Winterton, R.H.S.: The direct measurement of normal and retarded van der Waals Forces. Proc. R. Soc. Lond. A 312, 435–450 (1969)
Klein, J., Perahia, D., Warburg, S.: Forces between polymer-bearing surfaces undergoing shear. Nature (London) 352, 143–145 (1991)
Peachey, J., Van Alsten, J., Granick, S.: Design of an apparatus to measure the shear response of ultrathin liquid films. Rev. Sci. Instrum. 62, 463–473 (1991)
Israelachvili, J., et al.: Recent advances in the surface force apparatus (SFA) technique. Rep. Prog. Phys. 73, 036601 (2010)
Lundgren, S.M., Ruths, M., Danerlöv, K., Persson, K.: Effects of unsaturation on film structure and friction of fatty acids in a model base oil. J. Colloid Interface Sci. 326(2), 530–536 (2008)
Yamada, S., Inomata, K.A., Kobayashi, E., Tanabe, T., Kurihara, K.: Effect of a fatty acid additive on the kinetic friction and stiction of confined liquid lubricants. Tribol. Lett. 64, 23 (2016)
Mate, C.M., McClelland, G.M., Erlandsson, R., Chiang, S.: Atomic-scale friction of a tungsten tip on a graphite surface. Phys. Rev. Lett. 59, 1942–1946 (1987)
Yan, X., Perry, S., Spencer, N.D., Pasche, S., De Paul, S.M., Textor, M., Lim, M.S.: Reduction of friction at oxide interfaces upon polymer adsorption from aqueous solutions. Langmuir 20, 423–428 (2004)
Fernandez, N., Cayer-Barrioz, J., Isa, L., Spencer, N.D.: Direct, robust technique for the measurement of friction between microspheres. Langmuir 31, 8809–8817 (2015)
Tonck, A., Loubet, J.L., Georges, J.M.: French patent 87-11750 (1987)
Tonck, A.: Développement d’un appareil de mesure de forces de surface et de nanorhéologie. Ph.D. Thesis, Ecole Centrale de Lyon (1989)
Georges, J.M., Millot, S., Loubet, J.L., Tonck, A.: Drainage of thin liquid films between relatively smooth surfaces. J. Chem. Phys. 98(9), 7345–7360 (1993)
Dushkin, C.D., Kurihara, K.: A resonance shear force rheometer modelled as simple oscillating circuit. Rev. Sci. Instrum. 69, 2095–2104 (1998)
Dhinojwala, A., Granick, S.: New approaches to measure interfacial rheology of confined fluids. J. Chem. Soc. Faraday Trans. 92(4), 619–623 (1996)
Israelachvili, J.: Measurement of the viscosity of liquids in very thin films. J. Colloid Interface Sci. 110(1), 263–271 (1986)
Georges, E.: Dispersion et forces de surfaces dans les hydrocarbures. Ph.D. Thesis, Ecole Centrale de Lyon (1996)
Israelachvili, J.N.: Intermolecular and Surface Forces, 3rd edn. Elsevier, Amsterdam (2011)
Mazuyer, D., Cayer-Barrioz, J., Tonck, A., Jarnias, F.: Friction dynamics of confined weakly adhering boundary layers. Langmuir 24(8), 3857–3866 (2008)
Cayer-Barrioz, J., Mazuyer, D., Tonck, A., Yamaguchi, E.: Frictional rheology of a confined adsorbed polymer layer. Langmuir 25(18), 10802–10810 (2009)
Yoshizawa, H., Chen, Y.L., Israelachvili, J.: Fundamental mechanisms of interfacial friction. 1. Relation between adhesion and friction. J. Phys. Chem. 97, 4128–4140 (1993)
Berman, A., Drummond, C., Israelachvili, J.: Amontons’ law at the molecular level. Tribol. Lett. 4, 95–101 (1998)
Klein, J.: Shear, friction, and lubrication forces between polymer-bearing surfaces. Ann. Rev. Mater. Sci. 26, 581–612 (1996)
Lee, S., Spencer, N.D.: Achieving ultralow friction by aqueous brush-assisted lubrication. In: Erdemir, A., Martin, J.-M. (eds.) Superlubricity, pp. 365–396. Elsevier, Amsterdam (2007)
Mazuyer, D., Tonck, A., Cayer-Barrioz, J.: Friction control at the molecular level. In: Erdemir, A., Martin, J.-M. (eds.) Superlubricity, pp. 397–426. Elsevier, Amsterdam (2007)
Tonck, A., Houzé, F., Boyer, L., Loubet, J.L., Georges, J.M.: Electrical and mechanical contact between rough gold surfaces in air. J. Phys. Condens. Matter 3, 5195–5201 (1991)
Boyer, L., Houzé, F., Tonck, A., Loubet, J.L., Georges, J.M.: The influence of surface roughness on the capacitance between a sphere and a plane. J. Phys. D Appl. Phys. 27, 1504–1508 (1994)
Acknowledgements
The authors are more than grateful to Serge Zara for technical assistance in electronic and Mickaël Sylvestre for developing new acquisition and processing software, PilotX and ExploiX, under C++. Olivier Haag is also thanked for his help in developing ExploiX. The authors are indebted to Dr. J.-L. Loubet for helpful discussions. Financial support was obtained from the Institut Carnot Ingénierie@Lyon, from the Agence Nationale de la Recherche via the project Confluence ANR-13-JS09-0016-01 and from the LabEx Sise-Manutech via the project Dysco.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Crespo, A., Mazuyer, D., Morgado, N. et al. Methodology to Characterize Rheology, Surface Forces and Friction of Confined Liquids at the Molecular Scale Using the ATLAS Apparatus. Tribol Lett 65, 138 (2017). https://doi.org/10.1007/s11249-017-0921-x
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11249-017-0921-x