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Three-Body Abrasive Wear Behavior of Cementite with Different Chromium Concentrations

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Abstract

The abrasion-resistant properties of white cast iron, which is used as a wear-resistant material in many industrial applications, are affected by cementite properties. Hence, it is important to obtain an understanding of the mechanical properties and abrasive behavior of single-phase cementite. In this article, bulk cementite samples with 0, 3.01, 6.03, 8.22 and 9.76 wt% chromium were prepared using mechanical alloying and spark plasma sintering. Sample phase composition and mechanical properties were determined by X-ray diffractometry, microhardness testing and nano-indentation. When the chromium content was >6.03 wt%, bulk single-phase cementite was produced. The elastic modulus, elastic recovery and hardness increased with chromium content. When the chromium content was 9.76 wt%, the maximum microhardness was 1070.74 HV (Vickers hardness) and the maximum elastic modulus was 199.32 GPa. The cementite wear behavior was investigated using a three-body abrasive wear tester. Cementite with higher chromium content had a lower wear mass loss under a 3 kg load, which indicates that bulk cementite has an improved wear resistance. Short- and long-range plowing and chipping pits existed on the worn surface. Because a high-/low-chromium cementite composite structure was formed, this resulted in a significant decrease in worn surface roughness and chipping pit depth.

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References

  1. Moustafa, I.M., Moustafa, M.A., Nofal, A.A.: Carbide formation mechanism during solidification and annealing of 17 % Cr–ferritic steel. Mater. Lett. 42(6), 371–379 (2000)

    Article  Google Scholar 

  2. Uhlenhaut, D.I., Kradolfer, J., Püttgen, W., Löffler, J.F., Uggowitzer, P.J.: Structure and properties of a hypoeutectic chromium steel processed in the semi-solid state. Acta Mater. 54(10), 2727–2734 (2006)

    Article  Google Scholar 

  3. Wiengmoon, A., Chairuangsri, T., Brown, A., Brydson, R., Edmonds, D.V., Pearce, J.T.: Microstructural and crystallographical study of carbides in 30 wt% Cr cast irons. Acta Mater. 53(15), 4143–4154 (2005)

    Article  Google Scholar 

  4. Berns, H.: Comparison of wear resistant MMC and white cast iron. Wear 254(1), 47–54 (2003)

    Article  Google Scholar 

  5. Guo, D.Z., Wang, L.J., Li, J.Z.: Erosive wear of low chromium white cast iron. Wear 161(1), 173–178 (1993)

    Article  Google Scholar 

  6. Li, H., Burdett, C.F., Wang, Y.: Solidification characteristics of atomized white cast iron powders. Scripta Metall. Mater. 29(2), 249–254 (1993)

    Article  Google Scholar 

  7. Umemoto, M., Todaka, Y., Takahashi, T., Li, P., Tokumiya, R., Tsuchiya, K.: Characterization of bulk cementite produced by mechanical alloying and spark plasma sintering. J. Metastable Nanocryst. Mater. 15, 607–614 (2003)

    Article  Google Scholar 

  8. Andersson, J.O.: A thermodynamic evaluation of the Fe–Cr–C system. Metall. Mater. Trans. A 19(3), 627–636 (1988)

    Article  Google Scholar 

  9. Liu, Z.K., Höglund, L., Jönsson, B.: An experimental and theoretical study of cementite dissolution in an Fe–Cr–C alloy. Metall. Mater. Trans. A 22(8), 1745–1752 (1991)

    Article  Google Scholar 

  10. Benz, R.J., Elliott, F., Chipman, J.: Thermodynamics of the carbides in the system Fe–Cr–C. Metall. Mater. Trans. 5(10), 2235–2240 (1974)

    Article  Google Scholar 

  11. Zhou, C.T., Xiao, B., Feng, J., Xing, J.D., Xie, X.J., Chen, Y.H., Zhou, R.: First principles study on the elastic properties and electronic structures of (Fe, Cr)3C. Comp. Mater. Sci. 45(4), 986–992 (2009)

    Article  Google Scholar 

  12. Koo, B.W., Chang, Y.J., Hong, S.P., Kang, C.S., Jeong, S.W., Nam, W.J., Kim, Y.W.: Experimental measurement of Young’s modulus from a single crystalline cementite. Scripta Mater. 82, 25–28 (2014)

    Article  Google Scholar 

  13. Hartmann, S., Ruppersberg, H.: Thermal expansion of cementite and thermoelastic stresses in white cast iron. Mater. Sci. Eng. A 190(1), 231–239 (1995)

    Article  Google Scholar 

  14. Mizubayashi, H., Li, S.J., Yumoto, H., Shimotomai, M.: Young’s modulus of single phase cementite. Scripta Mater. 40(7), 773–777 (1999)

    Article  Google Scholar 

  15. Ledbetter, H.: Polycrystalline elastic constants of in situ cementite (Fe3C). Mater. Sci. Eng. A 527(10), 2657–2661 (2010)

    Article  Google Scholar 

  16. Nikolussi, M., Shang, S.L., Gressmann, T., Leineweber, A., Mittemeijer, E.J., Wang, Y., Liu, Z.K.: Extreme elastic anisotropy of cementite, Fe3C: first-principles calculations and experimental evidence. Scripta Mater. 59(8), 814–817 (2008)

    Article  Google Scholar 

  17. Umemoto, M., Liu, Z.G., Masuyama, K., Tsuchiya, K.: Influence of alloy additions on production and properties of bulk cementite. Scripta Mater. 45(4), 391–397 (2001)

    Article  Google Scholar 

  18. Umemoto, M., Liu, Z.G., Takaoka, H., Sawakami, M., Tsuchiya, K., Masuyama, K.: Production of bulk cementite and its characterization. Metall. Mater. Trans. A 32(8), 2127–2131 (2001)

    Article  Google Scholar 

  19. Umemoto, M., Todaka, Y., Takahashi, T., Li, P., Tokumiya, R., Tsuchiya, K.: High temperature deformation behavior of bulk cementite produced by mechanical alloying and spark plasma sintering. Mat. Sci. Eng.: A 375, 894–898 (2004)

    Article  Google Scholar 

  20. Yi, D.W., Xing, J.D., Ma, S.Q., Hang, Z.F., Li, Y.F., Chen, W., Zhang, J.J.: Investigations on microstructures and two-body abrasive wear behavior of Fe–B cast alloy. Tribol. Lett. 45(3), 427–435 (2012)

    Article  Google Scholar 

  21. American Society for Testing and Materials. ASTM E384–08: Standard test method for microindentation hardness of materials. American Society for Testing and Materials, West Conshohocken (2008)

    Google Scholar 

  22. Richardson, R.C.D.: The wear of metals by hard abrasives. Wear 10(4), 291–309 (1967)

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to appreciate the financial support for this work from the Natural Science Foundation of China (Grants No. 51371138).

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Correspondence to Baochao Zheng or Zhifu Huang.

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Zheng, B., Huang, Z., Xing, J. et al. Three-Body Abrasive Wear Behavior of Cementite with Different Chromium Concentrations. Tribol Lett 61, 13 (2016). https://doi.org/10.1007/s11249-015-0632-0

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