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Effects of Deposition Conditions and Counter Bodies on the Tribological Properties of Pulsed DC Magnetron Sputtered TiN–MoS x Composite Coating

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Abstract

In the current study, TiN–MoS x composite coatings were deposited by co-sputtering of MoS2 and Ti targets under a mixture of Ar and N2 gas environment using pulsed DC closed-field unbalanced magnetron sputtering. The tribological response of TiN–MoS x composite coatings was studied against two different counter bodies: cemented carbide (WC–6% Co) ball and pin made of aluminium alloy (AlSiMg). First, the effect of substrate bias was studied on tribological properties using cemented carbide ball. Lowest coefficient of friction in the range of 0.03–0.04 was obtained for the specimen deposited at a substrate bias of −60 V. Wear coefficient was also found to be minimum for the same specimen. Coatings were further deposited at an optimum bias of −60 V in order to vary MoS x content of TiN–MoS x composite coating. Effect of variation of chemical composition of the coating was then studied on tribological performance of the coating against aluminium alloy counterface. Excellent anti-sticking property of MoS x was found to have enabled the TiN–MoS x composite coating to achieve considerably low coefficient of friction against aluminium alloy. It was shown that with optimum MoS x content of TiN–MoS x composite coating, it was possible to attain as low coefficient of friction as 0.09 against aluminium alloy even under normal atmospheric condition.

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References

  1. Erdemir, A.: Solid lubricants and self lubricating films. In: Bhushan, B. (ed.) Modern Tribology Handbook, vol. II, p. 787. CRC Press, Boca Raton, FL (2001)

  2. Teer, D.G.: New solid lubricant coatings. Wear 251, 1068–1074 (2001)

    Article  Google Scholar 

  3. Donnet, C., Erdemir, A.: Solid lubricant coatings: recent developments and future trends. Tribol. Lett. 17(3), 389–397 (2004)

    Article  CAS  Google Scholar 

  4. Chromik, R.R., Baker, C.C., Voevodin, A.A., Wahl, K.J.: In situ tribometry of solid lubricant nanocomposite coatings. Wear 262, 1239–1252 (2007)

    Article  CAS  Google Scholar 

  5. Arslan, E., Bülbül, F., Alsaran, A., Celik, A., Efeoglu, I.: The effect of deposition parameters and Ti content on structural and wear properties of MoS2–Ti coatings. Wear 259, 814–819 (2005)

    Article  CAS  Google Scholar 

  6. Lahres, M., Müller-Hummel, P., Doerfel, O.: Applicability of different hard coatings in dry milling aluminium alloys. Surf. Coat. Technol. 91, 116–121 (1997)

    Article  CAS  Google Scholar 

  7. Renevier, N.M., Fox, V.C., Teer, D.G., Hampshire, J.: Coating characteristics and tribological properties of sputter-deposited MoS2/metal composite coatings deposited by closed field unbalanced magnetron sputter ion plating. Surf. Coat. Technol. 127, 24–37 (2000)

    Article  CAS  Google Scholar 

  8. Simmonds, M.C., Savan, A., Pflüger, E., Van Swygenhoven, H.: Mechanical and tribological performance of MoS2 co-sputtered composites. Surf. Coat. Technol. 126, 15–24 (2000)

    Article  CAS  Google Scholar 

  9. Vaz, F., Machado, P., Rebouta, L., Cerqueira, P., Goudeau, Ph., Rivière, J.P., Alves, E., Pischow, K., de Rijk, J.: Mechanical characterization of reactively magnetron-sputtered TiN films. Surf. Coat. Technol. 174–175, 375–382 (2003)

    Article  Google Scholar 

  10. Shum, P.W., Tam, W.C., Li, K.Y., Zhou, Z.F., Shen, Y.G.: Mechanical and tribological properties of titanium–aluminium–nitride films deposited by reactive close-field unbalanced magnetron sputtering. Wear 257, 1030–1040 (2004)

    Article  CAS  Google Scholar 

  11. Gilmore, R., Baker, M.A., Gibson, P.N., Gissler, W.: Preparation and characterisation of low-friction TiB2-based coatings by incorporation of C or MoS2. Surf. Coat. Technol. 105, 45–50 (1998)

    Article  CAS  Google Scholar 

  12. Goller, R., Torri, P., Baker, M.A., Gilmore, R., Gissler, W.: The deposition of low-friction TiN–MoSx hard coatings by a combined arc evaporation and magnetron sputter process. Surf. Coat. Technol. 120–121, 453–457 (1999)

    Article  Google Scholar 

  13. Cosemans, P., Zhu, X., Celis, J.P., van Stappen, M.: Development of low friction wear-resistant coatings. Surf. Coat. Technol. 174–175, 416–420 (2003)

    Article  Google Scholar 

  14. Rahman, M., Haider, J., Dowling, D.P., Duggan, P., Hashmi, M.S.J.: Deposition of magnetron sputtered TiN + MoS x coating with Ti–TiN graded interlayer. Surf. Coat. Technol. 200, 1071–1075 (2005)

    Article  CAS  Google Scholar 

  15. Kim, S.K., Cha, B.C.: Deposition of CrN–MoS2 thin films by D.C. magnetron sputtering. Surf Coat. Technol. 188–189, 174–178 (2004)

    Article  Google Scholar 

  16. Audronis, M., Leyland, A., Kelly, P.J., Matthews, A.: Composition and structure-property relationships of chromium-diboride/molybdenum-disulphide PVD nanocomposite hard coatings deposited by pulsed magnetron sputtering. Appl. Phys. A 91, 77–86 (2008)

    Article  CAS  ADS  Google Scholar 

  17. Ding, X.-z., Zeng, X.T., Goto, T.: Unbalanced magnetron sputtered Ti–Si–N: MoS x composite coatings for improvement of tribological properties. Surf. Coat. Technol. 198, 432–436 (2005)

    Article  CAS  Google Scholar 

  18. Kelly, P.J., Arnell, R.D.: Magnetron sputtering: a review of recent developments and applications. Vacuum 56, 159–172 (2000)

    Article  CAS  Google Scholar 

  19. Kelly, P.J., Beevers, C.F., Henderson, P.S., Arnell, R.D., Bradley, J.W., Backer, H.: A comparison of the properties of titanium-based films produced by pulsed and continuous DC magnetron sputtering. Surf. Coat. Technol. 174–175, 795–800 (2003)

    Article  Google Scholar 

  20. Kelly, P.J., vom Braucke, T., Liu, Z., Arnell, R.D., Doyle, E.D.: Pulsed DC titanium nitride coatings for improved tribological performance and tool life. Surf. Coat. Technol. 202, 774–780 (2007)

    Article  CAS  Google Scholar 

  21. Gangopadhyay, S., Acharya, R., Chattopadhyay, A.K., Paul, S.: Composition and structure-property relationship of low friction, wear resistant TiN–MoS x composite coating deposited by pulsed closed-field unbalanced magnetron sputtering. Surf. Coat. Technol. 203, 1565–1572 (2009)

    Article  CAS  Google Scholar 

  22. Bülbül, F., Efeoğlu, İ., Arslan, E.: The effect of bias voltage and working pressure on S/Mo ratio at MoS2–Ti composite films. Appl. Surf. Sci. 253, 4415–4419 (2007)

    Article  ADS  Google Scholar 

  23. Gangopadhyay, S., Acharya, R., Chattopadhyay, A.K., Paul, S.: Pulsed DC unbalanced magnetron sputtering of hard solid lubricant coating for dry machining of aluminium alloy. Proceedings of the 2nd International and 23rd AIMTDR Conference, IIT Madras, Chennai, India, pp. 177–182 (2008)

  24. Lauwerens, W., Wang, J., Navratil, J., Wieërs, E., D’haen, J., Stals, L.M., Celis, J.P., Bruynseraede, Y.: Humidity resistant MoS x films prepared by pulsed magnetron sputtering. Surf. Coat. Technol. 131, 216–221 (2000)

    Article  CAS  Google Scholar 

  25. Konca, E., Cheng, Y.-T., Weiner, A.M., Dasch, J.M., Erdemir, A., Alpas, A.T.: Transfer of 319 Al alloy to titanium diboride and titanium nitride based (TiAlN, TiCN, TiN) coatings: effects of sliding speed, temperature and environment. Surf. Coat. Technol. 200, 2260–2270 (2005)

    Article  CAS  Google Scholar 

  26. Diss, P., Brendle, M.: A general approach to discontinuous transfer films: influence of sliding speed and stick–slip phenomena. Wear 203–204, 564–572 (1997)

    Article  Google Scholar 

  27. Konca, E., Cheng, Y.-T., Weiner, A.M., Dasch, J.M., Alpas, A.T.: Vacuum tribological behavior of the non-hydrogenated diamond-like carbon coatings against aluminum: effect of running-in in ambient air. Wear 259, 795–799 (2005)

    Article  CAS  Google Scholar 

  28. Donnet, C., Le Mogne, T., Ponsonnet, L., Belina, M., Grill, A., Patel, V., Jahnes, C.: The respective role of oxygen and water vapor on the tribology of hydrogenated diamond-like carbon coatings. Tribol. Lett. 4, 259–265 (1998)

    Article  CAS  Google Scholar 

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Acknowledgement

The authors gratefully acknowledge the funding support they received from DST, FIST (Sanction No. SR/FST/ET-II-003/2000 dated 20.5.2002), Ministry of Human Resource Development, Government of India (Project code: MCS, Sanction No. F.26-14/2003-TS.V dated 14-01-2004).

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Correspondence to Soumya Gangopadhyay.

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Gangopadhyay, S., Acharya, R., Chattopadhyay, A.K. et al. Effects of Deposition Conditions and Counter Bodies on the Tribological Properties of Pulsed DC Magnetron Sputtered TiN–MoS x Composite Coating. Tribol Lett 37, 487–496 (2010). https://doi.org/10.1007/s11249-009-9544-1

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  • DOI: https://doi.org/10.1007/s11249-009-9544-1

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