Abstract
Carbon fibers are widely used as reinforcements in poly-ether-ether-ketone (PEEK). In recent years, these materials have also been used for tribological applications. For further optimization of these tribo-materials, the contribution and action mechanisms of carbon fiber reinforcements to the tribological performance of PEEK composites need to be understood. Toward this goal, we have studied carbon fibers in a PEEK composite by scratching experiments using Berkovich and conical indenters and friction imaging using contact atomic force microscopy. For comparison, scratching was extended into the PEEK matrix surrounding the carbon fibers. It is found that shearing dominates the friction and wear behavior of carbon fibers alone, while both shearing and plowing contribute to the overall friction of PEEK composites. There is no local variation in friction across a carbon fiber surface. The wear reduction by carbon fibers originates from their effective load-bearing capability. For the first time, fatigue of individual carbon fibers is revealed, as well as the dependence of interfacial debonding or delamination on the contact configuration between fibers and scratching asperities.
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References
Chand, S.: Review carbon fibers for composites. J. Mater. Sci. 35(6), 1303–1313 (2000). doi:10.1023/a:1004780301489
Masuelli, M.A.: Introduction of fibre-reinforced polymers—polymers and composites: concepts, properties and processes. In: Masuelli, M. (ed.) Fiber Reinforced Polymers—The Technology Applied for Concrete Repair. (2013). doi:10.5772/54629
Giltrow, J.P., Lancaster, J.K.: Carbon-fibre reinforced polymers as self-lubricating materials. In: Proceedings of the Institution of Mechanical Engineers Conference, vol. 182, no. 14, pp. 147–157 (1967). doi:10.1243/pime_conf_1967_182_417_02
Flöck, J., Friedrich, K., Yuan, Q.: On the friction and wear behaviour of PAN- and pitch-carbon fiber reinforced PEEK composites. Wear 225–229, 304–311 (1999). doi:10.1016/S0043-1648(99)00022-8
Zhang, G., Rasheva, Z., Schlarb, A.K.: Friction and wear variations of short carbon fiber (SCF)/PTFE/graphite (10 vol%) filled PEEK: effects of fiber orientation and nominal contact pressure. Wear 268(7–8), 893–899 (2010). doi:10.1016/j.wear.2009.12.001
Schön, J.: Coefficient of friction for aluminium in contact with a carbon fiber epoxy composite. Tribol. Int. 37(5), 395–404 (2004). doi:10.1016/j.triboint.2003.11.008
Voss, H., Friedrich, K.: On the wear behaviour of short-fibre-reinforced peek composites. Wear 116(1), 1–18 (1987). doi:10.1016/0043-1648(87)90262-6
Li, J., Xia, Y.C.: The reinforcement effect of carbon fiber on the friction and wear properties of carbon fiber reinforced PA6 composites. Fibers Polym. 10(4), 519–525 (2009). doi:10.1007/s12221-009-0519-5
Zhang, X., Pei, X., Mu, B., Wang, Q.: Effect of carbon fiber surface treatments on the flexural strength and tribological properties of short carbon fiber/polyimide composites. Surf. Interface Anal. 40(5), 961–965 (2008). doi:10.1002/sia.2846
Zhang, X.R., Pei, X.Q., Wang, Q.H.: The effect of fiber oxidation on the friction and wear behaviors of short-cut carbon fiber/polyimide composites. Express Polym. Lett. 1(5), 318–325 (2007). doi:10.3144/expresspolymlett.2007.45
Han, Y., Schmitt, S., Friedrich, K.: Microfriction of various phases in a carbon fiber, polytetrafluoroethylene, graphite and polyetheretherketone composite blend as measured by atomic force microscopy. Tribol. Int. 31(12), 715–725 (1998). doi:10.1016/s0301-679x(98)00051-6
Han, Y., Schmitt, S., Friedrich, K.: Nanoscale indentation and scratch of short carbon fiber reinforced PEEK/PTFE composite blend by atomic force microscope lithography. Appl. Compos. Mater. 6(1), 1–18 (1999). doi:10.1023/a:1008812915701
Molazemhosseini, A., Tourani, H., Naimi-Jamal, M.R., Khavandi, A.: Nanoindentation and nanoscratching responses of PEEK based hybrid composites reinforced with short carbon fibers and nano-silica. Polym. Test. 32(3), 525–534 (2013). doi:10.1016/j.polymertesting.2013.02.001
Lin, L.Y., Tlatlik, H., Gralla, R., Igartua, M.A., de Baets, P., Schlarb, A.K.: Mechanical and thermal behaviours of polyetheretherketone-based multi-scale composites. J. Compos. Mater. 47(17), 2087–2096 (2013). doi:10.1177/0021998312454317
Ji, M., Wang, C., Bai, Y., Yu, M., Wang, Y.: Structural evolution of polyacrylonitrile precursor fibers during preoxidation and carbonization. Polym. Bull. 59, 527–536 (2007). doi:10.1007/s00289-007-0773-x
Savage, R.H.: Graphite lubrication. J. Appl. Phys. 19(1), 1–10 (1948)
Rowe, G.W.: Some observations on the frictional behaviour of boron nitride and of graphite. Wear 3(4), 274–285 (1960). doi:10.1016/0043-1648(60)90292-1
Pei, X.-Q., Bennewitz, R., Busse, M., Schlarb, A.K.: Effects of single asperity geometry on friction and wear of PEEK. Wear 304(1–2), 109–117 (2013). doi:10.1016/j.wear.2013.04.032
Mazeran, P.-E., Loubet, J.-L.: Normal and lateral modulation with a scanning force microscope, an analysis: implication in quantitative elastic and friction imaging. Tribol. Lett. 7(4), 199–212 (1999). doi:10.1023/a:1019142025011
Bowden, F.P., Tabor, D.: Friction, lubrication and wear: a survey of work during the last decade. Br. J. Appl. Phys. 17(12), 1521–1544 (1966)
Stuart, B.H., Briscoe, B.J.: Scratch hardness studies of poly(ether ether ketone). Polymer 37(17), 3819–3824 (1996). doi:10.1016/0032-3861(96)00212-1
Schroeder, R., Torres, F.W., Binder, C., Klein, A.N., de Mello, J.D.B.: Failure mode in sliding wear of PEEK based composites. Wear 301(1–2), 717–726 (2013). doi:10.1016/j.wear.2012.11.055
Zhang, J.G., Cai, C.L.: Friction and wear properties of carbon fiber reinforced PEEK composites under water lubrication. Appl. Mech. Mater. 66–68, 1051–1054 (2011)
Elliott, D.M., Fisher, J., Clark, D.T.: Effect of counterface surface roughness and its evolution on the wear and friction of PEEK and PEEK-bonded carbon fibre composites on stainless steel. Wear 217(2), 288–296 (1998). doi:10.1016/S0043-1648(98)00148-3
Srinivasa, V., Shivakumar, V., Nayaka, V., Jagadeeshaiaih, S., Seethram, M., Shenoy, R., Nafidi, A.: Fracture morphology of carbon fiber reinforced plastic composite laminates. Mater. Res. 13, 417–424 (2010)
Ovaert, T.C.: On the wear behavior of longitudinally (parallel) oriented unidirectional fiber-reinforced polymer composites. Tribol. Trans. 38(1), 27–34 (1995). doi:10.1080/10402009508983376
Ovaert, T.C.: Wear of unidirectional polymer matrix composites with fiber orientation in the plane of contact. Tribol. Trans. 40(2), 227–234 (1997). doi:10.1080/10402009708983649
Zhang, H., Zhang, Z., Friedrich, K.: Effect of fiber length on the wear resistance of short carbon fiber reinforced epoxy composites. Compos. Sci. Technol. 67(2), 222–230 (2007). doi:10.1016/j.compscitech.2006.08.001
Acknowledgments
The authors would like to acknowledge the financial support for the FundTribo project from the German Research Foundation (DFG, SCHL280/12-1). The authors thank E. Arzt for the continuous support of this project. The authors are also grateful to Karl-Peter Schmitt, Birgit Heiland, and Marco Zeiger (INM) for their kind help in scratching tests, SEM observation, and Raman characterization.
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Pei, XQ., Bennewitz, R. & Schlarb, A.K. Mechanisms of Friction and Wear Reduction by Carbon Fiber Reinforcement of PEEK. Tribol Lett 58, 42 (2015). https://doi.org/10.1007/s11249-015-0520-7
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DOI: https://doi.org/10.1007/s11249-015-0520-7